Abstract: An active energy ray-curable composition is disclosed including: an anionically polymerizable compound represented by (1): wherein EWG represents an electron-withdrawing group, X represents a single bond or an oxygen atom (—O—), R represents an n-valent organic group, and n represents an integer of 1 to 6; when n is an integer of 2 to 6, the respective EWG and the respective X may be the same or different; and when n is 1, EWG and R may be bonded; and a compound (photobase generator) represented by (2): wherein ring A represents an aromatic ring that may be substituted or a heteroaromatic ring that may be substituted; R1 and R2 are the same or different and each represents a hydrogen atom or an alkyl group; R1 and R2 may be bonded to each other to form a ring together with an adjacent nitrogen atom; and the ring may be substituted.

Abstract: An ultraviolet curable organopolysiloxane composition which contains: (A) a linear or branched organopolysiloxane which contains, as monovalent substituents bonded to a silicon atom at an end of the molecular chain, at least three groups represented by formula (1) and/or formula (2) in each molecule, while having the main chain composed of repeated diorganosiloxane units (in the formulae, a represents a number of 1-3; and the broken line represents a bonding hand); (B) a linear or branched organopolysiloxane which contains at least two groups represented by formula (3) in each molecule, while having the main chain composed of repeated diorganosiloxane units R1bR23-bSi??(3) (in the formula, R1 represents an alkenyl group; R2 represents a monovalent hydrocarbon group; and b represents a number of 1-3); and (C) a photoinitiator.

Abstract: Described herein is an actinically curable adhesive composition, suitable for sealing flexible packaging, that includes an inert urethane polymer and an ethylenically unsaturated monomer component selected from at least one monofunctional ethylenically unsaturated monomer, at least one multifunctional ethylenically unsaturated monomer, and a combination thereof, wherein the ethylenically unsaturated monomer component disperses the inert urethane polymer. The compositions are suitable for forming flexible packaging materials for foods and other materials, particularly sensitive materials. Also described are flexible packaging materials and a method for preparing an actinically curable adhesive composition.

Abstract: Radiation curable compositions for additive fabrication processes, the components cured therefrom, and their use in particle image velocimetry testing methods are described and claimed herein. Such compositions include compounds which induce free-radical polymerization, optionally compounds which induce cationic polymerization, a filler constituent, and a light absorbing component, wherein the compositions are configured to possess certain absorbance values at wavelengths commonly utilized in particle image velocimetry testing. In another embodiment, the compositions include a fluoroantimony-modified compound. Such compositions may be used in particle imaging velocimetry testing methods, wherein the test object utilized is created via additive fabrication and is of a substantially homogeneous construction.

Abstract: A radiation-curable ink jet composition comprises a polymerizable compound component including a monofunctional monomer component and a multifunctional monomer component. The content of the monofunctional monomer component is 87 mass % or more based on the polymerizable compound. The monofunctional monomer component includes a nitrogen-containing monofunctional monomer component, and the content of the nitrogen-containing monofunctional monomer component is 14 mass % or less based on total amount of the radiation-curable ink jet composition. The weighted average of the glass transition temperatures of homopolymers of the respective polymerizable compounds is 42° C. or more when the mass ratios of the contents of the respective polymerizable compounds are weighted.

Abstract: This composition contains (A) 100 parts of an organopolysiloxane having two groups represented by general formula (1) (R1 represents a monovalent hydrocarbon group having 1-20 carbon atoms, R2 represents an oxygen atom or the like, R3 represents an acryloyloxyalkyl group or the like, p represents a number satisfying 0?p?10, and “a” represents a number satisfying 1?a?3) per molecule, (B) 1-500 parts of a monofunctional (meth)acrylate compound not containing a siloxane structure, (C) 1-5,000 parts of an organopolysiloxane resin containing (a) an R43SiO1/2 unit (in the formula, R4 represents a monovalent hydrocarbon group having 1-10 carbon atoms) and (b) a SiO4/2 unit, where the molar ratio of the unit (a) to the unit (b) is in the range of 0.6 to 1.2:1, (D) 1-100 parts of fine powder silica, and (E) 0.01-20 parts of an optical polymerization initiator.

Abstract: Provided herein is technology relating to polymerization and producing polymers and particularly, but not exclusively, to methods, systems, and compositions for producing articles using three-dimensional printing and for improving control of polymerization using a polymerization photoinhibitor having fast back reaction kinetics such as hexaarylbiimidazole compounds and bridged hexaarylbiimidazole compounds.

Abstract: Methods of forming cross-linked polysaccharides are disclosed in which one or more polysaccharides are dissolved in solution, gelled, modified to have a desired concentration, and subsequently irradiated. The irradiation of the gel crosslinks the polysaccharide(s) present. The disclosed techniques may be applied to various polysaccharides, including but not limited to agarose and/or hyaluronic acid.

Abstract: An inkjet ink composition for 3D printing is disclosed herein. In some embodiments, the ink composition includes at least one radical curable compound selected from the group consisting of an acrylate-based monomer, an acrylate-based oligomer, and a vinyl-based monomer, and a light initiator, wherein the ink composition has dimensional precision an evaluation index of dimensional precision of 90% or more. The ink composition can implement a shape of a target sculpture more accurately by significantly reducing the flow of ink after a 3D printing process.

Abstract: The present invention discloses a PEGylated thioxanthone photoinitiator and a photosensitive resin composition, the PEGylated thioxanthone compound is eco-friendly and has low toxicity, high initiation efficiency and good thermal stability, meanwhile, as a kind of photoinitiator, the compound has a small amount of fragment residue after cured, and may improve the compatibility of the photoinitiator and photosensitive resin composition system. The photosensitive resin composition provided by the present invention has reasonable allocation of ingredients and content in the components thereof, capable of 3D-printing a hydrogel having a specific structure; the hydrogel has lower cytotoxicity and better biocompatibility, and may applied in bioengineering fields, e.g., 3D cell culture.

Abstract: The present invention relates to a specific radiation-curable coating composition for improving the surface adhesion of plastic parts and its uses as a primer coat, as a base coat or as a clear coat. The composition may be pigmented or unpigmented and may be cured by UV and/or EB. The invention also relates to cured coating resulting from this cure and to the coated plastic substrate with improved surface adhesion.

Abstract: The objective of the present invention is to provide a method for producing a fluorinated carbonate derivative in a safe and efficient manner. The method for producing a fluorinated carbonate derivative according to the present invention is characterized in comprising irradiating light on a composition containing a C1-4 halogenated hydrocarbon having one or more kinds of halogen atoms selected from the group consisting of a chlorine atom, a bromine atom and an iodine atom, a fluorine-containing compound having a nucleophilic functional group and a base in the presence of oxygen.

Abstract: A curable composition includes: a near infrared absorbing colorant; a polymerizable monomer that has a group including an ethylenically unsaturated bond; a resin; and a radical polymerization initiator, in which a content of the near infrared absorbing colorant is 10 mass % or higher with respect to a total solid content of the curable composition and a content of the polymerizable monomer that has at least one group selected from an acid group or a hydroxyl group and a group having an ethylenically unsaturated bond is higher than 50 mass % with respect to a total mass of all the polymerizable monomers. A near infrared cut filter, a solid image pickup element, an image display device, and an infrared sensor include a film which is formed using the curable composition.

Abstract: A radiation-curable ink jet composition comprises a polymerizable compound component including a monofunctional monomer component and a multifunctional monomer component. The content of the monofunctional monomer component is 87 mass % or more based on the total amount of the polymerizable compound component, the monofunctional monomer component includes a monofunctional acrylate containing a polycyclic hydrocarbon group, and the weighted average of the glass transition temperatures of homopolymers of the respective polymerizable compounds is 42° C. or more when the mass ratios of the contents of the respective polymerizable compounds are weighted.

Abstract: A method for preparing a superabsorbent polymer, and more particularly, a method for preparing a superabsorbent polymer in which it is possible to stably operate a process for preparing a fine powder reassembly while maintaining assembly strength of the fine powder reassembly, wherein a refined ratio is reducible, and an initial absorption speed of the superabsorbent polymer is improved, by adjusting a stirring speed and divisionally adding water to a fine powder in a process for the preparation of the fine powder reassembly, is provided.

Abstract: Described herein are polymeric aminoacrylates formed by the reaction of polyalkylene glycol diacrylates with bireactive amines. The polymeric aminoacrylate are comprised of moieties of poly(alkylene glycol) diacrylate and moieties of bireactive amines. Also described herein are energy curable ink and coating compositions that include the described polymeric aminoacrylates. The energy curable ink and coating compositions that include the described polymeric aminoacrylates are well-suited for use in packaging applications where low migration of uncured monomer material after cure is desired, such as in the packaging of foodstuffs, pharmaceuticals, etc.

Abstract: Resin formulation including: a mixture of low volatility oligomers is about 40% to 75% weight of the resin formulation; a plasticizer is about 25% to 55% by weight of the resin formulation; a photoinitiator is about 0.1% to 3.0% by weight of the resin formulation; a thermal inhibitor is about 0.001% to 4% by weight of the resin formulation; and a defoaming agent is about 0.0001% to 0.1% by weight of the resin formulation. Wherein the mixture of low volatility oligomers is combined with the photoinitiator, the thermal inhibitor and the defoaming agent, and mixed, then degassed at a temperature of about 60 deg C. and at a pressure of less than 10 kPa for at least 10 minutes.

Abstract: The present disclosure relates to systems, methods and resins for additive manufacturing. In one embodiment, a method for additive manufacturing of a ceramic structure includes providing a resin including a preceramic polymer and inorganic ceramic filler particles dispersed in the preceramic polymer. The preceramic polymer is configured to convert to a ceramic phase. The method includes functionalizing inorganic ceramic filler particles with a reactive group and applying an energy source to the resin to create at least one layer of the ceramic phase from the resin.

Abstract: Embodiments in accordance with the present invention encompass a composition containing a latent catalyst and a compound capable of generating a Bronsted acid with a counterion capable of coordinating and activating the latent catalyst along with one or more monomers which undergo ring open metathesis polymerization (ROMP) and one or more multi-functional crosslinkable molecules when said composition is exposed to a suitable radiation forms a three-dimensional (3D) object. The catalyst system employed therein can be sensitive to oxygen and thus inhibits polymerization in ambient atmospheric conditions. The three-dimensional objects made by this process exhibits improved mechanical properties, particularly, high distortion temperature, impact strength, elongation to break, among others. Accordingly, compositions of this invention are useful as 3D inkjet materials for forming high impact strength objects of various sizes with microscale features lower than 100 microns, among various other uses.

Abstract: According to one aspect of the present invention, a dental photopolymerizable composition includes: a (meth)acrylate compound; a filler; a photopolymerization initiator; and a phthalic acid derivative and/or a thiophene derivative, wherein a content of the phthalic acid derivative and/or the thiophene derivative is greater than or equal to 0.05% by mass and less than or equal to 0.25% by mass.