Patents Examined by Juan C Valencia
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Patent number: 11879104Abstract: A hydrocarbon recovery facility includes: a washing column configured to bring a gas and water into contact to deposit a hydrocarbon contained in the gas into the water; an automatic strainer for continuously removing the hydrocarbon together with part of the water from the water mixed with the hydrocarbon; an oil-water mixing drum for mixing the water and the hydrocarbon removed by the automatic strainer with an organic solvent to prepare an oil-water mixture; and an oil-water separation drum for separating the oil-water mixture prepared in the oil-water mixing drum into an oil phase and a water phase.Type: GrantFiled: February 22, 2019Date of Patent: January 23, 2024Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Kaori Yoshida, Rikio Kan, Seiji Kakesako
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Patent number: 11873463Abstract: A method for re-refining used oils comprises contacting feedstock comprising purified used oil with extraction solvent to perform continuous liquid-liquid solvent extraction, to produce an extract stream comprising the extraction solvent and an extract dissolved in the extraction solvent. The feedstock and the extraction solvent are agitated by a variable speed agitator during the solvent extraction at a selected agitation speed. The extract is separated from the extraction solvent and subjected to a continuous flow liquid phase hydrogenation treatment to produce an oil product. A system for performing the method includes a purification unit for purifying the used oil; an extraction column for extracting the extract from the feedstock; and a continuous flow liquid phase hydrogenation unit. The extraction column comprises an agitator configured to agitate the feedstock and the extraction solvent flowing through the extraction column at a variable agitation speed.Type: GrantFiled: February 5, 2020Date of Patent: January 16, 2024Assignee: ReGen III Corp.Inventors: Gordon Driedger, Zachary Moore
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Methods for processing hydrocarbons to produce light olefins using catalyst formulations or mixtures
Patent number: 11873452Abstract: Light olefins may be produced from hydrocarbons by a method including passing a hydrocarbon feed stream into one or more feed inlets of a reactor, using catalyst formulations or mixtures. Catalyst formulations may include multi-zeolite composite particles, or a mixture that is a physically mixed combination of separate particles of at least first composite particles of a first type of zeolite and second composite particles of a second type of zeolite. The reactor may include an upper reactor portion defining an upper reaction zone and a lower reactor portion defining a lower reaction zone. The catalyst may move in a generally downward direction through the upper reactor portion and the lower reactor portion, and the hydrocarbon feed stream may move in a generally upward direction through the lower reactor portion and upper reactor portion such that the hydrocarbon feed stream and the catalyst move with a counter-current orientation.Type: GrantFiled: December 12, 2022Date of Patent: January 16, 2024Assignees: SAUDI ARABIAN OIL COMPANY, King Abdullah University Of Science And TechnologyInventors: Ola S. Ali, Khalid Ali Almajnouni, Jorge Gascon Sabate, Tuiana Bairovna Shoinkhorova, Alberto Rodriguez Gomez, Alla Dikhtiarenko -
Patent number: 11873458Abstract: A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; recovering at least part of the raw synthesis gas from the gasification zone and supplying at least part of the recovered raw synthesis gas to a partial oxidation zone; equilibrating the H2:CO ratio of the raw synthesis gas in the partial oxidation zone to obtain equilibrated synthesis gas; recovering at least part of the equilibrated synthesis gas from the partial oxidation zone and treating the gas to remove impurities and generate a fine synthesis gas; and converting the optionally adjusted fine synthesis gas into the useful product in a further chemical reaction requiring a usage ratio.Type: GrantFiled: January 5, 2023Date of Patent: January 16, 2024Assignee: Velocys Technologies LtdInventors: Ivan Philip Greager, Roger Allen Harris, Neil Alexander King, Soumitra R. Deshmukh, Zheyan Qiu, Ashish Gupta
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Patent number: 11866658Abstract: A process for the production of ultralow aromatic specialty distillate from different refinery streams particularly high sulfur streams. The process produces de-aromatized distillates with benzene content below 1 ppmw. Hydrocarbon feedstock having boiling temperature in the range of 90 and 350° C., preferably 140 and 320° C. The hydrocarbon feedstocks are obtained from any petroleum-refinery or bio-refinery or any other source producing hydrocarbon streams.Type: GrantFiled: December 19, 2022Date of Patent: January 9, 2024Inventors: Vasamsetty Naga Veera Hima Bindu, Mainak Sarkar, Ganesh Vitthalrao Butley, Ramesh Karumanchi, Sarvesh Kumar, Madhusudan Sau, Sankara Sri Venkata Ramakumar
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Patent number: 11866652Abstract: This disclosure relates to a procedure, which through the application of a catalyst in homogeneous phase, allows the transformation of heavy hydrocarbons (vacuum residue, atmospheric residue, heavy and extra-heavy crudes) into hydrocarbons of lower molecular weight, characterized because after its application, the hydrocarbons obtain greater API gravity, lower kinematic viscosity and different composition by hydrocarbon families (SARA) that increases the proportion of saturated and aromatic resins and asphalts. The sulphur and nitrogen content is also reduced, resulting in higher yields to high commercial value distillates and a lighter product as compared to the original crude.Type: GrantFiled: December 19, 2022Date of Patent: January 9, 2024Assignee: INSTITUTO MEXICANO DEL PETROLEOInventors: Persi Schacht Hernandez, Jose Manuel Dominguez Esquivel, Benjamin Portales Martinez, Ismael Soto Escalante
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Patent number: 11845901Abstract: A method of converting a liquid hydrocarbon stream to lower boiling point hydrocarbons may include converting the liquid hydrocarbon stream to an aerosolized hydrocarbon particle stream, and subjecting the aerosolized hydrocarbon particle stream to reaction conditions. Reaction conditions may include a temperature from 25° C. to 1,000° C. and a pressure from 1 bar to 15 bar. The method may further include forming the lower boiling point hydrocarbons in the aerosolized hydrocarbon particle stream and separating the lower boiling point hydrocarbons from the aerosolized hydrocarbon particle stream. The lower boiling point hydrocarbons may comprise at least C2—C4 olefins.Type: GrantFiled: July 11, 2022Date of Patent: December 19, 2023Assignee: SAUDI ARABIAN OIL COMPANYInventors: Brian Hanna, Michele Louisa Ostraat, Sergio Fernandez
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Patent number: 11840672Abstract: The present invention relates to a process and system for complete conversion of crude oils by integrating Desalter unit, Atmospheric and vacuum column, high severity FCC process, Naphtha cracking process, residue slurry hydrocracking process, Delayed coking process, Selective mild hydrocracking aromatic production unit, Dehydrogenation units, Aromatic/olefin recovery section, gasifier unit along with syngas to olefins conversion section.Type: GrantFiled: January 11, 2023Date of Patent: December 12, 2023Assignee: INDIAN OIL CORPORATION LIMITEDInventors: Ponoly Ramachandran Pradeep, Shahil Siddiqui, Vineeth Venu Nath, Darshankumar Manubhai Dave, Mainak Sarkar, Satyen Kumar Das, Madhusudan Sau, Sankara Sri Venkata Ramakumar
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Patent number: 11834616Abstract: Combined hydroprocessing and solvent deasphalting with sequential addition of a dispersed catalyst to process heavy oil without increasing equipment fouling. An example method includes: hydroprocessing heavy oil containing dispersed catalyst particles to yield upgraded heavy oil; subjecting a resid portion of the upgraded heavy oil to solvent deasphalting to produce DAO and pitch; and hydroprocessing the deasphalted oil containing dispersed catalyst particles to yield upgraded deasphalted oil.Type: GrantFiled: July 13, 2022Date of Patent: December 5, 2023Assignee: HYDROCARBON TECHNOLOGY & INNOVATION, LLCInventors: David M. Mountainland, Brett M. Silverman
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Patent number: 11827857Abstract: Systems and methods for producing olefins and/or aromatics are disclosed. Methods disclosed includes thermal hydro-processing of crude oils and/or heavy oils and/or residues, in a thermal hydro-processing unit, to produce intermediate products, which can then be used to make valuable chemicals such as olefins and aromatics.Type: GrantFiled: January 27, 2020Date of Patent: November 28, 2023Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Ravichander Narayanaswamy, Hatem Belfadhel, Girish Koripelly, Alexander Stanislaus, Krishna Kumar Ramamurthy, Krishnan Sankaranarayanan
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Patent number: 11827855Abstract: A process for converting crude oil to light olefins, aromatics, or both, includes contacting a crude oil with an FCC catalyst composition in a fluidized catalytic cracking system at a temperature of greater than or equal to 580° C., a weight ratio of the FCC catalyst to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. Contacting causes at least a portion of hydrocarbons in the crude oil to undergo cracking reactions to produce a cracked effluent comprising at least olefins. The FCC catalyst composition for producing olefins and aromatics from crude oil includes ultrastable Y-type zeolite impregnated with lanthanum, ZSM-5 zeolite impregnated with phosphorous, where the nano-ZSM-5 zeolite has an average particle size of from 0.01 ?m to 0.2 ?m, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay.Type: GrantFiled: July 6, 2022Date of Patent: November 28, 2023Assignee: Saudi Arabian Oil CompanyInventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami, Qi Xu, Aaron Akah
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Patent number: 11820948Abstract: A process for upgrading crude oil through steam enhanced catalytic cracking includes contacting crude oil with steam and a cracking catalyst at a mass ratio of steam to crude oil of 0.2-1. The cracking catalyst is a hierarchical mesoporous ZSM-5 zeolite impregnated with phosphorous, cerium, lanthanum, and iron. Contacting the crude oil with steam and the cracking catalyst cracks a portion of the crude oil to produce light olefins, light aromatic compounds, or both. The cracking catalyst is prepared by partially disintegrating a starting ZSM-5 zeolite in a first mixture comprising sodium hydroxide and a surfactant and, after the disintegrating, recrystallizing zeolite constituents in the presence of the surfactant to produce a recrystallized ZSM-5 zeolite having a hierarchical pore structure. The recrystallized ZSM-5 zeolite is recovered and calcined to produce the hierarchical mesoporous ZSM-5 zeolite, which is then impregnated with the phosphorous, lanthanum, cerium, and iron.Type: GrantFiled: September 29, 2022Date of Patent: November 21, 2023Assignee: Saudi Arabian Oil CompanyInventors: Aaron Chi Akah, Veera Venkata Ramakrishna Tammana
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Patent number: 11820950Abstract: An integrated process and associated system for conversion of crude oil to value added petrochemicals. The process includes separating crude oil into light and heavy crude fractions and processing the heavy fraction in a solvent deasphalting unit and a delayed coker unit, and then providing the light fraction and selected effluents of the solvent deasphalting unit and the delayed coker unit to a hydrotreater. The process further includes separating the effluent of the hydrotreater to generate a C1 fraction passed to a methane cracker, a C2-C4 fraction passed to a steam cracker, a hydrotreated light fraction passed to an aromatization unit, and a hydrotreated heavy fraction passed to a steam enhanced catalytic cracking unit. The process further includes separating effluents of the methane cracker, the steam cracker, the aromatization unit, and the steam enhanced catalytic cracking unit into product streams including a BTX stream and a light olefin stream.Type: GrantFiled: June 16, 2022Date of Patent: November 21, 2023Assignee: Saudi Arabian Oil CompanyInventors: Aaron Chi Akah, Essa Alnaimi, Qi Xu, Musaed Salem Al-Ghrami, Zhonglin Zhang
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Patent number: 11814589Abstract: Provided is a technology to convert an oil having a high content of Cl into a solvent. Impurities such as Cl, S, N, and metals are removed from an oil having a boiling point of 340° C. or lower in a waste oil having a high content of Cl, and hydrogenation is carried out to recover an oil, and the oil may be applied as a solvent. Separation by boiling points to meet the properties of the solvent product is performed, a solid acid material and an oil having a high Cl content are mixed, impurities are removed by a heat treatment at a high temperature, and hydrogenation is carried out with a metal oxide catalyst, thereby manufacturing a solvent product.Type: GrantFiled: April 20, 2022Date of Patent: November 14, 2023Assignees: SK Innovation Co., Ltd., SK Geo Centric Co., Ltd.Inventors: Do Kyoung Kim, Ka Young Kim, Jeong Eop Choi, Ok Youn Kim, Hee Soo Kim, Young Moo Park, Ho Won Lee, Jae Suk Choi, Hee Jung Jeon
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Patent number: 11813551Abstract: The methods and embodiments described herein involve installation of a gas sparging manifold into crude oil storage tanks, which facilitates removal of hydrogen sulfide (H2S) from bulk crude oil. Hydrogen sulfide stripped from the crude oil is scavenged via a forced-draft scavenging gas into a scavenging duct, and passes through an in-line filter. An alternative embodiment can be adapted for mobile use in a tank trailer/tank car capable of being towed by a tractor truck or locomotive.Type: GrantFiled: July 26, 2022Date of Patent: November 14, 2023Assignee: Viro Petroleum & Energy, LLCInventor: Robert D. Allison, III
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Patent number: 11814593Abstract: According to at least one aspect of the present disclosure, a process for processing a crude oil with an API between 30 and 35 degrees includes contacting the crude oil with one or more hydroprocessing catalysts to produce a hydroprocessed effluent. The hydroprocessed effluent is passed to an HS-FCC unit, where the hydroprocessed effluent is contacted with a cracking catalyst composition comprising nano-ZSM-5 zeolite and an ultrastable Y-type zeolite (USY zeolite) to form a cracked effluent comprising at least one product. The HS-FCC catalyst composition further comprises nano-ZSM-5 zeolite that has an average particle size of from 0.01 micrometers (?m) to 0.2 ?m, USY zeolite impregnated with lanthanum, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay. The cracked effluent comprises at least olefins, aromatic compounds, or both.Type: GrantFiled: December 12, 2022Date of Patent: November 14, 2023Assignee: Saudi Arabian Oil CompanyInventors: Mansour Ali Al Herz, Aaron Akah, Qi Xu, Lianhui Ding, Bander Al Ghamdi
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Patent number: 11814588Abstract: Methods for preventing elemental sulfur deposition from a hydrocarbon fluid is disclosed. A mercaptan is added to a hydrocarbon fluid that has elemental sulfur and reacted with the elemental sulfur to produce a disulfide and hydrogen sulfide. Amines and/or surfactants can assist with the process. Secondary reactions between the disulfide and the elemental sulfur result in a polysulfide and a solvated sulfur-disulfide complex. The disulfide, hydrogen sulfide, polysulfide and solvated sulfur-disulfide complex do not deposit, and can optionally be removed.Type: GrantFiled: January 5, 2023Date of Patent: November 14, 2023Assignee: CONOCOPHILLIPS COMPANYInventors: Jay Locklear, David P. Cope
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Patent number: 11814594Abstract: According to at least one aspect of the present disclosure, a process for processing a crude oil with an API between 25 and 29 degrees includes contacting the crude oil with one or more hydroprocessing catalysts to produce a hydroprocessed effluent. The hydroprocessed effluent is passed to an HS-FCC unit, where the hydroprocessed effluent is contacted with a cracking catalyst composition comprising nano-ZSM-5 zeolite and an ultrastable Y-type zeolite (USY zeolite) to form a cracked effluent comprising at least one product. The HS-FCC catalyst composition further comprises nano-ZSM-5 zeolite that has an average particle size of from 0.01 micrometers (?m) to 0.2 ?m, USY zeolite impregnated with lanthanum, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay. The cracked effluent comprises at least olefins, aromatic compounds, or both.Type: GrantFiled: December 12, 2022Date of Patent: November 14, 2023Assignee: Saudi Arabian Oil CompanyInventors: Mansour Ali Al Herz, Aaron Akah, Qi Xu, Lianhui Ding, Bander Al Ghamdi
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Patent number: 11802246Abstract: A combination of at least one basic compound, such as potassium hydroxide, together with at least one aldehyde donor can synergistically scavenge mercaptans from organic fluids, such as hydrocarbons, where “synergistically effective” is defined as the amount of mercaptans scavenged is greater as compared with a combination where either the basic compound or the reaction product is absent, used in the same total amount.Type: GrantFiled: March 11, 2021Date of Patent: October 31, 2023Assignee: BAKER HUGHES OILFIELD OPERATIONS LLCInventors: Peng Jin, Zhengwei Liu, Jerry J. Weers, Sunder Ramchandran, Jagrut Jani, Scott Lehrer, Johnathon Brooks
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Patent number: 11795405Abstract: The invention relates to a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut, hydrogen and a regenerated catalyst are brought into contact, said process being carried out at a temperature of between 200° C. and 400° C., a total pressure of between 1 and 3 MPa, an hourly space velocity, defined as being the flow rate by volume of feedstock relative to the volume of catalyst, of between 1 and 10 h?1; and a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 SI/I, said regenerated catalyst resulting from an at least partially spent catalyst resulting from a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut and comprises at least one metal from group VIII, at least one metal from group VIb and an oxide support.Type: GrantFiled: December 10, 2019Date of Patent: October 24, 2023Assignee: IFP Energies NouvellesInventors: Elodie Devers, Philibert Leflaive, Etienne Girard