Patents Examined by Irving Vaughn
  • Patent number: 4228020
    Abstract: Friction of internal combustion engines is reduced by using a crankcase motor oil containing the combination of graphite and a di-lower alkyl hydrocarbyl phosphonate, e.g. dimethyloctadecylphosphonate.
    Type: Grant
    Filed: May 4, 1979
    Date of Patent: October 14, 1980
    Assignee: Edwin Cooper, Inc.
    Inventor: Andrew G. Papay
  • Patent number: 4225447
    Abstract: An emulsifiable concentrate for use in water-in-oil fire-resistant hydraulic fluids, comprises lubricant and a polyalkenylsuccinic acid or anhydride or a salt thereof.
    Type: Grant
    Filed: January 8, 1979
    Date of Patent: September 30, 1980
    Assignee: Mobil Oil Corporation
    Inventors: Derek A. Law, Robert H. Davis, Harry J. Andress
  • Patent number: 4225446
    Abstract: A process for preparing highly basic magnesium sulfonates useful as lubricants including (a) forming an admixture of an oil-soluble sulfonic acid, a previously overbased magnesium sulfonate having a TBN in excess of about 200, a lower alkanol, and a volatile solvent, (b) heating the admixture to neutralize the acid, (c) cooling the first admixture and then forming a second admixture by adding magnesium oxide, naphthenic acid, a lower alkanol and a diluent oil, (d) carbonating the second admixture with carbon dioxide, while simultaneously adding water and ammonia or an ammonium compound as promoters, during the addition of about the first 25% of the carbon dioxide, (e) heating the carbonated solution to remove water and the lower alkanol, (f) further carbonating the solution for a short time between 180.degree. F. and 220.degree. F.
    Type: Grant
    Filed: April 3, 1978
    Date of Patent: September 30, 1980
    Assignee: Calumet Industries, Inc.
    Inventors: Jerry D. Arnold, Harry J. Fair, Laura V. Fair, Johnny D. Berry
  • Patent number: 4224170
    Abstract: Compositions which include mixtures of a calcium hydroxide overbased oil-soluble calcium sulfonate, hexylene glycol and a surfactant consisting of an ethoxylated aliphatic amine, particularly, diethoxylated cocoamine or diethoxylated soyamine, are useful as rust inhibiting additives for oils and the like. By incorporating these compositions in petroleum based oils such as petroleum based oils of lubricating oil quality which come into contact with metal surfaces under conditions such that the metal surfaces tend to rust or otherwise be subject to deterioration it is possible to inhibit rust formation on such metal surfaces.
    Type: Grant
    Filed: November 6, 1978
    Date of Patent: September 23, 1980
    Assignee: Texaco Inc.
    Inventor: Haakon Haugen
  • Patent number: 4224173
    Abstract: A lubricating oil containing polytetrafluoroethylene particles and a fluorochemical surfactant which stabilizes the dispersion and creates a molecular surface tension skin on the surface of the oil to reduce volatilization losses during use in an internal combustion engine.
    Type: Grant
    Filed: June 12, 1978
    Date of Patent: September 23, 1980
    Assignee: Michael Ebert
    Inventor: Franklin G. Reick
  • Patent number: 4222884
    Abstract: Organic material is stabilized against oxidative degradation by the addition of a small amount of an antioxidant compound or mixture of compounds containing a central segment of one to about ten divalent o-hydrocarbyl phenol groups (e.g. o-tert-butylphenol) bonded to each other through a methylene group and having terminal 3,5-dihydrocarbyl-4-hydroxybenzyl groups at each end. They are made by first condensing o-hydrocarbyl phenol with formaldehyde and then reacting the intermediate with 2,6-dihydrocarbyl phenol and formaldehyde.
    Type: Grant
    Filed: December 4, 1978
    Date of Patent: September 16, 1980
    Assignee: Ethyl Corporation
    Inventor: Robert E. Malec
  • Patent number: 4221673
    Abstract: Metal phenates especially overbased phenates are prepared by reacting a basic metallic compound with a mixture of an alkyl phenol and an alkyldihydroxybenzene. The products are useful as lubricant additives with improved antirust properties, and when overbased, with higher basicity and lower viscosity.
    Type: Grant
    Filed: January 20, 1978
    Date of Patent: September 9, 1980
    Assignee: Exxon Research & Engineering Co.
    Inventors: Robert Robson, Brian Swinney, Robert D. Tack
  • Patent number: 4218332
    Abstract: A novel class of compounds has been prepared comprising the tetrasulfides of C.sub.18 hydrocarbons, C.sub.18 fatty acids, and C.sub.18 fatty and alkyl and triglyceride esters. These tetrasulfides are useful as extreme pressure lubricant additives and show potential as replacements for sulfurized sperm whale oil.
    Type: Grant
    Filed: March 20, 1979
    Date of Patent: August 19, 1980
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: Arthur W. Schwab, Lyle E. Gast, Harold E. Kenney
  • Patent number: 4216099
    Abstract: Compositions made by reacting (I) a metal phenoxide salt of a bridged phenol of 2 to about 20 phenol groups and (II) a carboxylic acid reagent containing from one to about three carboxyl-based groups and a halogen-substituted hydrocarbon-based aliphatic or alicyclic group containing a halogen atom are useful as additives for lubricants and normally liquid fuels. Analogous thiophenoxide-based compositions are similarly useful. These compositions can also be used as intermediates for the preparation of other useful additive compositions through their reaction with alcohols, amino compounds, and reactive small ring heterocycles.
    Type: Grant
    Filed: December 4, 1978
    Date of Patent: August 5, 1980
    Assignee: The Lubrizol Corporation
    Inventor: Thomas F. Steckel
  • Patent number: 4213868
    Abstract: A coupling having dissimilar metal mating parts is provided with a grease comprising a hydrocarbon base oil containing a stearate gelling agent, particularly a Na, Li or Ba stearate. This coupling is anti-galvanic corrosive. Such couplings are useful in fire-fighting equipment where often aluminum and bronze components are in mating relationship, such as fire hose adaptors and hose nozzles.
    Type: Grant
    Filed: October 27, 1978
    Date of Patent: July 22, 1980
    Assignee: Witco Chemical Corporation
    Inventors: Clarence J. Bitely, Jr., Luther D. Dromgold, William S. Murray, Jr.
  • Patent number: 4206061
    Abstract: A fire-resistant grease comprises a fire-resistant base oil and graphitic carbon or oleophilic graphite as a thickener. Suitable base oils include fire-resistant hydraulic fluids, particularly phosphorus acid esters or amides and more particularly trihydrocarbyl phosphates. The graphitic carbon may be of the type described in U.K. Pat. No. 1,252,582 (U.S. Pat. No. 3,532,625) and the oleophilic graphite as described in U.K. Pat. No. 1,168,784 (U.S. Pat. No. 3,384,583). The thickener contact may be 1-20% wt of the grease, preferably 2-10% wt, and the grease may contain conventional additives.
    Type: Grant
    Filed: February 22, 1978
    Date of Patent: June 3, 1980
    Assignee: The British Petroleum Company Limited
    Inventors: Stanley C. Dodson, Christopher M. Elliott
  • Patent number: 4206062
    Abstract: A process for making an overbased low-soap alkaline earth metal hydrocarbylsulfonate in a single stage by mixing in an inert diluent (a) a hydrocarbyl sulfonic acid of 400-1500 molecular weight, (b) alkaline earth metal oxide or hydroxide in an amount to provide a stoichiometric excess equivalent to a total base number of at least 200 and to provide a "metal ratio" of at least 0.02.times.mol wt of the sulfonic acid, (c) an alkanol of 1-4 carbon atoms, preferably methanol, (d) water and (e) ammonium formate and then passing carbon dioxide into the mixture to convert excess alkaline earth metal base to carbonate.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: June 3, 1980
    Assignee: Edwin Cooper and Company Limited
    Inventors: Philip E. Derbyshire, Howard M. de Silva
  • Patent number: 4204968
    Abstract: This invention relates to a lubricant additive comprising a mixture of minute spherical copper and lead particles suspended in various lubricant bases depending upon its intended use. The minute spherical metal particles are presented to friction surfaces where they reduce friction by functioning as tiny ball bearings and platelets. In addition on the application of heat and pressure, the metal particles, particularly the copper particles, will plate on high wear areas where base metal has been removed by wear. The additive has been found to substantially reduce friction and wear between relatively moving parts.
    Type: Grant
    Filed: August 11, 1978
    Date of Patent: May 27, 1980
    Assignee: CLM International Corp.
    Inventors: Jack E. Mack, Patrick K. Mack
  • Patent number: 4203856
    Abstract: An article of manufacture and a method are disclosed herein for improving lubricity and wear resistance of a given substrate by applying thereto a solution comprising a fluoroalkyl ester and an organic carrier. The compositions herein disclosed have been found to be most effective as preservatives for coating sundry substrates, especially gramophone or phonograph record surfaces whereby there is effected a reduction of record groove wear while substantially reducing the friction between the stylus and the record groove. A preferred composition herein contemplated and disclosed is one comprising a perfluoroalkyl ester of stearic acid and a halogenated hydrocarbon carrier.
    Type: Grant
    Filed: July 12, 1978
    Date of Patent: May 20, 1980
    Assignee: Ball Corporation
    Inventor: Robert P. Pardee
  • Patent number: 4202781
    Abstract: A process for preparing molybdenum phosphosulfurized hydrocarbon compositions by reacting an aqueous solution of a molybdenum compound with a phosphosulfurized hydrocarbon.
    Type: Grant
    Filed: October 31, 1978
    Date of Patent: May 13, 1980
    Assignee: Standard Oil Company (Indiana)
    Inventors: Albert R. Sabol, Ernest H. Baughman
  • Patent number: 4201681
    Abstract: A metalworking lubricant composition which is effective as both a corrosion inhibitor and drawing lubricant and comprises a mineral oil and an additive combination of barium lanolate soap and barium sulfonate.
    Type: Grant
    Filed: March 26, 1979
    Date of Patent: May 6, 1980
    Assignee: Exxon Research & Engineering Co.
    Inventors: Henry F. Lipinski, Steven J. Wantling
  • Patent number: 4200541
    Abstract: The specification discloses advantageous dry bearing materials in which a material having characteristics making it useful as a dry bearing material has on its contacting or bearing surface a multiplicity of closely spaced, small, blind holes each filled with solid lubricant. It has been found that the holes should be less than 1 mm in diameter and have a center to center spacing of less than 1 mm and the specification discloses a phosphor bronze material of the invention using a polytetrafluoroethylene/lead solid lubricant of useful properties.
    Type: Grant
    Filed: December 2, 1977
    Date of Patent: April 29, 1980
    Assignee: National Research Development Corporation
    Inventors: George H. Kinner, John K. Lancaster
  • Patent number: 4200546
    Abstract: A novel product made by forming the metal salt reaction product of a sulfurized olefin possesses, among other things, a good copper strip corrosivity. Organic composition containing a minor amount thereof also possess good lubricating characteristics.
    Type: Grant
    Filed: January 8, 1979
    Date of Patent: April 29, 1980
    Assignee: Mobil Oil Corporation
    Inventor: Andrew G. Horodysky
  • Patent number: 4200543
    Abstract: Disclosed is a lubricating oil additive composition which imparts improved oxidation properties to internal combustion engine crankcase lubricants which comprises:(1) an antioxidant selected from aromatic or alkyl sulfides and polysulfides, sulfurized olefins, sulfurized carboxylic acid esters and sulfurized ester-olefins, and(2) an oil-soluble chlorinated hydrocarbon containing at least 6 carbon atoms.Lubricating oil compositions containing this additive composition are also disclosed. Particularly preferred are compositions which also contain an oil-soluble zinc salt.
    Type: Grant
    Filed: December 26, 1978
    Date of Patent: April 29, 1980
    Assignee: Chevron Research Company
    Inventors: Thomas V. Liston, Warren Lowe
  • Patent number: 4200545
    Abstract: Disclosed are combinations of amino phenols, wherein said phenols contain a substantially saturated hydrocarbon substituent of at least 10 aliphatic carbon atoms, and one or more detergent/dispersants selected from the group consisting of (I) neutral or basic metal salts of an organic sulfur acid, phenol or carboxylic acid; (II) hydrocarbyl-substituted amines wherein the hydrocarbyl substituent is substantially aliphatic and contains at least 12 carbon atoms; (III) acylated nitrogen-containing compounds having a substituent of at least 10 aliphatic carbon atoms; and (IV) nitrogen-containing condensates of a phenol, aldehyde and amino compound. Fuels and lubricants containing such combinations as additives are particularly useful in two-cycle (two-stroke) engines.
    Type: Grant
    Filed: July 3, 1978
    Date of Patent: April 29, 1980
    Assignee: The Lubrizol Corporation
    Inventors: Donald L. Clason, John F. Pindar, Jerome M. Cohen