Patents Examined by Melvyn Andrews
  • Patent number: 6849101
    Abstract: In a method for recovering Al from an off-gas (3,4) produced during carbothermic reduction of aluminum utilizing at least one smelter (1,2), the off-gas (3,4) is directed to an enclosed reactor (5) which is fed a supply of wood charcoal (7) having a porosity of from about 50 vol. % to 85 vol. % and an average pore diameter of from about 0.05 ?m to about 2.00 ?m, where the wood charcoal (7) contacts the off-gas (3,4) to produce at least Al4C3 (6), which is passed back to the smelter (1,2).
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: February 1, 2005
    Assignees: Alcoa Inc., Elkem ASA, Carnegie Mellon University
    Inventors: Richard J. Fruehan, Yun Li, Gerald Carkin
  • Patent number: 6846346
    Abstract: The invention provides a hydrometallurgical process for treating metal-containing sulfide ores and concentrates, comprising reacting said metal-containing sulfide with concentrated sulfuric acid at a temperature of between about 300° C. and 400° C. in the presence of oxygen to produce a solid metal sulfate product and a gaseous product which is primarily SO3, wherein said metal is selected from the group consisting of iron, copper, zinc, nickel, cobalt and manganese. Said metal sulfate product is then leached with dilute sulfuric acid to form a metal-containing solution, from which the metal values are separated by precipitation at raised H2SO4 concentrations obtained by saturating the solution with the gaseous SO3 from the sulfatization reaction step.
    Type: Grant
    Filed: August 29, 2000
    Date of Patent: January 25, 2005
    Assignee: Joma Chemicals AS
    Inventor: Solomon Flax
  • Patent number: 6843827
    Abstract: The method for smelting copper sulfide concentrate essentially consisting of the steps of: adding SiO2 source material and CaO source material for flux to the copper sulfide concentrate, and subjecting the copper sulfide concentrate to oxidation melting to produce slag and at least one selected from the group of white metal and blister copper, so that at least part of Fe in the copper sulfide concentrate is removed to the slag while at least part of S is removed in the form of SO2, and that copper is concentrated in the form of at least one selected from the group of white metal and blister copper, and wherein the composition of the slag is controlled such that the weight ratio CaO/(SiO2+CaO) is in the ramge of 0.6 to 0.85, while the weight ratio Fe/(FeOx+SiO2+CaO) is in the range of 0.5 to 0.6.
    Type: Grant
    Filed: August 22, 2001
    Date of Patent: January 18, 2005
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Yasuo Ojima, Yasuhiro Kondo, Kazunori Kawanaka
  • Patent number: 6843826
    Abstract: A vacuum treatment of cast metal in liquid form employing the steps of: introducing the cast metal in liquid form into a metallurgic ladle; filling the ladle until a guard height ranging between 0.4 and 0.6 m is reached; and treating the metal while bringing the atmosphere above the ladle under vacuum, and simultaneously stirring the cast metal by injecting helium into the base of the ladle during part of or the whole treatment.
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: January 18, 2005
    Assignee: Usinor
    Inventors: François Stouvenot, Marc Burty, Jean-François Domgin, Pascal Gardin, Dominique Viale, Raymond Reitz, Frédéric Leclercq
  • Patent number: 6843828
    Abstract: In a method for treating slags or slag mixtures having iron oxide contents of >5 wt.-%, in particular steelworks slags, in which the steel slags optionally mixed with other slags are charged onto a metal bath, a steel bath having a carbon content of <1.5 wt.-%, preferably <0.5 wt.-%, is used as the metal bath and the steel bath, after the charging of the steel slags, is carburized to above 2.0 wt.-% C, preferably >2.5 wt.-% C, by introducing carbon or carbon carriers.
    Type: Grant
    Filed: January 18, 2001
    Date of Patent: January 18, 2005
    Assignee: Holcim Ltd.
    Inventor: Alfred Edlinger
  • Patent number: 6840980
    Abstract: A method for eliminating bismuth from molten lead with calcium and magnesium, in which the addition of calcium and magnesium is made in the form of lumps two Mg—Ca alloys, one containing predominantly Mg, the other containing predominantly Ca, each having a liquidus temperature lower than 650° C., and preferably lower than 600° C. A preferred treatment utilizes a first alloy containing 12-25% Ca, close to the eutectic alloy at 16.2% by weight Ca, and a second alloy containing 60-80% Ca. The method enables rapid elimination of bismuth, and adjustment of the Ca/Mg ratio during the treatment.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: January 11, 2005
    Assignee: SKW la Roche de Rame Sas
    Inventor: Cyprien Maugras
  • Patent number: 6837916
    Abstract: A smelting reduction method comprising (a) charging a carbonaceous material and an ore into a reacting furnace to directly contact the carbonaceous material and the ore; (b) reducing the ore until at least a part of the ore is metallized, the resultant reduced ore containing at least a part of metallized metal being produced; (c) charging the carbonaceous material and the ore containing at least a part of the metallized metal from step (b) into a smelting furnace having a metal bath; and (d) blowing a gas containing 20% or more of oxygen into the metal bath in the smelting furnace to produce molten iron.
    Type: Grant
    Filed: October 10, 2001
    Date of Patent: January 4, 2005
    Assignee: NKK Corporation
    Inventors: Masahiro Kawakami, Terutoshi Sawada, Takeshi Sekiguchi, Masayuki Watanabe, Katsuhiro Iwasaki, Shinichi Isozaki, Junichi Fukumi
  • Patent number: 6835230
    Abstract: A method of leaching zinc from a zinc concentrate comprising leaching a zinc concentrate in an aqueous solution containing free sulfuric acid and ferric ions, whereby elemental sulfur is deposited on the zinc concentrate, and grinding the zinc concentrate under atmospheric pressure in the aqueous solution to provide particles of the zinc concentrate having surfaces, wherein the elemental sulfur and other by-products which form on the surfaces of the particles of the zinc concentrate are stripped by the grinding.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: December 28, 2004
    Assignee: Dowa Mining Co., Ltd.
    Inventors: Manabu Kanno, Yoshiyuki Watanabe, Kaoru Saruta, Akira Narumi
  • Patent number: 6835228
    Abstract: A process of recovering metals from waste lithium ion/Ni—H/Ni—Cd batteries, wherein the waste batteries are calcined and sieved to generate an ash containing metals and metal oxides. The process includes subjecting the ash to a first dissolution etching treatment, a first filtration treatment to obtain a filtrate containing Cd ions which are crystallized as cadmium sulfate, a second dissolution etching treatment for the filtered solid, and a second filtration treatment to obtain a second filtrate. Fe+3, Al+3 and rare earth metal ions in the second filtrate are precipitated as hydroxides by adding a base to the second filtrate. The remaining solution was extracted and counter-extracted to obtain aqueous solutions of Co and Ni ions, which were subjected separately to a electrolysis to deposit Co and Ni metals. Li ions in the residue solution from the electrolysis of Ni was precipitated as carbonate by adding a soluble carbonate salt.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: December 28, 2004
    Assignee: Industrial Technology Research Institute
    Inventors: Jiunn-Ren Lin, I-Long Chang, Yu-Lin Jiang, Jer-Yuan Shiu
  • Patent number: 6835227
    Abstract: A process for manufacturing alloy powder with dual consumable rotary electrodes arc melting is suitable for manufacturing pure and low-surface-area powder of metal, active metals and their alloys. In the process, rotary electrode and tungsten electrode adopted by conventional rotary electrode and arc process for manufacturing powder are respectively replaced with a rotary or anodic electrode containing a first metal and a feed or cathodic electrode containing a second metal. An inert gas is supplied into equipment for implementing the process to serve as a protective atmosphere and stabilize generated electric arc. The cathodic electrode melts under the high temperature of the arc at a cathodic spot, and droplets of the molten cathodic or second metal are sprayed toward the anodic electrode to mix with molten anodic or first metal and thrown-out by a centrifugal force of the rotary electrode to produce round-shaped alloy powder containing the first and the second metal.
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: December 28, 2004
    Assignee: National Taiwan University
    Inventors: Shuang-Shii Lian, Ming Lung Shih
  • Patent number: 6833106
    Abstract: In order to design a blast furnace in a space and cost-saving manner, the invention provides for an especially compact blast furnace (10) having no hearth, wherein the burden is transported to the charging platform by vertical conveyers (20) and a compactly designed burdening (30) and pouring bay (50) are placed in the immediate proximity of said installation.
    Type: Grant
    Filed: March 19, 2002
    Date of Patent: December 21, 2004
    Assignee: SMS Schloemann-Siemag Aktiengesellschaft
    Inventors: Franz Reufer, Wilhelm Müller, Thomas Kaluza, Rainer Beermann
  • Patent number: 6833479
    Abstract: Alkoxylated compounds of formula I R((AO)nH)mHp  (I) wherein each AO group is independently an alkyleneoxy group selected from ethyleneoxy, 1,2-propyleneoxy, 1,2-butyleneoxy, and styryleneoxy groups; n is an integer of from 2 to 100; m is an integer of from 1 to the total number of —OH plus —NH hydrogens in the R group prior to alkoxylation; the sum of m plus p equals the number of —OH plus —NH hydrogens in the R group prior to alkoxylation; and the R group is a group selected from the following: N(CH2CH2O)3  (II); R1N(CH2CH2O)2 where R1 is a C1-C24 alkyl, aryl, or aralkyl group  (III); R1N+(CH2CH2O)3Y− where R1 has the above meaning and  (IV) Y− is an anion, preferably an inorganic anion such as a halogen anion, a hydrogen sulfate anion, one-half of a sulfate anion, or one-third of a phosphate ion; NCH2CH2N  (V); NCH2CH2NCH2CH2N  (VI); CH3C(CH2O)3  (VII); CH3CH2C(CH2O)3  (VIII);
    Type: Grant
    Filed: July 14, 2003
    Date of Patent: December 21, 2004
    Assignee: Cognis Corporation
    Inventors: Mark Witschger, Jianhua Mao, Phillip L. Mattison, Michael J. Virnig, Marie-Esther Saint Victor
  • Patent number: 6833020
    Abstract: A method of recovering copper from a copper bearing sulphide mineral which includes the steps of subjecting the slurry to a bioleaching process, supplying a feed gas which contains in excess of 21% oxygen by volume, to the slurry, and recovering copper from a bioleach residue of the bioleaching process.
    Type: Grant
    Filed: July 19, 2002
    Date of Patent: December 21, 2004
    Assignee: Billiton Intellectual Property, B.V.
    Inventors: David William Dew, Petrus Basson, Deborah Maxine Miller
  • Patent number: 6833021
    Abstract: A method of processing a mineral composition comprising a refractory material the method comprising milling the composition to a particle size of P80 of less than 25 microns and leaching said composition with a solution comprising lime and/or limestone in the presence of an oxygen containing gas.
    Type: Grant
    Filed: May 14, 2001
    Date of Patent: December 21, 2004
    Inventors: Michael Matthew Hourn, Rodrigo Ulep Ventura, John Anthony Willis, David Winborne
  • Patent number: 6830605
    Abstract: Cermet material obtained from unused inert anodes, used inert anodes and cermet used in the production of inert anodes is beneficiated into a nonferrous metal concentrate composition from which metal values contained in the composition may be readily recovered by using a conventional smelting process.
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: December 14, 2004
    Assignee: World Resources Company
    Inventors: Peter T. Halpin, Ulrich R. Schlegel, Kenneth E. Riegel
  • Patent number: 6830606
    Abstract: The present invention: solves the problems of hitherto disclosed technologies, such as insufficient suppression of the oxidation loss of [Cr] and the excessive erosion of refractories, in the decarburization-refining of chromium-contained molten steel under a normal or reduced pressure; and is characterized by: determining, in sequence; a molten steel temperature during the refining through actual measurement or computation from a molten steel temperature before the refining and refining conditions; [C] and [Cr] concentrations during the refining through actual measurement or computation from molten steel components before the refining and refining conditions; a CO partial pressure PCO in an atmosphere during the refining from the total pressure P of the atmosphere, an oxygen gas supply rate and an inert gas supply rate, a Hilty's equilibrium temperature TH from said [C] and [Cr] concentrations and PCO; the difference &Dgr;T between said molten steel temp
    Type: Grant
    Filed: December 30, 2003
    Date of Patent: December 14, 2004
    Assignee: Nippon Steel Corporation
    Inventors: Ryuji Nakao, Tomoaki Tanaka, Masao Igarashi, Koichiro Yoshino
  • Patent number: 6827837
    Abstract: The present invention is directed to a method for the recovery of one or more trace elements including gold and one or more platinum group elements from coal. More particularly, the present invention may specify parameters for the selection of coal for combustion, the parameters for combustion of the pre-selected coal, the parameters for the preparation and mixing of a charge for a furnace including ash from the combustion of the coal with an inquart and a fluxing agent, the parameters for the heating of the charge and casting of a dore bar and the parameters for the production of an anode slime from the dore bar. The method of the present invention may also specify parameters for the recovery of silver, gold and one or more trace platinum group elements from the anode slimes.
    Type: Grant
    Filed: November 22, 2002
    Date of Patent: December 7, 2004
    Inventor: Bruce E. Minter
  • Patent number: 6827759
    Abstract: The present invention relates to producing cobalt having a low oxygen and a low oxide inclusion content for use as a sputter target thereby reducing the arcing and metal defects during sputtering commonly associated with high-oxygen cobalt sputter targets. Notably, the method for reducing the oxygen content and the oxide inclusion content in cobalt are separate processes which may be combined in successive order to procuce a low-oxygen cobalt sputter target having a low oxide inclusion content. The reduction in oxygen content preferably is performed prior to reducing the oxide inclusion content. Accordingly, the artisan will appreciate that one process can be performed without the other depending upon whether a reduction in oxygen or oxide inclusions is preferred in a desired cobalt sputter target.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: December 7, 2004
    Assignee: Tosoh SMD, Inc.
    Inventor: Hao Zhang
  • Patent number: 6824585
    Abstract: A method for refining a titanium metal containing ore such as rutile or ilmenite or mixtures to produce titanium ingots or titanium alloys and compounds of titanium involves production of titanium tetrachloride by processing the ore with a chlorinating procedure and removing various impurities by a distillation or similar procedures to form a relatively pure titanium tetrachloride. Thereafter, the titanium tetrachloride is introduced continuously into a reactor at the focal point of a plasma under atmospheric pressures of inert gas along with molten metallic reductant for the initial reduction of gas phase titanium tetrachloride into molten titanium drops which are collected in a set of skulled crucibles. Thereafter, further processing is carried out at atmospheric pressures in under inert gas where the titanium is heated by plasma guns to maximize titanium purity and, in a final optional stage, alloying compounds are added under the same controlled environment and high temperature conditions.
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: November 30, 2004
    Assignee: Adrian Joseph
    Inventors: Adrian A. Joseph, John G. Whellock
  • Patent number: 6821404
    Abstract: A process for recovering copper from an alkaline etch bath from an etching process in which printed boards plated with copper are etched with the alkaline etch bath and then rinsed with water, copper being removed by extraction with an organic solution, from which it is re-extracted in an acid solution. Said acid solution is passed to an operation for recovering copper, e.g. by electrolysis, but before said copper recovery a flow is diverted, in which the copper content is adjusted to a value below the value of the acid solution for copper recovery and which is used for the plating of printed boards.
    Type: Grant
    Filed: October 2, 2001
    Date of Patent: November 23, 2004
    Assignee: Mercer Holdings Corp.
    Inventors: Robert Pacholik, Gunnar Lidmer