Abstract: A process for the preparation of optionally cellular elastic moldings by the reaction injection molding technique in closed molds, in which isocyanate prepolymers A) based ona) polyisocyanates of the diphenylmethane series andb) polyether polyols having a maximum hydroxyl functionality of 2.4 are reacted with a reactive component B) consisting essentially of aromatic, alkyl-substituted diamines, optionally with the addition of auxiliary agents and additives d).

Abstract: A one component composition suitable for coating a substrate, including at least one crosslinker having a functionality thereon that is reactive with a functionality on at least one film forming polymer. The crosslinker includes at least one member selected from the group consisting of: blocked isocyanurates of isophorone diisocyanate; derivatives of blocked isocyanurates of isophorone diisocyanate; blocked biurets of isophorone diisocyanate; derivatives of blocked biurets of isophorone diisocyanate. The composition preferably includes a blend of this crosslinker with a second crosslinker, wherein the second crosslinker is at least one member selected from the group consisting of: blocked isocyanurates of hexamethylene diisocyanate; derivatives of blocked isocyanurates of hexamethylene diisocyanate; blocked biurets of hexamethylene diisocyanate; and derivatives of blocked biurets of hexamethylene diisocyanate.

Abstract: A polyurethane particulate liquid absorbent, optionally containing microspheres, and a process for its preparation. The absorbent is suitable for use in cleaning up spilled liquids ranging from mobile ones, such as gasoline, to visconsones, such as crude oil. The absorbent and absorbed liquid are readily separated by a centrifugation step, thus providing recovered liquid, and liquid-free absorbent for re-use.

Abstract: In one aspect, this invention is a primer comprising a solution of: (a) a polyester resin of a carboxylic acid and a glycol; (b) a polymethylene poly(phenyl isocyanate), diphenylmethane diisocyanate, or mixture thereof; and (c) a silane-containing moiety; in a solvent mixture comprising: (i) a high boiling polar solvent; (ii) an oxygenated solvent; and (iii) an aromatic solvent; wherein the weight ratio of (a):(b) is in the range of from about 0.25:1.0 to 2.0:1.0. In a second aspect, this invention is a primer comprising a solution of: (a) 5-50% of a polyester resin of a carboxylic acid and a glycol; (b) 5-50% of a polymethylene poly(phenyl isocyanate), diphenylmethane diisocyanate, or mixture thereof; (c) 0.1-50% of a silane-containing moiety; (d) 0.1-50% of a high boiling polar solvent; (e) 10-70% of an oxygenated solvent; and (f) 1-50% of an aromatic solvent.

Abstract: The present invention provides a curable coating composition comprising at least one fluorinated monoacrylate monomer, at least one polyethylenically unsaturated fluorinated crosslinking monomer different from the acrylate monomer, and at least one adhesion promoting monomer different from any other monomer in the composition of matter, which preferably is a fluorinated acrylamide silane. Optionally, fluorinated acrylamide silane monomers, non-fluorinated mono- or polyethylenically unsaturated monomers, or non-fluorinated silane adhesion promoting monomers may be added.The free radical polymerization product of the aforementioned coating composition provides a novel cladding material for optical fibers. The optical fibers of the invention can be used as waveguides in communications and laser delivery systems.

Abstract: Process for the preparation of filled heat-curable compounds of the polyurethane type by reaction of condensation of the constituents of the desired compound in the presence of a pulverulent filler, which is characterized in that the said filler is predispersed in the presence of a stabilizing agent in a liquid organic phase compatible with the desired heat-curable compound in the course of its formation reaction, the said filler being then in the form of a homogeneous and stable suspension, and the suspension thus prepared is then introduced into the reaction mixture before, during or after the introduction of at least one of the constituents of the desired heat-curable compound.The process according to the invention makes it possible to produce compounds of the polyurethane type whose mechanical and physical characteristics are at least equivalent or even improved in relation to those of the unfilled identical compounds by virtue of the excellent distribution of the inorganic filler.

Abstract: The present invention is directed to a process for sealing and/or priming concrete by applying to concrete an aqueous polyisocyanate dispersion which has an isocyanate content of at least 0.5% by weight, based on the weight of the polyisocyanate, and is prepared bya) dispersing in water a polyisocyanate which has an isocyanate content of at least 12% by weight andb) optionally reacting the dispersed polyisocyanate withi) a primary or secondary monoamine containing at least one hydroxyl group in an amount sufficient to provide an equivalent ratio of amino groups to isocyanate groups of 0:1.0 to 0.7:1.0 and/orii) a polyamine having primary and/or secondary amino groups and a molecular weight of 400 or less in an amount sufficient to provide an equivalent ratio of amino groups to isocyanate groups of 0:1.0 to 0.4:1.

Abstract: Linear chain extended poly(alkylene oxides) having at least a portion of hydrophobic hydrogen bonding chain extending groups are soluble in at least one solvent and swellable in water. The chain extending groups preferably comprise a urea linkage and can be produced by the reaction of an amine with an isocyanate. The extended polymers and their solutions may readily be fabricated into controlled release compositions, e.g. for the release of pharmaceuticals.

Abstract: The present invention is directed to a polyisocyanate mixture having an NCO content of 10 to 47% by weight and a viscosity of less than 10,000 mPa.s and containing isocyanurate and allophanate groups in a molar ratio of monoisocyanurates to monoallophanates of 10:1 to 1:5, wherein the allophanate groups are formed from urethane groups which are based on the reaction product of an organic diisocyanate having (cyclo)aliphatic bound isocyanate groups and a monoalcohol containing at least 10 carbon atoms and having a molecular weight of 158 to 2500.The present invention is also directed to a process for the production of a polyisocyanate mixture having an NCO content of 10 to 47% by weight, having a viscosity of less than 10,000 mPa.s and containing isocyanurate and allophanate groups in a molar ratio of monoisocyanurates to monoallophanates of 10:1 to 1:5 bya) catalytically trimerizing a portion of the isocyanate groups of an organic diisocyanate having (cyclo)aliphatically bound isocyanate groupsb) adding 0.

Abstract: According to the present invention, there is provided a rigid foamed polyurethane and a process for the manufacture of the polyurethane wherein the polyurethane is made up substantially of closed cells which contain at least a foaming agent designated by HCFC-22 and CO.sub.2 gas therein. The foamed polyurethane can be obtained by using HCFC-22 or a blend of the HCFC-22 with HCFC-142b as foaming agent which has a short life in the atmosphere because of having hydrogen atoms in their molecules. Thus, according to the present invention, it is possible to avoid the use of conventional foaming agents which are suspected of being substances eating a hole in the atmospher's layer of ozone and consequently linking to global warming.The rigid foamed polyurethanes of the present invention, which contain a foaming agent designated by HCFC-22 having a boiling point of -40.8.degree. C. in their closed cells, can retain their good thermal insulating properties over a temperature of from about -30.degree. to -40.degree. C.

Abstract: Microcellular polyurethane elastomers having nonpeelable skin surfaces having densities ranging from 0.1-1.1 gm/cm.sup.3 can be made from conventionally employed reactants using carbon dioxide gas as the sole source of blowing agent resulting from the H.sub.2 O/-NCO reaction when carried out in an admixture with nonhydratable particulate inorganic salts.

Abstract: A coating composition for a substrate to be imprinted with an image by means of sublimation or heat transfer that comprises a mixture of an epoxy resin and a blocked polyisocyanate in an equivalent-weight ratio in a range from 0.5 to 1.8 in appropriate solvents When cured, this composition results in a low glass-transition-temperature polyurethane that is smooth, colorless, tough, clear and glossy, capable of accepting a perfect reproduction of the transfer print. Upon exposure to hot water during dishwashing, the unreacted polymer-bound isocyanate groups further react to form a skin of highly crosslinked polymer chains. The skin creates a barrier to the deleterious effects of water on adhesion and to the diffusion of sublimation dyes out of the coating. The resulting transferred image is colorfast and the coating has strong adhesion to ceramic surfaces to survive repeated mechanical dishwashing.

Abstract: A novel polyurethane prepared by reacting a) a specific polyol or specific polyol blend, b) an organic diamine, c) fillers, and d) a specific polyisocyanate is described. The invention also relates to the use of the polyurethane in the preparation of a composite structure wherein the polyurethane is applied to an adhesive coated ceramic enamel layer. The composites are eminently suitable for use in plumbing applications (e.g. as a bathtub).

Abstract: A process for preparing an isocyanate having at least two --N.dbd.C.dbd.O groups is provided which comprises preparing a substituted aromatic amine having at least two --NH.sub.2 groups, recovering the substituted aromatic amine having at least two --NH.sub.2 groups, and preparing an isocyanate from the substituted aromatic amine having at least two --NH.sub.2 groups by (1) contacting the substituted aromatic amine with CO.sub.2 under conditions sufficient to produce the corresponding ammonium carbamate salt, and reacting the ammonium carbamate salt with an electrophilic or oxophilic dehydrating agent under conditions sufficient to produce the corresponding isocyanate, or (2) contacting the substituted aromatic amine with CO.sub.

Abstract: An insulated wire having excellent thermal resistance and good surface appearance is obtained by coating a condutor with a specific polyimide in a temperature range of 300.degree. C. to 450.degree. C. and controlling moisture content to 200 ppm or less.

Abstract: This invention relates to radiation curable abrasion resistant coatings for solid substrates which are tintable. The compositions of the present invention contain a quaternary ammonium salt as a tintability enhancing compound. The cured coatings of this invention simultaneously resist abrasion and provide superior tintability.

Abstract: The present invention relates to a blocked polyisocyanate which is based on the reaction product of a polyisocyanate with a reversible, monofunctional blocking agent for isocyanate groups, wherein the polyisocyanate is prepared by trimerizing 5 to 85% of the isocyanate groups of a cyclic organic diisocyanate having (cyclo)aliphatically bound isocyanate groups and containsi) an isocyanurate group-containing polyisocyanate andii) at least 5% by weight, based on the weight of the polyisocyanate, of unreacted diisocyanate.The present invention also relates to a one-component coating composition containing this blocked polyisocyanate and a polyhydroxyl polyacrylate and/or a polyhydroxyl polyester.Finally, the present invention relates to substrates coated with this coating composition.

Abstract: An improved process for preparing a one component self-crosslinking resin is provided. The process for making the self-crosslinking resin is carried out by copolymerizing an oxime-blocked m-isopropenyl-alpha, alpha-dimethylbenzyl isocyanate (m-TMI), hydroxyethyl acrylate, and another unsaturated monomer at 75.degree. C. to 85.degree. C. in a polar organic solvent having a dipole moment of at least 3, such as acetonitrile. The polar solvent retards the thermal deblocking of the blocked TMI, thereby preventing the premature self-crosslinking and gelation of the copolymerization product prior to its use as a self-crosslinking resin.

Abstract: A molded elastomer having high and low temperature resistance in dynamic applications. The elastomer includes the reaction product of an amine or hydroxy terminated polyol having an unsaturated level of less than about 0.06 milliequivalents per gram polyol, an hydroxyl or amine terminated chain extender, and a polyisocyanate-containing prepolymer capable of rapid reaction times with said chain extender when admixed together in a mold.

Abstract: Aqueous dispersions containA) from 96.95 to 45% by weight of a polyurethane,B) from 3.0 to 50% by weight of a phenol/formaldehyde condensation resin or of an epoxy resin andC) from 0.05 to 5.0% by weight of an inorganic salt having a solubility of less than 1 g/l in water at 20.degree. C.,the percentages by weight being based on the sum of the components A), B) and C).