Abstract: A moisture-curing hot-melt polyurethane adhesive foam comprising isocyanate-terminated polyurethane prepolymers based on polyester or polyether and having a melting point of 40.degree. to 60.degree. C. or a glass transition point above room temperature, melted together, optionally with a nucleating agent and/or a surfactant, treated with an inert gas under pressure and released in ambient pressure is allowed to cure as a foam whereby a cure rate is achieved of at least ten times that of the composition when not foamed; extremely rapid cure rates are achieved and thick bond lines are readily obtained.
Type:
Grant
Filed:
March 29, 1993
Date of Patent:
November 30, 1993
Assignee:
Bostik, Inc.
Inventors:
Heinz G. Gilch, Walter Rath, Karsten Seitz
Abstract: A non-yellowing, elastomeric polyurethane is made from a non-aromatic diisocyanate, a diol chain extender, a polyglycol and an aminodiol chain extender. The polyurethane is stable to sterilizing radiation, is made without any processing aids or toxic catalysts, and softens without swelling up to 95% when contacted with an aqueous liquid.
Type:
Grant
Filed:
October 26, 1992
Date of Patent:
November 30, 1993
Assignee:
Becton, Dickinson and Company
Inventors:
Theophilus O. Onwunaka, James M. Lambert
Abstract: The invention relates to rigid integral skin polyurethane structural foam having high impact strength, high heat distortion, and flame retardant properties. The foam is prepared from triisopropanolamine-initiated polyoxyalkylene (TIPA) polyether polyols oxyalkylated with a compound producing primary hydroxyl functional termination. The polyether polyol is advantageously of a molecular weight sufficient to enable TIPA to flow well while retaining its flame retardant characteristics in the foam.
Abstract: 2-component polyurethane sealants for the direct glazing of motor vehicles, comprising (A) a pasty polyurethane component containing a polyurethane prepolymer having free isocyanate groups, and a curing agent, and (B) a pasty solvent-containing component, where component (A) contains at least one latent, solvent-activatable curing agent which can be activated by means of solvents, and component (B) contains a polar, aprotic solvent and water reversibly bonded to a carrier substance which liberates the water in a delayed manner after components (A) and (B) have been mixed.
Abstract: A water-blown polyurethane foam is provided between two substrates in foamed-in-place applications such as cooling containers. The water-blown polyurethane foam is made dimensionally stable at low densities by adding lithium salts of a 2 to 24 carbon atom carboxylic acid to the polyol component. The dimensional stability of the foam at the low densities further results in raw material savings.
Abstract: The invention relates to a breathable, plastic film, useful as a wall covering material. A low boiling additive, such as water, is added to a plastisol before extrusion. During extrusion and curing of the plastisol into a film or coating, the low boiling additive is volatilized and the resulting evolved gas perforates the forming film. In this manner a permeable plastic film, such as vinyl, is produced.
Type:
Grant
Filed:
November 30, 1992
Date of Patent:
November 16, 1993
Assignee:
Borden, Inc.
Inventors:
George Rusincovitch, Paul J. Roe, Richard C. Andrews
Abstract: Disclosed is a coating composition comprising (A) 10 to 70 parts by weight of a poly(meth)acrylate of mono- or polypentaerythritol, (B) 5 to 50 parts by weight of a urethane poly(meth)acrylate having at least two unsaturated double bonds in the molecule, (C) 5 to 50 parts by weight of a poly[(meth)acryloyloxyalkyl] (iso)cyanurate, (D) 2 to 30 parts by weight of an ultraviolet absorber, (E) 0.1 to 10 parts by weight of a photopolymerization initiator, and (F) 0.1 to 5 parts by weight of a hindered amine type light stabilizer, provided that the combined amount of components (A) to (F) is 100 parts by weight. This coating composition can form a crosslinked and cured film having excellent abrasion resistance, surface smoothness, thermal resistance, chemical resistance, durability, weather resistance and adhesion to the substrate.
Abstract: A two-package polyurethane coating system is provided which consists of a paint component comprising an OH-containing film-forming resin, such as a polyacrylate polyol or an alkyd resin, and a thinner-curing agent component which is a solution, adjusted to insure a predetermined final application viscosity of the coating, of trimerized isophorone diisocyanate which functions as a curing agent for the resin in an active hydrogen-free organic solvent which functions as a thinner, the two components being supplied in independent cans for mixing and application at a coating site without need for viscosity adjustment.
Abstract: Reaction system for preparing elastomers according to the RIM process, the system comprising an allophanate modified polyisocyanate, a polyol and an aromatic polyamine chain extender. No IMR is necessary.
Type:
Grant
Filed:
November 23, 1992
Date of Patent:
November 9, 1993
Assignee:
Imperial Chemical Industries PLC
Inventors:
Edward F. Cassidy, Eric Huygens, Jan W. Leenslag
Abstract: The invention describes a new type of multi-functional water-dispersible crosslinking agents. These crosslinking agents are products consisting of oligomeric compounds containing carbodiimide functions and other reactive functional groups. Further the invention describes aqueous dispersions, emulsions or solutions with such crosslinking agents. Finally the invention comprises a process for the preparation of the crosslinking agent according to the invention.
Type:
Grant
Filed:
April 3, 1992
Date of Patent:
November 2, 1993
Assignee:
Stahl Holland B. V.
Inventors:
Laurentius C. J. Hesselmans, Johanna A. M. van den Goorbergh
Abstract: The present invention deals with a polymethylene polyphenylisocyanate blend having a viscosity range of from 15 to 37 cps at 25.degree. C. Specifically, the blend is prepared by mixing a polymethylene polyphenylisocyanate with monomeric diphenylmethane diisocyanate. The unique characteristics of this product are that it displays good storage stability under ambient conditions and has a low viscosity. It is useful in the production of polyurethane foams and adhesives.
Abstract: Particles of abrasives such as Garnet, Staurolite or Wollastonite bound to polymer are used as propellant particles to remove undesired materials from surfaces such as floors, walls, ceilings, machinery etc. For example, soil, paint, oil, grease etc. can be thereby removed.
Abstract: A composition and method for consolidating proppant or gravel for propping fractures about, or for gravel packs for sand control in, wells in subterranean formations characterized by an improvement in which there is used a combination of reactants, including a capped diisocyanate that will produce polyurethane and coat the catalyst in situ. Also disclosed are specific examples of satisfactory frac fluids, diluents and catalysts for both a specially designed one-pass system and, preferably, a two-pass system of putting and consolidating the proppant in a fracture.
Abstract: Methods for preparing highly conductive polymers in water-in-oil microemulsions are disclosed. The invention is particularly useful for preparing conductive polyaniline in the forms of fine particles, membrane composites and coatings on electrodes. The composites and the coatings of the polyaniline have been shown to exhibit conductivities in the range of 150-400 S cm.sup.-1.
Type:
Grant
Filed:
June 30, 1992
Date of Patent:
October 26, 1993
Assignee:
National University of Singapore
Inventors:
Leong-Ming Gan, Hardy S. O. Chan, Chwee-Har Chew, Liren Ma
Abstract: The invention relates to reaction injection molded elastomers derived from high molecular weight polyether polyols, an aromatic diamine chain extender, a polyisocyanate and a hydroxyl-containing organotin catalyst. The reaction injection molded (RIM) elastomers of this invention are useful, for example, as automobile body parts.
Abstract: Films of thermoplastic polyurethanes (TPU) with a Shore hardness of 75 A to 92 A having 5 to 20% by weight of polyether amide block copolymers and/or polyether ester block copolymers, and their use for adhering to other substrates, particularly for back-foaming with polyurethane foam. The invention also relates to the use of an addition of 5 to 20% by weight of polyether amide block copolymers and/or polyether ester block copolymers to thermoplastic polyurethanes with Shore hardnesses of 75 A to 92 A, based on the weight of the thermoplastic polyurethanes, for decreasing the adhesion and/or interlocking of thermoplastic polyurethanes produced by single layer blown extrusion technique.
Type:
Grant
Filed:
August 5, 1992
Date of Patent:
October 19, 1993
Assignee:
Elf Atochem Deutschland, GmbH
Inventors:
Patrick Alex, Andre Piard, Eduard de Jong
Abstract: Solutions of a) a fluorine-containing polyisocyanate in b) an isocyanate-inert solvent are used to impart water, oil and dirt resistance to porous inorganic substrates impregnated therewith. The fluorine-containing polyisocyanate is preferably selected from fluorine-containing polyisocyanates having a fluorine content in the form of perfluorinated alkyl groups of from about 15 to about 60% by weight and an isocyanate content of from about 0.5 to about 15% by weight. These isocyanates are obtained by reaction of (cyclo)aliphatic isocyanates with fluorine-containing mono- and polyhydric alcohols, and selected fluorine-containing alcohols suitable for the production of these polyisocyanates.
Type:
Grant
Filed:
November 2, 1992
Date of Patent:
October 19, 1993
Assignee:
Bayer Aktiengesellschaft
Inventors:
Stephan Kirchmeyer, Hanns-Peter Muller, Hermann Kober, Stefan Bohm, Josef Pedain
Abstract: To arrive at an economical method of producing water-expanded polymer resin moldings, it is proposed that a monomer component and a cross-linker on an acrylate basis and/or a PMMA prepolymer be used as resin-forming components of a curable mixture, with the weight ratio of the water component to the resin-forming component being at least 1:1.
Abstract: Urethane oligomers having the formula:H.sub.2 C:CHCOORO[[COHNR'NHCO[O[CH.sub.2 ].sub.t CCH.sub.3 X].sub.m O].sub.n [CONHR'NHCOYR"Y].sub.p ].sub.q CONHR'NHCOOROCOCH:CH.sub.2(I)as well as process therefor are described. These oligomers are photocurable and useful as coatings and ink.
Abstract: This invention relates to a process for forming polyaniline films or coatings on a substrate and to composite articles formed by said process.