Patents Examined by Lee C. Wright
  • Patent number: 5451501
    Abstract: A 1H-pyrazolo[1,5-b][1,2,4]triazole magenta coupler having a t-alkyl group at the position-6 and an amido group-substituted phenyl group at the position-2 is disclosed. There is also disclosed a silver halide color photographic material containing the same.
    Type: Grant
    Filed: May 26, 1993
    Date of Patent: September 19, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuki Mizukawa, Masuji Motoki, Tadahisa Sato, Osamu Takahashi
  • Patent number: 5451496
    Abstract: Color photographic materials comprise a substrate bearing a silver halide emulsion and a coupler composition comprising (a) a 2-phenylcarbamoyl-1-naphthol compound selected from the group consisting of development inhibitor releasing couplers and timed development inhibiting releasing couplers, and (b) a phenolic coupler solvent. The phenolic coupler solvent is employed to reduce dye density changes and/or dye hue changes resulting from cold storage of the photographic materials.
    Type: Grant
    Filed: March 28, 1994
    Date of Patent: September 19, 1995
    Assignee: Eastman Kodak Company
    Inventors: Paul B. Merkel, Melvin M. Kestner, Paul L. Zengerle
  • Patent number: 5449600
    Abstract: A silver halide color photographic material which contains a silver chlorobromide emulsion having a silver chloride content of 90 mol% or more or a silver chloride emulsion in at least one light-sensitive silver halide emulsion layer, said emulsion layer containing a 5-bromo-substituted simple cyanine dye. An image forming method comprising processing said photographic material with a processing solution containing a diaminostilbene compound having four or more strongly-hydrophilic substituents.
    Type: Grant
    Filed: September 15, 1994
    Date of Patent: September 12, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Inagaki, Toshiaki Kubo, Kentaro Okazaki, Akira Kase
  • Patent number: 5449589
    Abstract: A rewritable optical information recording medium of phase-change type wherein the recording, erasing, reproduction and rewriting of information are effected by irradiation of a high density energy flux such as laser beams. With the aim of obtaining a high erasing ratio in overwriting using a single laser beam, a constitution of medium has been devised whereby the same temperature-rise profile can be obtained for both the recorded mark part and the unrecorded (erased) part of the recording film. For example, by selecting the film thickness of each layer such that the optical absorbance at the wavelength of irradiation light source is the same in both the recorded part and the unrecorded part, an erasing ratio of -30 dB or more has been attained.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: September 12, 1995
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Noboru Yamada, Ken'ichi Nagata, Kenichi Nishiuchi
  • Patent number: 5449598
    Abstract: A silver halide color photographic material is disclosed, which comprises a support having provided thereon at least one hydrophilic colloidal layer, wherein the hydrophilic colloidal layer contains a novel coupler compound having a high dye forming rate and a high color density represented by general formula (I):(R.sup.1 COCHXCONR.sup.2 R.sup.3)--(CONHSO.sub.2 R.sup.4).sub.n(I)wherein R.sup.1 represents an alkyl group, an aryl group, a heterocyclic group, --NR.sup.5 R.sup.6 or --OR.sup.7 ; R.sup.2 and R.sup.3 each independently represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; R.sup.4 represents an alkyl group, aryl group, heterocyclic group or --NR.sup.8 R.sup.9 ; R.sup.5, R.sup.6, R.sup.8 and R.sup.9 each independently represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; R.sup.7 represents an alkyl group, an aryl group or a heterocyclic group; X represents a group capable of being released as an anion (X.sup.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: September 12, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoki Saito, Seiji Ichijima, Masuji Motoki, Takayoshi Kamio, Keiji Mihayashi
  • Patent number: 5447819
    Abstract: The invention provides a photographic element comprising a support bearing a photographic silver halide emulsion layer having associated therewith a high dye-yield coupler having the formula:COUP--(T).sub.m --L--DYEwhere COUP is the parent group of the coupler capable of reacting at the coupling position with oxidized color developer to form a first dye, T is one or more timing groups with m=1 or 2, L is a linking group selected from the group consisting of --OC(O)--, --OC(S)--, --SC(O)--, --SC(S)--, or --OC(.dbd.N SO.sub.2 R)--, where R is substituted or unsubstituted alkyl or aryl, and DYE is a second dye or precursor thereof, wherein there is present at least one T group that contains a substituent having the formula:--(LINK).sub.p --A--B--(C--D).sub.nwherein:LINK is an alkylene group capable of linking the above group to the group T, where p=0 or 1;A is a member selected from the group consisting of --NHCO--, --N(R')C(O)N(R--)--, --CONH--, --NR'SO.sub.2 --, --SO.sub.2 NR'--, and --OPO.sub.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: September 5, 1995
    Assignee: Eastman Kodak Company
    Inventors: Jared B. Mooberry, James J. Seifert, David Hoke, Zheng Z. Wu, David T. Southby, Frank D. Coms
  • Patent number: 5447830
    Abstract: Magenta image-dye couplers provide photographic elements and processes having superior photographic properties. The couplers are 3-anilino pyrazolone couplers having an aryl thio coupling-off group. The substituents of the coupler are specified to obtain advantageous properties.
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: September 5, 1995
    Assignee: Eastman Kodak Company
    Inventors: John L. Pawlak, David S. Bailey, William R. Schleigh, Charles E. Romano, Paul B. Merkel, Sundaram Krishnamurthy
  • Patent number: 5443945
    Abstract: The invention provides novel photographic compositions comprising a propene isomer of the formula ##STR1## wherein A B or E, each individually represent hydrogen, or an electron withdrawing group, selected for example from --CN, --NO.sub.2, --SO.sub.2 R, --SO.sub.2 NH--, --CO.sub.2 R, --COR, --CONHR, --CONHAr, --CF.sub.3 halogen, amino, aryl, aralkyl, alkyl, cycloalkyl, alkyl (carbonyl)oxy, aryl (carbonyl)oxy, carboxy, alkoxycarbonyl, aryloxycarbonyl, carbamomyl, acyl, alkylaminocarbonyl, arylaminocarbonyl, alkoxycarbonylamino, acylamino, ureido, alkylsulphonylamino, arylsulphonylamino, sulphamoylamino, alkylsulphonyl, arylsulphonyl, sulphamoyl, imido, alkylthio, arylthio and heterocycles; the invention also provides a propene isomer of the formula I wherein D represents a group of the formula Ar--L--wherein Ar is a phenyl group optionally substituted with one or more substituents, and --L-- is a linking group incorporating a lone pair of electrons; and A, B, E and X are defined as R is above defined.
    Type: Grant
    Filed: May 19, 1993
    Date of Patent: August 22, 1995
    Assignee: Eastman Kodak Company
    Inventor: Hugh M. Williamson
  • Patent number: 5441859
    Abstract: A silver halide photographic material having a hydrophilic colloid layer containing a dispersion of fine solid grains of at least one compound represented by formula (1) ##STR1## wherein R represents an alkyl group, an aryl group, an amino group, an alkoxy group, an aryloxy group or a heterocyclic group;L.sub.1, L.sub.2 and L.sub.3 each represents a methine group;Y represents a hydrogen atom, an alkyl group, an alkoxy group or a halogen atom;R and Y may be bonded to each other to form a ring; andn represents an integer of from 0 to 2;provided that R, Y, L.sub.1, L.sub.2 and L.sub.3 do not have a group having an ionizable proton or its salt.
    Type: Grant
    Filed: September 13, 1994
    Date of Patent: August 15, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiharu Yabuki, Keiichi Suzuki
  • Patent number: 5441862
    Abstract: A color photographic recording material with at least one silver halide emulsion layer and a color coupler associated with that layer, which contains in the silver halide emulsion layer or in an adjacent non-photosensitive binder layer a combination of a color coupler and a compound corresponding to general formula (I) or (II): ##STR1## in which R.sub.4 is the residue of a polymer produced by polycondensation andR.sub.1 to R.sub.3, m and n are as defined in the specification, ##STR2## in which R.sub.4 is as defined above and L.sub.1, L.sub.2, X, R.sub.5 to R.sub.11, p, q and r are as defined in the specification,is distinguished by improved stability of the image dyes produced from yellow couplers.
    Type: Grant
    Filed: October 27, 1994
    Date of Patent: August 15, 1995
    Assignee: Agfa-Gevaert AG
    Inventors: Beate Weber, Gunter Helling, Markus Geiger
  • Patent number: 5441851
    Abstract: A photographic element with a support and a silver halide emulsion layer includes a two-equivalent pyrazolone magenta dye-forming coupler and a heterocyclic nitrogen addendum which is a protic imidazole or a pyridine. The heterocylic nitrogen compound reduces continued coupling of two-equivalent magenta dye-forming couplers after removal from a developer solution, obviating the need for a stop bath after the development stage.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: August 15, 1995
    Assignee: Eastman Kodak Company
    Inventors: Stephen P. Singer, Paul B. Merkel
  • Patent number: 5441863
    Abstract: Novel imidazo[3,2-a]imidazole cyan dye-forming couplers and photographic elements containing them are described. The couplers are represented by the following structure: ##STR1## wherein: EWG.sub.1 and EWG.sub.2 each independently represent an electron withdrawing group;X is hydrogen or a coupling-off group; andR.sup.1 is hydrogen or a substituent group.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: August 15, 1995
    Assignee: Eastman Kodak Company
    Inventors: Ping W. Tang, Thomas H. Jozefiak, David J. Decker
  • Patent number: 5437962
    Abstract: A photographic element having at least one photosensitive silver halide layer and associated therewith both a particular type of color coupler and a particular type of stabilizer. The color coupler is of the general formula (1) or (2): ##STR1## wherein A and B represent the same or different electron-withdrawing group,X is H or a group which splits off on coupling with oxidized color developer,R is an alkyl, cycloalkyl, aryl or heterocyclic which may be substituted, --COR.sup.1, --CSR.sup.1, SOR.sup.1, SO.sub.2 R.sup.1, --NHCOR.sup.1, --CONHR.sup.1, --COOR.sup.1, --COSR.sup.1, --NHSO.sub.2 R.sup.1 wherein R.sup.1 is an alkyl, cycloalkyl, or aryl group any of which are optionally substituted, and wherein two or more of A, B, R, and X optionally form part of a ring,Link is a linking group andn is 0, 1 or 2.The stabilizer is of the general formula (II), (III) or (IV): ##STR2## wherein the substituents of (II), (III) and (IV) are as defined in the specification.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: August 1, 1995
    Assignee: Eastman Kodak Company
    Inventors: Rakesh Jain, Thomas H. Jozefiak, Hugh M. Williamson
  • Patent number: 5436124
    Abstract: A photographic element comprising a support, at least one photosensitive silver halide layer and associated therewith a color coupler and a stabilizer therefor which stabilizer is an acrylate or acrylamide homopolymer or copolymer of low water solubility, the color coupler being of the general formula (1) or (2): ##STR1## wherein A and B represent the same or different electron-withdrawing group,X is H or a group which splits off on coupling with oxidised color developer,R is an alkyl, cycloalkyl, aryl or heterocyclic which may be substituted, --COR.sup.1, --CSR.sup.1, SOR.sup.1, SO.sub.2 R.sup.1, --NHCOR.sup.1, --CONHR.sup.1, --COOR.sup.1, --COSR.sup.1, --NHSO.sub.2 R.sup.1 wherein R.sup.1 is an alkyl, cycloalkyl, or aryl group any of which are optionally substituted, and wherein two or more of A, B, R, and X optionally form part of a ring,Link is a linking group andn is 0, 1 or 2.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: July 25, 1995
    Assignee: Eastman Kodak Company
    Inventors: Rakesh Jain, Thomas H. Jozefiak, Hugh M. Williamson
  • Patent number: 5436125
    Abstract: In a color photographic recording material, the light stability of a dye image produced from a magenta coupler and stabilized with a compound of the formula I may be further improved by additionally using a compound of one of the formulae II and III. ##STR1## In the formulae I, II and III, R.sup.1, R.sup.21, R.sup.25, R.sup.31, R.sup.34 mean H, alkyl, aryl, acyl;R.sup.2, R.sup.22, R.sup.32 mean --OR.sup.1 alkyl, aryl, dialkylamino, acylamino, sulphonamido, acyl, sulphonyl;R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.23, R.sup.24, R.sup.33 mean H, halogen or a residue as R.sup.2 ;m, n, q mean 0, 1, 2 or 3;o means 0, 1 or 2;p means a positive integer;A means alkylene, --O--, --S--, --NR.sup.25 --, --SO.sub.2 ;B means alkylene, --O--, --S--, --NR.sup.34 --, --SO.sub.2 --;wherein two adjacent residues --OR.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 may together complete a 5- to 8-membered ring, two adjacent residues --OR.sup.21, R.sup.23, R.sup.22 or --OR.sup.21, R.sup.24, R.sup.22, or --OR.sup.31, R.sup.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: July 25, 1995
    Assignee: Agfa-Gevaert AG
    Inventors: Jorg Hagemann, Beate Weber
  • Patent number: 5434041
    Abstract: A photographic element having at least one photosensitive silver halide layer and associated therewith both a particular type of color coupler and a particular type of stabilizer. The color coupler is of the general formula (1) or (2): ##STR1## wherein A and B represent the same or different electron-withdrawing group,X is H or a group which splits off on coupling with oxidized color developer,R is an alkyl, cycloalkyl, aryl or heterocyclic which may be substituted, --COR.sup.1, --CSR.sup.1, SOR.sup.1, SO.sub.2 R.sup.1, --NHCOR.sup.1, --CONHR.sup.1, --COOR.sup.1, --COSR.sup.1, --NHSO.sub.2 R.sup.1 wherein R.sup.1 is an alkyl, cycloalkyl, or aryl group any of which are optionally substituted, and wherein two or more of A, B, R, and X optionally form part of a ring,Link is a linking group andn is 0, 1 or 2.The stabilizer is of the general formula: ##STR2## wherein: E.sup.1, E.sup.2, W.sup.2 and W.sup.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: July 18, 1995
    Assignee: Eastman Kodak Company
    Inventors: Rakesh Jain, Thomas H. Jozefiak, Hugh M. Williamson
  • Patent number: 5434040
    Abstract: A photographic element having at least one photosensitive silver halide layer and associated therewith both a particular type of color coupler and a particular type of stabilizer. The color coupler is of the general formula (1) or (2): ##STR1## wherein A and B represent the same or different electron-withdrawing group,X is H or a group which splits off on coupling with oxidized color developer,R is an alkyl, cycloalkyl, aryl or heterocyclic which may be substituted, --COR.sup.1, --CSR.sup.1, SOR.sup.1, SO.sub.2 R.sup.1, --NHCOR.sup.1, --CONHR.sup.1, --COOR.sup.1, --COSR.sup.1, --NHSO.sub.2 R.sup.1 wherein R.sup.1 is an alkyl, cycloalkyl, or aryl group any of which are optionally substituted, and wherein two or more of A, B, R, and X optionally form part of a ring,Link is a linking group andn is 0, 1 or 2.The stabilizer is of the general formula (I) below: ##STR2## wherein: M is Cu, Co, Ni, Pd or Pt;W.sup.2, W.sup.3, W.sup.4 and W.sup.5 are defined in the specification.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: July 18, 1995
    Assignee: Eastman Kodak Company
    Inventors: Rakesh Jain, Thomas H. Jozefiak, Sundaram Krishnamurthy, John L. Pawlak, Hugh M. Williamson
  • Patent number: 5429913
    Abstract: Photographic coupler compositions comprise a magenta dye-forming coupler and an alcohol in an amount sufficient to increase the activity of the dye-forming coupler. The alcohol is of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of (a) unsubstituted alkyl and alkenyl groups, (b) alkyl groups containing one or more substitutents selected from the group consisting of aryl groups, alkenyl groups, halogen atoms, alkoxy groups, alkoxy carbonyl groups and acyloxy groups, (c) unsubstituted aryl groups and (d) aryl groups containing one or more substituents selected from the group consisting of alkyl groups, alkoxy groups, alkoxy carbonyl groups and acyloxy groups; and R.sub.2 and R.sub.3 are individually selected from hydrogen and the group of moieties from which R is selected, provided that the total number of carbon atoms contained in R.sub.1, R.sub.2 and R.sub.3 is at least 10.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: July 4, 1995
    Assignee: Eastman Kodak Company
    Inventors: Paul B. Merkel, Edward Schofield
  • Patent number: 5429917
    Abstract: A silver halide color photographic material is disclosed. The photographic material comprises a support having provided thereon at least one light-sensitive emulsion layer containing a coupler represented by the general formula (I) and/or a coupler represented by the general formula (II), silver iodobromide containing 15 to 45 mol % silver iodide in a definite layer structure in the emulsion layer, and chemically sensitized silver halide grains having a total silver iodide content of more than 7 mol %: ##STR1## wherein X.sup.1 and X.sup.2 each represents an alkyl group, an aryl group or a heterocyclic group; X.sup.3 represents an organic residue which forms a nitrogen-containing heterocyclic group together with >N--; Y represents an aryl group or a heterocyclic group; and Z represents a group capable of being separated from the coupler upon the reaction of the coupler with the oxidation product of a developing agent.
    Type: Grant
    Filed: May 26, 1994
    Date of Patent: July 4, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Naoki Saito, Seiji Ichijima
  • Patent number: 5427902
    Abstract: There is disclosed an acylacetamide-type yellow coupler having an acyl group represented by formula (I) and a silver halide color photographic material containing same. ##STR1## wherein R.sub.1 represents a monovalent group, Q represents a group of non-metallic atoms required to form together with the C a substituted or unsubstituted 3- to 5-membered cyclic hydrocarbon group or a substituted or unsubstituted 3- to 5-membered heterocyclic group having in the group at least one hetero atom selected from a group consisting of N, O, S, and P, provided that R.sub.1 is not a hydrogen atom and does not bond to Q to form a ring.
    Type: Grant
    Filed: December 15, 1992
    Date of Patent: June 27, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Shimura, Hidetoshi Kobayashi, Yasuhiro Yoshioka