Abstract: The purpose of the present invention is to provide an extreme pressure agent which does not contain any metal element or the like and is highly safe but which exhibits performance equivalent to those of conventional extreme pressure agents each containing a metal element or the like when used in lubrication purposes. This extreme pressure agent comprises a copolymer (A) which comprises an alkyl acrylate (a) represented by general formula (1) and a hydroxyalkyl acrylate (b) represented by general formula (2) as the essential constituent monomers, and is characterized in that the reaction ratio of the component (a) to the component (b) (i.e., (a)/(b)) is 50/50 to 80/20 (by mole) and the copolymer (A) has a weight average molecular weight of 40,000-150,000. (In formula (1), R1 represents an alkyl group having 10-18 carbon atoms.) (In formula (2), R2 represents an alkylene group having 2-4 carbon atoms.
Abstract: An overbased calcium sulfonate grease composition comprising a reduced amount of overbased calcium sulfonate, added calcium carbonate, base oil, one or more converting agents, and one or more complexing acids if a complex grease is desired. The calcium sulfonate grease composition improves thickener yield and expected high temperature utility as demonstrated by dropping point. The calcium carbonate may be used to react with complexing acids when making a complex grease, such that the addition of calcium oxide or calcium hydroxide is not required. A method of making the composition comprising the steps of mixing the overbased calcium sulfonate and base oil, adding the calcium carbonate, adding one or more converting agents, and adding one or more complexing acids. All or a portion of one or more of the complexing acids may be added with or prior to the one or more converting agents.
Abstract: A lubricating composition comprising an oil of lubricating viscosity, 1 to 1000 parts per million by weight of titanium in the form of an oil-soluble titanium-containing material, and at least one additional lubricant additive provides beneficial effects on properties such as deposit control, oxidation, and filterability in engine oils.
Type:
Grant
Filed:
February 28, 2011
Date of Patent:
February 2, 2016
Assignee:
The Lubrizol Corporation
Inventors:
Mark C. Davies, Virginia A. Carrick, Jody A. Kocsis, Patrick E. Mosier, Matthew D. Gieselman, John K. Pudelski, Brent R. Dohner, Jonathan S. Vilardo
Abstract: The invention provides a lubricating composition containing a lubricating composition comprising an oil of lubricating viscosity and a polyester. The invention further relates to a method of lubricating a mechanical device (such as an internal combustion engine) with the lubricating composition. The invention further relates to the use of the polyester as a dispersant.
Abstract: A method of preparing a lubricating oil additive composition comprising reacting (A) a nitrogen-containing reactant derived from reacting a first reaction product with a triglyceride, wherein the first reaction product is derived by reacting an alkanolamine and a base, wherein the nitrogen-containing reactant comprises three equivalents of a nitrogen-containing compound and one equivalent of glycerol, and wherein the nitrogen-containing reactant contains less than 10 mass percent of glycerol alkyl ester; (B) a source of boron; and (C) glycerol.
Type:
Grant
Filed:
October 30, 2012
Date of Patent:
January 5, 2016
Assignee:
Chevron Oronite Company LLC
Inventors:
Yat Fan Suen, Jennifer Elizabeth Newell
Abstract: The present invention provides a lubricating composition for use in the crankcase of an engine comprising a base oil and one or more additives, wherein the base oil comprises a Fischer-Tropsch derived base oil and wherein the lubricating composition has a kinematic viscosity at 100 C (according to ASTM D 445} of below 5.6 cSt and a Noack volatility (according to ASTM D 5800) of below 15 wt. %.
Type:
Grant
Filed:
June 23, 2010
Date of Patent:
December 29, 2015
Assignee:
Shell Oil Company
Inventors:
Simon William Dunning, David John Wedlock
Abstract: The present invention relates to a low viscosity lubricant process, product, and composition characterized by low Noack volatility, low pour point, useful low temperature viscometrics, and high viscosity index and more particularly concerns a PAO composition having a kinetic viscosity at 100° C. in the range of about 4 cSt.
Type:
Grant
Filed:
March 28, 2013
Date of Patent:
December 8, 2015
Assignee:
INEOS USA LLC
Inventors:
Vahid Bagheri, Lionel D. Moore, Peter M. DiGiacinto, Michel Sanchezrivas
Abstract: A method is provided to determine the predisposition of a polymer to form network or gel in a lubricating oil which comprises obtaining a composition of a polymer in a diluent, measuring the shear stress as a function of shear rate, determining the yield stress using the Herschel-Bulkley equation and assessing the yield stress. A method is also provided to determine the predisposition of a polymer to form network or gel in a lubricating oil which comprises obtaining a composition of a polymer in a diluent, determining at least one of (i) the storage modulus G? and loss modulus G? of the composition by subjecting the composition to sinusoidal (oscillating) stress or strain of certain amplitude and frequency, (ii) the phase lag (angle) of the response strain or stress ?, or (iii) the tangent (tan) ?, and (c) assessing at least one of the G?, G?, ?, or tan(?) determined.
Type:
Grant
Filed:
September 6, 2012
Date of Patent:
December 1, 2015
Assignees:
ExxonMobil Chemical Patents Inc., Chevron Oronite Company LLC
Inventors:
Rainer Kolb, Sudhin Datta, Pritesh A. Patel, Kirk A. Nass
Abstract: Provided are ethylene-based copolymers, methods of preparing the same, lubricating oil compositions including the same, methods for preparing such lubricating oil compositions, and end uses for such ethylene-based copolymers and lubricating oil compositions. The ethylene-based copolymers may include from about 35 wt. % to about 60 wt. % of units derived from ethylene and at least 1.0 wt. % of one or more alpha-olefin comonomers having 3 to 20 carbon atoms. The ethylene-based copolymers are substantially amorphous and have a polydispersity index of about 2.8 or less.
Type:
Grant
Filed:
October 12, 2012
Date of Patent:
November 3, 2015
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Rainer Kolb, Sudhin Datta, Liehpao O. Farng, Vera Minak-Bernero, Eric B. Sirota, Thomas T. Sun, Mun-Fu Tse
Abstract: Disclosed herein is a composition comprising an organic polymer and about 2 to about 10 weight percent of an ionic liquid. The ionic liquid can be a halogenated or non-halogenated ionic liquid. Disclosed herein too are articles manufactured from the composition.
Abstract: An additive for lubricating oil of the present invention contains an amide compound represented by the following general formula (1). A lubricating oil composition of the present invention contains: a lubricating base oil containing a mineral base oil and/or a synthetic base oil; and an amide compound represented by the following general formula (1). R1R2N—COCH2OH??(1) (In the general formula (1), R1 and R2 may be the same or different and each represents an alkyl group having 16 to 22 carbon atoms.
Abstract: An operable transmission comprising toothed wheels. In order to operate the transmission with a lubricant and coolant which is environmentally friendly while providing improved heat dissipation and temperature-independent viscosity, the transmission contains a mixture of water and a glycol or similar, in which graphite particles are suspended. The mixture contains 40 to 60 percent per weight of the glycol and 2 to 25 percent by weight of graphite in the form of flaky graphite particles having a grain size of less than 12 micrometers, the remainder being composed of water and other admixtures and/or additives. Also disclosed are the lubricant and coolant as well as a method for starting a transmission operated with the lubricant and coolant.
Abstract: Provided are processes for making polymer compositions, especially those with reduced or no gel formation in lubricating oils as identified by rheological and visual gel tests and which are useful as viscosity modifiers. The processes described herein aim to achieve this objective by adjusting the concentrations of the hydrogen feed(s) in the first and/or second polymerization reaction zones, preferably such that (a) the hydrogen feed concentration in the first polymerization reaction zone is 0.0-1.0 wt %, based on total weight of feed(s) of hydrogen, ethylene monomer, ?-olefin comonomer, and solvent into the first polymerization reaction zone, and/or (b) the hydrogen feed concentration in the second polymerization reaction zone is 0.0-0.5 wt %, based on total weight of feed(s) of hydrogen, ethylene monomer, ?-olefin comonomer, and solvent into the second polymerization reaction zone.
Type:
Grant
Filed:
February 3, 2012
Date of Patent:
September 22, 2015
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Rainer Kolb, Phillip T. Matsunaga, Periagaram S. Ravishankar, Lisa B. Stefaniak, Quintin Paul Ward Costin
Abstract: Polymers suitable for use as a viscosity index improver for lubricating oil compositions including linear polymers characterized by the formula: D?-PA-D?; and star polymers characterized by the formula: (D?-PA-D?)n-X; wherein D? represents an “outer” block derived from diene having a number average molecular weight of from about 10,000 to about 120,000 daltons; PA represents a block derived from monoalkenyl arene having a number average molecular weight of from about 10,000 to about 50,000 daltons; D? represents an inner random derived from diene having a number average molecular weight of from about 5,000 to about 60,000 daltons; n represents the average number of arms per star polymer formed by the reaction of 2 or more moles of a polyalkenyl coupling agent per mole of arms; and X represents a nucleus of a polyalkenyl coupling agent.
Abstract: Polymer compositions for use as viscosity modifiers comprising at least two ethylene-based copolymer components are provided. The polymer composition comprises (a) a first ethylene-?-olefin copolymer and (b) a second ethylene-?-olefin copolymer. The first ethylene-?-olefin copolymer (a) has an ethylene content from about 60 to about 80 wt % and the second ethylene-?-olefin copolymer (b) has an ethylene content of less than about 60 wt %. The first ethylene-?-olefin copolymer (a) has a Melt Flow Rate Ratio (MFRR), defined as the ratio of the MFR measured at 230° C./21.6 kg and at 230° C./2.16 kg, of greater than 30 and optionally also has a Melt Flow Rate (MFR) of at least about 1.5 g/10 min, measured by ASTM D 1238 condition L (230° C./2.16 kg). The present disclosure is also directed to lubricant compositions comprising a lubricating basestock and a polymer composition of the present disclosure and is further directed to reducing gelation in the lubricant compositions.
Type:
Grant
Filed:
February 3, 2012
Date of Patent:
September 8, 2015
Assignees:
ExxonMobil Chemical Patents Inc., Chevron Oronite Company LLC
Inventors:
Phillip T. Matsunaga, Kirk A. Nass, Pritesh A. Patel, Rainer Kolb, Sudhin Datta
Abstract: A trunk piston engine lubricating oil composition comprising (a) a major amount of a base stock comprising at least 90% by weight saturated hydrocarbons; and (b) a minor amount of a base oil having a viscosity index of less than 70 and a cycloaliphatic hydrocarbon content of at least about 25 wt. % is disclosed.
Abstract: A grease composition for use in resin lubrication wherein at least one amine salt of an unsaturated or saturated fatty acid is incorporated in a grease base material which includes a base oil and a thickener, preferably wherein at least one fatty acid amine salt of the following general formula (1) is incorporated: RCOO? R? NH3+ wherein either (i) R is an unsaturated hydrocarbon group having from 15 to 21 carbon atoms, and R? is a saturated or unsaturated linear or branched hydrocarbon group having from 8 to 22 carbon atoms; or (ii) R is a linear saturated hydrocarbon group having from 5 to 21 carbon atoms, and R? is an unsaturated hydrocarbon group having from 16 to 18 carbon atoms. The grease composition of the present invention improves the lubricity between resin and resin or resin. and another material such as a metal.
Abstract: A process for detecting oil or lubricant contamination in the production of an article by adding a Stokes-shifting taggant to an oil or lubricant of a machine utilized to produce the article or a component thereof, irradiating the articles produced with a first wavelength of radiation, and monitoring the articles for emission of radiation at a second wavelength. The taggant can be in the form of a composition containing a Stokes-shifting taggant, which absorbs radiation at a first wavelength and emits radiation at a second wavelength, different from said first wavelength, dissolved or dispersed in an oil or lubricant.
Abstract: A lubricant composition suitable for lubricating an internal combustion engine comprises: (a) an oil of lubricating viscosity having a viscosity index of at least 105 and a kinematic viscosity at 100 C of less than 7 mm2s-1; (b) 0.01 to 2 weight percent of a friction modifier represented by the structure [I]; (c) 0.5 to 4 weight percent of a poly(meth)acrylate viscosity modifier polymer; (d) 0 to 500 parts per million by weight of molybdenum in the form of an oil-soluble molybdenum compound; and (e) 0 to 200 parts per million by weight of boron in the form of an oil-soluble boron compound.
Type:
Grant
Filed:
June 2, 2010
Date of Patent:
June 9, 2015
Assignee:
The Lubrizol Corporation
Inventors:
Jody A. Kocsis, Brent R. Dohner, Haihu Qin, Marina Baum
Abstract: The invention relates to a lubricant in the form of grease or thick lubricating gel or transmission oil, as well as motor or universal oils with a myriad of applications. As a result of its contents presented in the patent application is characteristic of low coefficient of friction ranging from 0.055 to 0.062. As the main component, the contents of the discussed lubricant includes three or four stearates of metals or hydroxistearates of metals, which interact and cause a noticeable reduction of friction drag on the lubricated surfaces. Additionally, these substances may include a number of other solid or liquid elements, which maintain low friction drags and, furthermore, improve the lubricant through increasing its load capacity, antirust characteristics, shear strength, etc.