Abstract: Embodiments are directed to glass articles which are resistant to UV photodarkening, the glass articles having a thickness ?1.3 mm and comprise UV absorbers such as Ti, V, Mn, Fe, Cu, Ce, Ge, Mo, Cr, Co and Ni, and combinations thereof, or alternatively comprising ZnO or SnO2.
Type:
Grant
Filed:
November 13, 2019
Date of Patent:
November 15, 2022
Assignee:
CORNING INCORPORATED
Inventors:
Dana Craig Bookbinder, Nicholas Francis Borrelli, Matthew John Dejneka, Timothy Michael Gross, Xiaoju Guo, Ronald Leroy Stewart
Abstract: Provided is an ultraviolet-radiation absorbing glass product, characterized by: having a transmittance of ultraviolet radiation (TUV), as specified by ISO 9050: 2003, of 2% or less at a plate thickness of 3.5 mm, and transmittance of visible light (TVA) of 8 to 28% inclusive, based on the Standard Illuminant A at a plate thickness of 3.5 mm; and the color of the glass, as denoted by the chromaticity coordinates x, y in the XYZ color coordinate system based on a 2-degree visual field of the Standard Illuminant C as specified by JIS Z8701: 1999, satisfying the following expressions (1) and (2). (1) y??0.735×x+0.544 (2) y?1.389×x?0.
Abstract: Glass compositions include niobia (Nb2O5), phosphorus oxide (P2O5) and titania (TiO2) as essential components and may optionally include calcium oxide (CaO), potassium oxide (K2O), barium oxide (BaO), sodium oxide (Na2O), lithium oxide (Li2O), magnesia (MgO), zinc oxide (ZnO) and other components. The glasses may be characterized by high refractive index at 587.56 nm at comparably low density at room temperature.
Type:
Grant
Filed:
January 14, 2022
Date of Patent:
November 1, 2022
Assignee:
Corning Incorporated
Inventors:
Bruce Gardiner Aitken, Jian Luo, Lina Ma, Alexander I Priven
Abstract: A glass composition includes: 50 mol % to 69 mol % SiO2; 12.5 mol % to 25 mol % Al2O3; 0 mol % to 8 mol % B2O3; greater than 0 mol % to 4 mol % CaO; greater than 0 mol % to 17.5 mol % MgO; 0.5 mol % to 8 mol % Na2O; 0 mol % to 2.5 mol % La2O3; and greater than 8 mol % to 18 mol % Li2O, wherein (Li2O+Na2O+MgO)/Al2O3 is from 0.9 to less than 1.3; and Al2O3+MgO+Li2O+ZrO2+La2O3+Y2O3 is from greater than 23 mol % to less than 50 mol %. The glass composition may be characterized by at least one of the following: a K1C value measured by a chevron short bar method of at least 0.75; and a K1C value measured by a double torsion method of at least 0.8. The glass composition is chemically strengthenable. The glass composition may be used in a glass article or a consumer electronic product.
Type:
Grant
Filed:
March 29, 2019
Date of Patent:
November 1, 2022
Assignee:
CORNING INCORPORATED
Inventors:
Xiaoju Guo, Peter Joseph Lezzi, Jian Luo
Abstract: A glass composition, including contrast enhancing glass and contrast enhancing sunglass, having approximately 45-65 wt.-%, SiO2, 0-12 wt.-% B2O3, 0-15 wt.-%, Na2O, 0-10 wt.-% K2O, and 10 0-7 wt.-% ZnO, 1-12 wt.-% Nd2O3, 1-10 wt.-% Er2O3, 0.5-8 wt.-% Ho2O3, and 0.00-0.05 wt.-% NiO, and methods of making the same.
Type:
Grant
Filed:
March 28, 2019
Date of Patent:
November 1, 2022
Assignee:
Barberini GmbH
Inventors:
Antje Gawronski, Simon Striepe, Ottmar Bartels
Abstract: Glass compositions include phosphorus oxide (P2O5), niobia (Nb2O5), titania (TiO2), potassium oxide (K2O) and calcium oxide (CaO) as essential components and may optionally include barium oxide (BaO), sodium oxide (Na2O), lithium oxide (Li2O), tungsten oxide (WO3), bismuth oxide (Bi2O3), tantalum oxide (Ta2O5), silica (SiO2) and other components. The glasses may be characterized by high refractive index at 587.56 nm at comparably low density at room temperature.
Type:
Grant
Filed:
January 14, 2022
Date of Patent:
October 25, 2022
Assignee:
Corning Incorporated
Inventors:
Bruce Gardiner Aitken, Jian Luo, Lina Ma, Alexander I Priven
Abstract: Glass compositions include phosphorus oxide (P2O5), niobia (Nb2O5), barium oxide (BaO) and potassium oxide (K2O) as essential components and may optionally include titania (TiO2), calcium oxide (CaO), sodium oxide (Na2O), lithium oxide (Li2O), bismuth oxide (Bi2O3), strontium oxide (SrO), tungsten oxide (WO3) and other components. The glasses may be characterized by high refractive index at 587.56 nm at comparably low density at room temperature.
Type:
Grant
Filed:
January 14, 2022
Date of Patent:
October 18, 2022
Assignee:
Corning Incorporated
Inventors:
Bruce Gardiner Aitken, Jian Luo, Lina Ma, Alexander I. Priven
Abstract: An ultraviolet light absorbing glass according to the present invention includes 1.6% or more of t-Fe2O3, more than 1.0% of TiO2, and 0.016% or more of CoO. The ultraviolet light absorbing glass has t-Fe2O3/TiO2 of 1.2 or more, and an ultraviolet light transmittance (TUV400) at a sheet thickness of 3.1 mm of 2.0% or less, a ratio of visible light transmittance (TVA)/TUV400 of 10 or more, and a dominant wavelength (?D) of 555 nm or less.
Abstract: Glasses having a high degree of resistance to damage cause by abrasion, scratching, indentation, and the like are disclosed. In embodiments, the glasses may include at least 50 mol % SiO2; 9 mol % to 22 mol % Al2O3; Na2O; Li2O; at least 10 mol % R2O, wherein R2O is the sum of alkali metal oxides in the glass; 2.7 mol % to 4.5 mol % B2O3; and greater than 0.1 mol % of MgO+ZnO, wherein (B2O3—(R2O—Al2O3)) is greater than or equal to 3.
Type:
Grant
Filed:
September 23, 2021
Date of Patent:
September 20, 2022
Assignee:
CORNING INCORPORATED
Inventors:
Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
Abstract: A composition for glass, alkaline earth aluminosilicate glass, and a preparation method therefor and applications thereof. Based on the total number of moles of each component and the counting of oxides, the composition contains 68-73 mol % of SiO2, 11.5-15 mol % of Al2O3, 2-6 mol % of MgO, 2.5-7.5 mol % of CaO, 0-3 mol % of SrO, 2-7 mol % of BaO, 0-4 mol % of ZnO and 0.05-1.5 mol % of TiO2. The glass has a high strain point, a high Young's modulus, a high specific modulus, a high Vickers hardness, high chemical stability, a high refractive index and high glass formation stability, and has a lower forming temperature, a lower melting temperature, a lower thermal expansion coefficient, a lower surface tension, a lower density, and low glass manufacturing difficulty.
Type:
Grant
Filed:
April 9, 2018
Date of Patent:
August 9, 2022
Assignees:
TUNGHSU TECHNOLOGY GROUP CO., LTD., TUNGHSU GROUP CO., LTD.
Inventors:
Guangtao Zhang, Junfeng Wang, Gang Li, Peng Tian, Dongcheng Yan, Lihong Wang, Quan Zheng
Abstract: Glass articles that are resistant to coloration when exposed to ultraviolet light or plasma cleaning processes. The glass articles comprise or consist of an alkali aluminosilicate glass containing from about 0.1 mol % to about 1 mol % of at least one of ZrO2, Sb2O3, and Nb2O5; and less than about 400 ppm each of oxides of titanium, iron, germanium, cerium, nickel, cobalt, and europium.
Abstract: New glass compositions and applications thereof are disclosed. Embodiments of the present invention relate to glass compositions, to fiber glass strands, to chopped fiber glass strands, to nonwoven mats of glass fibers, and to other products and methods. A fiber glass strand comprises a plurality of glass fibers comprising the glass composition of the present invention.
Abstract: Provided is a silicate article comprising SiO2, Al2O3, Na2O, K2O, MgO and ZrO2, wherein the content of Al2O3 is 15-28 parts by weight, the content of Na2O is 13-25 parts by weight, the content of K2O is 6-15 parts by weight, the content of MgO is 7-16 parts by weight, and the content of ZrO2 is 0.1-5 parts by weight, relative to 100 parts by weight of SiO2; and M is 5-13, as calculated by the following formula: M=P1*wt (Na2O)+P2*wt (K2O)+P3*wt (MgO)+P4*wt (ZrO2)?P5*wt (Al2O3)*wt (Al2O3). In the formula, P1 has a value of 0.53, P2 has a value of 0.153, P3 has a value of 0.36, P4 has a value of 0.67, and P5 has a value of 0.018.
Abstract: A glass tube for sealing a metal includes a glass that contains, in terms of mass %, 50% or more of SiO2+B2O3, 0% to 10% of Al2O3, 3% to 20% of RO (R is an alkaline earth metal), and 11% to 22% of R?2O (R? is an alkali metal), and that has 10 ?l/g or less of an amount of CO2 emitted when heated from a room temperature to 1100° C.
Abstract: A silicate glass that is tough and scratch resistant. The toughness is increased by minimizing the number of non-bridging oxygen atoms in the glass. In one embodiment, the silicate glass is an aluminoborosilicate glass in which ?15 mol %?(R2O+R?O—Al2O3—ZrO2)—B2O3?4 mol %, where R is one of Li, Na, K, Rb, and Cs, and R? is one of Mg, Ca, Sr, and Ba.
Type:
Grant
Filed:
October 24, 2019
Date of Patent:
June 28, 2022
Assignee:
CORNING INCORPORATED
Inventors:
Matthew John Dejneka, Adam James Ellison, Sinue Gomez, Robert Michael Morena
Abstract: Glass compositions and glass fibers having low dielectric constants and low dissipation factors that may be suitable for use in electronic applications and articles are disclosed. The glass fibers and compositions of the present invention may include between 48.0 to 57.0 weight percent SiO2; between 15.0 and 26.0 weight percent B2O3; between 12.0 and 18.0 weight percent Al2O3; between 3.0 and 8.0 weight percent P2O5; between 0.25 and 7.00 weight percent CaO; 5.0 or less weight percent MgO; and 6.0 or less weight percent TiO2. Further, the glass composition has a glass viscosity of 1000 poise at a temperature greater than 1350 degrees Celsius and a liquidus temperature greater than 1100 degrees Celsius.
Type:
Grant
Filed:
January 2, 2020
Date of Patent:
May 24, 2022
Assignee:
AGY HOLDING CORPORATION
Inventors:
Robert Lurie Hausrath, Anthony Vincent Longobardo
Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In an embodiment the glass composition may include from about 67 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; from about 2 mol. % to about 10 mol. % Al2O3; from about 2 mol. % to about 18 mol. % alkali oxide, wherein the alkali oxide comprises non-zero amounts of Na2O; from 0 mol. % to about 4 mol. % B2O3; and from about 0.01 mol. % to about 1 mol. % of a fining agent.
Type:
Grant
Filed:
December 21, 2018
Date of Patent:
May 10, 2022
Assignee:
CORNING INCORPORATED
Inventors:
Paul Stephen Danielson, Steven Edward DeMartino, Melinda Ann Drake, Robert Michael Morena, Santona Pal, Robert Anthony Schaut
Abstract: The invention discloses a borosilicate glass with high chemical resistance and an application thereof. The borosilicate glass contains 0.25-4.0 wt % of Y2O3 based on the oxide. The borosilicate glass has a high chemical stability, a suitable linear thermal expansion coefficient and is suitable for use in the field of pharmaceutical packaging materials.
Abstract: A borate glass includes from 25.0 mol % to 70.0 mol % B2O3; from 0.0 mol % to 10.0 mol % SiO2; from 0.0 mol % to 15.0 mol % Al2O3; from 3.0 mol % to 15.0 mol % Nb2O5; from 0.0 mol % to 12.0 mol % alkali metal oxides; from 0.0 mol % to 5.0 mol % ZnO; from 0.0 mol % to 8.0 mol % ZrO2; from 0.0 mol % to 15.0 mol % TiO2; less than 0.5 mol % Bi2O3; and less than 0.5 mol % P2O5. The optical borate glass includes a sum of B2O3+Al2O3+SiO2 from 35.0 mol % to 76.0 mol %, a sum of CaO+MgO from 0.0 mol % to 35.5 mol %. The borate glass has a refractive index, measured at 587.6 nm, of greater than 1.70, a density of less than 4.50 g/cm3, and an Abbe number, VD, from 20.0 to 47.0.
Abstract: Provided is a composition for a glass fiber which has a high elastic modulus and satisfactory productivity, and can facilitate the production of a fine-count glass fiber. The composition for a glass fiber of the present invention includes, as a glass composition expressed as a mass percent in terms of oxide, 50% to 70% of SiO2, 15% to 25% of Al2O3, 3% to 13% of MgO, 3% to 15% of CaO, and 0.5% to 5% of B2O3.