Patents Examined by Robert Sellers
  • Patent number: 9676887
    Abstract: Structural adhesives are prepared from an elastomeric toughener that contains urethane and/or urea groups, and have some terminal isocyanate groups that are capped with a phenol and other terminal isocyanate groups that are capped with a hydroxy-functional acrylate or a hydroxy-functional methacrylate. In certain embodiments, the presence of both types of capping on the toughener leads to higher impact peel strengths and a greater level of cohesive failure, than when the toughener is capped with a phenol an hydroxy-functional acrylate or hydroxy-functional methacrylate alone.
    Type: Grant
    Filed: April 28, 2014
    Date of Patent: June 13, 2017
    Assignee: Dow Global Technologies LLC
    Inventors: Andreas Lutz, Daniel Schneider
  • Patent number: 9670299
    Abstract: A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer with a coordination catalyst to form a reactive polymer; and (ii) reacting the reactive polymer with a nitroso compound.
    Type: Grant
    Filed: August 6, 2015
    Date of Patent: June 6, 2017
    Assignee: Bridgestone Corporation
    Inventor: Steven Luo
  • Patent number: 9658364
    Abstract: Disclosed is a method of storing a thioepoxy compound and a method of preparing a thioepoxy based optical material using the thioepoxy compound. Particularly, a method of preparing a high-quality thioepoxy based optical material having superior color and thermal stability and less time-dependent change, and being colorless and transparent by inhibiting time-dependent change of the thioepoxy compound during storage is disclosed. In addition, a method of storing the thioepoxy compound for an optical material, the thioepoxy compound having a water content of 500 to 2,500 ppm and stored at ?78 to 10° C., and a method of preparing the thioepoxy based optical material, the method including polymerizing a polymerizable composition including the stored thioepoxy compound, are provided. The high-quality thioepoxy based optical material, which is colorless and transparent, prepared according to the present invention may be broadly used in a variety of fields as a substitute for conventional optical materials.
    Type: Grant
    Filed: September 24, 2013
    Date of Patent: May 23, 2017
    Assignee: KOC SOLUTION CO., LTD.
    Inventors: Dong Gyu Jang, Soo Gyun Roh, Jong Hyo Kim, Bong-Keun So, Jin-Moo Seo
  • Patent number: 9644062
    Abstract: A toughener composition comprising: a) a polyol component selected from the group consisting of a polyether polyol, a polyester polyol, a polycaprolactone polyol, a hydroxyl-terminated polybutadiene, and mixtures or copolymers thereof; and b) a core shell rubber comprising a rubber particle core and a shell layer wherein said core shell rubber has a particle size of from 0.01 ?m to 0.5 ?m is disclosed. The toughener can be used in epoxy resin compositions for composite applications.
    Type: Grant
    Filed: October 17, 2013
    Date of Patent: May 9, 2017
    Assignee: Dow Global Technologies LLC
    Inventors: Rui Xie, Jeanette K. Nunley
  • Patent number: 9637598
    Abstract: A method of curing a thermosetting resin composition according to the present invention includes mixing a thermosetting resin containing a benzoxazine compound and a curing accelerator containing a triazine thiol compound to prepare a thermosetting resin composition, and heating this thermosetting resin composition to be cured.
    Type: Grant
    Filed: February 3, 2014
    Date of Patent: May 2, 2017
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Hiroaki Fujiwara, Yuki Kitai, Hirosuke Saito
  • Patent number: 9631099
    Abstract: This invention relates to an epoxy resin composition and its application in marine maintenance and repair coating with improved overcoatability.
    Type: Grant
    Filed: April 24, 2012
    Date of Patent: April 25, 2017
    Assignee: Dow Global Technologies LLC
    Inventors: Xiaomei Song, Hongyu Chen
  • Patent number: 9624330
    Abstract: The disclosure relates to a novel process for functionalizing NCC, a method for producing amine-cured epoxy-based nanocomposites through the use of said functionalized NCC, and nanocomposites thereof. The process for functionalizating NCC comprises providing a mixture of NCC and one or more monomers. The mixture is suitable for free radical polymerization and the monomer is cross-linkable with epoxy and is aqueous soluble. The polymerization takes place in the presence of a free radical initiator and oxygen is purged from the mixture and the initiator solution. The epoxy-based nanocomposite is produced by mixing the funtionalized NCC with an amine-curable epoxy resin and a hardener, in a solvent, and allowing the mixture to cure.
    Type: Grant
    Filed: November 12, 2013
    Date of Patent: April 18, 2017
    Assignee: CELLUFORCE INC.
    Inventors: Wadood Yasser Hamad, Shunxing Su
  • Patent number: 9616296
    Abstract: A golf ball includes an inner core layer formed from a thermoset rubber composition. The inner core layer has a first outer surface Shore D hardness and an outer diameter of about 0.8 to 1.40 inches. A thermoplastic outer core layer is formed around the inner core layer, has a second outer surface Shore D hardness, and is formed from a copolymer of ethylene and an ?,?-unsaturated carboxylic acid, a magnesium salt of oleic acid, and sufficient cation source to fully-neutralize the acid groups of the copolymer. The golf ball includes an inner cover layer and an outer cover layer. The first outer surface Shore D hardness is greater than the second outer surface Shore D hardness and the outer core layer has a thickness of about 0.01 inches to 0.05 inches.
    Type: Grant
    Filed: August 12, 2014
    Date of Patent: April 11, 2017
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Michael J. Sullivan
  • Patent number: 9605115
    Abstract: A process for preparing a reinforced and reactive thermoplastic composition having a continuous phase based on a thermoplastic polymer and dispersed therein is a discontinuous phase based on a reactive reinforcing agent that may be immiscible with the thermoplastic polymer is provided. A composition obtained by this process is also provided. The reinforcing agent is selected from the group consisting of epoxy resins, polyorganosiloxanes having SiH functional group(s), diisocyanates or polyisocyanates and mixtures thereof, comprises a grafting, a branching and/or a crosslinking, that are carried out in situ, by reactive compounding of these phases with a shear rate greater than 102 s?1, of the reinforcing agent onto the chain of the thermoplastic polymer, so that the discontinuous phase is dispersed homogeneously in the continuous phase in the form of nodules having a number-average size of less than 5 ?m.
    Type: Grant
    Filed: April 4, 2014
    Date of Patent: March 28, 2017
    Assignee: Hutchinson
    Inventors: Nicolas Garois, Philippe Sonntag, Gregory Martin, Matthieu Vatan, Jacques Drouvroy
  • Patent number: 9598616
    Abstract: The invention provides a pressure-sensitive adhesive composition, which is prepared by using an alcohol solvent to obtain a high-molecular weight acrylic polymer, and exhibits excellent levels of coating liquid storage stability, stability over time in the adhesiveness, aging suitability, adhesive strength, releasability and heat-resistant holding power, as well as providing a pressure-sensitive adhesive sheet. The pressure-sensitive adhesive composition comprises a specific crosslinking agent and an acrylic polymer with a glass transition temperature of ?60 to 0° C. obtained by radical polymerization in an alcohol solvent of an ethylenic unsaturated bond-containing monomer comprising specific amounts of specific monomers, wherein the acrylic polymer contains a low-molecular weight component and a high-molecular weight component with an area ratio therebetween of 65/35 to 80/20, and the monomer has a carboxyl group.
    Type: Grant
    Filed: April 23, 2014
    Date of Patent: March 21, 2017
    Assignee: TOYO INK SC HOLDINGS CO., LTD.
    Inventors: Yuki Sato, Toru Oya, Yoshitaka Tone, Takayuki Kobayashi
  • Patent number: 9579827
    Abstract: A casting apparatus is provided. The apparatus comprises a resin overflow container for use in casting processes, comprising: a curing accelerator for a resin in the overflow container. The resin overflow container may include a compartment arranged within the overflow container. The compartment may be adapted to release the curing accelerator after the overflow container has been at least partly filled with resin. The apparatus may also include a mold; and a drain connecting the mold and the overflow container or being part of an overflow container outlet for drawing off resin of the overflow container.
    Type: Grant
    Filed: June 15, 2015
    Date of Patent: February 28, 2017
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Martin Jensen, Simon Kwiatkowski Pedersen
  • Patent number: 9585248
    Abstract: A resin composition that becomes a cured product that exhibits force response behavior such that an area surrounded by a tensile stress-strain curve f1(x), when an amount of strain is increased from 0% to 0.3% by pulling at 999 ?m/min while plotting the amount of strain on the x axis and tensile stress on the y axis, and also surrounded by the x axis, is greater than an area surrounded by a stress-strain curve f2(x), when the amount of strain is decreased from 0.3%, and also surrounded by the x axis, and the amount of change in the amount of strain when tensile stress is 0, before and after applying tensile stress, is 0.05% or less.
    Type: Grant
    Filed: January 5, 2016
    Date of Patent: February 28, 2017
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Hiroharu Inoue, Shingo Yoshioka
  • Patent number: 9574048
    Abstract: The invention provides water-soluble compounds that include a polymer and at least one terminal azide or acetylene moiety. Also provided are highly efficient methods for the selective modification of proteins with PEG derivatives, which involves the selective incorporation of non-genetically encoded amino acids, e.g., those amino acids containing an azide or acetylene moiety, into proteins in response to a selector codon and the subsequent modification of those amino acids with a suitably reactive PEG derivative.
    Type: Grant
    Filed: July 14, 2011
    Date of Patent: February 21, 2017
    Assignee: Ambrx, Inc.
    Inventor: Troy E. Wilson
  • Patent number: 9567424
    Abstract: A method is described for producing liquid rubber containing an impact-resistance modifier terminated by epoxy groups, the method including the reaction of an isocyanate-terminated prepolymer with an epoxy resin, which includes an epoxy compound including a primary or secondary hydroxyl group, in the presence of a compound selected from anhydrides, ketones and aldehydes as glycol scavengers, wherein the isocyanate-terminated prepolymer, the epoxy resin and the glycol scavenger are mixed with one another, or the epoxy resin is reacted with the glycol scavenger, before they are mixed with the isocyanate-terminated prepolymer. Gelling in the reaction mixture is avoided by the method. The resulting products are suitable for improving the impact resistance of epoxy resin compositions, particularly one-component or two-component epoxy resin adhesives.
    Type: Grant
    Filed: November 7, 2013
    Date of Patent: February 14, 2017
    Assignee: SIKA TECHNOLOGY AG
    Inventors: Christian Krüger, Jan Olaf Schulenburg, David Hofstetter, Tina Voci
  • Patent number: 9562132
    Abstract: Thermosetting resins and thermosetting composites comprising the thermosetting resins are hot-formable. The compositions result from contacting at least one thermosetting resin precursor with at least one hardener selected from acid anhydrides in the presence of at least one transesterification catalyst. The thermosetting resin precursor includes hydroxyl functions and/or epoxy groups, and optionally ester functions, and the total molar quantity of the transesterification catalyst is between 5 and 25% of the total molar quantity of hydroxyl and epoxy contained in the thermosetting resin precursor. Methods for manufacturing articles comprising the thermosetting resins and methods for recycling the thermosetting resins are also disclosed.
    Type: Grant
    Filed: January 23, 2012
    Date of Patent: February 7, 2017
    Assignees: Centre National De La Recherche Scientifique, Arkema France
    Inventors: Ludwik Leibler, Francois Tournilhac, Damien Montarnal, Mathieu Capelot
  • Patent number: 9550852
    Abstract: Disclosed is a method for producing vinyl ester urethane resins, in which a dianhydrohexitol-compound is reacted with a diisocyanate in the presence of a monomeric radically co-polymerizable compound as a solvent and the product is reacted with a hydroxy-substituted (meth)acrylate. As a result, vinyl ester urethane resins based on dianhydrohexitol-compounds and also based on renewable raw materials can be obtained in a simple manner with high yields. The resins are suitable as binding agents in chemical fixing engineering.
    Type: Grant
    Filed: October 22, 2013
    Date of Patent: January 24, 2017
    Assignee: Hilti Aktiengesellschaft
    Inventors: Michael Leitner, Beate Gnass
  • Patent number: 9527996
    Abstract: The invention provides a thermosetting resin composition that demonstrates superior peel strength while retaining excellent heat resistance and tensile shear adhesion strength. The thermosetting resin composition comprises: an epoxy resin A containing an epoxy group and a thermoplastic resin B containing a functional group f having reactivity with an epoxy group, the thermoplastic resin B being obtained by modifying a thermoplastic resin b1 containing an unsaturated bond with a nitrone b2 containing the functional group f, and the content of the nitrone b2 relative to the unsaturated bonds being not less than 0.5 mol % and less than 10 mol %, and the content of the thermoplastic resin B being from 10 to 50 parts by mass per 100 parts by mass of the epoxy resin A.
    Type: Grant
    Filed: March 24, 2014
    Date of Patent: December 27, 2016
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Takahiro Okamatsu, Ryota Takahashi
  • Patent number: 9530946
    Abstract: A siloxane compound comprises a plurality of siloxane repeating units and at least a portion of the siloxane repeating units are cyclosiloxane repeating units conforming to a specified structure. A process for producing such siloxane compounds is also provided. A process and kit for producing a cross-linked silicone polymer using the described siloxane compounds is also provided. A light emitting diode (LED) comprises an encapsulant, and the encapsulant comprises a cross-linked silicone polymer produced from the described siloxane compounds.
    Type: Grant
    Filed: April 3, 2014
    Date of Patent: December 27, 2016
    Assignee: Milliken & Company
    Inventors: Yuzhou Liu, Yunzhang Wang, Russell A. Stapleton
  • Patent number: 9527950
    Abstract: A process comprising: a) contacting a polyhydric phenol and an epihalohydrin in the presence of a catalyst under reaction conditions to form an organic feed comprising a bishalohydrin ether and a solvent; b) contacting the organic feed and an aqueous feed comprising an inorganic hydroxide in a reciprocating-plate column reactor under reaction conditions to form a dispersed aqueous phase and an organic product; and c) collecting the organic product comprising an epoxy resin, is disclosed.
    Type: Grant
    Filed: August 31, 2012
    Date of Patent: December 27, 2016
    Assignee: BLUE CUBE IP LLC
    Inventors: Thomas C. Young, William G. Worley, Robert M. Drake
  • Patent number: 9518147
    Abstract: An amine endcapped adduct composition including an amine endcapped adduct formed from a monofunctional epoxide and a polyether amine. The monofunctional epoxide and the polyether amine are combined in a molar ratio of 1.0:2.0 to 1.0:8.0 moles of epoxide functionalities to moles of polyether amine functionalities.
    Type: Grant
    Filed: September 24, 2013
    Date of Patent: December 13, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Angela I. Padilla-Acevedo, Nathan Wilmot, Rajat Duggal, Harshad M. Shah, Kwanho Chang