Patents Examined by Patrick P. Garvin
  • Patent number: 5196136
    Abstract: A cleaning composition is disclosed which is suitable for cleaning substrates and particularly for cleaning flux residues from a printed circuit board. The cleaning composition comprises a hydrocarbon component, a compatibilizing agent, a multibasic ester additive, and optionally water. The multibasic ester may be an alkanoic acid ester of a diol or polyol, an alkanoic acid ester of a hydroxy alkanoate alkyl ester, or and alkyl ester of a compound containing two or more carboxylic acid groups and one or more hydroxyl groups which are optionally esterified with an alkanoic acid group. The cleaning composition may be used as a solution or as an emulsion or dispersion to clean a substrate.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: March 23, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Kenneth T. Dishart, Harold L. Jackson, Abraham B. Cohen, deceased
  • Patent number: 5194415
    Abstract: Prepolymer-containing catalysts compositions and processes for making and using such catalysts are disclosed. These catalysts compositions are particularly useful for polymerizing 4-methyl-1-pentene to poly(4-methyl-1-pentene) and to improve the optical properties of polyolefins.
    Type: Grant
    Filed: December 12, 1991
    Date of Patent: March 16, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Phil M. Stricklen, Francis X. Mueller, Jr., Kenneth W. Willcox, Joyce K. Snow
  • Patent number: 5194533
    Abstract: The invention relates to a new bis(trialkylsilyl) chromate of the formula ##STR1## where n is approximately 1-2. Such a compound can be prepared by causing a corresponding silyl halide to react with silver chromate. The product is especially suitable for the polymerization and copolymerization of ethylene, the formed polymer having a high molar mass and a wide molar mass distribution.
    Type: Grant
    Filed: April 23, 1991
    Date of Patent: March 16, 1993
    Assignee: Neste Oy
    Inventors: Aimo Sahila, Hilkka Knuuttila, Bill Gustafsson
  • Patent number: 5192730
    Abstract: A process for preparing chemically stable compositions of tetra(hydrocarbyl)metallic compounds in solution, and an improved process for the preparation of active 1-olefin polymerization catalysts.
    Type: Grant
    Filed: November 13, 1991
    Date of Patent: March 9, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Steven D. Ittel, Frederick N. Tebbe
  • Patent number: 5192731
    Abstract: In accordance with the present invention, there are provided carrier-supported titanium catalyst components containing magnesium, aluminum, halogen and titanium as essential ingredients, which are obtained by a reaction of[I] a magnesium containing support obtained by previously bringing a support into contact with an organometallic compound of a metal of the Group II to IIIA of the periodic table having at least one hydrocarbon group attached directly to the metal atom or with a halogen containing compound, followed by contact with a magnesium compound in the liquid state having no reducing ability,[II] a reducing organometallic compound, and[III] a titanium compound in the liquid state, and processes for preparing the same and, at the same time, catalysts containing the above-mentioned catalyst components for use in preparing ethylene polymer and processes for preparing ethylene polymer using the catalyst for use in preparing ethylene polymer.
    Type: Grant
    Filed: October 23, 1991
    Date of Patent: March 9, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Mamoru Kioka, Kazumitsu Kawakita, Akinori Toyota
  • Patent number: 5192732
    Abstract: A cocatalyst for use in association with a catalytic component comprising a titanium compound and an internal electron donor on a magnesium halide support for the polymerization of propylene alone or propylene with ethylene or a C.sub.4 to C.sub.12 alpha-olefin, said cocatalyst consisting essentially of an organic aluminum compound and an external electron donor consisting essentially of a non-aromatic silane with two Si--O--C bonds and a monoether and/or a silane with a single Si--O--C bond and the resultant catalyst wherein such cocatalyst is combined with a catalytic component known for use in polymerizing propylene.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: March 9, 1993
    Assignee: Atochem
    Inventors: Laurent Duranel, Roger Spitz, Thierry Soto
  • Patent number: 5192729
    Abstract: A highly active Ziegler-Natta catalyst for polymerizing HDPE and LLDPE at low temperature and pressure may be prepared by reacting a magnesium compound and a halogen compound with an electron donor compound to dissolve, reacting the resulting solution with a titanium compound to obtain the homogeneous solution and then adding a small quantity of surfactant to the homogeneous solution. Ethylene polymers and copolymers were prepared by activating the resulting catalyst to obtain the granular polymer having density of from 0.92 to 0.98 g/cm.sup.3 and in which the particle size distribution was narrow.
    Type: Grant
    Filed: October 9, 1991
    Date of Patent: March 9, 1993
    Assignee: Korea Advanced Institute of Science and Technology
    Inventors: Seong I. Woo, Il Kim
  • Patent number: 5191142
    Abstract: A process for efficiently converting methanol to C.sub.3 -C.sub.12 olefins or paraffinic gasoline components is disclosed. A gaseous reaction mixture containing methanol and olefins is contacted with a solid acid catalyst in a reaction zone under conditions whereby a positive methanol concentration is maintained throughout the reaction zone. The process provides extended catalyst life, reduced deactivation rates, improved yields, and enhanced selectively for valuable products.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: March 2, 1993
    Assignee: Amoco Corporation
    Inventors: Christopher L. Marshall, Jeffery T. Miller
  • Patent number: 5191138
    Abstract: There is provided a process for converting methane to hydrocarbons having at least two carbon atoms (i.e. higher hydrocarbons). The process involves oxidizing methane with a metal sulfide oxidizing agent. After this conversion of methane, the reduced metal sulfide may be regenerated by oxidation of the reduced metal sulfide.
    Type: Grant
    Filed: November 19, 1991
    Date of Patent: March 2, 1993
    Assignee: Mobil Oil Corp.
    Inventors: Scott Han, James N. Michaels, Robert E. Palermo, David L. Stern, Dennis E. Walsh
  • Patent number: 5191136
    Abstract: A process for production of sec-butylbenzene is disclosed, comprising reacting benzene and n-butene in the presence of a liquid aluminum chloride complex catalyst is disclosed, wherein the reaction is carried out under conditions satisfying formulae (1) to (4):40>C.times.T.times.2.sup.(K-20)/10 > (1)C.ltoreq.0.9 (2)T.ltoreq.0.7 (3)K.gtoreq.80 (4)wherein C is a concentration (% by weight) of a complex catalyst in the reaction mixture; T is a reaction time (hr); and K is a reaction temperature (.degree.C). sec-Butylbenzene is produced in high yield while suppressing the amount of isobutylbenzene formed as a by-product.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: March 2, 1993
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Kazuteru Takahashi, Yasuhiko Higashio
  • Patent number: 5191146
    Abstract: An improved process is disclosed for the isomerization of butenes, pentenes, and heavier olefins using a catalyst comprising a non-zeolitic molecular sieve. It is of particular interest to increase the proportion of olefins containing tertiary carbons in the product with low formation of undesirable by-products. Product olefins may be further processed to obtain ethers, which enjoy high current interest as components for reformulated gasoline.
    Type: Grant
    Filed: December 30, 1991
    Date of Patent: March 2, 1993
    Assignee: UOP
    Inventors: Gregory J. Gajda, Paul T. Barger
  • Patent number: 5191130
    Abstract: An improved process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks are prepared in good yield by oligomerizing linear olefins using montmorillonite clays which have a halogenated phosphorous- containing acid deposited thereon.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: March 2, 1993
    Assignee: Texaco Chemical Company
    Inventors: John R. Sanderson, John F. Knifton
  • Patent number: 5191140
    Abstract: A process for producing an olefin oligomer by the polymerization of an olefin in the presence of boron trifluoride as a catalyst, and further in the co-presence of water and/or an alcohol and a carboxylic acid anhydride as a co-catalyst. The process has advantages that (i) olefin oligomers having a low viscosity can be produced at high yields, (ii) the production efficiency can be improved by decreasing the time required for the reaction, (iii) the amount of the co-catalyst required can be decreased, and (iv) the viscosity of an olefin oligomer to be obtained can be freely controlled by changing the amounts of the olefin, the catalyst, the co-catalyst, etc.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: March 2, 1993
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Makoto Akatsu, Satoru Miyaji, Tatsuya Kawamura
  • Patent number: 5188998
    Abstract: A transition-metal catalyst component for a Ziegler catalyst system, obtainable by1) mixing an inorganic, oxidic carrier with a transition-metal starting component in an organic solvent,2) removing the solvent by evaporation,3) mixing the solid-phase intermediate from step (2) with3.1) an organoaluminum catalyst component of the formula AlR.sub.m X.sub.3-m, whereR is a C.sub.1 - to C.sub.18 -hydrocarbon radical,m is from 1 to 3, andX is OR, chlorine, bromine or hydrogen, and3.2) an organic carboxylate or an organosilicon compound or a mixture thereof in an organic solvent, and4) if desired, isolating the solid-phase intermediate by filtration, washing and drying,and the use thereof for the homopolymerization or copolymerization of ethene are described.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: February 23, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrich Bueschges, Roland Saive
  • Patent number: 5189233
    Abstract: Disclosed is an improvement in a process for production of cyclohexane by liquid phase hydrogenation of benzene wherein no diluent is necessary, which comprises contacting benzene and hydrogen in the presence of a mixed catalyst bed comprising a first catalyst which is a less active hydrogenation catalyst selected from elements of Group VIII of the Periodic Table and a second, more active catalyst, comprising a Group VIII metal supported on an oxide, such as, for example, alumina, silica or titania at a temperature of about 40.degree. C. to about 300.degree. C. and pressure sufficient to keep the benzene liquid at the chosen reaction temperature.
    Type: Grant
    Filed: August 23, 1991
    Date of Patent: February 23, 1993
    Assignee: Texaco Chemical Company
    Inventors: John M. Larkin, James H. Templeton, Donald H. Champion
  • Patent number: 5188756
    Abstract: A cleansing and conditioning composition for topical application comprising the combination of a surfactant, an emollient, a cationic material, a film former, a polyamino sugar condensate and water. The interaction of the ingredients effects both cleansing and moisturization of the skin.
    Type: Grant
    Filed: August 7, 1991
    Date of Patent: February 23, 1993
    Assignee: Kolmar Laboratories, Inc.
    Inventors: Christopher G. Baker, Elliott S. Zucker
  • Patent number: 5189003
    Abstract: The invention relates to a catalyst system, which comprises a source of a Group VIII metal and a polyphosphine. The invention further relates to a process for the preparation of alpha, beta-olefinically unsaturated compounds utilizing this catalyst system.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: February 23, 1993
    Assignee: Shell Oil Company
    Inventors: Peter A. A. Klusener, Hans A. Stil, Fit Drent, Peter Arnoldy
  • Patent number: 5188999
    Abstract: A catalyst support in the form of solid particles consisting essentially of a complex of MgCl.sub.2 and alcohol of the formula MgCl.sub.2, x(n-BuOH) in which 0.1.ltoreq.x.ltoreq.2, and which has a specific surface of 1 to 20 m.sup.2 /g and a particle porosity of 1 to 2 cm.sup.3 /g, and the process of making such support, and catalytic components comprising such support, a transition metal, and optionally, an electron donor.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: February 23, 1993
    Assignee: Atochem
    Inventors: Laurent Duranel, Jean Malinge, Marie-Laure Bousque
  • Patent number: 5188997
    Abstract: A solid component of a catalyst for the (co)polymerization of ethylene is composed of a silica carrier and a catalytically active part which includes titanium, magnesium, chlorine and also alkoxy groups, and is obtained: by suspending an activated silica in an ethanolic solution of magnesium chloride; by contact of the suspension with an alkoxy or halogen alkoxyde of titanium and with a silicon halide; by eliminating the ethanol from the resulting suspension in order to recover a solid matter; and by making this solid react with an aluminum alkyl chloride.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: February 23, 1993
    Assignee: ECP Enichem Polimeri s.r.l.
    Inventors: Luciano Luciani, Maddalena Pondrelli, Renzo Invernizzi, Italo Borghi
  • Patent number: 5189000
    Abstract: A supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds is described, comprising an organometallic compound of aluminium and a second component obtained by bringing a titanium, vanadium or chromium compound, at least one compound of a second metal chosen from V, Al, Zr, Hf, Mo and Nd and optionally a magnesium compound into contact with a porous support consisting of microbeads of aerogels of one or more inorganic oxides distinguished by low density, high porosity and the fact that at least 90% of the pores have a diameter lying within a very narrow range of values. The process for the polymerization or copolymerization of olefinically unsaturated compounds based on the use of said catalyst is also described.
    Type: Grant
    Filed: March 21, 1991
    Date of Patent: February 23, 1993
    Assignees: Montedipe S.r.l., Enichem S.p.A.
    Inventors: Francesco Masi, Renzo Invernizzi, Antonio Carbonaro, Lorenzo Costa, Angelo Moalli