Abstract: Provided are a pentasil-type zeolite that is less likely to adsorb water compared to conventional zeolites and has excellent strength when used as a molded body, and a method for producing the pentasil-type zeolite. A pentasil-type zeolite having a water adsorption amount of 4.0 g/100 g-zeolite or less under the conditions of 25° C. and a relative humidity of 90% and having a major axis diameter of primary particles of from 0.2 ?m to 4.0 ?m, and a method for producing the pentasil-type zeolite.
Type:
Grant
Filed:
October 18, 2019
Date of Patent:
September 12, 2023
Assignee:
TOSOH CORPORATION
Inventors:
Hidenori Yamada, Hiroshi Okaniwa, Satoshi Yoshida
Abstract: The present disclosure relates to the preparation of pyridine derivatives, such as ?-picoline or ?-parvoline, and catalysts useful for the selective preparation of such pyridine derivatives. Particularly, the present disclosure relates to the selective preparation of certain pyridine derivative using dealuminated zeolite catalysts.
Type:
Grant
Filed:
November 1, 2018
Date of Patent:
September 12, 2023
Assignee:
VERTELLUS HOLDINGS LLC
Inventors:
Colin H. McAteer, Mirza S. Baig, Kayla L. Powell, James W. Shogren-Harris, Rajamani Gounder
Abstract: Embodiments of the present disclosure are directed to hydrocracking catalysts and methods of making same. The hydrocracking catalyst comprises a platinum encapsulated zeolite having a crystallinity greater than 20% determined by X-ray powder diffraction analysis.
Abstract: The invention relates to a molecular sieve composition, a process of preparing same and use thereof in the production of lower olefins. The molecular sieve composition comprises an aluminophosphate molecular sieve and a CO adsorbing component, both of which are present independently of each other. When the molecular sieve composition is used as a catalyst for producing lower olefins using synthesis gas as a raw material, the molecular sieve composition has the advantages of high selectivity to lower olefins and the like.
Type:
Grant
Filed:
October 23, 2018
Date of Patent:
August 29, 2023
Assignees:
CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC
Inventors:
Yangdong Wang, Haibo Zhou, Weimin Yang, Su Liu, Chang Liu, Yu Zhao, Hongxing Liu, Xian Lu
Abstract: A fluid catalytic cracking catalyst for hydrocarbon oil that is a blend of two types of fluid catalytic cracking catalysts each of which has a different hydrogen transfer reaction activity or has a pore distribution within a specific range after being pseudo-equilibrated. One catalyst is a catalyst containing a zeolite and matrix components, and the other catalyst is a catalyst containing a zeolite and matrix components. This catalyst is composed of the one catalyst and the other catalyst blended at a mass ratio within a range of 10:90 to 90:10.
Abstract: The present disclosure recognizes a correlation between zeolitic surface area (ZSA) of a catalyst composition and its catalytic activity. Particularly, the disclosure provides catalyst articles for diesel NOx abatement, including a substrate and a washcoat layer containing metal-promoted molecular sieves, wherein the zeolitic surface area (ZSA) of the catalyst article is about 100 m2/g or greater, the volumetric surface area is about 900 m2/in3 or greater, and/or the total zeolitic surface area (tZSA) is about 1200 m2 or greater. The disclosure further relates to methods for evaluating ZSA, volumetric ZSA, and tZSA, e.g.
Type:
Grant
Filed:
June 8, 2018
Date of Patent:
August 8, 2023
Assignee:
BASF CORPORATION
Inventors:
Ivan Petrovic, Jaya L. Mohanan, Joseph J. Petenko
Abstract: The invention relates to a catalyst which comprises: a) a mixed metal oxide of molybdenum, vanadium, niobium and optionally tellurium; and b) ceria particles having a crystallite size greater than 15 nanometers (nm); wherein the amount of the ceria particles, based on the total amount of the catalyst, is of from 1 to 60 wt. %. Further, the invention relates to a process for preparing a catalyst, which comprises mixing a mixed metal oxide of molybdenum, vanadium, niobium and optionally tellurium with ceria particles having a crystallite size greater than 15 nanometers (nm), wherein the amount of the ceria particles, based on the total amount of the catalyst, is of from 1 to 60 wt. %. Still further, the invention relates to an alkane oxidative dehydrogenation and/or alkene oxidation process wherein such catalyst is used.
Type:
Grant
Filed:
July 20, 2017
Date of Patent:
July 25, 2023
Assignee:
SHELL USA, INC.
Inventors:
Hendrik Albertus Colijn, Michael Johannes Franciscus Maria Verhaak
Abstract: This exhaust gas purifying catalyst is provided with a substrate and a catalyst layer formed on a surface of the substrate. The catalyst layer contains zeolite particles that support a metal, and a rare earth element-containing compound that contains a rare earth element. The rare earth element-containing compound is added in such an amount that the molar ratio of the rare earth element relative to Si contained in the zeolite is 0.001 to 0.014 in terms of oxides.
Type:
Grant
Filed:
October 26, 2021
Date of Patent:
July 18, 2023
Assignee:
Cataler Corporation
Inventors:
Shu Miyasaka, Eriko Tanaka, Norihiko Aono, Mai Huong Tran, Keigo Hori, Daisuke Sugioka
Abstract: The present disclosure relates to a process for converting one or more methyl halides to acyclic C3-C6 olefins, said process comprising the steps of (a) providing a feedstream comprising one or more methyl halides; (b) providing a catalyst composition; and (c) contacting said feedstream with said catalyst composition under reaction conditions. The process is remarkable in that said reaction conditions include a reaction temperature below 400° C., and in that said catalyst composition comprises one or more molecular sieves with a Si/Al atomic ratio ranging from 2 to 18 and wherein said one or more molecular sieves comprise a plurality of pores, wherein said pores have a shape of an 8-membered ring or less.
Type:
Grant
Filed:
November 20, 2020
Date of Patent:
July 4, 2023
Assignees:
TOTALENERGIES ONETECH, SULZER MANAGEMENT AG
Inventors:
Nikolai Nesterenko, Gleb Veryasov, Raoul Dethier
Abstract: A process for the production of an aromatic compound which comprise reacting a mixture comprising ethylene and a furan compound over a zeolitic material having a BEA-type framework structure is described, wherein the zeolitic material having a BEA-type framework structure comprised in the catalyst is obtainable and/or obtained according to an organotemplate-free synthetic process.
Abstract: To provide a highly active structured catalyst for methanol reforming that suppresses the decline in catalytic function and has excellent catalytic function, and a methanol reforming device. A structured catalyst for methanol reforming, including: a support of a porous structure composed of a zeolite-type compound; and a catalytic substance present in the support, in which the support has channels communicating with each other, and the catalytic substance is present at least in the channels of the support.
Abstract: A family of new crystalline molecular sieves designated SSZ-91 is disclosed, as are methods for making SSZ-91 and uses for SSZ-91. Molecular sieve SSZ-91 is structurally similar to sieves falling within the ZSM-48 family of molecular sieves, and is characterized as: (1) having a low degree of faulting, (2) a low aspect ratio that inhibits hydrocracking as compared to conventional ZSM-48 materials having an aspect ratio of greater than 8, and (3) is substantially phase pure.
Type:
Grant
Filed:
May 11, 2021
Date of Patent:
June 20, 2023
Assignee:
CHEVRON U.S.A. INC.
Inventors:
Adeola Florence Ojo, Dan Xie, Yihua Zhang, Guan-Dao Lei
Abstract: A method for preparing a molecular sieve SCR (selective catalytic reduction) catalyst and a prepared catalyst therethrough. In the method, several molecular sieves are mixed and modified by transition metal or rare-earth metal via ion exchange, then loaded Fe by equivalent-volume impregnation, and loaded Cu by one or more liquid ion exchange. This present invention, combined with several techniques, such as modification of stable molecular sieve by transition and rare-earth metal, Fe loading by equivalent-volume impregnation and Cu loading by one or more liquid ion exchange, and after through stable and effective modification and loading control, the obtained catalyst material is coated on a carrier substrate via size mixing and coating process to be prepared into an integral catalyst.
Abstract: The present invention relates to a method for the preparation of a molecular sieve of the CHA-type as well as catalytic applications thereof.
Type:
Grant
Filed:
August 23, 2019
Date of Patent:
June 6, 2023
Assignee:
Umicore AG & Co. KG
Inventors:
Peter Nicolai Ravnborg Vennestrom, Nuria Martin Garcia, Manuel Moliner Marin, Avelino Corma Canos
Abstract: The invention includes an additive for maximizing production of olefins. The additive comprises a ZSM-5 molecular sieve, at least one inorganic oxide, and phosphorus oxide. The ZSM-5 molecular sieve has iron in the framework, and the additive comprises at least 0.5 weight percent iron, as measured as iron oxide, in the molecular sieve framework. The additive is useful for maximizing production of olefins in a FCC process.
Type:
Grant
Filed:
September 22, 2021
Date of Patent:
June 6, 2023
Assignee:
Johnson Matthey Process Technologies, Inc.
Inventors:
Mehdi Allahverdi, Paul Diddams, Charles Kanyi
Abstract: A method of removing one or more antibiotics from a dairy product, the method involve passing the dairy product comprising an antibiotic in a first amount through a bulk comprising, relative to a total bulk weight, at least 75 wt. % of titanium oxide nanostructures, to provide the dairy product comprising the antibiotic in a second, lesser amount, wherein the nanostructures have lengths at least two-fold in excess of their width and height. Bulk materials useful in this or related methods or applications may have loosely tangled, noodle-like morphologies on sub-100 nm scale, and need not employ graphene and/or polymeric support networks in columns, generally having only titanium oxides without silicon or iron oxides.
Type:
Grant
Filed:
October 21, 2022
Date of Patent:
May 30, 2023
Assignee:
Imam Abdulrahman Bin Faisal University
Inventors:
Hafedh Kochkar, Nuhad Abdullah Alomair, Reem Khalid Albilali, Suhailah Saud Aljameel
Abstract: A method of removing one or more antibiotics from a dairy product, the method involve passing the dairy product comprising an antibiotic in a first amount through a bulk comprising, relative to a total bulk weight, at least 75 wt. % of titanium oxide nanostructures, to provide the dairy product comprising the antibiotic in a second, lesser amount, wherein the nanostructures have lengths at least two-fold in excess of their width and height. Bulk materials useful in this or related methods or applications may have loosely tangled, noodle-like morphologies on sub-100 nm scale, and need not employ graphene and/or polymeric support networks in columns, generally having only titanium oxides without silicon or iron oxides.
Type:
Grant
Filed:
October 21, 2022
Date of Patent:
May 30, 2023
Assignee:
Imam Abdulrahman Bin Faisal University
Inventors:
Hafedh Kochkar, Nuhad Abdullah Alomair, Reem Khalid Albilali, Suhailah Saud Aljameel
Abstract: Disclosed are a catalyst and a preparation method therefor, the catalyst being able to maintain a high production yield of C8 aromatic hydrocarbons in the process of converting a feedstock containing alkyl aromatics to C8 aromatic hydrocarbons such as mixed xylene through disproportionation/transalkylation/dealkylation while reducing a content of ethylbenzene in the products.
Type:
Grant
Filed:
October 29, 2020
Date of Patent:
May 30, 2023
Assignee:
SK Innovation Co., Ltd.
Inventors:
Sang Il Lee, Ji Hoon Lee, Young Eun Cheon, Yeon Ho Kim
Abstract: The method for manufacturing a modified aluminosilicate includes a first step of treating an aluminosilicate with an acid, a second step of primarily calcining the treated material obtained in the first step at 550° C. to 850° C., and a third step of contacting the calcined material obtained in the second step with a liquid containing one or more Group 4 elements and/or Group 5 elements, and then drying and secondarily calcining the resultant. The modified aluminosilicate includes one or more Group 4 elements and/or Group 5 elements, and exhibits an absorbance at 300 nm in an ultraviolet visible spectrum of 1.0 or higher. The method for manufacturing aromatic dihydroxy compounds includes reacting a phenol with hydrogen peroxide in the presence of a specific modified aluminosilicate.
Abstract: To provide a structured catalyst for catalytic cracking or hydrodesulfurization that suppresses decline in catalytic activity, achieves efficient catalytic cracking, and allows simple and stable obtaining of a substance to be modified. The structured catalyst for catalytic cracking or hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound and at least one type of metal oxide nanoparticles (20) present in the support (10), in which the support (10) has channels (11) that connect with each other, the metal oxide nanoparticles (20) are present at least in the channels (11) of the support (10), and the metal oxide nanoparticles (20) are composed of a material containing any one or two more of the oxides of Fe, Al, Zn, Zr, Cu, Co, Ni, Ce, Nb, Ti, Mo, V, Cr, Pd, and Ru.