Abstract: A urethane oligomer according to a) or b) has: a) at least two backbone residues R issued from a polyisocyanate without the NCO groups, linked between them with a diol residue RB (diol without the two OH groups) by two urethane bonds and each backbone residues R carrying (or linked to) at least two urethane segments each containing at least one terminal allyl group, b) at least one backbone residue R issued from a polyisocyanate without the NCO groups, the backbone residue R carrying (or linked to) at least two urethane segments each linked to R by one urethane bond with at least one urethane segment (arm) containing at least one terminal allyl group, and at least one urethane segment (arm) containing at least one terminal (meth)acrylate group. A curable composition containing the urethane oligomer reduces oxygen inhibition in coatings, adhesives, sealants or in resin matrix with good surface properties.
Abstract: The present invention provides a composition for substrate surface modification and a method using the same, and the composition for substrate surface modification is composed of a compound of the general formula structure shown in formula 1: formula 1, wherein n1 is an integer of 1 to 6, and R is a zwitterionic group. The composition for substrate surface modification uses water as a medium to perform modifying reaction over a substrate surface, and at the same time has biological modification characteristics, and abilities of immobilizing biomolecules and anti-biofouling.
Abstract: The present invention provides a composition for substrate surface modification and a method using the same, and the composition for substrate surface modification is composed of a compound of the general formula structure shown in formula 1: formula 1, wherein n1 is an integer of 1 to 6, and R is a zwitterionic group. The composition for substrate surface modification uses water as a medium to perform modifying reaction over a substrate surface, and at the same time has biological modification characteristics, and abilities of immobilizing biomolecules and anti-biofouling.
Abstract: A photocurable composition can comprise a polymerizable material and a photoinitiator, wherein the polymerizable material can comprise 10-40 wt % of a mono-functional monomer of formula (1), with R1 being H or C1-C6 alkyl, and R2 and R3 being one or more substitutions of C1-C10 alkyl or alkyl-aryl, and R4, R5 being H or C1-C10 alkyl, The photocurable composition can have a viscosity of not greater than 15 mPa·s, and a photo-cured layer of the photocurable composition can have a low thermal shrinkage if subjected to a high temperature baking treatment, and a carbon content of at least 74%.
Abstract: A photocurable resin of the present technology contains: a main backbone chain having repeating units represented by Formulas (Ia) and (Ib), and a (meth)acryloyl group and a non-photoreactive group at terminals; the non-photoreactive group being at least one type selected from the group consisting of saturated hydrocarbon groups and aromatic hydrocarbon groups which optionally have a heteroatom; a hydroxy group, an amino group, —CH?NH, a carboxy group, or a mercapto group being not bonded to an end of the non-photoreactive group; a content of the repeating unit represented by Formula (Ia) being greater than 15 mol % of an amount of the main backbone chain; and contents of the (meth)acryloyl group and the non-photoreactive group each being 5 mol % or greater of an amount of the ends.
Abstract: An active energy ray-curable resin composition which contains (A) inorganic oxide particles each having an organic functional group on the surface, (B) a siloxane oligomer which has at least one functional group selected from the group consisting of a (meth)acryloyl group, an epoxy group and a vinyl group, while having a weight average molecular weight of 200-3,000, (C) a polyfunctional (meth)acrylate having a specific structure, (D) a urethane (meth)acrylate having two or more (meth)acryloyl groups in each molecule, and (E) an ultraviolet absorbent.
Abstract: Provided herein is a resin product useful for the production of three-dimensional objects by additive manufacturing, and methods using the same. The resin may include a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups; a polyol; a photoinitiator; and at least one organometallic catalyst. A packaged product useful for the production of three-dimensional objects by additive manufacturing, the product comprising a single container having a single chamber and a resin in the chamber with all components mixed together, is also provided.
Type:
Grant
Filed:
September 24, 2019
Date of Patent:
February 8, 2022
Assignee:
Carbon, Inc.
Inventors:
Robert K. Pinschmidt, Jr., Andrew Gordon Wright, Jason P. Rolland
Abstract: The present invention provides energy curable ink and coating compositions that comprise polymerizable compounds, photoinitiators, and colorants. The polymerizable compounds comprise one or more polymerizable monomers and/or oligomers, wherein at least a portion is 3-methyl-1,5-pentanediol diacrylate. The inks and coatings of the invention exhibit excellent print properties after UV-LED, standard UV mercury vapor lamp, and electron beam cure.
Abstract: The present invention provides a method for applying multiple ink and/or coating layers on a substrate. At least one of the ink and/or coating layers contains one or more photoinitiators, and at least one of the ink and/or coating layers does not contain any photoinitiators. In certain embodiments, all of the ink and/or coating layers are wet trapped and the entire print construct is cured by exposure to UV radiation after all of the ink and/or coating layers have been applied. In certain embodiments, the wet trapping method of the present invention can be used to prepare laminates.
Abstract: The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer.
Type:
Grant
Filed:
May 21, 2019
Date of Patent:
January 18, 2022
Assignee:
3M Innovative Properties Company
Inventors:
Thomas P. Klun, Zeba Parkar, John M. Riedesel, Richard J. Pokorny, Chad M. Amb, Benjamin R. Coonce, Robert S. Clough, Tianyu Wu, Saswata Chakraborty, Yongshang Lu, Benjamin C. MacMurray, Ian Dailey, David B. Olson
Abstract: The present application relates to an ink composition comprising a glycidyl ether compound and a method for forming an organic layer using the same, and provides an ink composition capable of forming an organic layer and adjusting haze in a curing process for an intended use, and a method of forming an organic layer using the same.
Type:
Grant
Filed:
October 19, 2018
Date of Patent:
January 4, 2022
Assignee:
LG CHEM, LTD.
Inventors:
Kook Hyun Choi, Joon Hyung Kim, Yu Jin Woo, Mi Lim Yu
Abstract: The present application discloses an adhesive composition comprising a polymer of the formulae A, B and C: and methods for using the adhesive composition. wherein x and y define the block polymer and are integer greater than 1.
Type:
Grant
Filed:
July 24, 2019
Date of Patent:
January 4, 2022
Assignee:
ACatechol, Inc.
Inventors:
Byung Jun Ahn, Sam Linh Nguyen, Roscoe Linstadt
Abstract: An essentially 100% solids, single-component, UV curable, low-viscosity, penetrating sealant composition for wood substrates and other porous substrates is prepared from an acrylate-methacrylate mixture, a functionalized resin, an unsaturated fatty acid triglyceride oil, and a photoinitiator. The sealant composition may further contain a metal catalyst, an amine synergist, fillers, pigments, dyes, flow and leveling additives, air release chemicals, UV absorbers, hindered amine light stabilizers, fungicides, insect repellents, and/or mold inhibitors. The sealant composition exhibits fast cure times along with resistance to degradation.
Type:
Grant
Filed:
February 17, 2020
Date of Patent:
December 21, 2021
Assignee:
BOND DISTRIBUTING, LTD.
Inventors:
Scott Fishel, Connor Fishel, Paul Smith
Abstract: The present invention relates to a method for preparing superabsorbent polymer. According to the preparation method of the present invention, the surface penetration depth of a surface crosslinking agent can be appropriately controlled, and superabsorbent polymer with excellent properties can be prepared though homogeneous surface crosslinking. Thus, superabsorbent polymer with improved absorption property can be provided without deterioration of absorbency under load.
Type:
Grant
Filed:
March 17, 2016
Date of Patent:
December 14, 2021
Inventors:
Ju Eun Kim, Gi Cheul Kim, Se Yeol Park, Ki Hyun Kim
Abstract: A hybrid mint plant characterized by an essential oil composition profile, methods of cultivating the hybrid mint plant, and methods of producing an essential oil composition with the essential oil composition profile using the hybrid mint plant are disclosed.
Abstract: An electrode and a method of making an electrode includes treating polymers that contain functional groups, which by surface functionalization, such as hydrolysis, ozone treatment or carbon-carbon double-bond oxidation to produce hydroxyl functional groups on the surface. Reacting methacryloyl chloride with the resulting hydroxyl functional groups thereby providing a reactive surface. Photopolymerizing or thermal polymerization of crosslinked acrylate or methacrylate polymers on the reactive surface to produce a membrane covalently bonded to the underlying substrate. In addition such an electrode can also be produced on a polystyrene substrate by reacting methacryloyl chloride with the polystyrene substrate and photopolymerizing or thermally polymerizing to produce crosslinked acrylate or methacrylate polymers on the reactive surface to produce a membrane covalently bonded to the underlying polystyrene substrate.
Type:
Grant
Filed:
March 13, 2020
Date of Patent:
December 7, 2021
Assignee:
Regents of the University of Minnesota
Inventors:
Evan Anderson, Philippe Buhlmann, Sujay Chopade, Marc Hillmyer, Tim Lodge
Abstract: A curable composition containing a magenta pigment; a polymerizable compound; and a polymer including an amino group, where the polymer including the amino group has a weight average molecular weight of 1,000 or more, wherein the polymer including the amino group is at least one selected from the group consisting of hydroxyl group-including carboxylate ester, salts of a long-chain polyamino amide and acid ester having a high molecular weight, salts of polycarboxylic acid having a high molecular weight, salts of long-chain polyaminoamide and polar acid ester, unsaturated acid esters having a high molecular weight, modified polyurethanes, modified polyacrylates, polyether ester anionic surfactants, salts of naphthalenesulfonic acid formalin condensates, polyoxyethylene alkyl phosphoric acid ester, polyoxyethylene nonylphenylether, polyester polyamine, and stearylamine acetate.
Abstract: A three-dimensional dental device is fabricated in a layer-by-layer approach using a support material. The support material is deposited in a liquid form on a surface, hardened by cooling or ultraviolet (UV) curing, and selectively ablated to create an area within which the desired structure of the dental device will be formed. Active dental material is deposited into this area, and the layer-by-layer process repeated until the three-dimensional dental device has been completed. Thereafter, any remaining support material is removed by water or other solvent.