Patents Examined by John M. Cooney
  • Patent number: 7183331
    Abstract: A method for producing a rigid polyurethane foam, which comprises reacting a polyol with a polyisocyanate in the presence of an amine catalyst and a blowing agent, wherein as the amine catalyst, at least one amine compound having at least one type of substituent selected from the group consisting of a hydroxyl group, a primary amino group and a secondary amino group in its molecule, or N-(2-dimethylaminoethyl)-N?-methylpiperazine, is used, and as the blowing agent, 1,1,1,3,3-pentafluoropropane (HFC-245fa) and/or 1,1,1,3,3-pentafluorobutane (HFC-365mfc) is used.
    Type: Grant
    Filed: February 19, 2004
    Date of Patent: February 27, 2007
    Assignee: Tosoh Corporation
    Inventors: Hiroyuki Kiso, Katsumi Tokumoto, Yutaka Tamano
  • Patent number: 7183330
    Abstract: A method for making a rigid polyurethane foam by reacting a polyisocyanate and a polyol in the presence of a urethane catalyst, a blowing agent and a silicone surfactant characterized by employing a blowing agent comprising a C4 or C5 hydrocarbon, or mixtures thereof, with an average molecular weight of ?72 g/mole and a boiling point in the range of 27.8 to 50° C., and a silicone surfactant comprising a polyether-polysiloxane copolymer represented by the following formula: (CH3)3—Si—O—(Si(CH3)2—O)x—(Si(CH3)(R)O)y—Si(CH3)3 where R=(CH2)3—O—(—CH2—CH2—O)a—(CH2—CH(CH3)—O)b—R?, and where R? is H, (CH2)zCH3, or C(O)CH3; x+y+2 is 60–130; x/y is 5–14; z is 0–4; the total surfactant molecular weight, based on the formula, is 7000–30,000 g/mole, the wt % siloxane in the surfactant is 32–70 wt %, the blend average molecular weight (BAMW) of the polyether portion is 450–1000 g/mole, and the mole % of ethylene oxide in the polyether portion is 70–100 mole %.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: February 27, 2007
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Wayne Robert Furlan, Mark Leo Listemann, Joan Sudbury-Holtschlag, Thomas John Markley, Gary Dale Andrew
  • Patent number: 7179845
    Abstract: The invention relates generally to a stable flexible latex foam. The latex foam will contain at least one polymer having a plurality of hard domains and a plurality of soft domains, a micelle forming agent, a hydrocarbon propellant substantially free of dimethyl ether, and an agent which is a solvent for said micelle forming agent and an emulsifier for said hydrocarbon propellant.
    Type: Grant
    Filed: January 10, 2003
    Date of Patent: February 20, 2007
    Assignee: Fomo Products, Inc.
    Inventor: Anthony Taylor
  • Patent number: 7179846
    Abstract: A structural element of closed-cell polyurethane rigid foam, with good thermal insulation and improved sound absorption is achieved by means of surface depressions satisfying specified criteria.
    Type: Grant
    Filed: March 9, 2004
    Date of Patent: February 20, 2007
    Assignee: Bayer MaterialScience AG
    Inventor: Thorsten Dreier
  • Patent number: 7169824
    Abstract: Process for preparing flexible polyurethane foam by reacting an MDI-based polyisocyanate and a polyether polyol with a high oxyethylene content in a mold.
    Type: Grant
    Filed: July 24, 2002
    Date of Patent: January 30, 2007
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Eric Huygens, Jan-Willem Leenslag, Herman Eugene Germain Moureau
  • Patent number: 7169823
    Abstract: The present invention relates to a method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, and a tertiary amine amide catalyst composition represented by formula (I): wherein A, R1–R6, and n are defined herein and wherein the tertiary amino amide catalyst of formula I is acid-blocked.
    Type: Grant
    Filed: December 2, 2003
    Date of Patent: January 30, 2007
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Juan Jesus Burdeniuc
  • Patent number: 7144926
    Abstract: Foam blowing agent blends containing trans-1,2-dichloroethylene and one or more hydrofluorocarbons are provided, as are foam compositions containing such blends. The resulting foams exhibit dramatic improvement in fire performance.
    Type: Grant
    Filed: March 25, 2003
    Date of Patent: December 5, 2006
    Assignee: Arkema Inc.
    Inventors: Steve M. Galaton, Christopher Bertelo
  • Patent number: 7141613
    Abstract: The invention relates to flame resistant rigid foams and formulations useful for the production thereof. The polyol formulation must include at least one substance which is inert with respect to isocyanates, does not deplete the ozone layer and has a boiling point below 55° C. and a reaction product of at least one compound with an aromatic ring, at least one aldehyde or ketone and at least one primary or secondary amine. This polyol formulation is reacted with an isocyanate, optionally with other commonly used additives, to produce rigid flame resistant foams.
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: November 28, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf Albach, Michael Brockelt, Juan Cirujeda-Ranzenberger
  • Patent number: 7098255
    Abstract: A process for producing a finely cellular polyurethane foam by mixing a first ingredient comprising an isocyanate compound and a second ingredient comprising a compound containing an active hydrogen group, characterized by comprising adding a nonionic silicone surfactant containing no hydroxyl group to at least one of the first ingredient and the second ingredient in an amount of 0.1 to 5 wt %, excluding 5 wt %, based on the total amount of the first ingredient and the second ingredient, subsequently agitating the surfactant containing ingredient together with an unreactive gas, which has no reactivity to isocyanate group or active hydrogen group, to disperse the unreactive gas as fine bubbles to prepare a bubble dispersion and then mixing the bubble dispersion with the remaining ingredient to cure the resultant mixture and forming finely cellular structure into the resultant polyurethane foam by the fine bubbles of the bubble dispersion.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: August 29, 2006
    Assignee: Toyo Tire & Rubber Co., Ltd.
    Inventors: Hiroshi Seyanagi, Kaoru Inoue, Kazuyuki Ogawa, Takashi Masui, Koichi Ono
  • Patent number: 7094811
    Abstract: Energy absorbing flexible foams can be produced by reacting an isocyanate with a first polyol, prepared at least in part by an active double metal cyanide catalyst and a second polyether polyol is prepared at least in part by a basic or acidic catalyst.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: August 22, 2006
    Assignee: Bayer Corporation
    Inventors: Neil H. Nodelman, David A. Radovich, Albert Magnotta, Carl E. Holsinger
  • Patent number: 7087657
    Abstract: The present invention relates to polyol dispersions with long-term stability, to cellular polyurethane moldings produced therewith, to processes for their preparation and to their use.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: August 8, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Haas, Alfred Neuhaus
  • Patent number: 7078443
    Abstract: A viscoelastic foam is provided having an amine-based polyol system to impart strength, recoverability and endurance to the foam, and an appropriately selected trifunctional non-amine-based polyol system to provide flexibility to the foam. The combination of amine-based and non amine-based polyols provides a viscoelastic semi-rigid foam with excellent impact and recovery properties, recovering to substantially 100% of its initial volume and shape following an impact, yet with high rigidity and stiffness so that it is effective at absorbing high as well as low-energy impacts. A method of making the above viscoelastic foam is also provided. In a preferred embodiment, the foam is made using an allophanate-modified MDI prepolymer in order to provide the isocyanate in liquid form at standard temperature and pressure in order to simplify the production of the invented viscoelastic foams.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: July 18, 2006
    Assignee: Intellectual Property Holdings, LLC
    Inventor: Charles M. Milliren
  • Patent number: 7078442
    Abstract: A composition and method for consolidating aggregate material is disclosed. The method includes introducing a reaction composition into the aggregate material and allowing it to reach on form a polymer which binds the aggregate together. The composition includes polyol, isocyanate, and ester.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: July 18, 2006
    Assignee: Baysystems North America LLC
    Inventor: Scott A Brown
  • Patent number: 7049265
    Abstract: Disclosed herein are compositions useful for introducing metal carboxylate salts as catalysts into systems useful for producing polyurethane and polyisocyanurate foams. The methods permit the introduction of such catalysts in the absence of substantial amounts of water which otherwise cause inferior foams to be produced. A method for producing foam employing the catalysts are also described.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: May 23, 2006
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Robert A. Grigsby, Jr., Robert L. Zimmerman, Ernest L. Rister, Jr.
  • Patent number: 7008974
    Abstract: Disclosed is a composition for preparing a rigid polyurethane foam having a good demolding property by defining polyol component and catalyst component. The polyol component comprises 40˜60 wt. % of polyol obtained by polymerization with an organic oxide using sorbitol as an initiator, 5˜10 wt. % of polyol obtained by polymerization with an organic oxide using ethylene diamine as an initiator, 20˜30 wt. % of polyol obtained by polymerization with an organic oxide using toluene diamine or toluene diamine and triethanol amine as a single or a complex initiator, and, optionally, 5˜20 wt. % of multivalent polyol of an ester structure, and the catalyst component is chosen in a group comprising a foaming catalyst, a gelling catalyst, a trimerization catalyst, a mixed form of the foaming catalyst and the gelling catalyst, and compound thereof.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: March 7, 2006
    Assignee: LG Electronics Inc.
    Inventors: Hyun-Keun Cho, Ju-Hyun Kim
  • Patent number: 7008973
    Abstract: A flexible, flame-retarded, polyurethane foam comprising brominated and/or phosphorous flame retardants and an acid scavenger.
    Type: Grant
    Filed: January 14, 2004
    Date of Patent: March 7, 2006
    Assignee: PABU Services, Inc.
    Inventors: Stephen B. Falloon, Richard S. Rose, Mathew D. Phillips
  • Patent number: 7005458
    Abstract: A static dissipative flexible polyurethane foam is formed under free rise expansion conditions from a polyether graft polyol and an isocyanate, wherein one or more anti-static additives are incorporated into the reaction mix in an amount from 0.10 to 20 parts by weight. Water is added in an amount of from 0.2 to 1.0 parts per weight. Upon curing, the foam has a density in the range of 6 to 20 pounds per cubic foot, a surface resistivity below 1×1011 ohms/square, and a pore size in the range of 100 to 250 pores per inch. The foam may be fabricated (cut or shaped) to form a shaped article, such as a roller, a clean room wipe, a cosmetic applicator or a packaging element.
    Type: Grant
    Filed: June 20, 2003
    Date of Patent: February 28, 2006
    Assignee: Foamex L.P.
    Inventor: Joseph W. Lovette
  • Patent number: 6979701
    Abstract: The present invention aims to provide a polyurethane foam, suitably usable as a polishing pad, having a uniform foam structure, which can achieve the improvements in the flatness of the surface of polished materials and in the planarization efficiency, and can extend the polishing pad life longer than that of the conventional polyurethane foams. This aim can be achieved by providing a polyurethane foam having a density of 0.5 to 1.0 g/cm3, a cell size of 5 to 200 ?m and a hardness [JIS-C hardness] of not less than 90, comprising a thermoplastic polyurethane which is obtained by a reaction of a high polymer polyol, an organic diisocyanate and a chain extender, contains not less than 6% by weight of a nitrogen atom derived from the isocyanate group, and has a storage elastic modulus measured at 50° C. [E?50] of not less than 5×109 dyn/cm2.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: December 27, 2005
    Assignee: Kuraray Co., Ltd.
    Inventors: Shunji Kaneda, Chihiro Okamoto
  • Patent number: 6960618
    Abstract: The present invention relates to a preparation method for low-density polyurethane foam excelling in the flame retardance and the dimensional stability, wherein rigid polyurethane foam having the average value for the ratio of lengthwise direction diameter/cross direction diameter of cells being 1.0 to 1.4 and the density of 20 to 40 kg/m3 is prepared by combining, as blowing agent, carbon dioxide generated in the reaction between water and polyisocyanate and carbon dioxide under supercritical state, subcritical state or liquid state, and by adding said water and said carbon dioxide under liquid state into said polyol component prior to mixing the polyisocyanate component and the polyol component, and to rigid polyurethane foam obtained by said method.
    Type: Grant
    Filed: August 25, 2003
    Date of Patent: November 1, 2005
    Assignee: Achilles Corporation
    Inventors: Yoshiyuki Ohnuma, Junichiro Mori, Hideki Tosaki
  • Patent number: 6949589
    Abstract: An elastic foamed grinder material of polyurea series for grinding and/or buffing, which is obtainable by subjecting a composition including a main ingredient component including a polyisocyanate, and a composition comprising an aromatic diamine, a foaming agent, a foam-adjusting agent and a curing catalyst to foaming and curing in the presence of grinder granules, wherein the aromatic diamine is an aromatic diamine oligomer alone or in mixture with an aromatic diamine compound, and a method for producing the grinder material.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: September 27, 2005
    Inventor: Yoshijiro Oyaizu