Abstract: A composition which comprises 1,1,1,3,3-pentafluorobutane-(HFC-365mfc) and 1,1,3,3-pentafluoropropane (HFC-245fa) in a weight ratio HFC-365mfc/HFC-245fa of from 60:40 to 75:25.

Abstract: A method of manufacturing a foam having a Poisson's ratio which varies across at least a region of the foam in a gradient distribution involves the steps of: a) providing a housing defining an internal space having an inlet aperture and an outlet aperture; b) providing an open-cell foam of a size and shape configured to fit inside the internal space of the housing; c) positioning the foam inside the internal space of the housing; d) establishing a flow of air through the foam via the inlet and outlet apertures; e) heating the foam to a predetermined temperature while maintaining the flow of air through the foam; and f) subsequently cooling the foam while continuing to maintain the flow of air through the foam. A foam of such a type is also presented.

Abstract: Using general purpose raw materials, a polyurethane foam having higher water stopping properties than conventional ones is provided. The polyurethane foam is a polyurethane foam obtained by foaming and curing a composition containing a polyol component, an isocyanate component, a foam stabilizer, a cross-linking agent, and a catalyst.

Abstract: Nano-sized polyurea particles or a dispersion of polyurea particles suitable for improving the mechanical properties of a polyurethane material, said particles having at least equivalent diameter dimensions in the nanosize range of 50 nm up to 700 nm, a uniform equivalent diameter particle size distribution, an amount of urethane bonds calculated on the total amount of urea+urethane bonds in said particles of <1%, and a glass transition temperature (Tg) of >100° C., preferably Tg>120° C., more preferably >150° C. measured in a second heating cycle after heating to >220° C. at 20° per minute using Differential Scanning calorimetry.

Abstract: The present invention relates to an alkoxysilane-terminated prepolymer, characterized in that it is obtainable by reaction of at least A) a polyol, B) a compound having two or more isocyanate groups, and C) an alkoxysilane having at least an isocyanate group and/or an isocyanate-reactive group, wherein the polyol A) comprises at least a polyethercarbonatepolyol obtainable by addition of carbon dioxide and alkylene oxides onto H-functional starter molecules. The present invention further relates to a process for preparing the alkoxysilane-terminated prepolymer of the present invention and also to a composition and a multicomponent system comprising an alkoxysilane-terminated prepolymer of the present invention. The present invention further relates to a shaped article obtainable by polymerizing the alkoxysilane-terminated prepolymer of the present invention, by polymerizing a composition of the present invention or by polymerizing a multicomponent system of the present invention.

Abstract: A polyrotaxane is blended into a polyol composition, which can reduce the tensile stress of a flexible polyurethane foam. A vertical compressive stress due to the weight of a sitting user and a tensile stress due to the input of lateral vibrations act on a urethane pad. However, by reducing the tensile stress of the flexible polyurethane foam, the direction (inclination) of a resultant force obtained by combining the compressive stress and the tensile stress can be brought close to the vertical direction. Thus, the angle of inclination of the user's hip (ischium) on the urethane pad to the vertical direction due to the input of lateral vibrations can be reduced, so that the sense of wobble of the urethane pad can be reduced.

Abstract: A polyrotaxane is blended into a polyol composition, which can reduce the tensile stress of a flexible polyurethane foam. A vertical compressive stress due to the weight of a sitting user and a tensile stress due to the input of lateral vibrations act on a urethane pad. However, by reducing the tensile stress of the flexible polyurethane foam, the direction (inclination) of a resultant force obtained by combining the compressive stress and the tensile stress can be brought close to the vertical direction. Thus, the angle of inclination of the user's hip (ischium) on the urethane pad to the vertical direction due to the input of lateral vibrations can be reduced, so that the sense of wobble of the urethane pad can be reduced.

Abstract: A polyurethane foam having an initial UL 94 vertical flame classification of V-0 and maintaining a UL 94 vertical flame classification of V-0 after one week of heat aging at 150° C. is formed as the reaction product of an isocyanate component and an isocyanate-reactive component in the presence of a blowing agent. The isocyanate component includes an isocyanate-containing compound and a non-reactive phosphorous compound that is present in an amount ranging from 1 to 20 weight percent based on the total weight of the polyurethane foam. The isocyanate-reactive component includes a polyether polyol and expandable graphite that is present in an amount ranging from 3 to 30 weight percent based on the total weight of the polyurethane foam.

Abstract: A method for continuously preparing solvent-free open-cell and closed-cell polyimide foams, firstly, one or a few of dianhydrides dissolve in or suspend in the polyhydric alcohol and form the precursor A. All kinds of additives dissolve in the polyhydric alcohol and form the precursor B. The aromatic isocyanates with different structure mix well and form the precursor C. Finally the three precursors are mixed foaming by one-step, after solidify, the polyimide foams are obtained with advantage performance. The method does not utilize the volatile solvent that does not participate in the reaction, therefore not existing the process of removing the solvent, it can continuously produce with the double-side heat conveyor belt. CO2, the main gas producing in the reaction, causes the system to foam, thus there is no cost on the solvent recovery and it reduces the environment contamination.

Abstract: The present invention relates to a process for producing a shoe sole comprising a hybrid material made of a polyurethane foam as matrix material and of foamed particles of thermoplastic polyurethane by preparing an inlay of joined expanded particles (c?) of thermoplastic polyurethane and placing the joined expanded particles of thermoplastic polyurethane in a mould and embedding the inlay with a reaction mixture obtainable by mixing (a) polyisocyanates with (b) compounds having hydrogen atoms reactive toward isocyanates, and if appropriate, with (d) chain extenders and/or crosslinking agents, and with (e) catalysts, and with (f) blowing agents, and with (g) further additives and reacting the reaction mixture to give the shoe sole. The present invention further relates to shoe soles, obtainable by such a process.

Abstract: The present invention relates to a process for producing rigid polyurethane foams by reaction of a) at least one organic polyisocyanate with b) at least one polyol component in the presence of a blowing agent mixture comprising water and halogenated alkenes, wherein the amount of water is at least 1.40 mol/kg of polyol component b) and the amount of halogenated alkene is at most 2.00 mol/kg of polyol component b), and also to the use of such a blowing agent mixture for producing corresponding rigid polyurethane foams and for increasing the adherence and reducing the thermal conductivity of corresponding rigid polyurethane foams. The present invention further relates to a rigid polyurethane foam obtainable by the process of the present invention.

Abstract: The present invention provides trimerization catalyst compositions having a sterically hindered carboxylate salt and methods to produce a polyisocyanurate/polyurethane foam using such trimerization catalyst compositions.

Abstract: The present invention provides trimerization catalyst compositions and methods to produce a polyisocyanurate/polyurethane foam using such trimerization catalyst compositions. The catalyst composition is the contact product of at least one ?,?-unsaturated carboxylate salt and at least one second carboxylate salt.

Abstract: A thermoplastic polyurethane foamed article has a plurality of bubbles distributed throughout the thermoplastic polyurethane foamed article and comprises a thermoplastic polyurethane composition and an epoxy-functional styrene acrylic copolymer which are foamed in the presence of a blowing agent. The epoxy-functional styrene acrylic copolymer is present in an amount ranging from 0.1 to 5% of the total combined weight of the thermoplastic polyurethane composition and the epoxy-functional styrene acrylic copolymer. The thermoplastic polyurethane foamed article has an average diameter of the plurality of bubbles ranging from 50 to 120 ?m with at least 75% of the plurality of bubbles having a diameter of less than 200 ?m.

Abstract: A bio-based polyol-containing polymer foam material, which includes a bio-based polyol-containing polymer foam present in a bulk concentration of the bio-based polymer foam material of 99% by weight or greater; and a graphite material present in a bulk concentration of the bio-based polyol-containing polymer foam material of 1% by weight or less. The bio-based polyol-containing polymer foam material is especially suitable for automotive components having deadening and vibration management features.

Abstract: Methods for preparing polyurethane flexible foam are described, wherein an organic polyisocyanate is reacted with an active hydrogen-containing component such as an organic polyol, in the presence of a urethane catalyst, a blowing agent, optionally a cell opener, and a siloxane-based surfactant composition as a stabilizer for the foam. The siloxane-based surfactant composition comprises a silanol-functionalized organosiloxane having general formula (I), wherein: the R groups are independently a C1-C3 alkyl, phenyl, or —OSi(R)3; provided that at least one R group is a hydroxyl (—OH) bonded directly to any silicon atom and X is an integer from 0-200.

Abstract: Low-scorch flame-retardant polyurethane foams include phosphorus-containing propionic ester flame retardants. Methods for producing and using the foams are also provided.

Abstract: The present disclosure is directed to a composition and articles containing the composition. The composition comprises a foam and a plurality of gel particles dispersed in the foam. The gel particles comprise an olefin block copolymer and an oil.

Abstract: Polyester polyols made from thermoplastic polyesters are disclosed. The polyols can be made by heating a thermoplastic polyester such as virgin PET, recycled PET, or mixtures thereof, with a glycol to give a digested intermediate, which is then condensed with a dimer fatty acid to give the polyol. The invention includes a polyester polyol comprising recurring units of a glycol-digested thermoplastic polyester and a dimer fatty acid. The polyester polyol can also be made in a single step by reacting the thermoplastic polyester, glycol, and dimer acid under conditions effective to produce the polyol. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

Abstract: A polyurethane foam for comfort application, includes the reaction product of a first composition that includes from 20 wt % to 80 wt % of an aqueous component and from 20 wt % to 80 wt % of a hydrophilic isocyanate-terminated prepolymer component. The aqueous component includes at least 90 wt % of water based on the total weight of the aqueous component and the hydrophilic isocyanate-terminated prepolymer component has a free NCO content from 1 wt % to 15 wt % and is a reaction product of a second composition that includes an isocyanate component and an isocyanate-reactive component.