Patents Examined by Elizabeth A. Bolden
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Patent number: 11702360Abstract: A chemically temperable borosilicate glass article has a low boron content and a corresponding Na2O content. The articles have good diffusivities and hydrolytical resistance values. When chemically tempered, the borosilicate glass article exhibits a compressive stress CS >400 MPa and a penetration depth DoL >20 ?m. A pharmaceutical primary packaging including the borosilicate glass article is also disclosed.Type: GrantFiled: June 18, 2019Date of Patent: July 18, 2023Assignee: Schott AGInventors: Malte Grimm, Christof Kass, Rainer Eichholz
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Patent number: 11697611Abstract: Glass compositions suitable for fiber forming having low levels of Li2O and glass fibers having high-modulus are disclosed. The glass composition may include SiO2 from about 59 to about 63 weight percent, Al2O3 from about 13.7 to about 16 weight percent, CaO from about 14 to about 16.5 weight percent, MgO from about 6 to about 8.5 weight percent, Fe2O3 less than 1 weight percent, and TiO2 less than 1 weight percent. In some cases, the composition may be substantially free of Li2O. In some cases, the composition may include Li2O up to 0.5 weight percent. In some cases, RE2O3 may be present in the composition in an amount up to 1.5 weight percent. The glass compositions can be used to form glass fibers which can be incorporated into a variety of other fiber glass products (e.g., strands, rovings, fabrics, etc.) and incorporated into various composites.Type: GrantFiled: March 5, 2019Date of Patent: July 11, 2023Assignee: Electric Glass Fiber America, LLCInventor: Hong Li
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Low LOI tellurium-lithium-silicon-zirconium frit system and conductive paste and application thereof
Patent number: 11697612Abstract: The present disclosure discloses a low LOI tellurium-lithium-silicon-zirconium frit system and a conductive paste and application thereof, and belongs to the field of conductive paste. In the low LOI tellurium-lithium-silicon-zirconium frit system, components of the frit are 24%-40% TeO2, 18%-24% Li2O, 4%-13% SiO2, 0-2% ZrO2, and a balance MOx, and M is one or a mixture of Na, K, Mg, Ca, Sr, Ti, V, Cr, Mo, W, Mn, Cu, Ag, Zn, Cd, B, Al, Ga, Tl, Ge, Pb, P, and Bi. There is no need to add additional surfactants, a viscosity change of the conductive paste prepared after standing for 30 days is less than 20%, the conductive paste has good stability, the water related weight loss of inorganic oxide of the conductive paste is less than 1.6%, and the application performance of the conductive paste is not affected after standing for 30 days.Type: GrantFiled: February 25, 2022Date of Patent: July 11, 2023Assignee: JIANGSU RIYU PHOTOVOLTAIC NEW MATERIAL TECHNOLOGY CO. LTDInventors: Li Yan, Song Xu, Rui Tian -
Patent number: 11655180Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs) and active matrix organic light emitting diode displays (AMOLEDs). In accordance with certain of its aspects, the glasses possess good dimensional stability as a function of temperature.Type: GrantFiled: July 9, 2020Date of Patent: May 23, 2023Assignee: Corning IncorporatedInventors: Adam James Ellison, Sinue Gomez, Yoshiaki Kato
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Patent number: 11643360Abstract: An electronic-grade glass fiber composition includes the following components with corresponding amounts by weight percentages: 54.2-60% SiO2, 11-17.5% Al2O3, 0.7-4.5% B2O3, 18-23.8% CaO, 1-5.5% MgO, less than or equal to 24.8% CaO+MgO, less than 1% Na2O+K2O+Li2O, 0.05-0.8% TiO2, 0.05-0.7% Fe2O3, and 0.01-1.2% F2. The weight percentage ratio C1=SiO2/(RO+R2O) is greater than or equal to 2.20, and the total weight percentage of the above components is greater than or equal to 98.5%.Type: GrantFiled: October 30, 2019Date of Patent: May 9, 2023Assignee: JUSHI GROUP CO., LTD.Inventors: Wenzhong Xing, Guorong Cao, Lin Zhang, Xiucheng Hong, Shuangbao Zuo, Zhonghua Yao
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Patent number: 11634353Abstract: To provide a glass plate for a window material and a window comprising the glass plate, which are less likely to be a barrier to radio transmitting/receiving in use of a radio-utilizing apparatus, and a radio communication apparatus comprising the glass plate. A glass plate having a radio transmittance of at least 20% at a frequency of 100 GHz as calculated as 18 mm thickness, a window comprising the glass plate, and a radio communication apparatus comprising the glass plate.Type: GrantFiled: October 2, 2019Date of Patent: April 25, 2023Assignee: AGC Inc.Inventors: Eriko Maeda, Takato Kajihara, Kensuke Nagai, Yutaka Kuroiwa, Osamu Kagaya, Ryuta Sonoda, Hiroyuki Hijiya
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Patent number: 11634355Abstract: The present disclosure discloses a ceramic glass powder and a solar cell metallization paste containing the ceramic glass powder, and belongs to the technical field of solar cells. The present disclosure provides a novel formula mode of a glass powder including a crystallization nucleus component and a glass network component, that is, a formula of a ceramic glass powder that has a special crystallization behavior, a low crystallinity before sintering and a high crystallinity after the sintering, and a conductive metallization paste containing the ceramic glass powder is further obtained. The present disclosure solves the technical problem that by using metallization pastes in the prior art, a balance between corrosion of a silicon wafer and an ohmic contact is difficult to achieve. The efficiency of a solar cell is improved.Type: GrantFiled: February 25, 2022Date of Patent: April 25, 2023Assignee: JIANGSU RIYU PHOTOVOLTAIC NEW MATERIAL TECHNOLOGYInventors: Song Xu, Rui Tian
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Patent number: 11634354Abstract: A colored glass article may include 50-80 mol % SiO2; 7-20 mol % Al2O3; 1-35 mol % R2O, wherein R2O comprises at least one of Li2O, Na2O, and K2O; 1×10?6-10 mol % of a colorant, wherein the colorant comprises at least one of Cr2O3, Au, Ag, CuO, NiO, Co3O4, TiO2, CeO2; and 12-24 mol % of Al2O3+MgO+CaO+ZnO. The colored glass article may have a transmittance color coordinate in the CIELAB color space with an L* value of 55 to 96.5. The colored glass article may have a compressive stress profile with a depth of compression ?0.15t, a thickness t from 0.4 mm-5 mm, a compressive stress ?200 MPa, and a central tension ?60 MPa. The colored glass article may have a dielectric constant from 5.6 to 6.4 over the frequency range from 10 GHz to 60 GHz.Type: GrantFiled: March 10, 2022Date of Patent: April 25, 2023Assignee: Corning IncorporatedInventors: Xiaoju Guo, Jesse Kohl, Nicole Taylor Wiles
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Patent number: 11629091Abstract: Optically transparent glass ceramic materials comprising a glass phase containing and a crystalline tungsten bronze phase comprising nanoparticles and having the formula MxWO3, where M includes at least one H, Li, Na, K, Rb, Cs, Ca, Sr, Ba, Zn, Cu, Ag, Sn, Cd, In, Tl, Pb, Bi, Th, La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, and U, and where 0<x<1. Aluminosilicate and zinc-bismuth-borate glasses comprising at least one of Sm2O3, Pr2O3, and Er2O3 are also provided.Type: GrantFiled: December 1, 2021Date of Patent: April 18, 2023Assignee: Corning IncorporatedInventors: Matthew John Dejneka, Jesse Kohl, Mallanagouda Dyamanagouda Patil
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Patent number: 11597674Abstract: A colored glass article includes from 40 mol % to 70 mol % SiO2; from 8 mol % to 20 mol % Al2O3; from 1 mol % to 10 mol % B2O3; from 1 mol % to 20 mol % Li2O; from 1 mol % to 15 mol % Na2O; from 0 mol % to 8 mol % MgO; from 0 mol % to 5 mol % ZnO; and from 0.0005 mol % to 1 mol % Au. MgO+ZnO is from 0.1 mol % to 6 mol %.Type: GrantFiled: February 22, 2022Date of Patent: March 7, 2023Assignee: Corning IncorporatedInventors: Xiaoju Guo, Jill Marie Hall, Karl William Koch, III, Jesse Kohl, Liping Xiong Smith, Nicole Taylor Wiles
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Patent number: 11591253Abstract: A glass composition is provided. The glass composition includes: 25-40 wt % SiO2; 2.5-10 wt % B2O3; 0-10 wt % Al2O3; 0-15 wt % Li2O; 0-16 wt % of Li2O, Na2O, and K2O in total; 10-25 wt % CaO; 0-15 wt % BaO; 0-5 wt % MgO; 0-5 wt % SrO; 10-30 wt % CaO, BaO, MgO, and SrO in total; 0-7 wt % ZnO; 2-10 wt % ZrO; 2-15 wt % TiO2; 5-25 wt % Nb2O5; 0-5 wt % Ta2O5; 5-25 La2O3; and 0-5 wt % Y2O3. The glass composition has a refractive index from about 1.74 to about 1.80, a density from about 3.5 g/cm3 to about 4.0 g/cm3, a critical cooling rate from about 1° C./min to about 50° C./min, and a liquidus viscosity greater than 25 Poises.Type: GrantFiled: November 7, 2019Date of Patent: February 28, 2023Assignee: CORNING INCORPORATEDInventor: Paulo Jorge Gaspar Marques
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Patent number: 11577987Abstract: A glass composition includes from 55.0 mol % to 75.0 mol % SiO2; from 8.0 mol % to 20.0 mol % Al2O3; from 3.0 mol % to 15.0 mol % Li2O; from 5.0 mol % to 15.0 mol % Na2O; and less than or equal to 1.5 mol % K2O. The glass composition has the following relationships: Al2O3+Li2O is greater than 22.5 mol %, R2O+RO is greater than or equal to 18.0 mol %, R2O/Al2O3 is greater than or equal to 1.06, SiO2+Al2O3+B2O3+P2O5 is greater than or equal to 78.0 mol %, and (SiO2+Al2O3+B2O3+P2O5)/Li2O is greater than or equal to 8.0. The glass composition may be used in a glass article or a consumer electronic product.Type: GrantFiled: February 1, 2021Date of Patent: February 14, 2023Assignee: CORNING INCORPORATEDInventors: Timothy Michael Gross, Xiaoju Guo, Peter Joseph Lezzi, Alexandra Lai Ching Kao Andrews Mitchell, Rostislav Vatchev Roussev
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Patent number: 11577990Abstract: Provided is a glass fiber having a low spinning temperature and a low liquidus temperature, and besides, having a large difference between the liquidus temperature and the spinning temperature, and a method of manufacturing the same. The glass fiber of the present invention includes as a glass composition, in terms of mass % on an oxide basis, 50% to 65% of SiO2, 0% to 3% of Al2O3, 0% to 1% of MgO, 0% to less than 0.7% of CaO, 0% to 1% of Li2O, 10% to 20% of Na2O, 0% to 2% of K2O, 6% to 10% of TiO2, and 15% to 20% of ZrO2, and has a value for (Na2O+K2O)/(MgO+CaO) of 6.0 or more.Type: GrantFiled: November 21, 2018Date of Patent: February 14, 2023Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Yuki Yokota, Hiroshi Sawasato, Minoru Matsumoto
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Patent number: 11577988Abstract: According to one embodiment, a glass may include from about 50 mol. % to about 70 mol. % SiO2; from about 12 mol. % to about 35 mol. % B2O3; from about 4 mol. % to about 12 mol. % Al2O3; greater than 0 mol. % and less than or equal to 1 mol. % alkali metal oxide, wherein Li2O is greater than or equal to about 20% of the alkali metal oxide; from about 0.3 mol. % to about 0.7 mol. % of Na2O or Li2O; and greater than 0 mol. % and less than 12 mol. % of total divalent oxide, wherein the total divalent oxide includes at least one of CaO, MgO and SrO, and wherein a ratio of Li2O (mol. %) to (Li2O (mol. %)+(Na2O (mol. %)) is greater than or equal 0.4 and less than or equal to 0.6. The glass may have a relatively low high temperature resistivity and a relatively high low temperature resistivity.Type: GrantFiled: May 29, 2019Date of Patent: February 14, 2023Assignee: CORNING INCORPORATEDInventors: Megan Aurora DeLamielleure, John Christopher Mauro, Charlene Marie Smith, Liying Zhang
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Patent number: 11572302Abstract: A glass pharmaceutical package having a glass composition of 68.00 mol % to 81.00 mol % SiO2, from 4.00 mol % to 11.00 mol % Al2O3, from 0.10 mol % to 16.00 mol % Li2O, from 0.10 mol % to 12.00 mol % Na2O, from 0.00 mol % to 5.00 mol % K2O, from 0.10 mol % to 8.00 mol % MgO, from 0.10 mol % to 5.00 mol % CaO, from 0.00 mol % to 0.20 mol % fining agent. The glass pharmaceutical package is delamination resistant, and has class 1 or class 2 chemical durability in acid, base, and water. The glass pharmaceutical package may have a surface compressive stress of at least 350 MPa.Type: GrantFiled: April 1, 2020Date of Patent: February 7, 2023Assignee: CORNING INCORPORATEDInventors: Steven Edward DeMartino, Nadja Teresia Lönnroth, Lina Ma, Robert Anthony Schaut, Charlene Marie Smith, Zhongzhi Tang, Jamie Todd Westbrook
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Patent number: 11565967Abstract: A glass composition for glass fiber includes SiO2 in the range of 52.0% by mass or more and 56.0% by mass or less; B2O3 in the range of 21.0% by mass or more and 24.5% by mass or less; Al2O3 in the range of 9.5% by mass or more and 13.0% by mass or less; MgO in the range of 0% by mass or more and less than 1.0% by mass; CaO in the range of 0.5% by mass or more and 5.5% by mass or less; SrO in the range of 0.5% by mass or more and 6.0% by mass or less; and TiO2 in the range of 0.1% by mass or more and 3.0% by mass or less; and includes F2 and Cl2 in the range of 0.1% by mass or more and 2.0% by mass or less in total, with respect to the total amount.Type: GrantFiled: December 24, 2020Date of Patent: January 31, 2023Assignee: Nitto Boseki Co., Ltd.Inventors: Masaru Urushizaki, Takanobu Hosokawa, Takashi Nonaka
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Patent number: 11554984Abstract: An article comprises a glass substrate. The glass substrate has a first surface having a plurality of vias therein, and a second surface parallel to the first surface. At least one of the first surface and the second surface is an etched surface having a surface roughness (Ra) of 0.75 nm or less. The glass substrate comprises, in mol percent on an oxide basis: 65 mol %?SiO2?75 mol %; 7 mol %?Al2O3?15 mol %; 26.25 mol %?RO+Al2O3?B2O3; 0 mol %?R2O?2 mol %. RO=MgO+CaO+SrO+BaO+ZnO. R2O=Li2O+Na2O+K2O+Rb2O+Cs2O.Type: GrantFiled: February 11, 2019Date of Patent: January 17, 2023Assignee: Corning IncorporatedInventors: Timothy Michael Gross, Yuhui Jin, Ruchirej Yongsunthon, Liying Zhang
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Patent number: 11554983Abstract: A glass substrate has a compaction of 0.1 to 100 ppm. An absolute value |??50/100| of a difference between an average coefficient of thermal expansion ?50/100 of the glass substrate and an average coefficient of thermal expansion of single-crystal silicon at 50° C. to 100° C., an absolute value |??100/200| of a difference between an average coefficient of thermal expansion ?100/200 of the glass substrate and an average coefficient of thermal expansion of the single-crystal silicon at 100° C. to 200° C., and an absolute value |??200/300| of a difference between an average coefficient of thermal expansion ?200/300 of the glass substrate and an average coefficient of thermal expansion of the single-crystal silicon at 200° C. to 300° C. are 0.16 ppm/° C. or less.Type: GrantFiled: February 1, 2019Date of Patent: January 17, 2023Assignee: AGC INC.Inventors: Shuhei Nomura, Kazutaka Ono
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Patent number: 11548807Abstract: A soda lime glass plate has, on the basis of oxides, a total sulfur content in terms of SO3 of 0.001 to 0.2% in mass %, a total iron content in terms of Fe2O3 of 0.15 to 0.4% in mass %, and a total tin content in terms of SnO2 of 0.02 to 1% in mass %, and has a mass proportion of a divalent iron in terms of Fe2O3 in the total iron in terms of Fe2O3 of 45 to 70%. The soda lime glass plate has, as a conversion value for a 3.85 mm-thickness glass plate, a visible light transmittance Tv_A of 70% or more, a total solar transmittance Tts of 63.7% or less, and c* in the L*a*b* color space of 4 or less.Type: GrantFiled: April 18, 2019Date of Patent: January 10, 2023Assignee: AGC Inc.Inventors: Hiroyuki Hijiya, Kensuke Nagai
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Patent number: 11535548Abstract: A glass for chemical strengthening has a Young's modulus E of 70 GPa or more. The glass satisfies X1+X2+X3 being 1760 or less. Here, X1 is a numerical value equivalent to a value [unit: kPa/° C.] obtained by multiplying the Young's modulus E by an average coefficient ? of thermal expansion at 50° C. to 350° C., X2 is a numeral value equivalent to a value of a temperature Tf [unit: ° C.] at which a viscosity of the glass reaches 100 MPa·s, and X3 is a numerical value equivalent to a value of a difference [unit: 105 Pa·s] between the viscosity (100 MPa·s) at the Tf and a viscosity ?+10 at a temperature 10° C. higher than the Tf.Type: GrantFiled: April 17, 2019Date of Patent: December 27, 2022Assignee: AGC INC.Inventors: Suguru Murayama, Satoshi Kanasugi, Madoka Ono