Patents Examined by Elizabeth A. Bolden
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Patent number: 11814315Abstract: A glass has a basic soda-lime-silica glass portion, and a colorant portion, the colorant portion including total iron as Fe2O3 in the range of at least 0.10 to no more than 2.00 weight percent, a redox ratio in the range of 0.35 to 0.6, and tin metal providing tin in an amount within the range of greater than 0.005 to 5.0 weight percent; the glass product has a tin side and an opposite air side, said tin side of the glass having a higher concentration of tin than the air side, the air side having a uniform concentration of tin from the air side of the glass product towards the tin side of the glass product.Type: GrantFiled: June 30, 2020Date of Patent: November 14, 2023Assignee: Vitro Flat Glass LLCInventors: Mark O. Naylor, Lawrence E. Jansen, Larry J. Shelestak
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Patent number: 11802072Abstract: A glass composition includes greater than or equal to 60 mol % and less than or equal to 85 mol % SiO2; greater than or equal to 0.5 mol % and less than or equal to 20 mol % Al2O3; greater than or equal to 0 mol % and less than or equal to 15 mol % Li2O; greater than or equal to 0.5 mol % and less than or equal to 25 mol % Na2O; greater than or equal to 0.1 mol % and less than or equal to 20 mol % 1(20; greater than or equal to 0 mol % and less than or equal to 10 mol % CaO; greater than or equal to 0 mol % and less than or equal to 10 mol % MgO; and greater than or equal to 0.005 mol % and less than or equal to 0.5 mol % Au.Type: GrantFiled: June 17, 2022Date of Patent: October 31, 2023Assignee: Corning IncorporatedInventors: Xiaoju Guo, Lina Ma, Liping Xiong Smith
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Patent number: 11787732Abstract: New glass compositions and applications thereof are disclosed. A glass composition as described herein can include 50 to 55 weight percent SiO2, 17 to 26 weight percent B2O3, 13 to 19 weight percent Al2O3, 0 to 8.5 weight percent MgO, 0 to 7.5 weight percent ZnO, 0 to 6 weight percent CaO, 0 to 1.5 weight percent Li2O, 0 to 1.5 weight percent F2, 0 to 1 weight percent Na2O, 0 to 1 weight percent Fe2O3, 0 to 1 weight percent TiO2, and 0 to 8 weight percent of other constituents. Also described herein are glass fibers formed from such compositions, composites, and articles of manufacture comprising the glass compositions and/or glass fibers.Type: GrantFiled: October 14, 2019Date of Patent: October 17, 2023Assignee: Electric Glass Fiber America, LLCInventor: Hong Li
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Patent number: 11767252Abstract: A glass for chemical strengthening contains, in mole percentage on an oxide basis, 58 to 80% of SiO2, 13 to 18% of Al2O3, 0 to 5% of B2O3, 0.5 to 4% of P2O5, 4 to 10% of Li2O, 5 to 14% of Na2O, 0 to 2% of K2O, 0 to 11% of MgO, 0 to 5% of CaO, 0 to 20% of SrO, 0 to 15% of BaO, 0 to 10% of ZnO, 0 to 1% of TiO2, and 0 to 2% of ZrO2. A value of X is 30000 or more. The value of X is calculated based on the formula, X=SiO2×329+Al2O3×786+B2O3×627+P2O5×(?941)+Li2O×927+Na2O×47.5+K2O×(?371)+MgO×1230+CaO×1154+SrO×733+ZrO2×51.8, by using the contents in mole percentage on an oxide basis of components.Type: GrantFiled: September 17, 2020Date of Patent: September 26, 2023Assignee: AGC Inc.Inventors: Suguru Murayama, Seiki Ohara, Qing Li, Shusaku Akiba
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Patent number: 11767256Abstract: A method of making a ceramic glaze additive formulation having an antimicrobial property for use with a ceramic article is provided. The method comprises fritting an antimicrobial formulation in a flux frit, providing a silver carrier in a glass matrix, combining the flux frit and the silver carrier in the glass matrix to form the ceramic glaze additive formulation, wherein the silver carrier is combined at an addition rate of at least 2 weight %, based on a dry weight basis of the ceramic glaze formulation. The flux frit is present in the ceramic glaze additive formulation in a range of 94 weight % to 99.5 weight %, based on a dry weight basis of the ceramic glaze additive formulation. A ceramic glaze additive formulation and a ceramic glazed article comprising a ceramic glaze additive formulation are also provided.Type: GrantFiled: December 16, 2020Date of Patent: September 26, 2023Assignee: MICROBAN PRODUCTS COMPANYInventors: Alvin Lamar Campbell, Jr., Nathan L. Fields
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Patent number: 11767254Abstract: A glass composition includes: from 55.0 mol % to 70.0 mol % SiO2; from 12.0 mol % to 20.0 mol % Al2O3; from 5.0 mol % to 15.0 mol % Li2O; and from 4.0 mol % to 15.0 mol % Na2O. The glass composition has the following relationships ?8.00 mol %?R2O+RO?Al2O3?B2O3?P2O5??1.75 mol %, 9.00?(SiO2+Al2O3+Li2O)/Na2O, and (Li2O+Al2O3+P2O5)/(Na2O+B2O3)?3.50. The glass composition may be used in a glass article or a consumer electronic product.Type: GrantFiled: March 27, 2020Date of Patent: September 26, 2023Assignee: CORNING INCORPORATEDInventors: Timothy Michael Gross, Xiaoju Guo, Peter Joseph Lezzi, Alexandra Lai Ching Kao Andrews Mitchell, Rostislav Vatchev Roussev
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Patent number: 11767258Abstract: Glass-based articles that include a compressive stress layer extending from a surface of the glass-based article to a depth of compression are formed by exposing glass-based substrates to water vapor containing environments. The methods of forming the glass-based articles may include elevated pressures and/or multiple exposures to water vapor containing environments.Type: GrantFiled: November 13, 2019Date of Patent: September 26, 2023Assignee: Corning IncorporatedInventors: Timothy Michael Gross, Adam Robert Sarafian, Jingshi Wu, Zheming Zheng
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Patent number: 11767253Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).Type: GrantFiled: February 24, 2020Date of Patent: September 26, 2023Assignee: CORNING INCORPORATEDInventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
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Patent number: 11760684Abstract: The present invention provides a glass composition not requiring a large quantity of rare earth material, producible by a common apparatus for producing a glass, having a high Young's modulus and a large crack initiation load, and suitable for glass fibers etc. A glass composition according to the present invention contains, in mol %: 50 to 65% SiO2; 7.5 to 26% Al2O3; 15 to 30% MgO; 0 to 8% CaO; 0 to 3% B2O3; 0 to 3% Li2O; and 0 to 0.2% Na2O. In this glass composition, a total content of MgO and CaO is in a range of 18 to 35 mol %, and a mol ratio calculated by Al2O3/(MgO+CaO) is less than 1.Type: GrantFiled: October 11, 2017Date of Patent: September 19, 2023Assignee: NIPPON SHEET GLASS COMPANY, LIMITEDInventors: Aya Nakamura, Masanori Shojiya
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Patent number: 11739023Abstract: Glass compositions and glass fibers having low dielectric constants and low dissipation factors that may be suitable for use in electronic applications and articles are disclosed. The glass fibers and compositions of the present invention may include between 48.0 to 58.0 weight percent SiO2; between 15.0 and 26.0 weight percent B2O3; between 12.0 and 18.0 weight percent Al2O3; between greater than 0.25 and 3.0 weight percent P2O5; between greater than 0.25 and 7.00 weight percent CaO; 5.0 or less weight percent MgO; between greater than 0 and 1.5 weight percent SnO2; and 6.0 or less weight percent TiO2. Further, the glass composition has a glass viscosity of 1000 poise at a temperature greater than 1350 degrees Celsius and a liquidus temperature greater than 1000 degrees Celsius.Type: GrantFiled: February 17, 2020Date of Patent: August 29, 2023Assignee: AGY HOLDING CORPORATIONInventors: Robert Lurie Hausrath, Anthony Vincent Longobardo
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Patent number: 11731896Abstract: The present invention provides for synthesizing high optical quality multicomponent chalcogenide glasses without refractive index perturbations due to striae, phase separation or crystal formation using a two-zone furnace and multiple fining steps. The top and bottom zones are initially heated to the same temperature, and then a temperature gradient is created between the top zone and the bottom zone. The fining and cooling phase is divided into multiple steps with multiple temperature holds.Type: GrantFiled: April 27, 2021Date of Patent: August 22, 2023Assignee: The Government of the United States of America, as represented by the Secretary of the NavyInventors: Vinh Q. Nguyen, Mikhail Kotov, Daniel J. Gibson, Shyam S. Bayya, Jasbinder S. Sanghera, Gryphon A. Drake
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Patent number: 11724957Abstract: An antibacterial composition, includes: a borate-based glass material having a composition of: 0-25 wt. % SiO2, 30-75 wt. % B2O3, 0-10 wt. % P2O5, 0-30 wt. % Al2O3, 0-5 wt. % Li2O, 1-25 wt. % Na2O, 0-15 wt. % K2O, 0-10 wt. % MgO, 10-25 wt. % CaO, 12-30 wt. % MO, 8-25 wt. % R2O, and 30-75 (B2O3+Al2O3), such that at least one of P2O5 or Al2O3 is present, MO is the sum of MgO, CaO, SrO, and BaO, R2O is the sum of Na2O, K2O, Li2O, and Rb2O, and the borate-based glass material is configured to achieve at least a 3.5-log kill rate of at least one of E. coli, P. gingivalis, or S. mutans bacteria.Type: GrantFiled: March 4, 2020Date of Patent: August 15, 2023Assignee: CORNING INCORPORATEDInventor: Qiang Fu
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Patent number: 11724958Abstract: Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P2O5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.Type: GrantFiled: February 18, 2020Date of Patent: August 15, 2023Assignee: CORNING INCORPORATEDInventor: Timothy Michael Gross
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Patent number: 11724959Abstract: An optical glass contains: a P2O5 component of 30 to 60 mass % (exclusive of 30); an Al2O3 component of 2 to 10 mass % (exclusive of 2); a TiO2 component of 10 to 36 mass % (exclusive of 36); an Nb2O5 component of 0 to 5 mass %; a Ta2O5 component of 0 to 15 mass %; a Bi2O3 component of 0 to 5 mass % (exclusive of 5); and an Sb2O3 component of 0 to 1 mass %; and a BaO component of 1 to 20 mass %.Type: GrantFiled: April 27, 2020Date of Patent: August 15, 2023Assignee: NIKON CORPORATIONInventor: Tetsuya Koide
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Patent number: 11718554Abstract: A group of glass compositions in the Li2O—Al2O3—SiO2—B2O3 family that can be chemically strengthened in single or multiple ion exchange baths containing at least one of NaNO3 and KNO3 for a short time (2-4 hours) to develop a deep depth of layer (DOL). In some instances, the DOL is at least 70 ?m; in others, at least about 100 ?m. The ion exchanged glasses have a high damage resistance (indentation fracture toughness ranging form greater than 10 kgf to greater than 50 kgf) that is better than or at least comparable to that of sodium aluminosilicate glasses.Type: GrantFiled: November 9, 2021Date of Patent: August 8, 2023Assignee: CORNING INCORPORATEDInventors: George Halsey Beall, Matthew John Dejneka, Qiang Fu, Sinue Gomez, Robert Michael Morena, Charlene Marie Smith
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Patent number: 11718552Abstract: The invention relates to a glass sheet having a boron-, strontium- and lithium-free glass composition comprising the following in weight percentage, expressed with respect to the total weight of glass: 65?SiO2?78% 8?Na2O?15% 1?K2O<6% 1?Al2O3<6% 2?CaO<10% 0?MgO?6%; as well as a K2O/(K2O+Na2O) ratio which is ranging from 0.1 and 0.7. The invention corresponds to an easy chemically-temperable soda-lime-silica type glass composition, which is more suited for use in electronic devices applications.Type: GrantFiled: November 11, 2019Date of Patent: August 8, 2023Assignee: AGC GLASS EUROPEInventor: Thomas Lambricht
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Patent number: 11713275Abstract: The present disclosure relates to compositions that can be used for optical fibers and other systems that transmit light in the near-, mid- and/or far-ranges of the infrared spectrum, such as for example in the wavelength range of 1.5 ?m to 14 ?m. The optical fibers may comprise a light-transmitting chalcogenide core composition and a cladding composition. In some embodiments, the light-transmitting chalcogenide core composition has a refractive index n(core) and a coefficient of thermal expansion CTE(core), and the cladding composition has a refractive index n(cladding) and a coefficient of thermal expansion CTE(cladding), wherein n(cladding) is less than n(core) and in some embodiments wherein CTE(cladding) is less than CTE(core). In some embodiments, the chalcogenide glass core composition comprises a) sulfur and/or selenium, b) germanium, and c) gallium, indium, tin and/or one or more metal halides.Type: GrantFiled: June 12, 2019Date of Patent: August 1, 2023Assignee: SCHOTT CORPORATIONInventors: Bernd Schultheis, Nathan Carlie, Lothar Willmes, Simone Monika Ritter, Bernd Hoppe, William James
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Patent number: 11708294Abstract: A glass substrate for a high-frequency device, which contains SiO2 as a main component, the glass substrate having a total content of alkali metal oxides in the range of 0.001-5% in terms of mole percent on the basis of oxides, the alkali metal oxides having a molar ratio represented by Na2O/(Na2O+K2O) in the range of 0.01-0.99, and the glass substrate having a total content of alkaline earth metal oxides in the range of 0.1-13% in terms of mole percent on the basis of oxides, wherein at least one main surface of the glass substrate has a surface roughness of 1.5 nm or less in terms of arithmetic average roughness Ra, and the glass substrate has a dielectric dissipation factor at 35 GHz of 0.007 or less.Type: GrantFiled: December 19, 2019Date of Patent: July 25, 2023Assignee: AGC Inc.Inventors: Kazutaka Ono, Shuhei Nomura, Nobutaka Kidera, Nobuhiko Takeshita
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Patent number: 11702360Abstract: A chemically temperable borosilicate glass article has a low boron content and a corresponding Na2O content. The articles have good diffusivities and hydrolytical resistance values. When chemically tempered, the borosilicate glass article exhibits a compressive stress CS >400 MPa and a penetration depth DoL >20 ?m. A pharmaceutical primary packaging including the borosilicate glass article is also disclosed.Type: GrantFiled: June 18, 2019Date of Patent: July 18, 2023Assignee: Schott AGInventors: Malte Grimm, Christof Kass, Rainer Eichholz
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Patent number: 11697611Abstract: Glass compositions suitable for fiber forming having low levels of Li2O and glass fibers having high-modulus are disclosed. The glass composition may include SiO2 from about 59 to about 63 weight percent, Al2O3 from about 13.7 to about 16 weight percent, CaO from about 14 to about 16.5 weight percent, MgO from about 6 to about 8.5 weight percent, Fe2O3 less than 1 weight percent, and TiO2 less than 1 weight percent. In some cases, the composition may be substantially free of Li2O. In some cases, the composition may include Li2O up to 0.5 weight percent. In some cases, RE2O3 may be present in the composition in an amount up to 1.5 weight percent. The glass compositions can be used to form glass fibers which can be incorporated into a variety of other fiber glass products (e.g., strands, rovings, fabrics, etc.) and incorporated into various composites.Type: GrantFiled: March 5, 2019Date of Patent: July 11, 2023Assignee: Electric Glass Fiber America, LLCInventor: Hong Li