Abstract: A catalyst composition is prepared by mixing at least an aluminum halide (preferably AlCl.sub.3), at least one copper(II) salt (preferably CuCl.sub.2), calcium aluminate and at least one alcohol (preferably ethanol), shaping the mixture, and drying the shaped particles. The thus-obtained catalyst composition is employed in the isomerization of alkanes and/or cycloalkanes.
Abstract: Rhodium hydroformylation catalysts containing bisphosphite ligands of the formula I ##STR1## where --X-- is a divalent bisarylene radical or R.sup.1,W is a divalent arylene, bisarylene or alkylene radical, andR.sup.1 and R.sup.2 are identical or different and are substituted or unsubstituted alkylene or ortho-arylene.
Type:
Grant
Filed:
August 20, 1991
Date of Patent:
April 13, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter M. Lorz, Werner Bertleff, Michael Roeper, Dieter Koeffer
Abstract: An air filter is treated with a reactive functional organosilixane composition so as to increase the oxygen concentration in air drawn through a carburetor system of an internal combustion engine and is also directed to the method of treating a standard air filter of cellulosic material by intermixing an organosiloxane and metal salt catalyst with a volatile solvent, applying the solution in liquid form to the filter and draining and drying the filter until the solvent is evaporated on the surface of the filter.
Abstract: Benzyltoluene/dibenzyltoluene oligomers essentially devoid of contaminating amounts of chlorine values, well adapted as dielectric liquids, are prepared by (a) condensing benzyl chloride with toluene or with lower benzyltoluene oligomers in the presence of a catalytically effective amount of ferric chloride, and then (b) directly dechlorinating the crude product of condensation, e.g., by contacting same with sodium methylate.
Abstract: A composition for treating oversprayed paints that contains an effective amount of a carbonyl compound such as alcohol esters and alcohol ester derivatives in water together with a suitable emulsifier. The carbonyl compound is capable of dissolving paint while remaining non-reactive with water. The alcohol ester employed has the general formula: ##STR1## The alcohol ester derivative employed has the general formula: ##STR2## R' and R" are a substituted or unsubstituted linear alkyl group containing 1 to 8 carbon atoms, R and R"' are linear or branched alkyl groups containing 1 to 10 carbon atoms, and R and R"' are either identical or different alkyl functionalities.
Type:
Grant
Filed:
November 8, 1991
Date of Patent:
April 6, 1993
Assignee:
Nortru, Inc.
Inventors:
Edwin C. Zuerner, Robert R. Patzelt, Norman Foster
Abstract: A method of preparing a catalyst for hydrogenation of a hydrocarbon oil, wherein an aqueous solution containing a metal of Group VI of the Periodic Table and a metal of Group VIII of the same, along with a hydroxycarboxylic acid and optionally phosphoric acid is added to a carrier substance consisting essentially of at least one of an inorganic oxide and an inorganic hydrate, and the resulting blend is kneaded, shaped and thereafter dried at a temperature not higher than 200.degree. C. The catalyst has a high catalyst activity and is used for hydrogenation of a hydrocarbon oil, especially satisfying the requirement of reducing the sulfur content in a light oil.
Abstract: A catalyst is disclosed comprising a thin outer shell of catalytic material bonded to an inner core of catalytically inert material. The catalyst is made by coating a catalytically inert core such as alpha alumina, with a thin layer of finely divided catalytically active material in a slurry of colloidal boehmite/pseudo boehmite then calcining to convert the boehmite/pseudo boehmite into .gamma. alumina thereby bonding it to the inert core. Catalysts made by this technique containing an outer shell of platinum on fluorided alumina in an inert core of alpha alumina .gamma. are attractive isomerization catalysts.
Type:
Grant
Filed:
November 15, 1991
Date of Patent:
April 6, 1993
Assignee:
Exxon Research and Engineering Company
Inventors:
Ian A. Cody, Mahmoud M. Hafez, David N. Zinkie
Abstract: Olefin polymerization catalysts, processes for preparing the catalysts and processes for producing polyolefins utilizing the catalysts are provided. The catalysts are basically comprised of a pentadienyl derivative-transition metal complex adsorbed on an activated inorganic refractory compound.
Abstract: A process is disclosed for pillaring layered materials which do not swell appreciably in water. The process comprises first intercalating an amine or other neutral molecule such as an amide or dimethyl sulfoxide between the layers of the material to be pillared. This allows the subsequent incorporation of inorganic pillars which are more temperature stable than the intercalated amine. Also, disclosed are different pillared products produced by the process. The starting materials do not appreciably swell in water and the pillared composition final product is produced by swelling with an inorganic intercalate and then displacing the inorganic intercalate with an inorganic pillaring substance.
Abstract: Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support to trimerize and/or polymerize olefins.
Abstract: A seam cleaning paste, cream or liquid is disclosed, which comprises a hydrocarbon solvent and a finely divided inorganic powder. Treatment of the area near the seams of various types of floor coverings, especially highly stain resistant and soil resistant floor coverings, does not significantly change the appearance of the floor nor its resistance to soiling or staining. Yet it results in much improved adhesion of certain seam coaters subsequently applied to bridge the seam and prevent dirt from lodging therein. These creams do not exaggerate bubble formation in subsequently applied seam coaters and in fact, preferred embodiments help prevent such bubbles from forming.
Type:
Grant
Filed:
July 29, 1991
Date of Patent:
March 30, 1993
Assignee:
Armstrong World Industries, Inc.
Inventors:
Wendell A. Ehrhart, William T. Sigman, Albert C. Weidman
Abstract: Mixed catalyst compositions comprised of a first supported chromium-containing catalyst component and a second supported chromium-containing catalyst component and which additionally have one or more metallic or non-metallic catalytic agents associated therewith are provided. The additional metallic or non-metallic elements associated with the catalyst components can be aluminum, titanium, zirconium, boron, phosphorous or combinations thereof. The pore volume of the silica supports used for the first and second catalyst components differs by at least 0.3 cc/g. The mixed catalyst compositions of the invention are useful for the preparation of polyolefins. They are particularly useful of polymerization of ethylene in particle form polymerizations to produce high density polyethylene blow molding resins having good processability and physical properties. The improved particle form polymerization process and products obtained thereby using the above-described mixed catalyst compositions are also described.
Type:
Grant
Filed:
March 26, 1991
Date of Patent:
March 30, 1993
Assignee:
Quantum Chemical Corporation
Inventors:
Stanley J. Katzen, Thomas J. Pullukat, Michael W. Lynch, Louis J. Rekers
Abstract: A composition for treating oversprayed paints that contains an effective amount of an essentially non-volatile carbonyl compound, an effective amount of an ethoxylated alkyl phenol surfactant in water together with a suitable emulsifier. The carbonyl compound is capable of dissolving paint solids while remaining essentially insoluble in and non-reactive with water. The carbonyl compound can be an alcohol ester having the general formulae ##STR1## an alcohol ester derivative having the general formula: ##STR2## in which R' and R" are a substituted or unsubstituted linear alkyl groups containing 1 to 8 carbon atoms, and R and R"' are linear or branched alkyl groups containing 1 to 10 carbon atoms. The surfactant has an average ethylene oxide-to-nonyl phenol ratio between 4:1 and 8:1.
Type:
Grant
Filed:
March 31, 1992
Date of Patent:
March 30, 1993
Assignee:
Nortru, Inc.
Inventors:
Edwin C. Zuerner, Robert A. Patzelt, Norman Foster
Abstract: Ionic catalyst compositions can be prepared by combining two components. The first component is a bis(cyclopentadienyl) Group IV-B metal complex containing at least one ligand which will combine irreversibly with the second component or at least a portion thereof such as a cation portion thereof. The second component comprises a cation which will irreversibly react with at least one ligand on the Group IV-B metal complex and a non-coordinating anion. The combination of the two components produces an ionic catalyst composition comprising a cationic bis(cyclopentadienyl) Group IV-B metal complex which has a formal coordination number of 3 and a 4+ valence charge and the aforementioned non-coordinating anion.
Type:
Grant
Filed:
July 30, 1991
Date of Patent:
March 30, 1993
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Howard W. Turner, Gregory G. Hlatky, Richard R. Eckman
Abstract: A bathing preparation comprising at least one organic acid and at least one carbonate is disclosed. This bathing preparation contains fumaric acid in an amount of 20% by weight or more of the total of the organic acid and at least one highly volatile perfume. The perfume is not vaporized into the atmosphere. Therefore, the bathing preparation sustains its aroma in bath water for a long time, thus giving improved relaxant and refreshing effects.
Abstract: A composition of matter is provided comprising a catalytic mixture resulting from contacting at least one of each of the following compounds, an pyridine compound, a clay compound, and an organo-nickel compound. Additionally, a process is provided comprising contacting, under polymerization conditions, at least one alpha-olefin, wih a catalytic mixture resulting from contacting at least one of each of the following compounds, an pyridine compound, a clay compound, and an organo-nickel compound.
Type:
Grant
Filed:
December 16, 1991
Date of Patent:
March 30, 1993
Assignee:
Phillips Petroleum Company
Inventors:
Margie F. Jackson, Ronald D. Knudsen, Joseph S. Shveima
Abstract: A dimerization process for producing linear and/or mono-branched C.sub.10 to C.sub.28 olefins using dimerization catalysts and new C.sub.10 to C.sub.28 olefins mixtures are disclosed. The C.sub.10 to C.sub.28 olefin product is especially useful for the production of biodegradable alkylbenzene sulfonates detergents and intermediates therefor.
Abstract: A contact material composition containing an intimately mixed, mixed oxide of at least one cationic species of a naturally occurring Group IIIB element, at least one cationic species of a Group IIA metal of magnesium, calcium, strontium, and barium and a cationic species of aluminum, as well as methods for hydrocarbon conversion using such contact material compositions are provided.
Type:
Grant
Filed:
October 11, 1991
Date of Patent:
March 23, 1993
Assignee:
Amoco Corporation
Inventors:
Don M. Washecheck, Mark K. Barr, George A. Huff, Jr., Mark P. Kaminsky, Mark S. Kleefisch, Victor K. Shum
Abstract: A dimerization process for producing linear and/or mono-branched C.sub.10 to C.sub.28 olefins using dimerization catalysts and new C.sub.10 to C.sub.28 olefins mixtures are disclosed. The C.sub.10 to C.sub.28 olefin product is especially useful for the production of biodegradable alkylbenzene sulfonates detergents and intermediates therefor.
Type:
Grant
Filed:
May 6, 1992
Date of Patent:
March 23, 1993
Assignee:
Chevron Research and Technology Company
Inventors:
Richard S. Threlkel, Victor P. Kurkov, Gar L. Woo
Abstract: A fluorided silca-alumina catalyst, particularly one with a silica:alumina ratio in the range of 1:1-9:1 containing from 1 to 6 weight percent fluoride, is particularly effective in the liquid phase alkylation of benzene to produce linear alkyl benzenes at temperatures no greater than 140.degree. C. Conversions in excess of 98% with selectivity exceeding 85% and linearity exceeding 90% may be achieved readily.