Abstract: According to the present invention, there is provided a polysilicon production apparatus including: a horizontal reaction tube having an inlet port through which gaseous raw materials including reactant gases and a reducing gas are supplied, an outlet port through which residual gases exit, a reaction surface with which the gaseous raw materials come into contact, and bottom openings through which molten polysilicon produced by the reactions of the gaseous raw materials is discharged; and first heating means adapted to heat the reaction surface of the horizontal reaction tube. The horizontal reaction tube includes reaction regions consisting of first reaction regions where polysilicon is deposited and second reaction regions where reaction by-products are converted to the reactant gases. The first reaction regions are connected in series with the second reaction regions. Also provided is a polysilicon production method using the polysilicon production apparatus.
Type:
Grant
Filed:
July 3, 2015
Date of Patent:
June 18, 2019
Assignee:
LG CHEM, LTD.
Inventors:
Eunsu Jang, Yoo Seok Kim, Jeong Kyu Kim, JinHyoung Yoo, JungWoo Lee
Abstract: The present invention provides a catalyst and a process for the selective oxidation of carbon monoxide (CO) to produce carbon dioxide gas (CO2). The process provides a process which selectively oxidizes CO to CO2 in presence of excess hydrogen. The process provides a selective oxidation of CO to CO2 gas over Cu/CeO2 catalyst between temperature range 40° C. to 90° C. at atmospheric pressure in presence of excess H2, H2O and CO2. The process provides a CO conversion up to 100% without deactivation till 100 h.
Type:
Grant
Filed:
December 15, 2016
Date of Patent:
June 18, 2019
Assignee:
Council of Scientific & Industrial Research
Abstract: An anode and a secondary battery capable of improving the charge and discharge efficiency are provided. The anode includes an anode current collector, and an anode active material layer provided on the anode current collector. The anode active material layer has a plurality of anode active material particles containing at least one of a simple substance of silicon, a compound of silicon, a simple substance of tin and a compound of tin, and has a coat containing an oxo acid salt in at least part of the surface of the anode active material particles.
Abstract: Methods for synthesizing a water-soluble titanium-silicon complex are disclosed herein. The titanium-silicon complex can be utilized to produce titanated solid oxide supports and titanated chromium supported catalysts. The titanated chromium supported catalysts subsequently can be used to polymerize olefins to produce, for example, ethylene based homopolymer and copolymers.
Type:
Grant
Filed:
November 17, 2017
Date of Patent:
May 28, 2019
Assignee:
Chevron Phillips Chemical Company L.P.
Inventors:
Max P. McDaniel, Kathy S. Clear, Eric D. Schwerdtfeger, Jeremy M. Praetorius
Abstract: Provided is a process for producing satisfactory particles held in porous silica. The process comprises (a) the step of preparing porous silica, (b) the step of bringing the porous silica into contact with a liquid which contains either a metal or a compound that has the metal as a component element and infiltrating the liquid into the pores of the porous silica, and (c) the step of subjecting, after the step (b), the impregnated porous silica to a heat treatment to thereby form fine particles comprising the metal or the metal compound in the pores of the porous silica. When porous silica is synthesized by hydrolyzing an alkoxysilane in a solvent-free system, it is possible to synthesize porous silica having a fine pore diameter. Use of this porous silica as a template facilitates formation of particles (e.g., W, Cu, Cr, Mn, Fe, Co, or Ni or an oxide of any of these metals) that show peculiar properties not observed in the bulk material.
Type:
Grant
Filed:
August 28, 2012
Date of Patent:
May 21, 2019
Assignee:
Tokyo Metropolitan Industrial Technology Research Institute
Abstract: There is provided a coating composition comprising nonspherical nanoparticles; spherical nanoparticles; optionally hydrophilic groups and optional an surfactant; and a liquid medium comprising water and no greater than 30 wt % organic solvent, if present, based on the total weight of liquid medium, where at least a portion of the nonspherical nanoparticles or at least a portion of the spherical nanoparticles comprises functional groups attached to their surface through chemical bonds, wherein the functional groups comprise at least one group selected from the group consisting of epoxy group, amine group, hydroxyl, olefin, alkyne, (meth) acrylato, mercapto group, or combinations thereof. There is also provided a method for modifying a substrate surface using the coating composition and articles made therefrom.
Type:
Grant
Filed:
March 23, 2018
Date of Patent:
May 21, 2019
Assignee:
3M Innovative Properties Company
Inventors:
Yiwen Chu, Zhigang Yu, Naiyong Jing, Rui Pan
Abstract: A nitrogen oxide (NOx) reduction catalyst that includes a transition metal tungstate having the formula: MWO4 wherein M is selected from the group consisting of Mn, Fe, Co, Ni, and Cu. The catalyst may be utilized in various environments including oxygen rich and oxygen deficient environments.
Type:
Grant
Filed:
January 19, 2018
Date of Patent:
May 21, 2019
Assignees:
Toyota Motor Engineering & Manufacturing North America, Inc., Toyota Jidosha Kabushiki Kaisha
Inventors:
Hongfei Jia, Charles A. Roberts, Mitsuru Sakano, Keiichi Minami, Torin C. Peck, Paul T. Fanson
Abstract: A carrier for selectively synthesizing kerosene fraction from syngas, the carrier including the following components in parts by weight: 5-50 parts of mesoporous zirconia (ZrO2), 10-55 parts of a silicoaluminophosphate (SAPO) molecular sieve, 5-50 parts of modified mesoporous molecular sieve Al-SBA-16, 1-3 parts of sesbania gum powder, and 10-70 parts of alumina A catalyst includes a soluble cobalt salt and the aforesaid carrier. The soluble cobalt salt is loaded on the surface of the carrier.
Type:
Grant
Filed:
December 12, 2017
Date of Patent:
May 14, 2019
Assignee:
WUHAN KAIDI ENGINEERING TECHNOLOGY RESEARCH INSTITUTE CO., LTD.
Abstract: The present invention discloses a method for preparing a catalyst, comprising the following steps: (1) taking a noble metal salt solution A, adding a modified alumina support material, stirring until uniform and standing; (2) drying the material obtained in step (1) in a vacuum, and calcining at 500° C.-600° C. for 1-4 hours to obtain a powder material containing the noble metal; (3) mixing the noble metal powder material, an adhesive and other components to be added, and ball-milling to obtain a uniform slurry; (4) preparing a noble metal solution B and adjusting pH to 0.5-1; and (5) mixing the slurry of the step (3) with the noble metal solution B, coating the mixture on a support, drying, and calcining at 500° C.-600° C. for 1-2 hours to obtain the target product. The method for preparing the catalyst of the present invention is simple, the conditions of the preparation process are easy to control and the preparation method has strong practicality.
Abstract: The present disclosure provides systems and methods for dismantling and/or recycling liquid metal batteries. Such methods can include cryogenically freezing liquid metal battery components, melting and separating liquid metal battery components, and/or treating liquid metal battery components with water.
Type:
Grant
Filed:
December 18, 2015
Date of Patent:
April 23, 2019
Assignee:
AMBRI INC.
Inventors:
David S. Deak, Ivana Polim, David J. Bradwell, Paul Burke
Abstract: Provided are a preparation method of a silica aerogel-containing blanket which includes mixing a water glass solution, a polar organic solvent, and a silazane-based surface modifier to prepare a sol, preparing a silica gel-base material composite by immersion and gelation of a base material for a blanket in the sol, and drying the silica gel-base material composite, and a silica aerogel-containing blanket prepared by using the preparation method. A silica aerogel-containing blanket having a high degree of hydrophobicity as well as excellent physical properties, particularly, low tap density, high porosity, and excellent mechanical flexibility may be prepared by the minimal use of a surface modifier without a surface modification step by the above method.
Type:
Grant
Filed:
February 4, 2016
Date of Patent:
April 16, 2019
Assignee:
LG CHEM, LTD.
Inventors:
Mi Ri Kim, Jin Hee Oh, Kyoung Shil Oh, Je Kyun Lee
Abstract: An autothermal reforming catalytic structure for generating hydrogen gas from liquid hydrocarbons, steam and an oxygen source. The autothermal reforming catalytic structure includes a support structure and nanosized mixed metal oxide particles dispersed homogenously throughout the support structure.
Type:
Grant
Filed:
April 1, 2016
Date of Patent:
April 9, 2019
Assignees:
Saudi Arabian Oil Company, The University of Queensland
Inventors:
Jorge N. Beltramini, Moses O. Adebajo, Joao Carlos Diniz Da Costa, Gao Qing Lu, Thang V. Pham, Sai P. Katikaneni
Abstract: An autothermal reforming catalytic structure for generating hydrogen gas from liquid hydrocarbons, steam and an oxygen source. The autothermal reforming catalytic structure includes a support structure and nanosized mixed metal oxide particles dispersed homogenously throughout the support structure.
Type:
Grant
Filed:
April 1, 2016
Date of Patent:
April 9, 2019
Assignees:
Saudi Arabian Oil Company, The University of Queensland
Inventors:
Jorge N. Beltramini, Moses O. Adebajo, Joao Carlos Diniz Da Costa, Gao Qing Lu, Thang V. Pham, Sai P. Katikaneni
Abstract: Described herein are methods for forming inorganic composite oxides. Such methods include combining, at a substantially constant pH of between about 5 and about 6.75 over a period of at least about 5 minutes, an acidic precursor composition and a basic composition to form a precipitate composition, wherein the acidic precursor composition comprises an alumina precursor, a ceria precursor, a zirconia precursor and optionally one or more dopant precursors; stabilizing the precipitate by increasing the pH of the precipitate composition to between about 8 and about 10; and calcining the stabilized precipitate to form an inorganic composite oxide. Also described are inorganic composite oxides formed using such methods.
Type:
Grant
Filed:
December 23, 2014
Date of Patent:
March 26, 2019
Assignee:
Rhodia Operations
Inventors:
Qiang Zhao, Barry W. L. Southward, Francis Francis, Fabien Ocampo
Abstract: A photocatalytic functional film has a structure of a substrate, a barrier layer and a photocatalytic layer stacked one on another. The barrier layer is a SiO2 film, the photocatalyst layer comprises an amorphous TiO2 film, and particles of visible light responsive photocatalytic material formed on the surface of the amorphous TiO2 film. A method for producing a photocatalytic functional film includes: adding an alcohol solvent and an acid to a silicate precursor to obtain a SiO2 sol by dehydration and de-alcoholization reaction; applying and drying the SiO2 sol on a substrate to form a barrier layer; adding an alcohol solvent and an acid to a titanium precursor to obtain a TiO2 amorphous sol by dehydration and de-alcoholization reaction; and applying and drying a composition formed by mixing particles of visible light responsive photocatalyst material with the TiO2 amorphous sol on the barrier layer, to form a photocatalyst layer.
Type:
Grant
Filed:
July 31, 2015
Date of Patent:
March 19, 2019
Assignee:
LG HAUSYS, LTD.
Inventors:
Dong-Il Lee, Joo-Hwan Seo, Hyun-Jae Kim, Hye-Youn Jang, Seong-Moon Jung
Abstract: A photocatalytic functional film has a structure of a substrate, a barrier layer and a photocatalytic layer stacked one on another. The barrier layer is an amorphous TiO2 film, the photocatalyst layer comprises an amorphous TiO2 film, and particles of visible light responsive photocatalytic material formed on the surface of the amorphous TiO2 film. A method for producing a photocatalytic functional film includes: adding an alcohol solvent and an acid to a titanium precursor to obtain a TiO2 amorphous sol by dehydration and de-alcoholization reaction; applying and drying the TiO2 amorphous sol on a substrate to form a barrier layer; and applying and drying a composition formed by mixing particles of visible light responsive photocatalyst material with the TiO2 amorphous sol on the barrier layer, to form a photocatalyst layer.
Type:
Grant
Filed:
July 31, 2015
Date of Patent:
March 5, 2019
Assignee:
LG HAUSYS, LTD.
Inventors:
Dong-Il Lee, Joo-Hwan Seo, Hyun-Jae Kim, Hye-Youn Jang, Seong-Moon Jung
Abstract: An oxygen storage material comprises three pyrochlore-type composite oxides which are a ceria-zirconia composite oxide, a lanthana-zirconia composite oxide, and a ceria-zirconia-lanthana composite oxide, and which coexist together, wherein the oxygen storage material contains: first secondary particles made of the pyrochlore-type ceria-zirconia composite oxide and the pyrochlore-type ceria-zirconia-lanthana composite oxide; and second secondary particles made of the pyrochlore-type lanthana-zirconia composite oxide and the pyrochlore-type ceria-zirconia-lanthana composite oxide.
Abstract: A method includes transferring at least one feed stream including calcium oxide, calcium carbonate, water, and a fluidizing gas into a fluidized bed; contacting the calcium oxide with the water; based on contacting the calcium oxide with the water, initiating a hydrating reaction; producing, from the hydrating reaction, calcium hydroxide and heat; transferring a portion of the heat of the hydrating reaction to the calcium carbonate; and fluidizing the calcium oxide, calcium hydroxide, and the calcium carbonate into a first fluidization regime and a second fluidization regime. The first fluidization regime includes at least a portion of the calcium carbonate and at least a portion of the calcium oxide, and the second fluidization regime includes at least a portion of the calcium hydroxide and at least another portion of the calcium oxide. The first fluidization regime is different than the second fluidization regime.
Abstract: The present invention relates generally to the field of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.) and, in particular to a new and useful method and apparatus for reducing or preventing the poisoning and/or contamination of an SCR catalyst. In still another embodiment, the present invention relates to a method and apparatus for increasing the service life and/or catalytic activity of an SCR catalyst while simultaneously controlling various emissions. In yet another embodiment, the present invention relates to a method and apparatus for controlling, mitigating and/or reducing the amount of selenium contained in and/or emitted by one or more pieces of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.).
Type:
Grant
Filed:
February 18, 2013
Date of Patent:
February 26, 2019
Assignee:
The Babcock & Wilcox Company
Inventors:
Mandar R Gadgil, Bryan J Jankura, Jeb W Gayheart
Abstract: Provided are a preparation method of a silica aerogel-containing blanket which includes mixing a water glass solution, a polar organic solvent, and a silazane-based surface modifier to prepare a sol, preparing a silica gel-base material composite by immersion and gelation of a base material for a blanket in the sol, and drying the silica gel-base material composite, and a silica aerogel-containing blanket prepared by using the preparation method. A silica aerogel-containing blanket having a high degree of hydrophobicity as well as excellent physical properties, particularly, low tap density, high porosity, and excellent mechanical flexibility may be prepared by the minimal use of a surface modifier without a surface modification step by the above method.
Type:
Grant
Filed:
February 4, 2016
Date of Patent:
February 5, 2019
Assignee:
LG CHEM, LTD.
Inventors:
Mi Ri Kim, Jin Hee Oh, Kyoung Shil Oh, Je Kyun Lee