Abstract: Disclosed is a process for passivating a metal surface in a metal/polyimide structure, such as a polyimide layer on a semiconductor substrate containing a pattern of metallization. The process involves the formation of an intermediate layer of a silsesquioxane polymer between the polyimide layer and the substrate. The silsesquioxane layer passivates the metal, to inhibit interaction between the metal surface and the polyimide precursor material used in forming the polyimide, to provide a moisture-resistant and oxidation-resistant interface.
Type:
Grant
Filed:
February 26, 1992
Date of Patent:
March 16, 1993
Assignee:
International Business Machines Corporation
Inventors:
John E. Cronin, Paul A. Farrar, Sr., Harold G. Linde, Rosemary A. Previti-Kelly
Abstract: A method of coating a substrate with an aqueous coating composition that includes an alkali-swellable associative thickener is disclosed. The associative thickener is produced from a monoethylenically unsaturated carboxylic acid, a monoethylenically unsaturated monomer lacking surfactant capacity, a non-ionic urethane monomer, and, optionally, a polyethylenically unsaturated monomer.
Type:
Grant
Filed:
March 5, 1992
Date of Patent:
March 9, 1993
Assignee:
Union Carbide Chemicals & Plastics Technology Corporation
Abstract: The present invention relates to a process for the encapsulation of a solid substrate with a neutralized sulfonated polymer, which comprises the steps of: (a) forming a solution of a non-conjugated, diene polymer in a solvent selected from the group consisting of aliphatic, aromatic hydrocarbons and mixtures thereof; (b) contacting the solution of the unsaturated polymer with a sulfonating agent at a sufficient temperature and for a sufficient period of time to form a solution of a sulfonated polymer containing free acid; (c) forming a solution of a base selected from the group consisting of alkali metal hydroxides and mixtures thereof in a mixtrue of an aliphatic alcohol and a hydrocarbon, the hydrocarbon being selected from the group consisting of aliphatic and aromatic hydrocarbons and mixtures thereof; (d) adding the solution of base to the solution of sulfonated polymer in an amount sufficient to neutralize the polymer and the free acid, thereby forming a coating solution; (e) contacting the solid substr
Type:
Grant
Filed:
June 24, 1991
Date of Patent:
March 2, 1993
Assignee:
Exxon Research and Engineering Company
Inventors:
Warren A. Thaler, Cruise K. Jones, Evelyn N. Drake, Pacifico V. Manalastas, Edward N. Kresge
Abstract: A method of applying a layer of exogenous inorganic oxide to a metal article which method involves heating a coating of a coupling agent for a temperature and for a time sufficient to convert the coating to a layer of exogenous inorganic oxide. Also a method of adhering a metal article to an adhesive and/or a composite and a method of adhering a metal article to a substrate.
Type:
Grant
Filed:
February 11, 1991
Date of Patent:
March 2, 1993
Assignee:
Minnesota Mining and Manufacturing Company