Abstract: In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).
Type:
Grant
Filed:
January 30, 2012
Date of Patent:
March 18, 2014
Assignees:
UT-Battelle, LLC, University of Tennessee Research Foundation, Virginia Museum of Natural History
Inventors:
James G. Blencoe, Donald A. Palmer, Lawrence M. Anovitz, James S. Beard
Abstract: Highly compactable granulations and methods for preparing highly compactable granulations are disclosed. More particularly, highly compactable calcium carbonate granulations are disclosed. The granulations comprise powdered materials such as calcium carbonate that have small median particle sizes. The disclosed granulations are useful in pharmaceutical and nutraceutical tableting and provide smaller tablet sizes upon compression than previously available.
Type:
Grant
Filed:
April 20, 2012
Date of Patent:
March 11, 2014
Assignee:
Delavau L.L.C.
Inventors:
Kevin W. Lang, James W. Dibble, Raya Levin, Gregory B. Murphy
Abstract: The present teachings relate to processes to impregnate activated carbon derived from a vegetal source with permanganate and optionally, iron (III) oxide. The present teachings also include the adsorbent compositions resulting from such processes.
Abstract: The present invention provides a process for producing an activated carbon having a small average particle diameter, a uniform particle size and a relatively large specific surface area suitable for an electric double layer capacitor electrode, in an easy and cost effective manner. The process comprises calcining an easily graphitizable carbon material such as petroleum coke or coal coke, used as the raw material under an oxidizing gas atmosphere, adjusting the particle size of the carbon material, and then activating the carbon material. The use of the activated carbon produced by the process of the present invention in an electrode can provide an electric double layer capacitor having a large capacitance per unit volume.
Abstract: A process for manufacturing a block of material that imitates natural stone. The manufactured stone not only looks and appears like natural stone, but is also consistent with the composition of natural stone. The process comprises forming an aqueous mixture of limestone aggregates, treating the mixture with carbon dioxide under pressure and then highly compressing the treated mixture in a sealed mold. This process recreates the endogenous matrix of the natural stone and its original composition. The block of material is intended for construction and decoration purposes.
Abstract: Highly compactable granulations and methods for preparing highly compactable granulations are disclosed. More particularly, highly compactable calcium carbonate granulations are disclosed. The granulations comprise powdered materials such as calcium carbonate that have small median particle sizes. The disclosed granulations are useful in pharmaceutical and nutraceutical tableting and provide smaller tablet sizes upon compression than previously available.
Type:
Grant
Filed:
January 30, 2013
Date of Patent:
March 4, 2014
Assignee:
Delavau L.L.C.
Inventors:
Kevin W. Lang, James W. Dibble, Raya Levin, Gregory B. Murphy
Abstract: A method of producing calcium carbonate from a waste sludge containing calcium carbonate and at least one silicate mineral. The method comprises the steps of: (i) incinerating the sludge to an ash in which at least 60% of the calcium carbonate present in the sludge is converted to free calcium oxide which is unreacted with the silicate mineral(s), (ii) optionally slaking the ash to convert at least a portion of the free calcium oxide therein to calcium hydroxide, (iii) treating either the ash from step (i) or the slaked ash from step (ii) with an aqueous solution of a polyhydroxy compound to provide a solution of dissolved calcium hydroxide, (iv) separating insoluble material from the solution of calcium ions obtained in step (iii), (v) dispersing carbon dioxide through the solution obtained from step (iv) so as to produce calcium carbonate, and (vi) separating the calcium carbonate produced in step (v).
Abstract: A reduced puffing needle coke is formed from decant oil, which includes a lesser amount of nitrogen within the coke so that carbon articles produced from such coke experience minimal expansion upon heating to graphitization temperatures.
Type:
Grant
Filed:
July 21, 2011
Date of Patent:
February 25, 2014
Assignee:
GrafTech International Holdings Inc.
Inventors:
Douglas J. Miller, Ching-Feng Chang, Irwin C. Lewis, Aaron Tomasek, Richard L. Shao
Abstract: The present invention provides a microporous carbon material capable of expressing functions that supported metal has while maintaining pore functions that the microporous carbon material inherently possesses. The microporous carbon material 5 includes: a three-dimensional long-range ordered structure within a range from 0.7 nm or more to 2 nm or less; and micropores 2a, wherein a transition metal 4 is supported on surfaces of the micropores 2a. The microporous carbon material is obtained by a method including: introducing an organic compound on a surface of and inside the micropores of a porous material containing transition metal, and obtaining a composite of the microporous carbon material containing the transition metal and the porous material by carbonizing the organic compound by a chemical vapor deposition method; and removing the porous material.
Abstract: An improved process for reduction-oxidation desulphurization uses an oxidizer operating at a pressure greater than the absorber where a liquid reduction-oxidation catalyst solution contacts a sulfur-containing gas feed stream.
Abstract: A method for producing an activated carbon material includes heating a non-lignocellulosic carbon precursor to form a carbon material and reacting the carbon material with steam to form an activated carbon material. The activated carbon material is suitable to form improved carbon-based electrodes for use in high energy density devices.
Type:
Grant
Filed:
July 19, 2011
Date of Patent:
February 18, 2014
Assignee:
Corning Incorporated
Inventors:
Kishor Purushottam Gadkaree, Andrew Fleitz Husted, Jia Liu
Abstract: A pre-charged material including silicon-comprising fibers characterized in that two or more of the fibers are bonded together to create both a bonded felt anode structure, with or without a current collector, and a composite anode structure with a current collector and an electrode structure. The structure overcomes problems associated with charge/discharge capacity loss.
Abstract: A method and a plant for capturing CO2 from an exhaust gas from combustion of carbonaceous material are described. At least a part of the combustion gas is introduced into a biol fuel boiler as an oxygen containing gas, to increase the concentration of CO2 and decrease the oxygen concentration in the gas before introduction into an absorption column for separation of CO2.
Abstract: An adsorptive composition comprising a composition that contains at least one kind of fatty acid metal salt of any one of Ni, Cu or Co and ultrafine metal particles having a plasmon absorption over 300 to 700 nm. The adsorptive composition has an excellent effect of adsorbing both amine-type smelling components and sulfur-containing smelling components.
Abstract: The present invention relates to nanocomposite materials comprising: graphite-based material dispersed among transition metal-organic framework (MOF) units, wherein the graphite-based material is chemically linked to MOF units; wherein the graphite-based material is present in the range of about 5 wt. % to about 60 wt. % of the composite material.
Type:
Grant
Filed:
September 10, 2010
Date of Patent:
January 21, 2014
Assignee:
Research Foundation of the City University of New York
Abstract: A process for the catalytic removal of hydrogen cyanide, formic acid and formic acid derivatives from synthesis gas comprising these compounds, carbon monoxide and hydrogen, the process comprising contacting the synthesis gas with a catalyst comprising one or more metals selected from the group consisting of silver, gold, copper, palladium, platinum and their mixtures and supported on a carrier comprising at least one of the oxides of scandium, yttrium, lanthanum, cerium, titanium, zirconium, aluminum, zinc, chromium and molybdenum.
Abstract: A system is arranged to remove carbon dioxide (CO2) from a gas stream by bringing the gas stream into contact with a circulating ammoniated solution stream such that CO2 is removed from the gas stream by the ammoniated solution stream. A method of removing non-volatile compounds from the circulating ammoniated solution stream includes: introducing a portion of the circulating ammoniated solution stream into a gas-liquid separating device; and separating the introduced ammoniated solution into an ammonia rich gas phase and a liquid phase comprising the non-volatile compounds; and reintroducing the ammonia rich gas phase into the circulating ammoniated solution stream.
Type:
Grant
Filed:
September 14, 2010
Date of Patent:
January 7, 2014
Assignee:
ALSTOM Technology Ltd.
Inventors:
Peter Ulrich Koss, Michael Koch, Joseph P. Naumovitz
Abstract: Highly compactable granulations and methods for preparing highly compactable granulations are disclosed. More particularly, highly compactable calcium carbonate granulations are disclosed. The granulations comprise powdered materials such as calcium carbonate that have small median particle sizes. The disclosed granulations are useful in pharmaceutical and nutraceutical tableting and provide smaller tablet sizes upon compression than previously available.
Type:
Grant
Filed:
January 30, 2013
Date of Patent:
December 31, 2013
Assignee:
Delavau L.L.C.
Inventors:
Kevin W. Lang, James W. Dibble, Raya Levin, Gregory B. Murphy
Abstract: The disclosure utilizes a hydroxide sorbent for humidification and CO2 removal from a gaseous stream comprised of CO and CO2 prior to entry into a water-gas-shift reactor, in order to decrease CO2 concentration and increase H2O concentration and shift the water-gas shift reaction toward the forward reaction products CO2 and H2. The hydroxide sorbent may be utilized for absorption of CO2 exiting the water-gas shift reactor, producing an enriched H2 stream. The disclosure further provides for regeneration of the hydroxide sorbent at temperature approximating water-gas shift conditions, and for utilizing H2O product liberated as a result of the CO2 absorption.
Type:
Grant
Filed:
September 22, 2010
Date of Patent:
December 31, 2013
Assignee:
U.S. Department of Energy
Inventors:
Ranjani V. Siriwardane, James C. Fisher, II