Patents Examined by Robert Sellers
  • Patent number: 9382455
    Abstract: An adhesive composition includes an acrylic polymer (A), a heat curable resin (B) having unsaturated hydrocarbon group, and a filler (C) having reactive double bond on a surface.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: July 5, 2016
    Assignee: LINTEC Corporation
    Inventors: Sayaka Tsuchiyama, Isao Ichikawa
  • Patent number: 9376614
    Abstract: An optically active composition is described. The composition may include a copolymer of two or more polyepoxides covalently linked by a fused arene.
    Type: Grant
    Filed: August 22, 2012
    Date of Patent: June 28, 2016
    Assignee: Empire Technology Development LLC
    Inventor: Vincenzo Casasanta, III
  • Patent number: 9371416
    Abstract: An epoxy terminated prepolymer formed as a reaction product of a cycloaliphatic epoxide resin and an amine terminated polymeric polyol, and a catalyst that promotes the reaction of the cycloaliphatic epoxide resin and the aminated polyol. The epoxy terminated prepolymer and an anhydride hardener react to form an epoxy elastomer composition having a microphase separated morphology of hard particles, formed with the anhydride hardener reacted with the epoxy terminated prepolymer, dispersed in a soft continuous phase formed from polymeric polyol in the epoxy terminated prepolymer.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: June 21, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Kwanho Chang, Harshad M Shah, Rajat Duggal
  • Patent number: 9346984
    Abstract: An epoxy adhesive composition is provided that has superior wash-off resistance after pre-gelling, and may be used, e.g., in manufacturing processes, e.g., in the automobile industry. The compositions comprise an epoxy resin, a gelling agent, and a phenolic agent, and may optionally comprise other components. Methods of making and using the compositions are also provided.
    Type: Grant
    Filed: January 17, 2013
    Date of Patent: May 24, 2016
    Assignee: Dow Global Technologies LLC
    Inventor: Andreas Lutz
  • Patent number: 9346983
    Abstract: A heat-curable structural adhesive includes at least one non-rubber-modified epoxy resin; an optional rubber or toughener, one or more epoxy curing agents, one or more epoxy curing catalysts; and a flame retardant mixture that includes (i) alumina trihydrate, (ii) zinc borate and (iii) melamine or a melamine derivative. The structural adhesive is useful for bonding metals to other materials or metals to other metals. The structural adhesive strongly resists ignition when welding is performed in the presence of the uncured material, and does not interfere significantly with weld performance.
    Type: Grant
    Filed: March 22, 2013
    Date of Patent: May 24, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Glenn G. Eagle, Andreas Lutz, Gary L. Jialanella
  • Patent number: 9346909
    Abstract: The invention relates to thermosetting compositions containing isocyanurate ring(s) prepared through chain extension of an epoxy resin (a) with carboxyl-functional oligomers (b), which are the reaction product of polyols (i) containing one or more isocyanurate ring(s) and polycarboxylic acids or their anhydrides (ii). The polyols (i) containing one or more isocyanurate ring(s) can be prepared from the reactions of tris (2-hydroxyalkyl) isocyanurates with a modifier from a caprolactone or alkylene oxide, or glycidyl ester or glycidyl ether and mixtures thereof. The epoxy-functional thermosetting compositions containing an isocyanurate ring(s) can be further reacted with unsaturated acids, preferably (meth)acrylic acid, to obtain a curable polyacrylate. Both epoxy-functional isocyanurate and acrylate-functional isocyanurate thermosetting compositions can be further modified with a polyisocyanate to produce a composition that is useful as a reactive adhesive, binder or in other applications.
    Type: Grant
    Filed: January 10, 2014
    Date of Patent: May 24, 2016
    Inventors: Ming Yang Zhao, Chih-Pin Hsu
  • Patent number: 9346911
    Abstract: A salicylic acid salt-containing liquid composition useful as an accelerator for a hardener includes a reaction product of (a) salicylic acid; and (b) at least one amine compound compatible with said salicylic acid such that the composition is in liquid form, the composition has a concentration of salicylic acid at from about 35 weight percent to about 55 weight percent, and the composition has a viscosity in the range of from about 500 mPas to about 20,000 mPa-s at 25° C.; a curable epoxy resin composition containing the salicylic acid salt-containing liquid composition accelerator; and a cured product made from the curable composition.
    Type: Grant
    Filed: November 20, 2012
    Date of Patent: May 24, 2016
    Assignee: BLUE CUBE IP LLC
    Inventors: Markus Schrötz, Stefano C. Grassini, Marcus Pfarherr, Jeurgen Gaebel
  • Patent number: 9340701
    Abstract: The present invention relates to curing agents for epoxy resins including an alkylated polyethyleneimine. These curing agents have high functionality and a high content of secondary amino groups. Together with epoxy resins, they cure surprisingly quickly and without blushing effects even under humid and cold conditions to form films having very high cross-linking density. They are suited for coatings with high resistance requirements.
    Type: Grant
    Filed: November 8, 2012
    Date of Patent: May 17, 2016
    Assignee: SIKA TECHNOLOGY AG
    Inventors: Andreas Kramer, Urs Burckhardt, Ursula Stadelmann, Edis Kasemi
  • Patent number: 9340700
    Abstract: The present invention relates to an epoxy resin composition for semiconductor encapsulation, including the following components (A) to (E), in which the component (D) is contained in an amount of from 0.1 to 1.5% by weight of the whole of the epoxy resin composition: (A) an epoxy resin; (B) a phenol resin; (C) an inorganic filler; (D) a compound represented by the following formula (1) in which R1 represents a hydroxyl group or an alkoxy group, R2 represents a hydrogen atom or a monovalent hydrocarbon group, and n is an integer of from 1 to 7; and (E) a release agent including at least one of the following (?) and (?): (?) a linear saturated carboxylic acid having a number average molecular weight of from 550 to 800, and (?) an oxidized polyethylene wax: R1CH2—CH2—OnR2??(1).
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: May 17, 2016
    Assignee: NITTO DENKO CORPORATION
    Inventors: Tomohito Iwashige, Tomoaki Ichikawa, Naoya Sugimoto
  • Patent number: 9334426
    Abstract: A latent curing agent obtained by the reaction of a coumarin compound of the general formula (1), where X and Y can be independently H, an alkyl group, a heteroalkyl group, an aromatic group, a heteroaromatic group or an acetyl group and Z can be H, OH, an alkyl group, a heteroalkyl group, an aromatic group, a heteroaromatic group with an amine of the general formula (2), where “a” is 1 or 2, A can be an alkylene group, a heteroalkylene group, an aromatic group, a heteroaromatic group, and B can be an alkyl group (if a=1), an alkylene group (if a=2), a heteroalkyl group (if a=1), a heteroalkylene group (if a=2), an aromatic group, a heteroaromatic group, a hydroxyl group (if a=1), a secondary amino group (if a=2), O or S (if a=2), whereby B has the valency “a”, or where B alone or where A and B together form a ring system selected from an aliphatic ring system, a heteroaliphatic ring system, or an aromatic ring system, can be used for curable compositions with a polyepoxide which has at least 2 1,2-e
    Type: Grant
    Filed: May 1, 2014
    Date of Patent: May 10, 2016
    Assignee: Henkel AG & Co. KGaA
    Inventors: Masashi Horikiri, Atsushi Sudo, Takeshi Endo
  • Patent number: 9328237
    Abstract: A two-pack type epoxy resin composition for fiber-reinforced composite materials includes components [A] to [D], with component [D] being a liquid at room temperature or a solid having a melting point of 130° C. or less: [A] an epoxy resin; [B] an acid anhydride; [C] a compound that has an average of 2.5 or more hydroxyphenyl structures in each molecule; and [D] an organic phosphorus compound or imidazole derivative.
    Type: Grant
    Filed: October 23, 2012
    Date of Patent: May 3, 2016
    Assignee: Toray Industries, Inc.
    Inventors: Hideki Oka, Nobuyuki Tomioka, Shirou Honda
  • Patent number: 9315664
    Abstract: A thermoset resin, including the reaction product of: an epoxy resin mixture including at least one cycloaliphatic epoxy resins; a cycloaliphatic anhydride hardener; and a catalyst; wherein the reaction product has a glass transition temperature greater than or equal to 210° C. Also disclosed is a process for forming a thermoset resin, including: admixing two or more epoxy resins and a cycloaliphatic anhydride hardener to form a curable composition, wherein the epoxy resins include at least one cycloaliphatic epoxy resin; thermally curing the curable composition at a temperature of at least 150° C. to result in a thermoset resin having a glass transition temperature of at least 210° C. Such curable compositions may include: 35 to 65 weight percent of an epoxy resin mixture having at least one cycloaliphatic epoxy resins; 35 to 65 weight percent of a cycloaliphatic anhydride hardener; and from greater than 0 to 10 weight percent of a catalyst.
    Type: Grant
    Filed: April 29, 2014
    Date of Patent: April 19, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Jeffery L. Reynolds, Rajesh H. Turakhia, George C. Jacob, Marty J. Null
  • Patent number: 9310680
    Abstract: Provided is an alkali-developable photocurable/thermosetting resin composition from which a cured coating film that has excellent thermal shock resistance and exhibits excellent PCT resistance, HAST resistance and electroless gold plating resistance, which are important as a solder resist for semiconductor packages, can be formed. The alkali-developable photocurable/thermosetting resin composition is characterized by comprising (A) a carboxyl group-containing photosensitive resin, (B) a photopolymerization initiator, (C) a block copolymer and (D) a thermosetting component.
    Type: Grant
    Filed: June 15, 2012
    Date of Patent: April 12, 2016
    Assignee: TAIYO INK MFG. CO., LTD.
    Inventors: Nobuhito Ito, Masao Arima
  • Patent number: 9309352
    Abstract: An epoxy resin composition for RTM molding of a fiber-reinforced composite material includes [A] to [D] below, wherein [A]/[B], which is a blend mass ratio of [A] to [B], is in the range of 55/45 to 95/5: [A] a multifunctional epoxy resin that is liquid at normal temperature or has a softening point of 65° C. or lower, the multifunctional epoxy resin being at least one selected from phenol novolac epoxy resin, cresol novolac epoxy resin, and triphenylmethane epoxy resin; [B] an alicyclic epoxy resin; [C] an acid anhydride curing agent; and [D] a curing accelerator.
    Type: Grant
    Filed: January 20, 2012
    Date of Patent: April 12, 2016
    Assignee: Toray Industries, Inc.
    Inventors: Hideki Oka, Nobuyuki Tomioka, Shiro Honda
  • Patent number: 9296843
    Abstract: The present invention provides a simple, non-destructive and versatile method that enables layer-by-layer (LbL) assembly to be performed on virtually any substrate. A novel catechol-functionalized polymer which adsorbs to virtually all surfaces and can serve as a platform for LbL assembly in a surface-independent fashion is also provided.
    Type: Grant
    Filed: June 3, 2014
    Date of Patent: March 29, 2016
    Assignee: NORTHWESTERN UNIVERSITY
    Inventors: Phillip B. Messersmith, Haeshin Lee, Yuhan Lee, Zhongqiang Liu, Lesley Hamming
  • Patent number: 9290609
    Abstract: The present invention concerns low-odor, low-viscosity hardeners for epoxy resins, including an amine with at least one amino group of formula (I) and an amine with at least one amino group of formula (II), wherein the amino groups of formulas (I) and (II) are present in a particular ratio. These hardeners harden quickly with epoxy resins and without blushing to form films of high hardness and good resistance. They are especially suitable for low-emission coatings.
    Type: Grant
    Filed: July 9, 2012
    Date of Patent: March 22, 2016
    Assignee: SIKA TECHNOLOGY AG
    Inventors: Andreas Kramer, Edis Kasemi
  • Patent number: 9284434
    Abstract: A re-epoxidized polyfunctional epoxy resin composition comprising the reaction product of: (I) an epoxidized polyfunctional epoxy resin oligomeric composition comprising a polyfunctional aliphatic or cycloaliphatic epoxy resin which has been isolated from an epoxy resin product formed as a result of an epoxidation process comprising the reaction of: (i) an aliphatic or cycloaliphatic hydroxyl-containing material; (ii) an epihalohydrin, (iii) a basic-acting substance, in the presence of (iv) a non-Lewis acid catalyst; and (v) optionally, one or more solvents; (II) an epihalohydrin; (III) a basic acting substance; in the presence of (IV) a non-Lewis acid catalyst; and (V) optionally, one or more solvents. A curable epoxy resin composition of the re-epoxidized polyfunctional epoxy resin composition and a thermoset of the curable composition is also disclosed.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: March 15, 2016
    Assignee: BLUE CUBE IP LLC
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 9279031
    Abstract: An amine-terminated, substantially linear siloxane compound comprises siloxane repeating units conforming to specified structures, one of which contains pendant aromatic groups. The amine-terminated, substantially linear siloxane compound further comprises amine-substituted terminal siloxy groups. An epoxy product is made by reacting an epoxy resin and the amine-terminated, substantially linear siloxane compound.
    Type: Grant
    Filed: March 18, 2014
    Date of Patent: March 8, 2016
    Assignee: MILLIKEN & COMPANY
    Inventors: Steven P. Christiano, Olha V. Hoy, John G. Lever, Nathaniel O. Hayes
  • Patent number: 9260560
    Abstract: An epoxy-functional resin composition including the reaction product of (a) a stoichiometric excess of at least one divinylarene dioxide, and (b) at least one of: a primary (1°) monoamine, a bis-secondary (2°) amine lacking nitrogen atoms, or mixtures thereof; a curable composition including (i) the epoxy-functional resin composition, and (ii) at least one curing agent; and a cured thermoset resin prepared from the curable composition.
    Type: Grant
    Filed: September 5, 2012
    Date of Patent: February 16, 2016
    Assignee: Blue Cube IP LLC
    Inventors: Maurice J. Marks, Gyongyi Gulyas
  • Patent number: 9243139
    Abstract: An epoxy resin composition comprising an epoxy resin [A], an amine-based curing agent [B] and a block copolymer [C] as components, wherein the epoxy resin [A] contains [Aa] an epoxy resin having at least one structure selected from a condensed polycyclic structure, biphenyl structure and oxazolidone ring structure; [Ab] an epoxy resin selected from a polyfunctional amine type epoxy resin [Ab1] and a liquid bisphenol type epoxy resin [Ab2], and the block copolymer [C] is at least one block copolymer selected from the group consisting of S-B-M, B-M and M-B-M. The present invention provides an epoxy resin composition that can be cured to form a cured product excellent in heat resistance, elastic modulus and toughness.
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: January 26, 2016
    Assignee: TORAY INDUSTRIES, INC.
    Inventors: Maki Nagano, Nobuyuki Tomioka, Takayuki Imaoka, Shiro Honda