Abstract: The present invention is directed to an electroconductive silver thick film paste composition comprising Ag, a glass frit and rhodium resinate, Cr2O3 or a mixture thereof all dispersed in an organic medium. The present invention is further directed to an electrode formed from the paste composition and a semiconductor device and, in particular, a solar cell comprising such an electrode. The paste is particularly useful for forming a tabbing electrode.
Type:
Grant
Filed:
September 25, 2012
Date of Patent:
May 5, 2015
Assignee:
E I du Pont de Nemours and Company
Inventors:
Kenneth Warren Hang, Yu-Cheng Lin, Yueli Wang
Abstract: The invention relates to a novel method for producing a carbon-doped lithium sulfide powder, according to which elementary lithium is reacted with elementary sulfur and/or a sulfur-containing compound selected from the group containing CS2, COS, SO2 and SO, in a liquid state, in an aliphatic or cycloaliphatic hydrocarbon solvent. The products of the method according to the invention are used to produce lithium battery electrodes or a lithium-ion-conducting solid.
Abstract: The invention relates to a novel process for preparing lithium sulfide and to the use thereof, wherein a reaction of lithium-containing strong bases with hydrogen sulfide is undertaken in an aprotic organic solvent within the temperature range from ?20 to 120° C. under inert conditions. The lithium sulfide obtained by the process is used as a positive material in a galvanic element or for the synthesis of Li ion-conductive solids, especially for the synthesis of glasses, glass ceramics or crystalline products.
Type:
Grant
Filed:
May 29, 2012
Date of Patent:
April 28, 2015
Assignee:
Chemetall GmbH
Inventors:
Peter Rittmeyer, Ulrich Wietelmann, Uwe Lischka, Dieter Hauk, Bernhard Füger, Armin Stoll, Dirk Dawidowski
Abstract: The object of the present invention is to provide a method for producing a conductive material that has a low electric resistivity and that is obtained using an inexpensive and stable conductive material composition. A conductive material having a low electric resistivity can be obtained by a method including the step of heating a conductive material composition that contains at least one of a full-cured or semi-cured thermosetting resin and a thermoplastic resin, as well as silver particles. Such a conductive material is a conductive material that includes fused silver particles, and thermosetting resin fine particles that have an average particle diameter of 0.1 ?m to 10 ?m both inclusive and are dispersed in the fused silver particles. Further, in such a conductive material is a conductive material that includes fused silver particles, and a thermoplastic resin welded among the fused silver particles.
Abstract: The present invention relates to a composition for a one-part die attach adhesives material useful for packaging semi-conductors including HB-LED. The composition of the present invention includes a thermal and electrical conductive filler, a polymer matrix and a solvent which form a material with high thermal conductivity, low curing temperature and high self-life temperature. The present invention also relates to a method of preparing said composition by mixing a size-selected and surface-modified filler formulation, a polymer matrix and a non-reactive organic solvent together followed by curing the mixture at a low temperature.
Type:
Grant
Filed:
March 22, 2012
Date of Patent:
April 14, 2015
Assignee:
Nano and Advanced Materials Institute Limited
Inventors:
Chenmin Liu, Dong Lu, Xianxin Lang, Bo Wang, Zhiying Li
Abstract: The invention relates to a method for manufacturing a composite positive electrode active material being a composite of a positive electrode active material and carbon nanotubes. The manufacturing method includes preparing an aqueous solution of a starting material of a positive electrode active material containing a starting material of the positive electrode active material, and an aqueous solution of solubilized carbon nanotubes containing the carbon nanotubes and a solubilizing material that is composed of a water-soluble polymer whose solubilization retention rate of carbon nanotubes does not decrease with rising temperature; and synthesizing a positive electrode active material-carbon nanotube composite by mixing the aqueous solution of a starting material of a positive electrode active material and the aqueous solution of solubilized carbon nanotubes, and performing hydrothermal synthesis.
Abstract: Methods of manufacturing nano-engineered carbon materials, such as carbon aerogels and carbon xerogels, and methods of manufacturing precursor solutions and sol-gels for making the same are provided. A method for manufacturing a precursor solution comprises programmed-addition of a cross-linking agent to a component mixture comprising a resorcinol compound. A method for manufacturing a sol-gel comprises subjecting a precursor solutions to at least one heat treatment. Methods for producing nano-engineered carbon materials from precursor solutions and sol-gels are also provided. Methods for using the nano-engineered carbon materials are also disclosed. The resulting nano-engineered carbon materials can be useful in a range of products including, supercapacitor applications, high-surface-area electrodes, fuel cells, and desalination systems.
Type:
Grant
Filed:
June 9, 2011
Date of Patent:
April 7, 2015
Assignee:
Georgia-Pacific Chemicals LLC
Inventors:
Sudhir M. Mulik, Joseph F. Ludvik, Robert W. Fleming, Christopher M. Lee
Abstract: An oxide sintered body including indium element (In), gallium element (Ga) and tin element (Sn) in atomic ratios represented by the following formulas (1) to (3): 0.10?In/(In+Ga+Sn)?0.60??(1) 0.10?Ga/(In+Ga+Sn)?0.55??(2) 0.0001<Sn/(In+Ga+Sn)?0.60??(3).
Type:
Grant
Filed:
February 22, 2011
Date of Patent:
April 7, 2015
Assignee:
Idemitsu Kosan Co., Ltd.
Inventors:
Masayuki Itose, Mami Nishimura, Masashi Kasami, Koki Yano
Abstract: Metal nanoparticles having improved migration resistance are provided. The present invention relates to a method for manufacturing composite nanoparticles including obtaining composite nanoparticles containing at least silver and copper in a single particle by heat treating a mixture containing an organic silver compound and an organic copper compound at a temperature of 150° C. or more in a non-oxidative atmosphere in the presence of a tertiary amine compound represented by the general formula R1R2R3N (wherein R1 through R3 are optionally substituted alkyl groups or aryl groups that may be the same or different, R1 through R3 may be linked in a ring, and the number of carbon atoms in each of R1 through R3 is 5 through 18 and may be the same or different).
Type:
Grant
Filed:
August 6, 2009
Date of Patent:
April 7, 2015
Assignees:
Osaka Municipal Technical Research Institute, Daiken Chemical Co., Ltd.
Abstract: In a manufacturing process of a positive electrode active material for a power storage device, which includes a lithium silicate compound represented by a general formula Li2MSiO4, heat treatment is performed at a high temperature on a mixture material, grinding treatment is performed, a carbon-based material is added, and then heat treatment is performed again. Therefore, the reactivity between the substances contained in the mixture material is enhanced, favorable crystallinity can be obtained, and further microparticulation of the grain size of crystal which is grown larger by the high temperature treatment and crystallinity recovery are achieved; and at the same time, carbon can be supported on the surfaces of particles of the crystallized mixture material. Accordingly, a positive electrode active material for a power storage device, in which electron conductivity is improved, can be manufactured.
Type:
Grant
Filed:
October 14, 2011
Date of Patent:
March 31, 2015
Assignee:
Semiconductor Energy Laboratory Co., Ltd.
Inventors:
Masaki Yamakaji, Koji Nara, Mako Motoyoshi
Abstract: Disclosed is a silicon-carbon composite for a negative active material of a lithium secondary battery, including carbon nanofibers and silicon particles, wherein the silicon particles are coated with amorphous silica. In the silicon-carbon composite of the invention, silicon is provided in the form of a composite with carbon fibers and the surface of silicon particles is coated with amorphous silica, thereby reducing volume expansion upon lithium ion insertion and exhibiting superior ionic conductivity and electrical conductivity to thus maintain high capacity, and also, amorphous silica-coated silicon is positioned inside the carbon fibers having a one-dimensional structure, thus ensuring a large specific surface area and a stable composite structure.
Type:
Grant
Filed:
August 22, 2012
Date of Patent:
March 24, 2015
Assignee:
Dongguk University Industry-Academic Cooperation Foundation
Inventors:
Yong-Mook Kang, Young-Min Lee, Kyeong-Se Song
Abstract: A conductive paste containing a conductive powder (A), a vinyl chloride-vinyl acetate resin (B), a polyester resin and/or polyurethane resin (C), a blocked isocyanate (D) blocked with an active methylene compound, and an organic solvent (E), wherein the resin (C) has a glass transition temperature of ?50° C. to 20° C., a sum of amounts of the resin (C) is 50 to 400 parts by weight relative to 100 parts by weight of the resin (B), and a sum of amounts of the resin (B), the resin (C) component, and the blocked isocyanate (D) is 10 to 60 parts by weight relative to 100 parts by weight of the conductive powder (A). An electric wiring in which this conductive paste is formed on an insulating substrate.
Abstract: The present invention discloses a method for producing a positive electrode active material for a lithium secondary battery constituted by a lithium-nickel-cobalt-manganese complex oxide with a lamellar structure, the method including: (1) a step of preparing a starting source material for producing the complex oxide including a lithium supply source, a nickel supply source, a cobalt supply source, and a manganese supply source; (2) a step of pre-firing the starting source material by heating at a pre-firing temperature that has been set to a temperature lower than 800° C. and higher than a melting temperature of the lithium supply source; and (3) a step of firing the pre-fired material obtained in the pre-firing step by raising a temperature to a temperature range higher than the pre-firing temperature.
Abstract: A method of manufacturing a metal paste for an internal electrode according to the present invention includes preparing each of a metal powder and an organic vehicle; preparing a ceramic inhibitor powder in which a nano glass added with a rare-earth element is mixed; manufacturing a primary mixture by mixing the metal powder of 70 to 95 wt % and the ceramic inhibitor powder of 5 to 30 wt % when each of the metal powder, the organic vehicle, and the ceramic inhibitor powder in which the nano glass added with the rare-earth element is mixed is prepared; manufacturing a secondary mixture by mixing the primary mixture of 50 to 70 wt % and the organic vehicle of 30 to 50 wt % when the primary mixture is manufactured; and manufacturing the metal paste for the internal electrode by filtering the secondary mixture when the secondary mixture is manufactured.
Abstract: An active material for a nonaqueous electrolyte secondary battery includes first particles and second particles provided to coat the first particles so as to be scattered on the surfaces of the first particles. The circularity of the first particles coated with the second particles is 0.800 to 0.950, and the ratio r1/r2 of the average particle diameter r1 of the second particles to the average particle diameter r2 of the first particles is 1/20 to 1/2.
Abstract: To provide a power storage device including an electrode material having a large capacity. First heat treatment is performed on a mixture of a compound containing lithium; a compound containing a metal element selected from manganese, iron, cobalt, and nickel; and a compound containing phosphorus. A cleaning step is performed on the mixture subjected to the first heat treatment. Second heat treatment is performed on the mixture subjected to the cleaning step, so that a lithium phosphate compound is produced. With the use of the lithium phosphate compound, an electrode is formed.
Type:
Grant
Filed:
October 3, 2011
Date of Patent:
March 17, 2015
Assignee:
Semiconductor Energy Laboratory Co., Ltd.
Abstract: A conductive paste may include a conductive powder, a metallic glass including a first element having a heat of mixing value with the conductive powder of less than 0, and an organic vehicle, and an electronic device and a solar cell may include an electrode formed using the conductive paste.
Type:
Grant
Filed:
October 26, 2011
Date of Patent:
March 10, 2015
Assignees:
Samsung Electronics Co., Ltd., Industry-Academic Cooperation Foundation, Yonsei University of Yonsei Unversity
Inventors:
Se Yun Kim, Eun Sung Lee, Sang Soo Jee, In Yong Song, Sang Mock Lee, Do-Hyang Kim, Ka Ram Lim
Abstract: Planar or tubular sputtering targets made of a silver base alloy and at least one further alloy component selected from indium, tin, antimony, and bismuth accounting jointly for a weight fraction of 0.01 to 5.0% by weight are known. However, moving on to ever larger targets, spark discharges are evident and often lead to losses especially in the production of large and high-resolution displays having comparatively small pixels. For producing a sputtering target with a large surface area on the basis of a silver alloy of this type, which has a surface area of more than 0.3 m2 as a planar sputtering target and has a length of at least 1.0 m as a tubular sputtering target, and in which the danger of spark discharges is reduced and thus a sputtering process with comparatively high power density is made feasible, the invention proposes that the silver base alloy has a crystalline structure with a mean grain size of less than 120 ?m, an oxygen content of less than 50 wt.
Type:
Grant
Filed:
March 18, 2013
Date of Patent:
March 10, 2015
Assignee:
Heraeus Deutschland GmbH & Co. KG
Inventors:
Martin Schlott, Sabine Schneider-Betz, Uwe Konietzka, Markus Schultheis, Ben Kahle, Lars Ebel
Abstract: A method is employed for producing a positive electrode active material for a lithium secondary battery that comprises mixing lithium phosphate having a particle diameter D90 of 100 ?m or less, an M element-containing compound having a particle diameter D90 of 100 ?m or less (where, M is one type or two or more types of elements selected from the group consisting of Mg, Ca, Fe, Mn, Ni, Co, Zn, Ge, Cu, Cr, Ti, Sr, Ba, Sc, Y, Al, Ga, In, Si, B and rare earth elements) and water, adjusting the concentration of the M element with respect to water to 4 moles/L or more to obtain a raw material, and producing olivine-type LiMPO4 by carrying out hydrothermal synthesis using the raw material.
Abstract: An object of the present invention is to provide a method for producing a conductive material that allows a low electric resistance to be generated, and that is obtained by using an inexpensive and stable conductive material composition containing no adhesive. The conductive material can be provided by a producing method that includes the step of sintering a first conductive material composition that contains silver particles having an average particle diameter (median diameter) of 0.1 ?m to 15 ?m, and a metal oxide, so as to obtain a conductive material. The conductive material can be provided also by a method that includes the step of sintering a second conductive material composition that contains silver particles having an average particle diameter (median diameter) of 0.1 ?m to 15 ?m in an atmosphere of oxygen or ozone, or ambient atmosphere, at a temperature in a range of 150° C. to 320° C., so as to obtain a conductive material.
Type:
Grant
Filed:
January 9, 2009
Date of Patent:
March 3, 2015
Assignee:
Nichia Corporation
Inventors:
Masafumi Kuramoto, Satoru Ogawa, Katsuaki Suganuma, Keun-Soo Kim