Abstract: Provided are ligand compounds containing two or more diphosphinoamine functional groups, where the two or more diphosphinoamine functional groups are linked by 4 carbon atoms, a catalyst system including the ligand compounds for olefin oligomerization, and a method for olefin oligomerization using the same. The catalyst system for olefin oligomerization according to the present invention has excellent catalytic activity, and yet, exhibits high selectivity to 1-hexene and 1-octene, thus enabling efficient preparation of alpha-olefin.

Abstract: The process is provided for forming the reaction product comprising the homologue mixture of I(CF2)nI, wherein n is 3 to 7, which may contain at least one of the contaminants ICF2I and I(CF2)2I, by the steps comprising (a) reacting iodine with hexafluoropropylene oxide at a temperature of 150° C. to 210° C. in a reactor, the amount of said hexafluoro-propylene oxide being a portion of the total amount of hexafluoropropylene oxide to be reacted with said iodine, thereby forming a reaction product containing gaseous perfluoroacetyl fluoride as a reaction by-product, (b) cooling said reaction product to become liquid except for said gaseous perfluoroacetyl fluoride, (c) venting said perfluoroacetyl fluoride from said reactor, and (d) repeating said steps (a), (b), and (c) until said total amount of said HFPO is reacted with said iodine.

Abstract: A method and system for producing methanol that employs steam methane reforming (SMR) and/or autothermal (ATR) synthesis gas production system, together with a partial oxidation system, is disclosed. The dual mode system and method for producing the synthesis gas in a methanol production process optimizes the efficiency and productivity of the methanol plant by using the partial oxidation based reforming system as an independent source of synthesis gas. The disclosed methods and systems are configurable either as a retrofit to existing methanol production facilities or as an integrated package into newly constructed methanol production facilities.

Abstract: The invention relates to methods and facility systems (100) for providing storable and transportable carbon-based energy carriers (108) by application of carbon dioxide (101) as a carbon supplier and by application of electric energy (E1, E2). The facility system (100) comprises a plant (300, 301; 400) for providing a first portion of energy in the form of direct current energy (E1) from renewable energy sources. In addition, a power supplies facility (501) is provided for tying the facility system (100) to a mixed network (500), wherein the power supplies facility (501) produces a second portion of energy in the form of direct current energy (E2) from an alternating current voltage of the mixed network (500). A device (102, 105) is adapted to provide hydrogen (103), wherein a part of the energy requirement of this device (102, 105) is covered by said first portion of energy and another part is covered by said second portion of energy.

Abstract: The invention relates to methods for creating high value liquid fuels such as gasoline, diesel, jet and alcohols using carbon dioxide and water as the starting raw materials and a system for using the same. These methods combine a novel solid oxide electrolytic cell (SOEC) for the efficient and clean conversion of carbon dioxide and water to hydrogen and carbon monoxide, uniquely integrated with a gas-to-liquid fuels producing method.

Abstract: A system for removing salt from a process stream being fed into a flash separator introduces a swirling motive fluid into the fluid column of the separator. The swirling motive fluid comes into contact with salt components residing in the fluid of the column to create a salt slurry. Means to limit the upward movement of the swirling motive fluid can be provided. The salt slurry is then removed and can be sent to a brine generation vessel. Saturated brine from the vessel is transported back to the fluid column to replace the motive fluid in the column.

Abstract: In the production of fuel such as ethanol from carbonaceous feed material such as biomass, a stream comprising hydrogen and carbon monoxide is added to the raw gas stream derived from the feed material, and the resulting combined stream is converted into fuel and a gaseous byproduct such as by a Fischer-Tropsch reaction. The gaseous byproduct may be utilized in the formation of the aforementioned stream comprising hydrogen and carbon monoxide.

Abstract: Process for the treatment of an alcohol composition containing nitrogen-containing contaminants by contacting the alcohol composition in the vapor phase with an adsorbent in an adsorption zone.

Abstract: An improved process for producing perfluoroalkyl iodides of formula (I) F(CF2CF2)n—I??(I) wherein n is an integer from 2 to 3, wherein the improvement comprises thermolyzing at least one perfluoroalkyl iodide of formula (II), optionally in the presence of perfluoroethyl iodide, formula (III) F(CF2CF2)m—I??(II) F(CF2CF2)p—I??(III) wherein m is an integer greater than or equal to 4, and p is 1, wherein a) the molar ratio of formula (III) to formula (II) is less than 1.0, b) the residence time is from about 0.1 to about 10 seconds, and c) the temperature is from about 450° C. to about 500° C.

Abstract: The invention relates to a process for removing one or more undesired (hydro)halocarbon compounds from a (hydro)fluoroalkene, the process comprising contacting a composition comprising the (hydro)fluoroalkene and one or more undesired (hydro)halocarbon compounds with an aluminum-containing absorbent, activated carbon, or a mixture thereof.

Abstract: A carbon to liquids system comprising: a source of syngas; a first reactor coupled in flow communication with said syngas source and configured to receive a flow of syngas therein, said first reactor comprising a polymeric material, wherein said first reactor reacts the syngas and a catalyst in a Fischer-Tropsch reaction that produces a product comprising steam, wherein the polymeric material is configured to permit the permeation of the steam therethrough; and a recycle path coupled in flow communication with said first reactor, wherein said recycle path is configured to channel the permeated steam to a vessel positioned upstream from said first reactor. A method of operating a carbon to liquids system includes receiving a flow of syngas and reacting the syngas and a catalyst to produce a product including steam. The method also includes recycling the permeated steam to a vessel positioned upstream from the reactor.

Abstract: The present invention provides a process of catalytic fluorination in gas phase of product 1,1,1,2,3-pentachloropropane or/and 1,1,2,2,3-pentachloropropane into product 2,3,3,3-tetrafluoropropene in presence of a catalyst.

Abstract: Disclosed is a process for preparing a chlorinated alkene, comprising contacting a chlorinated alkane with a catalyst in a dehydrochlorination zone to produce a liquid reaction mixture comprising the chlorinated alkane and the chlorinated alkene, and extracting chlorinated alkene from the reaction mixture, wherein the concentration of the chlorinated alkene in the reaction mixture present in the dehydrochlorination zone is controlled such that the molar ratio of chlorinated alkene:chlorinated alkane is from 1:99 to 50:50.

Abstract: The present invention relates to a fluorination process, comprising: an activation stage comprising contacting a fluorination catalyst with an oxidizing agent-containing gas flow for at least one hour; and at least one reaction stage comprising reacting a chlorinated compound with hydrogen fluoride in gas phase in the presence of the fluorination catalyst, so as to produce a fluorinated compound.

Abstract: Provided are a method of preparing an alkanol and a device for preparing the same. According to the method and device, economic feasibility and stability of a preparation process may be enhanced, and mass production of an alkanol may be performed.

Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.

Abstract: Embodiments of the present invention are directed to apparatus and methods for converting carbon dioxide and/or methane into higher alkanes and hydrogen gas in a single reaction chamber using a catalyst and microwave radiation.

Abstract: The present invention describes a process and catalysts for the conversion of a light hydrocarbon and carbon dioxide input stream into high quality syngas with the subsequent conversion of the syngas into fuels or chemicals. In one aspect, the present invention provides an efficient, solid solution catalyst for the production of a carbon containing gas from carbon dioxide and light hydrocarbons. The catalyst comprises a single transition metal, and the transition metal is nickel.

Abstract: The invention relates to a method of carrying out a chemical equilibrium reaction using a permselective membrane, wherein quantitative proportions of at least one product obtained in the reaction are separated and removed from the reaction through the action of the permselective membrane. The chemical equilibrium reaction is carried out in the presence of a water-containing gas mixture, and a permselective membrane made from a material having a porous structure with mean pore sizes of less than 0.45 nm (4.5 ?), which material is hydrophobic at least on the free surfaces thereof is used.

Abstract: A method for the utilization of reaction water formed during the synthesis of hydrocarbons from synthesis gas in a GTL process includes the cleaning of oxygenates while quenching of the synthesis gas at a temperature of more than 500° C. while in contact with a catalyst for steam conversion of oxygenates, and the degasification of the cleaned up reaction water. Cleaned up and degasified water is utilized for cooling synthesis gas to a temperature of lower than 400° C. and for water steam production. The invention ensures efficient treatment of reaction water with removal of oxygenates, the use of obtained treated water as boiler feed water, and for the production of water steam.