Patents Examined by Rip A. Lee
  • Patent number: 12221533
    Abstract: A heterophasic polypropylene composition comprises a matrix based on a propylene-random copolymer and a linear low density polyethylene dispersed in the matrix. The heterophasic polypropylene composition has both improved impact strength and reduced amount of fraction soluble in cold xylene (XCS), while maintaining optical properties. Further, the heterophasic polypropylene composition has an optimised ratio of impact strength to the amount of fraction soluble in cold xylene (XCS).p.
    Type: Grant
    Filed: May 14, 2020
    Date of Patent: February 11, 2025
    Assignee: BOREALIS AG
    Inventors: Jingbo Wang, Elisabeth Potter, Luc Monnissen, Meta Cigon
  • Patent number: 12215208
    Abstract: The present invention relates to a film comprising at least one sealing layer wherein at least one layer A of the sealing layer(s) comprises a polyethylene comprising moieties derived from ethylene and moieties derived from an ?-olefin comprising 4 to 10 carbon atoms, the polyethylene having a density of ?870 and ?920 kg/m3 as determined in accordance with ASTM D792 (2013), wherein the polyethylene has: x a fraction of material that is eluted in analytical temperature rising elution fractionation (a-TREF) at a temperature ?30.0° C. of ?5.0 wt %, preferably ?10.0 wt %, with regard to the total weight of the polyethylene; x a shear storage modulus G? determined at a shear loss modulus G?=5000 Pa of >700 Pa, G? and G? being determined in accordance with ISO 6721-10 (2015) at 190° C.; x a melt mass-flow rate, determined at 190° C. under a load of 2.16 kg in accordance with ASTM D1238 (2013) of ?2.60 and ?4.90 g/10 min; and x a chemical composition distribution broadness (CCDB) of ?15.0, preferably ?20.0.
    Type: Grant
    Filed: January 13, 2020
    Date of Patent: February 4, 2025
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Priya Garg, Maria Soliman
  • Patent number: 12209178
    Abstract: A composition suitable for automotive application obtainable by blending at least components (A), (B), (C) and (D): (A) 15 wt.-% to 50 wt.-%, preferably 18 to 44 wt.-%, more preferably 20 to 40 wt.-% of a mixed-plastics polypropylene blend; (B) 20 wt.-% to 50 wt.-%, preferably 22 to 47 wt.-%, more preferably 25 to 45 wt.-% of a heterophasic propylene copolymer; (C) 5 wt.-% to 25 wt.-%, preferably 7 to 23 wt.-%, more preferably 10 to 22 wt.-% of an ethylene-based plastomer and (D) 5 wt.-% to 25 wt.-%, preferably 7 to 22 wt.-%, more preferably 10 to 20 wt.-% of an inorganic filler.
    Type: Grant
    Filed: June 7, 2022
    Date of Patent: January 28, 2025
    Assignee: BOREALIS AG
    Inventors: Daniela Mileva, Susanne Margarete Kahlen, Angelica Maëlle Delphine Legras, Hermann Braun, Christophe Salles
  • Patent number: 12202920
    Abstract: High molecular weight elastomers, such as ethylene-propylene-diene monomer (EPDM) polymers, are conventionally formulated with a post-polymerization oil extension to mitigate their high Mooney viscosity. Post-polymerization oil extension adds to processing costs and precludes use of polymerization facilities lacking oil extension capabilities. A low molecular weight polymer may be co-produced with a high molecular weight elastomer containing the same monomers, where the low molecular weight polymer may function in place of conventional oil extension. Polymerization methods may comprise: combining one or more olefinic monomers, a metallocene first catalyst component and a non-metallocene transition metal second catalyst component, and a solvent; and reacting the one or more olefinic monomers under solution polymerization conditions to form a polyolefin blend comprising first and second polyolefins having a bimodal molecular weight distribution.
    Type: Grant
    Filed: January 7, 2020
    Date of Patent: January 21, 2025
    Assignee: ExxonMobil Engineering & Technology Company
    Inventor: Peijun Jiang
  • Patent number: 12202915
    Abstract: The polyethylene powder has an average particle diameter (D50) of 30 ?m or more and 150 ?m or less and a powder spreading parameter of 1.5 or more and 2.1 or less.
    Type: Grant
    Filed: February 17, 2020
    Date of Patent: January 21, 2025
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventor: Yoshiaki Hamada
  • Patent number: 12202935
    Abstract: A resin compound has a structure represented by a chemical formula (I): In the chemical formula (I), each R1 independently represents a C1-C20 alkylene group or a C7-C40 alkylarylene group, and R1 are the same or different from each other; n independently represents an integer of 1-4; each R2 independently represents a C1-C20 alkyl group or a C2-C20 terminal alkenyl group, and R2 are the same or different from each other. When at least one of R1 represents a C1-C20 alkylene group, at least one of R2 is a C2-C20 terminal alkenyl group.
    Type: Grant
    Filed: February 1, 2022
    Date of Patent: January 21, 2025
    Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Meei-Yu Hsu, Chih-Hao Lin, Kai-Chi Chen, Yi-Chun Chen
  • Patent number: 12202959
    Abstract: The invention relates to a composition comprising (A) a heterophasic propylene copolymer and (B) an ethylene copolymer of ethylene and an alpha-olefin comonomer units having 4 to 10 carbon atoms, wherein (A) the heterophasic propylene copolymer consists of (a) a propylene-based matrix, wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene copolymer consisting of at least 70 wt % of propylene monomer units and at most 30 wt % of ethylene and/or ?-olefin monomer units, based on the total weight of the propylene-based matrix and wherein the propylene-based matrix is present in an amount of 80 to 95 wt % based on the total heterophasic propylene copolymer and (b) a dispersed ethylene-?-olefin copolymer, wherein the dispersed O ethylene-?-olefin copolymer is present in an amount of 5 to 20 wt %, preferably 8 to 15 wt %, based on the total heterophasic propylene copolymer and wherein the sum of the total amount of propylene-based matrix and total amount of the dispersed ethylene-
    Type: Grant
    Filed: February 11, 2020
    Date of Patent: January 21, 2025
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Marc Herklots, Daniel Bande, Ginger De La Croix, Dimphna Johanna Maria Van Beek
  • Patent number: 12202919
    Abstract: Cast film made from terpolymers, and terpolymers containing units derived from propylene, ethylene and 1-butene.
    Type: Grant
    Filed: July 29, 2021
    Date of Patent: January 21, 2025
    Assignee: Borealis AG
    Inventors: Jingbo Wang, Markus Gahleitner, Klaus Bernreitner, Pauli Leskinen
  • Patent number: 12202955
    Abstract: The present invention relates to a polyethylene composition comprising a) a polyethylene blend comprising from 95.5% to 99.5 wt % low density polyethylene (LDPE) and from 0.5% to 4.5 wt % high density polyethylene (HDPE), wherein the wt % (% by weight) is based the total amount of low density polyethylene and high density polyethylene in the blend, and b) a mixture of glycerol-mono-stearate and glycerol-mono-palmitate.
    Type: Grant
    Filed: December 11, 2019
    Date of Patent: January 21, 2025
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Johan Maria Krist, Mark Leo Hendrik Theunissen, Douwe Wiebe Van Der Meer, Maria Johanna Willems, Emanuel Joseph Herman Marie Van Der Meer
  • Patent number: 12202956
    Abstract: A bimodal polyethylene-based composition that is useful for making under film extrusion conditions a film that beneficially has both decreased water vapor transmission rate and decreased haze. The composition comprises an improved design of the composition of the polyethylene blend of a higher molecular weight polyethylene polymer constituent and a lower molecular weight polyethylene polymer constituent and an effective amount of a nucleating agent. Additional embodiments include a method of making the bimodal polyethylene-based composition, a formulation comprising the bimodal polyethylene-based composition and at least one additive, a method of making a manufactured article from the bimodal polyethylene-based composition or formulation; the manufactured article made thereby, use of the bimodal polyethylene-based composition for protecting a moisture-sensitive material, and a sealed package made therefrom.
    Type: Grant
    Filed: August 19, 2020
    Date of Patent: January 21, 2025
    Assignee: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Alexander Williamson, Andrew T. Heitsch, Stephanie M. Whited, Mridula Babli Kapur
  • Patent number: 12195563
    Abstract: This invention relates to a process to produce an ionomer comprising: 1) contacting, in a reactor, one or more C2-C60 ?-olefins, an optional diene, and a metal alkenyl with a catalyst system comprising an activator, a catalyst compound, and a support; 2) forming a copolymer comprising one or more C2-C60 ?-olefin monomers and about 0.01 wt % to about 20 wt %, based on the weight of the copolymer, of metal alkenyl; 3) functionalizing and quenching the polymerization reaction with one or more electrophilic groups; and 4) obtaining ionomer.
    Type: Grant
    Filed: December 20, 2021
    Date of Patent: January 14, 2025
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Carlos R. Lopez-Barron, Tzu-Pin Lin, Avery R. Smith, Nikola S Lambic
  • Patent number: 12195611
    Abstract: The present disclosure provides embodiments of a halogen-free flame retardant composition including one or more polyolefin copolymers having a melt flow index of 350 grams per 10 minutes (g/10 min) to 1000 g/10 min measured at 190 C and 2.16 kg, wherein the one or more polyolefin copolymers comprises maleic anhydride-grafted polyolefin, ethylene-vinyl acetate copolymer, or both; and greater than 83 wt. % of inorganic fillers based on the total weight of the halogen-free flame retardant composition.
    Type: Grant
    Filed: March 26, 2020
    Date of Patent: January 14, 2025
    Assignee: Dow Global Technologies LLC
    Inventors: Stefan Ultsch, Svyatoslav Burmistrov
  • Patent number: 12195614
    Abstract: A cellulose fiber-reinforced polypropylene resin formed body that is a resin formed body having respective diffraction peaks observed at positions of a scattering vector s of 1.61±0.1 nm?1, 1.92±0.1 nm?1, and 3.86±0.1 nm?1 in a wide-angle X-ray diffraction measurement, and is characterized by having ?T calculated by the following formula (1) of 40.0° C. or more; and a cellulose fiber-reinforced polypropylene resin formed body that is a resin formed body having the above diffraction peaks and is characterized by having ?Tm and ?Tc expressed by the following formulae (2) and (3) and satisfying ?Tm<?Tc; and a producing method of these.
    Type: Grant
    Filed: September 24, 2021
    Date of Patent: January 14, 2025
    Assignee: FURUKAWA ELECTRIC CO., LTD.
    Inventors: Yukihiro Ikura, Mayu Satake, Suzune Ito, Yasuo Nakajima, Kenichi Suyama, Jae Kyung Kim, Hiroki Tanaka, Isao Tomomatsu
  • Patent number: 12187880
    Abstract: Polypropylene polymer compositions are disclosed that have excellent stiffness properties. The polypropylene polymer compositions are made by combining a first polypropylene polymer with a second polypropylene polymer. The combination of polymers has been found to produce a composition having high stiffness properties in addition to excellent toughness properties. In addition, the polymer composition has good flow properties for being molded into various products and articles. Of particular advantage, the different polypropylene polymers can be produced at relatively high catalyst activity, especially in comparison to high crystalline polymers made in the past.
    Type: Grant
    Filed: April 3, 2020
    Date of Patent: January 7, 2025
    Assignee: W.R. GRACE & CO.-CONN
    Inventors: John Kaarto, Jing Zhong, Amaia Montoya-Goni
  • Patent number: 12180314
    Abstract: The present disclosure relates to unsaturated polyolefins and processes for preparing the same. The present disclosure further relates to curable formulations comprising the unsaturated polyolefins that show improved crosslinking.
    Type: Grant
    Filed: December 27, 2019
    Date of Patent: December 31, 2024
    Assignee: Dow Global Technologies LLC
    Inventors: Jeffrey C. Munro, Colin Li Pi Shan, Johnathan E. DeLorbe, Juan C. Tuberquia, Lixin Sun, Endre Szuromi, Edmund M. Carnahan
  • Patent number: 12180309
    Abstract: The invention relates to an ethylene polymer comprising a low molecular weight component and a high molecular weight component, wherein—the ethylene polymer has a density of 955 to 977 kg/m3 and a viscosity value ?100 of at most 1500 Pa·s and a strain hardening as determined according to ISO18488 of at least 25 MPa, for example 30 to 40 MPa,—the amount of the low molecular weight component with respect to the total ethylene polymer is at least 60 wt %,—the low molecular weight component has a Mw of 10,000 to 50,000 g/mol, a ratio of Mw/Mn of 2.5 to 4.5 and a density of 965 to 985 kg/m3 and—the high molecular weight component has a Mw of 100,000 to 1,000,000, a ratio of Mw/Mn of 2.5 to 4.0 and a density of 920 to 950 kg/m3.
    Type: Grant
    Filed: June 23, 2020
    Date of Patent: December 31, 2024
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Francisco Perez Valencia, Coen Hendriksen
  • Patent number: 12180409
    Abstract: The present invention discloses a double-crosslinked thermal phase transition gel temporary plugging agent and an application thereof, and relates to the technical field of oil and gas field development. The gel temporary plugging agent comprises the following components in percentage by weight: 5.8-18.3% of acrylic acid, 2.8-6.5% of 2-acrylamide-2-methylpropanesulfonic acid, 2.8-7.0% of hydroxyethyl acrylate, 0.2-1.0% of a degradable crosslinking agent, 0.4-1.2% of borax or boric acid, 0.2-0.8% of a high-temperature initiator, 2.6-4.5% of palygorskite attapulgite, 1.5-3.1% of a urea-formaldehyde resin, and the balance of water, wherein the gel temporary plugging agent is formed by underground gelation. The gel temporary plugging agent is applied to oil and gas reservoirs with a temperature of 100-150° C., can automatically be subjected to gelation and degradation, and has a low filtration loss before gelation.
    Type: Grant
    Filed: September 4, 2024
    Date of Patent: December 31, 2024
    Assignee: SOUTHWEST PETROLEUM UNIVERSITY
    Inventors: Yu Peng, Pengjun Shi, Yongming Li, Zhenglan Li, Jiandu Ye, Jinzhou Zhao
  • Patent number: 12173142
    Abstract: The present disclosure relates to a polyethylene having high degree of crosslinking and a crosslinked polyethylene pipe including the same. The polyethylene according to the present disclosure has a high content of ultra-high molecular weight, and thus a crosslinking rate is improved, and thus a sufficient degree of crosslinking is exhibited even when the crosslinking time is shortened, thereby exhibiting excellent strength and pressure resistance characteristics.
    Type: Grant
    Filed: February 20, 2020
    Date of Patent: December 24, 2024
    Assignee: LG Chem, Ltd.
    Inventors: Sol Cho, Hyunsup Lee, Sun Mi Kim, Yi Young Choi, Myunghan Lee, Yeonsoo Kim
  • Patent number: 12173108
    Abstract: A method of independently changing a melt rheology property value of a bimodal polyethylene polymer being made using a bimodal catalyst system in a single gas phase polymerization reactor. The method comprises process conditions comprising alkane(s) in the reactor. The method comprises a bimodal catalyst system that is characterized by an inverse response to alkane(s) concentration. The method comprises changing concentration of the alkane(s) in the reactor by an amount sufficient to effect a measurable change in the melt rheology property value; wherein the bimodal catalyst system is characterized by an inverse response to alkane(s) concentration such that when the alkane(s) concentration is increased, the melt rheology property value of the resulting bimodal polyethylene polymer is decreased, and when the alkane(s) concentration is decreased, the melt rheology property value of the resulting bimodal polyethylene polymer is increased.
    Type: Grant
    Filed: August 21, 2019
    Date of Patent: December 24, 2024
    Assignee: UNIVATION TECHNOLOGIES, LLC
    Inventors: Chuan He, Timothy R. Lynn, Robert N. Reib, Bo Liu
  • Patent number: 12163012
    Abstract: A dual reactor solution polymerization process gives polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which has a balance of barrier properties, toughness and environmental resistance. The polyethylene compositions are suitable for end use applications which may benefit from low oxygen transmission rates such as closures for bottles or barrier film.
    Type: Grant
    Filed: January 24, 2020
    Date of Patent: December 10, 2024
    Assignee: NOVA Chemicals (International) S.A.
    Inventor: Xiaochuan Wang