Abstract: Acidic stripping solutions comprising hydrogen peroxide as oxidant, either at least one phosphorous-oxy acid, or the addition of nitric acid, together with accelerators and surface active agents, are effective for the rapid and selective removal of protective hard surface coatings and nickel-base brazes from a variety of metal surfaces.
Abstract: Disclosed is a process for ammoxidation of paraffins containing 2-5 C atoms over a vanadium-antimony oxide catalyst, the catalyst, and a precursor slurry for making such catalyst.
Type:
Grant
Filed:
April 17, 1985
Date of Patent:
May 24, 1988
Assignee:
Standard Oil Company
Inventors:
Andrew T. Guttmann, Robert K. Grasselli, James F. Brazdil
Abstract: A process for upgrading diesel oil comprising the steps of:(1) reacting the diesel oil with a nitrogenous treating agent;(2) contacting the diesel oil from step (1) above with(a) a primary solvent selected from the group consisting of organic solvents having a dipole moment of about 1.
Abstract: Gypsum is calcined by contacting it with the hot gases spewing out of a combustion tube submerged in the mass of gypsum. The formation of dead-burned anhydrite is reduced by surrounding the combustion tube with a second tube called a draft tube. Gypsum passing through the annulus between the tubes is heated by the hot gases and is ejected from the annulus to prevent repeated excursions into the hot gas zone at the muzzle of the combustion tube.
Abstract: A system for adding and withdrawing solids to a high pressure reactor wherein there is provided improved control of flow and concentrations of a slurry of solids in a transport oil for introducing and withdrawing solids from the reactor. In addition, there is provided for improved heating and cooling of the solids.
Type:
Grant
Filed:
December 20, 1985
Date of Patent:
May 17, 1988
Assignee:
Lummus Crest Inc.
Inventors:
Roger P. Van Driesen, William R. Adams, Mario Baldasarri, John Caspers, Harold Trimble
Abstract: A regeneration zone for fluid catalytic cracking contains ammonia (NH.sub.3) when the regeneration zone is operated in a partial combustion mode as defined by a content of CO of between 1 and 6 percent by volume. If the ammonia is not removed from the regeneration zone off gass, the same will be passed to a CO combustion zone where, in the presence of oxygen, CO is oxidized to CO.sub.2 and some of the ammonia will undesirably be oxidized to NO.sub.x. This invention reduces the presence of ammonia in the feed gas to a CO combustion zone of an FCC process by the introduction of a NO.sub.x -containing gas to dilute phase of a regeneration zone or to a regeneration zone off gas. Ammonia, NO.sub.x and oxygen present in the regeneration zone off gas of the regeneration zone, will tend to react to produce nitrogen and water vapor, which then is passed to the CO combustion zone for CO oxidation to CO.sub.2. Where the addition of NO.sub.x is made at temperatures greater than 1700.degree. F.
Type:
Grant
Filed:
July 22, 1987
Date of Patent:
May 17, 1988
Assignee:
Shell Oil Company
Inventors:
Gregory L. Johnson, Norman C. Samish, Diana M. Altrichter
Abstract: Hydrodynamic pumping of the fluidized calcining mass in a kettle is set up by the continuous flow of the mass to and from heating rods immersed therein which are constantly emitting at least about 1 British Thermal Unit of heat per minute per square inch of the surface of the rods. The transfer of heat from the walls and bottom of the kettle is enhanced so that more of the available heat is actually absorbed than in a kettle lacking such heating rods. The rate of calcination may be increased while the rate of heat input is decreased.
Type:
Grant
Filed:
August 14, 1986
Date of Patent:
May 17, 1988
Assignee:
United States Gypsum Company
Inventors:
Otto L. Dozsa, Donald R. Janninck, Richard F. Stone, Larbi Bounini
Abstract: Catalytic cracking catalysts, the process of their preparation and the process of their use. Cracking catalysts are disclosed for improving the octane number of gasoline products. The catalysts comprise a zeolitic aluminosilicate having a mole ratio of oxides in the dehydrated state of(0.85-1.1) M.sub.2/n O:Al.sub.2 O.sub.3 :xSiO.sub.2wherein M is a cation having a valence of "n" and "x" has a value greater than 6.0 to about 11.0; has an x-ray powder diffraction pattern having at least the d-spacings of Table A; has extraneous silicon atoms in the crystal lattice in the form of framework SiO.sub.4 tetrahedra; has between greater than zero to less than 5.0 percent by weight, expressed as the oxide, of at least one rare earth cation selected from the group consisting of cerium, lanthanum, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium; and less than 1.2 weight percent Na.sub.
Abstract: A simpler and new process for the polycondensation of a sulfonated coal tar fraction comprising: sulfonating a coal tar fraction having a distillation range of 200.degree. to 240.degree. at normal pressure, with an excess of 20-30% mole of sulfuric acid, as opposed to 105% in the prior art, for 4-8 hours at a temperature of 160.degree. C..+-.10.degree. C. under reflux. The product is diluted with water to render it fluid at about 80.degree. C. and molar ratio of formaldehyde per mole of the sulfonated coal tar fraction is then added gradually at a temperature of about 85.degree. C..+-.5.degree. C., then gradually heated for about 1 to 4 hours at 100.degree. to 106.degree. C., and then further raised to 106.degree. C.-120.degree. C. for 2 to 4 hours. The product is then cooled and neutralized. With this process, new polycondensates with improved properties are produced. The polycondensation including neutralization is completed within 16 hours from the time the formaldehyde is added.
Abstract: The present invention relates to the coproduction of a combustible feed gas stream useable as an energy source and a sulfur-containing second gas stream useable as a feedstock for the production of sulfuric acid. The process includes heating coal in the presence of an oxygen-lean atmosphere under partial coal gasifying conditions to produce a solid carbonaceous char and a crude coal-gas stream. Sulfur-containing compounds are removed from the coal gas stream and converted to solid sulfur-containing materials. The solid sulfur-containing materials are combined with the solid carbonaceous char and gypsum to form a feed mixture. The non-gypsum portion of the feed mixture contains sufficient reducing potential to release substantially all of the sulfur in the gypsum as gaseous compounds of sulfur in a +4 or lower oxidation state. The feed mixture is heated under reducing conditions to produce a sulfur-containing second gas stream and a solid sintered product.
Abstract: This invention relates to a novel stabilized aqueous hydrogen peroxide solution which comprises hydrogen peroxide in admixture with an aromatic polysulfonic acid, or a salt thereof.
Abstract: We disclose a catalyst system which is capable of removing sodium from a hydrocarbon feed having at least 1 ppm oil-soluble sodium. It comprises a catalyst layer characterized as a fixed bed of catalyst particles having a low volume percent of their pore volume percent in the form of macropores above 1000 .ANG. in diameter, high surface area, and high hydrogenation activity. We also disclose a process of using the system.
Abstract: Full-range shale oils or fractions thereof, after hydrotreating, or hydrowaxed and then hydrogenated to produce lubricating oil fractions boiling above 650.degree. F., having a pour point at or below +10.degree. F., and a viscosity index of at least 95. In the preferred operation, the hydrogenation is effected with a noble metal-containing catalyst wherein the noble metal is dispersed by cation exchange into a carrier comprising a silica-alumina cogel or copolymer dispersed in a large pore alumina gel matrix. It has been found with shale oils that the hydrogenation in the preferred embodiment also results in hydrocracking of some of the polynaphthenic compounds.
Abstract: A waxy hydrocarbon feedstock is converted into a high quality lube oil stock of reduced pour point by hydrodewaxing the feedstock in the presence of molecular hydrogen and a hydrodewaxing catalyst under conditions such that the pour point of the feedstock is reduced by selectively converting waxy paraffins into lower molecular weight hydrocarbons. At least a portion of the effluent from the hydrodewaxing zone is then passed to a hydrocracking zone where it is contacted with a hydrocracking catalyst under conditions such that a further reduction in pour point is effected and the overall conversion of components boiling above about 650.degree. F. to components boiling at or below about 650.degree. F. in the hydrodewaxing and hydrocracking steps combined is no more than about 20 percent by volume, preferably no more than about 10 percent by volume.
Abstract: A process for removing the basic nitrogen compounds from gas oils comprises treating the gas oils with a homogeneous solvent mixture comprising a diluted aqueous acid solution and an alcohol having from 1 to 6 carbon atoms, the volume ratio of alcohol to diluted aqueous acid solution being between 90/10 and 10/90, the volume ratio of solvent mixture to gas oils being between 0.5 and 5.
Type:
Grant
Filed:
October 23, 1986
Date of Patent:
May 10, 1988
Assignee:
Labofina, S.A.
Inventors:
Michel Melin, Jacques F. Grootjans, Andre Vanderlinden
Abstract: A process for separating a C.sub.10 aromatic isomer, particularly paradiethylbenzene, from a feedstream containing a mixture of C.sub.10 aromatic isomers by contacting the feedstream with a bed of the adsorbent zeolite beta. The adsorbed C.sub.10 aromatic isomer is removed from the adsorbent by desorption.
Type:
Grant
Filed:
March 24, 1986
Date of Patent:
May 10, 1988
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Daniel D. Rosenfeld, Lawrence G. Daniel
Abstract: Resid hydrotreating conversion of resid can be substantially increased by decreasing the feed gas rate and simultaneously increasing the concentration of hydrogen in the feed gases. Hydrogen purity can be increased by increasing the flow rate of lean sponge oil into the sponge oil absorbers, bleeding some of the recycled reactor tail gases, and increasing the makeup gas rate.
Type:
Grant
Filed:
September 24, 1986
Date of Patent:
May 10, 1988
Assignee:
Amoco Corporation
Inventors:
David J. Soderberg, Norman K. McDaniel, Norman R. Woods
Abstract: Sugar cane is processed using an apparatus, which includes an input end with a comb back conveyor for controlling the quantity of cane passing to the remainder of the apparatus; an aligning; first cleaning and thin out section, where randomly oriented cane stalks are aligned and foreign bodies, especially stones and ferrous objects are removed from the cane; a billeting or cutting section for cutting the stalks into billets; a second cleaning section in the form of a cleaning tower in which vertically moving air is used to remove leaves, dust and any other trash from the flow of cane; a chute and pivotally mounted swing conveyor for distributing cane billets in an elongated, partitioned distributing hopper; a surge elimination chute; a billet aligner and delivery unit for delivering cane billets to a plurality of separators for separating the epidermis from the cane billets and separating the rind from the core; and a discharge section, including conveyors for discharging the separated material from the appar
Abstract: A waxy hydrocarbon feedstock is converted into a product hydrocarbon of reduced normal paraffin content by either dewaxing or hydrodewaxing the feedstock in the presence a dewaxing or hydrodewaxing catalyst under conditions such that the normal paraffin content of the feedstock is reduced by selectively converting waxy paraffins into lower molecular weight hydrocarbons. At least a portion of the effluent from the dewaxing or hydrodewaxing zone is then passed to a hydrocracking zone where it is contacted with a hydrocracking catalyst in the presence of hydrogen under conditions such that a further reduction in the normal paraffin content is effected. When the desired product is a lube oil base stock, the overall conversion of components in the feed boiling above about 650.degree. F. to components boiling at or below about 650.degree. F.
Abstract: A process for converting heavy hydrocarbons into light hydrocarbons which comprises contacting, in a reaction zone, a heavy hydrocarbon having an API gravity at 25.degree. C. of less than about 20, such as Boscan heavy crude oil or tar sand bitumen, with a liquid comprising water and with an effective amount of selected catalyst materials such as iron (II and/or III) oxides, sulfides or sulfates, in the absence of externally added hydrogen, at a temperature between greater than about 340.degree. and about 480.degree. C. and at a pressure between about 1350 kPa (about 196 psig, about 13.2 atm) and about 15,000 kPa (about 2175 psig, about 148 atm), for a time sufficient to produce a residue and a vapor phase comprising light hydrocarbons, gaseous product and water, withdrawing the residue and said phase from the second zone; and recovering a light hydrocarbon product having an API gravity at 25.degree. C. of greater than about 20 and substantially free of vanadium and nickel values, i.e.
Type:
Grant
Filed:
December 26, 1985
Date of Patent:
May 10, 1988
Assignee:
Allied Corporation
Inventors:
Kundanbhai M. Patel, Andiappan K. S. Murthy, Alex Y. Bekker