Patents Examined by Jacob Ziegler
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Patent number: 5218026Abstract: A fluorine-containing elastomer composition comprising a specific fluorine-containing elastomer having iodine bonded thereto and having a multimodel molecular weight distribution, a specific vulcanizing agent, an organic peroxide, and a polyfunctional unsaturated compound. The fluorine-containing elastomer composition has not only excellent processability, mold release properties and burr-removal performance in molding but also capability of providing a vulcanization product which is not only improved with respect to mechanical properties, but also has extremely excellent resistance to chemicals and solvents, particularly methanol, and good metal-adhesion properties.Type: GrantFiled: December 20, 1990Date of Patent: June 8, 1993Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Keiichi Toda, Kenichi Hayashi, Hiroshi Saito
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Patent number: 5218053Abstract: Polymers comprising anionically polymerized monomers such as butadiene or styrene and adjacent units of (1-methyl-1-alkyl)alkyl esters such as t-butylmethacrylate, as well as selectively hydrogenated derivatives thereof, are heated to at least 180.degree. C. to convert the adjacent ester units to stable anhydride rings.Type: GrantFiled: May 8, 1992Date of Patent: June 8, 1993Assignee: Shell Oil CompanyInventor: Donn A. DuBois
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Patent number: 5218037Abstract: There is here provided a thermoplastic resin composition which comprises (I) 99 to 1% by weight of an aromatic polyester resin, (II) 1 to 99% by weight of at least one kind of resin selected from the group consisting of a polyphenylene ether resin, a mixture of the polyphenylene ether resin and a styrene polymer, a polycarbonate resin, and a polyarylene sulfide resin, (III) 0.1 to 100 parts by weight, based on 100 parts by weight of the aforesaid resins (I)+(II), of a multi-phase structure thermoplastic resin which is composed of 5 to 95% by weight of an epoxy group-containing olefin copolymer and 95 to 5% by weight of a vinyl polymer or copolymer obtained from at least one kind of vinyl monomer, either of both the components being formed with a dispersion phase having a particle diameter of 0.001 to 10 .mu.m. A method for preparing the above-mentioned thermoplastic resin composition is also provided here.Type: GrantFiled: July 25, 1991Date of Patent: June 8, 1993Assignees: Nippon Petrochemicals Co., Ltd., Nippon Oil & Fats Co., Ltd.Inventors: Yuichi Orikasa, Suehiro Sakazume, Sadahiro Nishimura, Yoshinori Maki
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Patent number: 5218030Abstract: A novel curable polyphenylene ether resin composition is disclosed, which comprises (a) a curable polyphenylene ether resin having at least one group selected from the group consisting of an allyl group and a propargyl group and (b) at least one cyanurate. The resin composition has excellent storage stability, film-forming properties and melt moldability. If desired, a fire retardant, optionally together with an antimony-containing auxiliary fire retardant, and/or a reinforcement is incorporated into the resin composition in order to improve the fire retardance and mechanical properties of the resin composition, respectively. By curing the resin composition, a cured polyphenylene ether resin composition comprising a chloroform nonextractable polyphenylene ether resin component and a chloroform extractable, polyphenylene ether-containing component is obtained, which has excellent chemical resistance, electrical properties, dimensional stability and heat resistance.Type: GrantFiled: February 7, 1990Date of Patent: June 8, 1993Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Teruo Katayose, Hiroji Oda, Haruhisa Sasaki
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Patent number: 5216080Abstract: A rubber composition comprising, as rubber components, 10-40 % by weight of (1) a styrene-butadiene copolymer rubber obtained by solution polymerization, having a styrene content of less than 20% by weight and a trans-1,4 bond content in butadiene portion, of more than 90% by weight and 60-90% by weight of (2) a diene rubber other than the styrene-butadiene copolymer rubber (1), having a glass transition temperature of -60.degree. C. or below.Type: GrantFiled: May 15, 1990Date of Patent: June 1, 1993Assignee: Nippon Zeon Co., Ltd.Inventors: Fumitoshi Suzuki, Shuichi Akita, Hiroyuki Watanabe
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Patent number: 5215818Abstract: A repositionable pressure-sensitive adhesive comprising from about 70% to about 99% solid, polymeric, acrylate, inherently tacky, infusible, solvent-insoluble, solvent-dispersible, elastomeric microspheres comprising at least one alkyl acrylate or alkyl methacrylate ester; and at least one polar monomer, and correspondingly, from about 30% to about 1% of a binder copolymer comprising an elastomeric polymeric backbone having pendant therefrom high Tg polymeric moieties.Type: GrantFiled: May 15, 1992Date of Patent: June 1, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Spencer F. Silver, Roger W. Leinen, Joaquin Delgado
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Patent number: 5216089Abstract: The processability and resistance to oxidative degradation of polyphenylene ether resins, alone, or in combination with a styrene resin, is improved by including a modifier comprising an alpha, beta-unsaturated carboxylic acid or derivative. In an embodiment, the formation of a composition comprising a poly(2,6-dimethyl-1,4-phenylene ether) and 2 parts per hundred of dibutyl maleate results in a 26 percent improvement in spiral flow, and a 30 percent reduction in oxygen uptake at 115.degree. C. enhancing the utility of polyphenylene ether resins as extrusion and injection molding materials.Type: GrantFiled: August 24, 1988Date of Patent: June 1, 1993Assignee: General Electric CompanyInventors: Robert R. Gallucci, Ronald J. Wroczynski
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Patent number: 5214109Abstract: The processability and resistance to oxidative degradation of polyphenylene ether resins, alone, or in combination with a styrene resin, is improved by including a modifier comprising an alpha, beta-unsaturated carboxylic acid or derivative. In an embodiment, the formation of a composition comprising a poly(2,6-dimethyl-1,4-phenylene ether) and 2 parts per hundred of dibutyl maleate results in a 26 percent improvement in spiral flow, and a 30 percent reduction in oxygen uptake at 115.degree. C. enhancing the utility of polyphenylene ether resins as extrusion and injection molding materials.Type: GrantFiled: November 28, 1990Date of Patent: May 25, 1993Assignee: General Electric CompanyInventors: Robert R. Gallucci, Ronald J. Wroczynski
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Patent number: 5212256Abstract: The present invention provides a thermoplastic resin composition which is improved in compatibility between polyphenylene ether and polyamide and is excellent in processability and impact strength. This composition comprises:(A) 100 parts by weight of a composition comprising 95-5% by weight of a polyphenylene ether obtained by oxidation polymerization of one or more of phenol compounds represented by the following formula: ##STR1## (wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 which may be identical or different, each represents a hydrogen atom, a halogen atom, a hydrocarbon radical or a substituted hydrocarbon radical and at least one of them is a hydrogen atom) and 5-95% by weight of a polyamide,(B) 0-30 parts by weight of an impact strength modifier, and(C) 0.01-10 parts by weight of an amino resin obtained by modifying with an alcohol an addition reaction product of formaldehyde and at least one compound selected from the group consisting of melamine, guanamine and urea.Type: GrantFiled: November 8, 1990Date of Patent: May 18, 1993Assignee: Sumitomo Chemical Co., Ltd.Inventors: Yukio Mizuno, Takashi Maruyama, Hiroomi Abe, Yutaka Terada
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Patent number: 5212249Abstract: A method for preparing asymmetric radial polymers wherein the different polymeric arms are contacted sequentially with a nonpolymerizable coupling agent. Contacting of the final step in the process, which frequently but not necessarily always will be the second step in the process, will be carried out in the presence of a polar compound suitable for increasing the amount of vinyl content in a conjugated diolefin polymer during polymerization thereof. The method used narrows the relative arm distribution of the several asymmetric radial polymers produced and significantly increases the amount of total product having the desired ratio of polymeric arms and accomplishes this objective in relatively short reaction time.Type: GrantFiled: October 28, 1991Date of Patent: May 18, 1993Assignee: Shell Oil CompanyInventors: Gary W. Richie, deceased, Raymond C. Tsiang, Ronald J. Hoxmeier, Arthur R. Bean, Harvey E. Atwood
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Patent number: 5212236Abstract: A polyphenylene ether resin composition comprising(A) a polyphenylene ether resin,(B) a polystyrene resin, and(C) a graft copolymer prepared by graft-polymerizing one or more vinyl monomers onto a compound rubber having an average particle diameter of 0.08 to 0.6 .mu.m and a structure wherein 10 to 90% by weight of a polyorganosiloxane rubber component and 90 to 10% by weight of a polyalkyl (meth)acrylate rubber component are tangled with each other so as not to separate, the total amount of the polyorganosiloxane rubber component and the polyalkyl (meth)acrylate rubber component being 100% by weight of the compound rubber. This resin composition provides molded products superior in impact resistance, heat resistance, mechanical strength, and surface appearance and is superior in moldability and flow properties.Type: GrantFiled: July 11, 1991Date of Patent: May 18, 1993Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Isao Sasaki, Naoki Yamamoto, Akira Yanagase
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Patent number: 5210119Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether, a sterically hindered amine, an epoxy compound, and a salt of a fatty acid. The polymer mixtures according to the invention have a good stability against discoloring by light.Type: GrantFiled: July 3, 1991Date of Patent: May 11, 1993Assignee: General Electric CompanyInventors: Christianus A. A. Claesen, Hideo Koike
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Patent number: 5208083Abstract: Polymer blends of a) polymers containing predominantly mers of (meth)acrylates and/or glutarimides with b) up to about 40 weight percent of polymers having greater than about 50 mol % vinyl alcohol mers exhibit useful barrier properties to oxygen and other environmental gases, while maintaining or enhancing physical properties and clarity.Type: GrantFiled: February 28, 1992Date of Patent: May 4, 1993Assignee: Rohm and Haas CompanyInventor: William T. Freed
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Patent number: 5206290Abstract: A thermoplastic resin composition which exhibits improved compatibility between polyphenylene ether and thermoplastic polyester constituents, excellent processability and impact strength contains 95-5% by wt. a polyphenylene ether and 5-95% by wt. of a thermoplastic polyester; 0.1-30 parts by wt. of an impact strength modifier; and 0.01-10 parts by weight of an amino resin.Type: GrantFiled: December 3, 1990Date of Patent: April 27, 1993Assignee: Sumitomo Chemical CompanyInventors: Yukio Mizuno, Takashi Maruyama
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Patent number: 5206289Abstract: The present invention relates to a rubber stock containing 0.1 to 10.0 phr of a polyhydric phenoxy resin. The polyhydric phenoxy resins may be used as a replacement for resorcinol and function as a methylene acceptor. The rubber stocks of the present invention exhibit improved tensile strength at break without the inherent fuming problems associated with resorcinol containing rubber stocks. These beneficial properties are obtained while maintaining high low strain stiffness and cord adhesion associated with resorcinol containing stocks.Type: GrantFiled: January 27, 1992Date of Patent: April 27, 1993Assignee: The Goodyear Tire & Rubber CompanyInventors: Mark S. Sinsky, Richard G. Bauer, Paul H. Sandstrom, Jerry L. Brenner
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Patent number: 5206281Abstract: Disclosed herein is a thermoplastic resin composition comprising:(a) a polyphenylene ether or a composition containing a polyphenylene ether,(b) (i) a modified propylene polymer obtainable by grafting a propylene polymer with a styrene-based monomer alone or in combination with a monomer copolymerizable with a styrene-based monomer, or (ii) a composition composed of said modified propylene polymer and a propylene polymer,(c) a rubbery substance, and(d) an inorganic filler having an average particle diameter of 0.05-10 .mu.m.Not only does this resin composition exhibit good processability but it also provides molded articles having well-balanced physical properties.Type: GrantFiled: March 21, 1990Date of Patent: April 27, 1993Assignee: Sumitomo Chemical Company, LimitedInventor: Motonobu Furuta
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Patent number: 5206276Abstract: There are provided flame retardant, flexibilized thermoplastic compositions which comprise, in admixture, a normally flammable polyphenylene ether resin, an aromatic phosphate plasticizer in an amount at least sufficient to provide a flame retardant, flexibilized composition after molding, and a thermoplastic elastomer comprising a block copolymer of a vinyl aromatic compound and a diene monomer. Preferred features comprise such compositions which also include a halogenated hydrocarbon, alumina trihydrate and/or elemental red phosphorus.Type: GrantFiled: November 9, 1987Date of Patent: April 27, 1993Inventor: Gim F. Lee, Jr.
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Patent number: 5204407Abstract: A pneumatic tire has a tread with a rubber composition produced by blending a rubber component with a styrene based thermoplastic elastomer. The rubber component is composed mainly of a diene based rubber, and the elastomer is so preliminarily internally crosslinked that tensile stress at a 100% elongation is increased to 10 to 1,000% of that of the styrene based thermoplastic elastomer not internally crosslinked. A pneumatic tire is also disclosed, having a tread portion with a rubber composition blended with a vinyl aromatic hydrocarbon thermoplastic elastomer in an amount of 5-80 parts by weight relative to 100 parts by weight of the rubber component.Type: GrantFiled: June 10, 1991Date of Patent: April 20, 1993Assignee: Bridgestone CorporationInventors: Mitsuru Araki, Yoshiyuki Morimoto
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Patent number: 5202381Abstract: This invention relates to improved poly(vinyl chloride) compositions which contain ionomeric additive polymers, and to a process for preparing such compositions.Type: GrantFiled: April 4, 1990Date of Patent: April 13, 1993Assignee: Rohm and Haas CompanyInventor: Hsing-Yeh Parker
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Patent number: 5202073Abstract: A method for preparing a stretched polymeric material of high strength and high modulus which comprises shaping a dilute solution of a synthetic polymer having an average molecular weight of not less than 3.times.10.sup.5, followed by cooling to make a gel-like filament or film, and stretching the resultant gel-like filament or film at a high stretch ratio, characterized in that a solution or dispersion of (a) the gel-like globules of said synthetic polymer having the solvent occluded therein or (b) the fine powders of said synthetic polymer having an average particle weight of not more than 5.times.10.sup.-5 mg per particle in a solvent is used as or for preparation of said polymer solution to be shaped.Type: GrantFiled: January 28, 1991Date of Patent: April 13, 1993Assignee: Toyo Boseki Kabushiki KaishaInventors: Shosuke Nanri, Tokio Kawaguchi, Hiroshi Yasuda