Abstract: A bifunctional catalyst for example for conversion of oxygenates, said bifunctional catalyst comprising zeolite, alumina binder, Zn and P, wherein Zn is present at least partly as ZnAl2O4.
Abstract: Bimetallic catalysts for the hydrodeoxygenation (HDO) conversion of lignin into useful hydrocarbons are provided. The catalysts are bifunctional bimetallic ruthenium catalysts Ru-M/X+Y comprising a metal M such as iron (Fe), nickel (Ni), copper (Cu) or zinc (Zn), zeolite Y and cation X+ (e.g. H+) associated with zeolite Y.
Abstract: The present disclosure generally provides catalysts, catalyst articles and catalyst systems including such catalyst articles. In particular, the catalyst composition includes a metal ion-exchanged molecular sieve ion-exchanged with at least one additional metal, which reduces the number of metal centers often present in metal promoted zeolite catalysts. Methods of making and using the catalyst composition are also provided, as well as emission treatment systems including a catalyst article coated with the catalyst composition. The catalyst article present in such emission treatment systems is useful to catalyze the reduction of nitrogen oxides in gas exhaust in the presence of a reductant while minimizing the amount of dinitrogen oxide emission.
Type:
Grant
Filed:
September 7, 2018
Date of Patent:
August 3, 2021
Assignee:
BASF Corporation
Inventors:
Wenyong Lin, Jaya Lakshmi, Xinsheng Liu, John Hochmuth
Abstract: Powder metallurgy, in particular production of tungsten monocarbide spherical powders, which is a major component of metalloceramic hard alloys used for manufacture of tools, drill bits, steel alloying, wear-resistant coating cladding at elements operating in intensive wear conditions. The method includes melting of the starting material, and melt atomization with forming of spherical powder. As starting material a tungsten monocarbide grit is used. Melting and atomization of the material is implemented by continuous filling of grit into a rotating crucible of a centrifugal atomization device under an inert atmosphere and melting it by a plasma arc. After that an annealing of the obtained powder is made at a temperature of 1200-1400° C. during a time necessary for W2C breakup with subsequent cooling of the powder in a furnace. And, the production of tungsten monocarbide spherical powder with WC content of more than 70%.
Type:
Grant
Filed:
July 21, 2017
Date of Patent:
July 27, 2021
Assignee:
HÖGANÄS AB (PUBL)
Inventors:
Ruslan Alekseevich Shevchenko, Alexander Yurievich Vakhrushin, Andrey Pavlovich Chukanov
Abstract: The present invention relates to crystalline zeolites with an ERI/CHA intergrowth framework type and to a process for making said zeolites. The ERI content of the zeolites ranges from 10 to 85 wt.-%, based on the total weight of ERI and CHA. The zeolites may further comprise 0.1 to 10 wt.-% copper, calculated as CuO, and one or more alkali and alkaline earth metal cations in an amount of 0.1 to 5 wt.-%, calculated as pure metals.
Type:
Grant
Filed:
November 16, 2017
Date of Patent:
July 27, 2021
Assignee:
Umicore AG & Co. KG
Inventors:
Sreeprasanth Pulinthanathu Sree, Stef Jules Peter Kerkhofs, Elke Jane June Verheyen, Johan Adriaan Martens, Frank-Walter Schuetze
Abstract: A xenon adsorbent capable of efficiently adsorbing xenon, even at a low concentration, from a mixture gas is Provided. A xenon adsorbent comprising a zeolite having a pore size in the range of 3.5 to 5 ? and a silica alumina molar ratio in the range of 10 to 30.
Abstract: The purpose of the present invention is to provide a metal-substituted beta zeolite that exhibits a more excellent catalytic performance than conventional one, and a method for producing the same. The present invention provides a metal-substituted beta zeolite by subjecting an alkali metal-form beta zeolite produced without using an organic structure-directing agent to ion exchange with ammonium ion and then, using a filter cake procedure, to ion exchange with copper ion or iron(II) ion. The present invention also provides a metal-substituted beta zeolite which has been ion exchanged with copper ion or iron(II) ion and in which the amount of Lewis acid sites is greater than the amount of Bronsted acid sites when the amount of Bronsted acid sites and the amount of Lewis acid sites are measured by ammonia infrared-mass spectroscopy temperature-programmed desorption on the as-produced state.
Type:
Grant
Filed:
October 25, 2018
Date of Patent:
July 20, 2021
Assignees:
Mitsui Mining & Smelting Co., Ltd., NATIONAL UNIVERSITY CORPORATION TOTTORI UNIVERSITY, NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY
Abstract: A catalyst composition for converting an alcohol to olefins, the catalyst composition comprising the following components: (a) beta zeolite; (b) at least one element selected from the group consisting of zinc, magnesium, calcium, strontium, sodium, and potassium; and (c) at least one element selected from the group consisting of hafnium, yttrium, zirconium, tantalum, niobium, and tin; wherein the components (b) and (c) are independently within or on a surface of said beta zeolite. The catalyst may also further include component (d), which is copper or silver. Also described herein is a method for converting an alcohol to one or more olefinic compounds, the method comprising contacting the alcohol with a catalyst at a temperature of at least 100° C. and up to 500° C. to result in the alcohol being converted to the one or more olefinic compounds.
Abstract: The polycrystalline cubic boron nitride contains a cubic boron nitride at a content greater than or equal to 98.5% by volume, and has an area rate S1 of crystal grains, the crystal grains having an equivalent circle diameter greater than or equal to 1 ?m, less than or equal to 20 area % at a cross section of the polycrystalline cubic boron nitride as observed with a scanning electron microscope at a magnification of 10,000.
Abstract: A coating composition for use in recycled beverage containers is disclosed. An emulsification of oil, fatty acids, a sorbitan ester and an alkoxylated alcohol is disclosed. Methods directed to using the coating composition are also disclosed.
Abstract: Disclosed are supported platinum-tin (Pt—Sn) based catalysts and methods of their use in selective light alkane dehydrogenation to corresponding alkenes and preparation. The supported catalysts contain a support of blended zeolite, in particular SAPO-34, zinc aluminate compound, and calcium aluminate, impregnated with Pt and Sn metal and a promoter that includes an alkali metal or compound thereof, an alkaline earth metal or compound thereof, or any combination thereof.
Abstract: A hydroprocessing catalyst or catalyst precursor has been developed. The catalyst is a transition metal molybdotungstate material or metal sulfides derived therefrom. The hydroprocessing using the transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.
Abstract: The invention relates to a catalyst for benzene hydroxylation for preparation of phenol and a preparation method thereof, wherein said catalyst uses a mesoporous material as carrier, and the catalyst is prepared by first modifying the surface of the carrier using aminosilane, then immersing with acetylacetonate salt of metal, and finally washing and drying. Advantage of the invention is that a reactive metal is loaded on the silane-modified mesoporous material to form a homogeneous-heterogeneous composite catalyst, wherein, the reactive metal component is present in a reaction system in a homogeneous form, which ensures high catalytic performance of the catalyst component, and it is loaded on the carrier through bridging action of aminosilane, which improves the acting force between the metal component and the carrier, enhances stability of the catalyst, and facilitates separation of the catalyst from the product.
Abstract: A method of making a multifunctional catalyst for upgrading pyrolysis oil includes contacting a zeolite support with a solution including at least a first metal catalyst precursor and a second metal catalyst precursor, the first metal catalyst precursor, the second metal catalyst precursor, or both, including a heteropolyacid. Contacting the zeolite support with the solution deposits or adsorbs the first metal catalyst precursor and the second catalyst precursor onto outer surfaces and pore surfaces of the zeolite support to produce a multifunctional catalyst precursor. The method further includes removing excess solution from the multifunctional catalyst precursor and calcining the multifunctional catalyst precursor to produce the multifunctional catalyst comprising at least a first metal catalyst and a second metal catalyst deposited on the outer surfaces and pore surfaces of the zeolite support.
Abstract: Disclosed herein are compositions including aluminosilicate zeolite crystals with an 8 ring pore size having a depth dependent silica to alumina molar ratio and processes of making aluminosilicate zeolite crystals with an 8 ring pore size having a depth dependent silica to alumina molar ratio.
Type:
Grant
Filed:
April 2, 2019
Date of Patent:
June 1, 2021
Assignee:
BASF Corporation
Inventors:
Eduard L Kunkes, Ahmad Moini, Martitza I. Ortega
Abstract: In a vanadium nitride film formed on a surface of a base material, a ratio V [at %]/N [at %] between a vanadium element concentration and a nitrogen element concentration in the film is 1.08 or more and a chlorine element concentration in the film is 1 at % or more and 5 at % or less.
Abstract: A catalyst for synthesizing aromatic hydrocarbons, a preparation method thereof and a method for synthesizing aromatic hydrocarbons by using the catalyst. The catalyst comprises acidic molecular sieve particles and zinc-aluminum composite oxide particles. The catalyst has relatively high selectivity to aromatic hydrocarbons, particularly BTX, stable performance, and a long single-pass life.
Type:
Grant
Filed:
August 22, 2017
Date of Patent:
May 25, 2021
Assignee:
Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Abstract: The present disclosure relates to a molecular sieve, preparation thereof and acoustic absorption material and speaker containing the same. The molecular sieve having an MFI-structure, comprising a framework and an off-framework cation, wherein the framework comprises SiO2 and a metal oxide MxOy with M comprising boron, gallium or aluminium; the off-framework cation is at least one of hydrogen ion, alkali metal ion and alkaline earth metal ion. The molecular herein can effectively prevent the failure of the molecular sieve and improve the performance stability of the speaker.
Type:
Grant
Filed:
December 30, 2018
Date of Patent:
May 25, 2021
Assignee:
AAC Technologies Pte. Ltd.
Inventors:
Kun Tang, Hezhi Wang, Hongshu Feng, Guochuang Huang