Abstract: This invention relates to a continuous process for making a polymer polyol, the polymer polyol produced according to the said process and its applications.

Abstract: Disclosed herein is a composition comprising a polymer; and a superheated fluid; where at least a portion of the polymer and the superheated fluid co-exist in a single phase. Disclosed herein is a method comprising exposing a polymer to a superheated fluid; swelling at least a portion of the polymer with the superheated fluid so that the polymer and the superheated fluid co-exist in a single phase; and changing pressure or temperature within the single phase to change a property in the polymer.

Abstract: The present invention relates to a composition suitable for production of rigid polyurethane or polyisocyanurate foams, said composition comprising at least one isocyanate component, at least one polyol component, at least one foam stabilizer, at least one urethane and/or isocyanurate catalyst, optionally water and/or blowing agent, and optionally at least one flame retardant and/or further additives, which comprises at least two different varieties 1 and 2 of polyether siloxanes as foam stabilizers, and to the use of this composition for production of foamed polyurethane or polyisocyanurate materials, preferably rigid foams.

Abstract: Embodiments of the present disclosure relate to a polyurethane foam, a refrigerator including the same, and a method of manufacturing polyurethane foam. According with the present inventions, a refrigerator, comprising a polyurethane foam formed of a composition for preparing polyurethane, includes a cabinet; a door configured to open and close the cabinet; and a thermal insulation disposed in at least one of the cabinet and the door, wherein the thermal insulation includes a polyurethane foam-forming polyol system comprising a fiber having hydroxyl groups; and isocyanate.

Abstract: Polyester polyols made from thermoplastic polyesters are disclosed. The polyols can be made by heating a thermoplastic polyester such as virgin PET, recycled PET, or mixtures thereof, with a glycol to give a digested intermediate, which is then condensed with a dimer fatty acid to give the polyol. The invention includes a polyester polyol comprising recurring units of a glycol-digested thermoplastic polyester and a dimer fatty acid. The polyester polyol can also be made in a single step by reacting the thermoplastic polyester, glycol, and dimer acid under conditions effective to produce the polyol. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

Abstract: The present invention relates to mixtures of 1,1,1,4,4,4-hexafluorobutene (1336mzzm) and 1-chloro-3,3,3-trifluoropropene (1233zd). The blends are useful as blowing agents for polymer foam, solvents, aerosol propellants and heat transfer media.

Abstract: Combinations of gelatinous elastomer and polyurethane foam may be made by introducing a plasticized A-B-A triblock copolymer resin and/or an A-B diblock copolymer resin into a mixture of polyurethane foam forming components including a polyol and an isocyanate. The plasticized copolymer resin is polymerized to form the gelatinous elastomer in-situ while simultaneously polymerizing the polyol and the isocyanate to form polyurethane foam. The polyurethane reaction is exothermic and can generate sufficient temperature to melt the styrene-portion of the A-B-A triblock copolymer resin thereby extending the crosslinking and in some cases integrating the A-B-A triblock copolymer within the polyurethane polymer matrix. The combination has a marbled appearance. The gel component has higher heat capacity than polyurethane foam and thus has good thermal conductivity and acts as a heat sink. Another advantage of in situ gel-foam is that the gel component provides higher support factors compared to the base foam alone.

Abstract: A rigid polyurethane foam which has ultrafine cells, has a low thermal conductivity of 0.0190 W/(m·K) or lower, exhibits excellent heat insulating properties and flame retardancy, and has very little impact on global warming, without using a special apparatus such as a gas loading device. Provided is a rigid polyurethane foam which is obtained by mixing and reacting raw materials including a polyol, a polyisocyanate, a blowing agent, and a catalyst. The rigid polyurethane foam contains the polyol containing a polyester polyol having an aromatic component concentration of 17-35 wt. %, and a non-amine-based polyether polyol and/or an aromatic amine-based polyether polyol; the polyisocyanate in which MDI/TDI are mixed at a ratio of 4/6 to 9/1; and the blowing agent containing a halogenated olefin.

Abstract: The present invention relates to a process for the production of polyurethanes where (a) polyisocyanate, (b) polymeric compounds having groups reactive toward isocyanates, (c) catalysts, (d) polymer P formed from ethylenically unsaturated monomers and having an average of more than 2 functional groups of the formula —O—NH2 and optionally (e) blowing agent, (f) chain extender and/or crosslinking agent, and (g) auxiliaries and/or additives are mixed to give a reaction mixture, and the reaction mixture is allowed to complete a reaction to give the polyurethane. The present invention further relates to polyurethanes produced by this process and to the use of these polyurethanes in the interior of means of transport.

Abstract: Methods and combinations of mattress support surfaces comprising one or more flexible polyurethane foam layers containing highly thermally-conductive solids, such as diamond or silicon carbide, and said layer combination is capable of transferring heat from a warm surface, such as a person sleeping on a bed, to a cooler region at a faster rate throughout the mattress than the thermal dissipation rate obtained from flexible polyurethane foam without highly thermally-conductive solids.

Abstract: A composite material includes, in an exemplary embodiment a polyurethane foam and a plurality of inorganic particles dispersed therein. The polyurethane foam is formed from a reaction mixture that includes a first polyether polyol having a first molecular weight and a functionality of about 3 or less, a second polyether polyol having a second molecular weight less than the first molecular weight and a functionality of greater than about 3, and at least one isocyanate. The ratio of an amount of the first polyol in the reaction mixture to an amount of the second polyol in the reaction mixture is between about 1:1 to about 5:1.

Abstract: A bio-polyol composition and a bio-polyurethane foam are provided. The bio-polyol composition includes polyol, a surface-modified lignin, and a surfactant represented by formula 1. wherein R is represented by CnH2n+1, n is an integer of 0 to 3; x/y is between 5 and 13; a is an integer of 1 to 100; b is an integer of 1 to 100.

Abstract: A polyurethane foam based on MDI (diphenylmethane diisocyanate) and on a polyol with an ethylene oxide content of greater than 50%, is made by mixing, under pressure, to form a foaming liquid precursor of polyurethane foam: a first reactive liquid, referred to as liquid A, comprising (a) a urethane prepolymer based on a first portion of the MDI and on a first portion of said polyol, and (b) the second portion of the MDI in the free state, said prepolymer being dissolved in this second portion of MDI and a second reactive liquid, referred to as liquid B, comprising the second portion of said polyol and water as foaming agent. The amount of said polyol in the liquid B represents between 25% and 75% by weight of the total of said polyol; this method is advantageously used for casting a polyurethane foam into the cavity of a tire casing.

Abstract: Methods for forming a TPE-skinned composite include forming a skin layer having at least one surface and having a thermoplastic elastomer and an adhesive promoting agent; providing a foam layer; and forming the foam layer onto the said surface of the skin layer to form the TPE-skinned composite. Optional additives such as an organo-silane compound may be added to further improve the adhesion between the skin layer and the foam. The present disclosure also provides a TPE-skinned composite including a skin layer having a thermoplastic elastomer present in an amount of greater than 90 wt. %; and an adhesive promoting agent present in an amount of from 0.5 wt. % to 10 wt. % based upon the total weight of the skin layer.

Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.

Abstract: A polyol pre-mix composition includes a blowing agent having a halogenated hydroolefin, a polyol, a catalyst composition, and an antioxidant. The antioxidant may be, for example, a benzene diol or a benzene triol or other polyhydroxy-substituted aromatic compound, which is optionally substituted with one or more substituents such as alkyl groups. A two-part system for producing a thermosetting foam blend includes (a) a polyisocyanate and, optionally, one or more isocyanate compatible raw materials; and (b) the polyol pre-mix composition. A method for producing a thermosetting foam blend includes combining: (a) a polyisocyanate; and (b) the polyol pre-mix composition.

Abstract: Disclosed are a dynamic non-wicking PU foam and preparation and application thereof The PU foam is prepared from polyether polyol, toluene-2,4-diisocyanate, non-wicking additive and auxiliary agent. The dynamic non-wicking additive is composed of carboxylic acids, amines and alkyl alcohols in any proportion. The auxiliary agent is composed of silicone surfactant, amine promoter, tin catalyst, pigment and water. The dynamic non-wicking PU foam has a high stability and an extremely non-wicking effect. The shoes made of the dynamic non-wicking PU foam also have extremely good dynamic non-wicking and waterproof effects, thus ensuring both comfort and stability of quality.

Abstract: An in-situ foaming system for forming a flame-retardant polyurethane foam in situ comprising a first liquid containing a polyisocyanate (A), a second liquid containing a polyol (B), a trimerization catalyst (C), a foaming agent (D), a foam stabilizer (E), and additives (F) comprising red phosphorus and at least one member selected from the group consisting of phosphoric acid esters, phosphate-containing flame retardants, bromine-containing flame retardants, boron-containing flame retardants, antimony-containing flame retardants, and metal hydroxides.

Abstract: The present invention relates to a process for producing a polyurethane sealant, which comprises mixing (a) polyisocyanate, (b) polyetherpolyols, (c) aliphatic, exclusively amine initiated alkoxylation products having an OH-number of 400 to 1000 mg KOH/g and a functionality of 4, (d) blowing agents and optionally (e) chain extenders and/or crosslinking agents, (f) catalysts and (g) auxiliaries and/or additives to give a reaction mixture and reacting the reaction mixture to give the polyurethane sealant. The present invention further relates to a cast in place polyurethane sealant, obtained according to a process according to the present invention.

Abstract: A polyurethane composite element has one or more gaps containing a polyurethane foam. The polyurethane foam has a density of 16-40 kg/m3 and a closed cell proportion of 50-90% determined according to ASTM D6226-2010 Standard Test Method. The polyurethane foam is formed by applying a polyurethane composition into the gaps in situ. A process for producing a polyurethane composite element is also described.