Patents Examined by Juan C Valencia
  • Patent number: 10407623
    Abstract: The disclosure describes a one-step liquid biphasic catalytic process for converting a carbohydrate-containing feedstock, preferably lignocellulose, to light naphtha (e.g., hexane, pentane, methyl cyclopentane, cyclohexane, etc.) in the presence of an acidic reactive aqueous phase and a redox catalyst in the organic extracting/reaction phase. The process provides a cost-effective route for producing light-naphtha components, in presence or not of deoxygenates. The light naphtha components are useful as feedstock for steam and catalytic cracking to produce value-added platform molecules like ethylene and propylene, as precursor for the synthesis of bioaromatics like benzene and as gasoline fuel feedstock, and as fuel additives (e.g., the concomitantly formed oxygenates) to improve the biological origin of carbon in the fuel.
    Type: Grant
    Filed: May 12, 2015
    Date of Patent: September 10, 2019
    Assignee: Katholieke Universiteit Leuven, K.U. Leuven Research & Development
    Inventors: Michiel Julien Dusselier, Beau Op De Beeck, Bert Frans Sels
  • Patent number: 10400183
    Abstract: The invention involves an integrated process in which a hydrocarbon feedstock is treated with a caustic (alkaline) extraction to remove sulfides, disulfides, and mercaptans. These extracted materials are further treated, and are then used to activate hydrotreating catalysts.
    Type: Grant
    Filed: February 5, 2019
    Date of Patent: September 3, 2019
    Assignee: Saudi Arabian Oil Company
    Inventors: Omer Refa Koseoglu, Robert Peter Hodgkins
  • Patent number: 10385283
    Abstract: Embodiments herein relate to a process flow scheme for the processing of gas oils and especially reactive gas oils produced by thermal cracking of residua using a split flow concept. The split flow concepts disclosed allow optimization of the hydrocracking reactor severities and thereby take advantage of the different reactivities of thermally cracked gas oils versus those of virgin gas oils. This results in a lower cost facility for producing base oils as well as diesel, kerosene and gasoline fuels while achieving high conversions and high catalyst lives.
    Type: Grant
    Filed: March 16, 2017
    Date of Patent: August 20, 2019
    Assignee: Lummus Technology Inc.
    Inventors: Arun Arora, Ujjal K. Mukherjee, Wai Seung Louie, Marvin I. Greene
  • Patent number: 10385282
    Abstract: A method and system for upgrading and separating hydrocarbon are provided. The method may include preheating hydrocarbon containing impurities, removing non-hydrocarbon impurities from the hydrocarbon using a hydroprocessing catalyst and hydrogen gas after inserting the preheated hydrocarbon into a reactor, and separating gas from liquid.
    Type: Grant
    Filed: June 5, 2017
    Date of Patent: August 20, 2019
    Assignee: Korea Institute of Energy Research
    Inventors: Dong Woo Cho, Kang Hee Cho, Jong Nam Kim, Bharat S. Rana, Cheol Hyun Kim, Joon Ho Ko, Hee Tae Beum
  • Patent number: 10385281
    Abstract: Systems, methods and compositions for reducing the heteroatom content of hydrocarbon feed using transition metal complexes and adsorption techniques. The transition metal complexes include titanyl, hafnyl and zirconyl complexes activated using one or more hydroperoxides or peracids. The activated adsorbents are incorporated into one or more vessels as an adsorption bed for adsorbing the heteroatoms present in hydrocarbon feeds. The systems, methods and compositions separate the heteroatoms passed through the system by contacting the adsorption compositions with the heteroatoms of the hydrocarbon feed, adsorbing the heteroatom to the adsorption material, further allowing for the retrieval of a hydrocarbon product having a reduced heteroatom content.
    Type: Grant
    Filed: February 26, 2019
    Date of Patent: August 20, 2019
    Inventors: Kyle E. Litz, Jonathan P. Rankin, Erica H. Shipley, Michael Scudder, Trent A. McCaskill
  • Patent number: 10386018
    Abstract: The invention relates to injecting steam into crude oil for several benefits, primarily of which is to remove salt by transferring the salt into the condensed water from the steam. Steam transfers salt via a different transfer mechanism and therefore doesn't require the high shear mixing of conventional water injection systems. As such, steam injection through a variety of procedures, is more efficient at gathering salt into water that itself is easier to remove from the crude oil.
    Type: Grant
    Filed: November 21, 2017
    Date of Patent: August 20, 2019
    Assignee: Phillips 66 Company
    Inventors: Keith H. Lawson, Derek H. Willman
  • Patent number: 10376865
    Abstract: Disclosed is a method of synthesizing nano-sized tungsten-silica core-shell particles by a silica-based sol-gel process. According to the method, tungsten-silica nanoparticles are very easy to synthesize by a simple process at ambient pressure and temperature. In addition, tungsten oxide-silica (WOx@SiO2) nanoparticles including tungsten in a stable oxidation state can be synthesized. In the tungsten oxide-silica nanoparticles, the size of the tungsten protected with the silica shell can be maintained in the nanometer range without further processing. Also disclosed is a method of synthesizing nano-sized tungsten oxide (WOx) and tungsten carbide (WC) particles by further processing of the tungsten-silica core-shell particles.
    Type: Grant
    Filed: October 27, 2017
    Date of Patent: August 13, 2019
    Assignee: Korea University Research and Business Foundation
    Inventors: Kwan-Young Lee, Chan Hun Kim, Gwang-Sik Jeong, Young Gul Hur
  • Patent number: 10377955
    Abstract: The present invention describes a device for controlling cooling of a heat transfer solid supplying or withdrawing heat to or from a unit carrying out globally endothermic or exothermic reactions respectively. The exchange bundle of said device is in a triangular pattern.
    Type: Grant
    Filed: October 13, 2017
    Date of Patent: August 13, 2019
    Assignee: AXENS
    Inventors: Jean-Francois Le Coz, Yann Le Vot
  • Patent number: 10370602
    Abstract: An apparatus for producing diesel fuel and jet fuel using Fischer-Tropsch synthetic oil, the apparatus including a hydrofining reactor, a hot separator, a first rectifying column, a hydrocracking reactor, a hydroisomerization reactor, a second rectifying column, a first mixing chamber and a second mixing chamber. The hydrofining reactor includes a raw material inlet and a hydrofining product outlet. The hot separator includes a separated oil outlet and a hydrofining product inlet which is connected to the hydrofining product outlet. The first rectifying column includes a tail oil fraction outlet, a diesel fraction outlet and a separated oil inlet which is connected to the separated oil outlet. The first mixing chamber includes a circulating hydrogen inlet, a first mixture outlet and a tail oil fraction inlet which is connected to the tail oil fraction outlet.
    Type: Grant
    Filed: September 4, 2017
    Date of Patent: August 6, 2019
    Inventors: Tao Zhao, Bo Lai, Weiguang Yang, Dawei Wang, Xuewen Hao, Yanjie Zhou, Li Xu
  • Patent number: 10358611
    Abstract: An apparatus and process is disclosed for hydrocracking a hydrocarbon feed stream following hydrotreating the feed stream. A separator removes diesel and lower boiling materials in a hydrotreated stream before a hydrocracking reactor, so only liquid materials heavier than diesel are hydrocracked in a hydrocracking reactor. A vapor hydrotreated stream and the hydrocracked stream are separated and fractionated together.
    Type: Grant
    Filed: February 3, 2017
    Date of Patent: July 23, 2019
    Assignee: UOP LLC
    Inventors: Gabriela M. Gonzalez Lippke, Simerjeet Singh, Richard K. Hoehn
  • Patent number: 10358608
    Abstract: A process for the hydrocracking of heavy oils and/or oil residues, the process comprising the step of contacting the heavy oils and/or oil residues with a non-metallised carbonaceous additive in the presence of a hydrogen-containing gas at a temperature of from 250° C. to 600° C. wherein the non-metallised carbonaceous additive has an average pore size of at least 2 nm.
    Type: Grant
    Filed: February 12, 2015
    Date of Patent: July 23, 2019
    Assignee: BP Corporation North America Inc.
    Inventors: Andreas Schleiffer, Hong Yang
  • Patent number: 10351778
    Abstract: Methods and systems for producing anode grade coke are disclosed, which allow anode grade coke to be produced from crude oil having a high sulfur content. A fraction of the resid is hydrotreated while another fraction of the resid is treated in a solvent deasphalting unit. A synthetic stream is provided by blending hydrotreated resid with one or more streams from the deasphalting unit. The synthetic stream is fed to an anodic coker unit.
    Type: Grant
    Filed: May 23, 2017
    Date of Patent: July 16, 2019
    Assignee: Kellogg Brown & Root LLC
    Inventor: Rashid Iqbal
  • Patent number: 10351785
    Abstract: Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by with an apparatus arranged for flashing the feed at a target cut point temperature to obtain two fractions. A low boiling temperature fraction contains refractory, sterically hindered sulfur-containing compounds, which have a boiling point at or above the target cut point temperature. A high boiling temperature fraction, having a boiling point below the target cut point temperature, is substantially free of refractory sulfur-containing compounds. The high boiling temperature fraction is contacted with isomerization catalyst, and the isomerized effluent and the low boiling temperature fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level.
    Type: Grant
    Filed: October 10, 2018
    Date of Patent: July 16, 2019
    Assignee: Saudi Arabian Oil Company
    Inventor: Omer Refa Koseoglu
  • Patent number: 10351784
    Abstract: The invention relates weldments useful as heat transfer tubes in pyrolysis furnaces. The invention relates to tubes that are useful in pyrolysis furnaces. The weldments include a tubular member and at least one mixing element. The tubular member comprises an aluminum-containing alloy. The mixing element comprises an aluminum-containing alloy. The mixing element's aluminum-containing alloy can be the same as or different from the tubular member's aluminum-containing alloy. Other aspects of the invention relate to pyrolysis furnaces which include such weldments, and the use of such pyrolysis furnaces for hydrocarbon conversion processes such as steam cracking.
    Type: Grant
    Filed: November 16, 2015
    Date of Patent: July 16, 2019
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: David B. Spicer, ChangMin Chun
  • Patent number: 10344238
    Abstract: An oil-coal co-hydrotreating processing includes the following steps: pulverized coal, vacuum residue and recycle oil are mixed to prepare coal slurry. After mixed with hydrogen, catalyst and additive, oil-coal slurry is preheated into a slurry bed reactor with high reacting pressure for thermal cracking and hydrogenation reaction. After reaction, all the products go into the hot high pressure separator for separation of solid from the bottom and gas from the top. The gas obtained goes into the fixed bed reactor for further hydrocracking or refining, and the distillate obtained enter the fractionating tower. The vacuum gas oil from the bottom of fractionating tower is taken as recycle oil piped to the oil-coal slurry mixing device as solvent.
    Type: Grant
    Filed: February 4, 2016
    Date of Patent: July 9, 2019
    Inventor: Suan Li
  • Patent number: 10345048
    Abstract: An apparatus is provided for processing reusable fuel comprising a first-type cyclone cooler having a first configuration. The apparatus also provides one or more second-type cyclone coolers, wherein each one or more second-type cyclone coolers has a substantially identical second configuration to respective other one or more second-type cyclone coolers, wherein the second configuration is different than the first configuration. The apparatus may also provide an air cooled heat exchanger, a coil condenser and one or more bubblers. The first-type cyclone cooler and the one or more second-type cyclone coolers are connected. One of the one or more second-type cyclone coolers is connected to the air cooled heat exchanger. The air cooled heat exchanger is connected to the coil condenser. The coil condenser is connected to the one or more bubblers.
    Type: Grant
    Filed: May 12, 2017
    Date of Patent: July 9, 2019
    Assignee: Golden Renewable Energy, LLC
    Inventors: Anthony F. Tenore, David Fowler, Oluwaseun Oluwadare
  • Patent number: 10344225
    Abstract: Processes for upgrading partially converted vacuum residua hydrocarbon feeds are disclosed. The upgrading processes may include: steam stripping the partially converted vacuum residua to generate a first distillate and a first residuum; solvent deasphalting the first residuum stream to generate a deasphalted oil and an asphaltenes fraction; vacuum fractionating the deasphalted oil to recover a deasphalted gas oil distillate and a heavy deasphalted residuum; contacting the first distillate and the deasphalted gas oil distillate and hydrogen in the presence of a first hydroconversion catalyst to produce a product; contacting the heavy deasphalted residuum stream and hydrogen in the presence of a second hydroconversion catalyst to produce an effluent; and fractionating the effluent to recover a hydrocracked atmospheric residua and a hydrocracked atmospheric distillate.
    Type: Grant
    Filed: January 17, 2017
    Date of Patent: July 9, 2019
    Inventors: Ujjal K. Mukherjee, Mario C. Baldassari, Marvin I. Greene
  • Patent number: 10336947
    Abstract: The present invention relates to a process for conversion of a hydrocarbon feed comprising saturated hydrocarbon compounds to olefin products comprising contacting a hydrocarbon feed stream with a catalyst in an oxidic form of the formula M1M2M3M4O comprising metals M1, M2, M3 and M4, wherein: M1 is selected from Si, Al, Zr, and mixtures thereof; M2 is selected from Pt, Cr, and mixtures thereof; M3 is selected from W, Mo, Re, and mixtures thereof; and M4 is selected from Sn, K, Y, Yb and mixtures thereof; wherein: mass fraction of M1 is in the range of 0.1 to 0.8; mass fraction of M2 is in the range of 0.001 to 0.2; mass fraction of M3 is in the range of 0.001 to 0.2; mass fraction of M4 is in the range of 0.0001 to 0.2; and mass fraction of oxygen is in the range of 0.1 to 0.8.
    Type: Grant
    Filed: June 29, 2016
    Date of Patent: July 2, 2019
    Assignee: SMH Co., Ltd
    Inventors: Kongkiat Suriye, Amnart Jantharasuk, Wuttithep Jareewatchara
  • Patent number: 10335713
    Abstract: An extraction apparatus and a processes for preparing extracts of natural products, such as plant material, and for preparing purified extracts from crude extracts of natural products by extraction with a non-polar solvent hot gas.
    Type: Grant
    Filed: March 18, 2016
    Date of Patent: July 2, 2019
    Assignee: Precision Extraction Corporation
    Inventor: Nicholas Tennant
  • Patent number: 10329495
    Abstract: A process is presented for the removal of contaminants like oxygenates from hydrocarbons. The contaminant oxygenates are removed from hydrocarbons that may be feed to cracking units. A crude feed stream is fed to a water wash column along with water to remove oxygenates and is subsequently treated with an adsorbent to effectively remove all the oxygenates from the crude hydrocarbon. A regenerant medium from a naphtha hydrotreating unit is used to regenerate the adsorbent.
    Type: Grant
    Filed: August 11, 2017
    Date of Patent: June 25, 2019
    Assignee: UOP LLC
    Inventors: Soumendra Mohan Banerjee, Jayant K. Gorawara, Pijus Kanti Roy