Abstract: A method for the highly selective production of a p-alkyltoluene or 4,4'-alkylmethylbiphenyl involving the use of a specific Lewis acid catalyst and a highly regeospecific methylating agent.

Abstract: A catalyst composition consisting essentially of(A) a crystalline aluminosilicate zeolite having a silica/alumina mole ratio of at least 10, at least 50% of all its cation sites being occupied by an alkali metal cation (component A), and(B) a refractory inorganic oxide having (b-1) platinum and (b-2) tin and/or indium supported thereon (component B). A process for cracking non-aromatic hydrocarbons in the presence of the catalyst composition, and a process for isomerizing C.sub.8 aromatic hydrocarbons, particularly xylenes, by applying the catalyst composition in combination with a conventional isomerization catalyst.

Abstract: An amine-boron composition for catalyzing the urethane reaction, particularly in preparing a polyurethane foam, consisting essentially of the addition product of a tertiary amine and a boron compound of the formula R.sub.n B(OH).sub.3-n wheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.Preferred catalysts are prepared by mixing triethylenediamine with boric acid.

Abstract: A novel catalyst composition containing a Group VIII metal and a phosphorus bidentate ligand wherein each phosphorus atom forms part of a phosphacyclohexyl structure.

Abstract: A method for the removal and concentration of desired ions such as Pd(II), Pt(IV), Pt(II), Pd(IV), Ru(III), Ru(II), Au(III), Os(IV), Au(I), Cu(I), Cu(II), Ag(I), and Hg(II) from a multiple ion source solution which may contain larger concentrations of other undesired ions including H.sup.+ comprises bringing the source solution into contact with a compound comprising a thiol and/or thioether aralkyl nitrogen-containing ligand covalently bonded through an organic spacer silicon grouping to a solid inorganic support. The thiol and/or thioether aralkyl nitrogen-containing ligand portion(s) of the compound has an affinity for the desired ions to form a complex thereby removing the desired ions from the source solution. The desired ions are removed from the compound by contacting the compound with a much smaller volume of a receiving solution having a greater affinity for the desired ions than does the thiol and/or thioether aralkyl nitrogen-containing ligand portion of the compound.

Abstract: An olefin polymerization catalyst is prepared from titanium tetrachloride and an organolithium compound wherein the gram atom ratio of lithium to titanium is in the range of about 20/1 to about 50/1 or from a rare earth metal halide, an organolithium compound and a transition metal compound selected from dicyclopentadienyl zirconium dichloride and TiX4 wherein each X is individually selected from halogen, alkyl, alkoxy and aryl radicals.

Abstract: Synthetic lubricant base stocks having a low pour point are disclosed. These synthetic lubricant base stocks comprise a mixture of (1) oligomers prepared from a linear olefin having from 10 to 24 carbon atoms; and (2) alkylated decalin having an alkyl group containing from 10 to 24 carbon atoms. These synthetic lubricant base stocks may be prepared by hydrogenating the co-reaction products of a linear olefin having from 10 to 24 carbon atoms and naphthalene.

Abstract: A composition for gas purification, comprising a reaction product of at least one metal selected from the group consisting of iron, manganese, chromium, nickel, zinc, aluminum, copper, tin and cobalt, and alloys containing these metal elements, with at least one oxypolybasic acid, wherein the metal co-exists therein while in an unreacted state.

Abstract: A process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing long-chain olefins using certain acidic calcium montmorillonite clay catalysts. When long-chain vinylidene olefin and long-chain alpha- and/or internal-olefin are co-oligomerized, a synthetic lubricant base stock having a lower pour point is obtained.

Abstract: A method for the highly selective production of a p-alkylethylbenzene or 4,4'-alkylethylbiphenyl involving the use of a Lewis acid or Bronsted acid alkylation catalyst and a highly regiospecific ethylating agent.

Abstract: In accordance with the present invention, there are provided olefin polymerization catalyst components comprising an organoaluminum oxy-compound having less than 10% in terms of Al atom of Al component dissolving in benzene kept at 60.degree. C., and olefin polymerization catalyst containing said olefin polymerization catalyst components. The olefin polymerization catalysts have excellent polymerization activities, and are capable of giving olefin (co)polymers having a narrow molecular weight distribution and a narrow composition distribution.

Abstract: A steam activated catalyst containing phosphorus and H-ZSM-5 may be used to convert higher hydrocarbons to lower olefins, especially ethylene, propylene, butylenes and pentenes at a preferred temperature range of 500.degree. to 700.degree. C. and a preferred WHSV range of 10 to 1000 hr..sup.-1. Catalysts containing H-ZSM-5 with surface Si/Al ratios of 20 to 60 were found to undergo steam activation more readily and achieve higher activity than those catalysts which contained H-ZSM-5 with surface Si/Al ratios greater than 60.

Abstract: The present invention relates to an olefin polymerization obtainable by depositing on a dry inorganic oxide support at least one mononuclear chromium complex, which is representable by the general formula: ##STR1## wherein: the cyclopentadienyl ligand is substituted with 4 or 5 hydrocarbyl groups (R.sub.1 -R.sub.5) containing 1 to 3 carbon atoms, andL is one or more hydrocarbyl ligands which are sufficiently reactive to enable the complex to react with the inorganic oxide without thermal activation.The catalyst can be used without thermal activation for polymerizing olefins, particulary ethylene optionally with C.sub.3-8 alpha-olefins. It produces polyolefins having broad molecular weight distribution.

Abstract: A catalyst comprising a high-molecular complex formed from a palladium compound and a nitrile group-containing polymer, and a method for hydrogenating a conjugated diene polymer which comprises selectively hydrogenating only a carbon-carbon double bond of the conjugated diene polymer using same.

Abstract: The present invention relates to an olefin polymerization catalyst obtainable by depositing on a dry inorganic oxide support a monocuclear chromium complex to produce a catalyst precursor and thereafter by thermally activating the said catalyst precursor. The catalyst is characterized in that the mononuclear chromium complex is representable by the general formula: ##STR1## wherein: the cyclopentadienyl ligand is substituted with 4 or 5 hydrocarbon groups containing 1 to 3 carbon atoms,L is either a four or five-substituted cyclopentadienyl ligand, or (CO).sub.3 R in which R is H, methyl or ethyl.The catalyst is used for polymerizing olefins, particularly ethylene optionally with C.sub.3 -C.sub.8 alpha-olefins. It produces polyolefins having a relatively high molecular weight and a broad molecular weight distribution.

Abstract: The present invention relates to an olefin polymerization catalyst obtainable by depositing on a dry inorganic oxide support a mononuclear chromium complex which is a mixture of (A) a first mononuclear chromium complex represented by the general formula: ##STR1## wherein three of R.sub.1 to R.sub.5 are H and the other two are H, or C.sub.1 -3 hydrocarbyl group, andL is one or more hydrocarbyl ligands which are sufficiently reactive to enable the complex to react with the inorganic oxide without thermal activation, and(B) a second mononuclear chromium complex representable by the general formula ##STR2## wherein the cyclopentadienyl ligand is substituted with 4 or 5 hydrocarbyl groups (R1-R5) containing 1 to 3 carbon atoms, andL has the same definition as above, being identical or different.The catalyst can be used for polymerizing olefins, particularly ethylene optionally with C.sub.3 -8 alpha-olefins. It can be thermally activated before use in olefin polymerization.

Abstract: Surfactant mixtures which provide denser foams than the individual components consist of 50-90% by weight of an amine oxide corresponding to the formula RR'R"NO in which R is a primary alkyl group containing 6-24 carbons and R' and R" are independently selected from methyl, ethyl, and 2-hydroxyethyl and 50-10% by weight of an alkylbenzenesulfonate surfactant. Preferred mixtures are those in which the amine oxide is N-tetradecyldimethylamine oxide and the alkylbenzenesulfonate surfactant is sodium dodecylbenzenesulfonate.

Abstract: A method of separating organic materials is disclosed utilizing a chromatographic packing material. This packing material includes a coated support material which is a chromatographically suitable substrate. An immobilized butadiene acrylonitrile polymer coating is provided on the substrate. The copolymer can be crosslinked by gamma radiation, or by means of a crosslinking agent such as dicumyl peroxide. The support material can be silica, alumina, diatomaceous earth, zeolite, porous glass or carbon, but preferably is spherical lamellar shaped crystals of aluminum hydroxide. The aluminum hydroxide crystals are bonded together at a central core and extend radially outward from a central core with a particle density ranging from 0.3 to 2.5 g/cm.sup.3 and a diameter of 2 to 150 microns.

Abstract: Surfactant mixtures which have foamability performance and/or cost advantages over the individual components consist of 50-95% by weight of an alkyldimethylbetaine in which the alkyl group contains 8-18 carbons and 50-5% by weight of a fatty acid alkanolamide. Preferred mixtures are those in which the betaine is tetradecyldimethylbetaine and the alkanolamide is cocodiethanolsuperamide.

Abstract: The invention relates to aqueous disperse systems of photoinitiators which are particularly useful in the photopolymerization of aqueous disperse systems and emulsions of oligomers or polymers carrying photopolymerizable functionalities which are widely used in the field of dyes and packaging.