Abstract: 4,4'-dinitrodibenzyls are prepared by reaction of 4-nitrotoluenes, in the presence of an organic solvent and/or diluent, with an alkali metal-alcoholate and/or an alkaline earth metal alcoholate, and subsequent treatment of the reaction mixture with an aqueous solution of hypohalous acids and/or their salts or with chlorine, bromine or an aqueous solution of hydrogen peroxide and/or its salts, or with organic or inorganic peracids and/or their salts.

Abstract: An ozone generator has a construction in which: an outer and an inner sleeves made of fused quartz or ordinary glass are mounted inside a casing of the generator, which sleeves are substantially concentrically arranged to form an air gap therebetween, while conducting films are formed on the outer periphery of the outer sleeve and the inner periphery of the inner sleeve to provide opposite discharge electrodes an inner one of which is grounded and an outer one of which is connected to high voltage side of an electric source, to which air gap a raw gas is fed while electrical discharge is conducted between these electrodes to produce ozonized gas from the raw gas.

Abstract: A method and formulation are provided which are effective for fighting coal fueled fires. The composition puts out the fire, penetrates the burning coal, disperses fire gases, and does not generate any gases that are toxic to humans. The basic formulation comprises a linear alkylbenzolyate sulfonate, non-ionic detergent and lauric superamide detergent mixture comprising about 50% by volume of the formulation, vitamin B-6 in the amount of about 0.5-3% by weight of the detergent mixture, bicarbonate of soda in the amount of about 3-18% by weight of the detergent mixture, red vegetable color in the amount of about 0.25-0.75% by weight of the detergent mixture, eucalyptus oil (if present) in the amount of about 1-2% by weight of the detergent mixture, and water comprising about 37-47% percent by volume of the total formulation.

Abstract: Apparatus for immunoassay of biological fluids, e.g. for AIDS antibodies, comprising an enclosed channel with fittings at the ends and a transparent top, together with a strip of nitrocellulose paper or other suitable material impregnated with antigens to the antibodies which are to be defected. The apparatus may have a single channel or it may have multiple channels.

Abstract: What is disclosed is an improvement in a method for treating the reaction residue from the preparation of organochlorosilanes or chlorosilanes from the reaction of metallic silicon with a chlorinated hydrocarbon or hydrogen chloride, said method comprising combining the reaction residue with water and granulating the mixture of the reaction residue and water, the improvement comprising (A) coating the resulting granules from the granulating of the mixture of the reaction residue and water with an inert inorganic powder.

Abstract: Method for preparing bibenzyl systems with nitro groups as substituents. Toluene derivates with nitro groups are coupled oxidatively in methanolic alkali solution under influence of metal catalysts. The oxidation is preferably done with air. As catalysts metal acetonylacetonates are used. The metal can be Ni, Cu, Co, Mn, Cr or Ti. This catalyst can be used together with a crown ether. Another suitable catalyst is a metal tetraphenylporphin of porfyrin type where the metal can be Ni, vanadium (V=O) or Fe(FeIII).

Abstract: This invention comprises a process for separating the minor dinitrotoluene isomers, 2,3-dinitrotoluene and 3,4-dinitrotoluene from a feed mixture comprising 2,4- and 2,6-dinitrotoluene, and the minor isomers, which process comprises contacting the mixtures at adsorption conditions with an adsorbent comprising a Y type, or dealuminated Y type, zeolite, cation exchanged with Na, Ca or H, thereby selectively adsorbing the 2,3- and 3,4- isomers or 2,4- and 2-6 isomers, respectively. The remainder of the feed mixture is removed from the adsorbent and the minor isomers are recovered by desorption at desorption conditions with a desorbent material comprising an alcohol, ketone or an ester.

Abstract: Reflectance standards are prepared in accordance with the present invention by incorporating at least 40 percent by weight of barium sulphate into acrylate polymer such as methyl acrylate or methyl methacrylate. Thickness of the resulting polymer should be in excess of 0.25 centimeters. By incorporating varying percentages of carbon black in the mixture during mixing--various reflectance values can be obtained. The resulting reflectance standards can be utilized in the form of chips, plaques, sheets, or can be molded into various configurations, including that of an integrating sphere.

Abstract: Apparatus for magnetically treating a fluid is disclosed. The magnetized fluid may comprise a hydrocarbon fuel or water. The apparatus is arranged to maximize the magnetic fields generated by magnets within the apparatus and to cause the fluid to flow therethrough in a manner to maximize the exposure of the fluid to the optimized magnetic fields.

Abstract: Recovery and disposing of waste materials containing inorganic chemicals not be effected by incineration to meet environmental regulations as is the situation with waste organic materials. As long as the inorganic toxic materials are in some soluble form, they can pollute the environment, and, also, end up in the water supplies. Two different disposal methods are disclosed wherein one method is effective for removing the insoluble inorganic salts by converting them into mesylates by reaction with methanesulfonic acid or with methanedisulfonic acid. Most mesylate salts are highly soluble in aqueous and certain organic systems. As an illustration, 1.0 part of silver mesylate or 2.0 parts of stannous mesylate or lead(II) mesylate will dissolve in 1.0 part of water at room temperature. This unique solubilizing property offers the ability of leaching such toxic metal contaminants as lead, cadmium, etc. from sewage sludge. The metal salts can thus be recovered and recycled.

Abstract: An ion mobility spectrometer for analysis of a gaseous sample wherein only nitrogen and phosphorus containing molecules of the sample are ionized. The spectrometer is of the type having an ion source for ionizing the sample gas and a shutter for gating ions into a drift region, wherein an electric field gradient exists. The ion source includes a bead which comprises a thermally stable material, such as a ceramic or glass, having an alkali metal compound on its surface. The bead is immersed in a gaseous mixture of hydrogen and air, and is heated to a temperature of 200.degree.-1000.degree. C. The bead selectively ionizes phosphorus and nitrogen containing molecules of the sample upon contact with the bead.

Abstract: Cadmium sulfide is formed successfully from the laser-induced chemical reion between a first reactant of a dialkylcadmium and a second reactant of a dialkylsulfide. Infrared laser radiation in the range of 10.4 or 9.4 micrometers is provided by a continuous-wave CO.sub.2 laser. In single line operation, output powers between 10 and 150 watts/centimeters square (W/cm.sup.2) are obtained by variation of the CO.sub.2 -N.sub.2 -He gas mixture in the laser. The process procedure and sample handling is accomplished using standard vacuum line techniques. The irradiation of dimethylsulfide at R(18) of (00.degree.1-10.degree.0) for 5 seconds at 100 W/cm.sup.2 produced the products methane, ethane, and sulfur. A mixture of a dialkylsulfide (CH.sub.3).sub.2 S, and a dialkylcadmium (CH.sub.3).sub.2 Cd is irradiated at R(18) of (00.degree.1-10.degree.0), 979 cm.sup.-1 for a total of 5 seconds at 100 W/cm.sup.2 to form CdS on the windows of the reaction cell. A higher yield of CdS is obtained when the sensitizer SR.sub.

Abstract: Process and Apparatus for preparing O--X--O and O--X--X (i.e., zero nitrogen) suspension fertilizers wherein phosphate rock is acidulated with merchant-grade wet-process orthophosphoric acid. The instant invention requires only a minimal amount of relatively inexpensive equipment. The process comprises a first-charging step wherein a reactor vessel is partially filled with water of formulation, phosphoric acid, and phosphate rock. The resulting mixture is subjected to a digestion step for a predetermined period of time to effect reaction of the acid and phosphate rock added thereto. Said digestion step is subsequently followed by a second-charging step wherein predetermined amounts of potassium chloride and/or suspending agent are added to said reactor vessel.

Abstract: An air/fuel ratio detector comprising a pump and an electrochemical cell in which both the pump and electrochemical cell comprise an oxygen ion conductive solid electrolyte sandwiched between porous electrodes. One of the elements has an insulating substrate formed on a portion of the electrolyte. Over the substrate is formed a layer of semiconducting metal oxide. The cell and pump face each other with the cell providing an EMF and the pump being pumped by a pump current. The size of the resistance of the metal oxide layer indicates whether the air/fuel mixture is rich or lean relative to a stoichiometric mixture and the values of the EMF and pump current indicate the deviation from stoichiometry.

Abstract: A process of preparing 1,3,5-trinitro-1,3,5-triazacyclohexane of high teccal purity by a one-step direct liquid nitrolysis of hexamethylenetetramine with dinitrogen pentoxide in 100% nitric acid under a separate chlorinated hydrocarbon phase.

Abstract: A cathode suitable for use in a lithium electrochemical cell is made from a ixture of active cathode material, carbon, and non fluorinated linear chain polymer by a method including the steps of(A) dissolving the non fluorinated linear chain polymer in a non polar solvent at a temperature near the melting point of the polymer,(B) adding the active cathode material and carbon and evaporating the solvent, and(C) grinding the dried mixture into a fine powder and making it into a cathode by pressing the powdered mixture onto both sides of an expanded metal screen and then cutting to the desired dimensions.The cathode can be combined with lithium as the anode and a solution of 0.8 mol dm.sup.-3 LiAlCl.sub.4 in a mixed organic solvent of 24 mass percent 4-butyrolactone in 1, 2 dimethoxyethane as the electrolyte to provide a mechanically stable, relatively inexpensive lithium electrochemical cell having good cell performance.

Abstract: A thermodevelopable photographic material is described, comprising a support, at least one photographic silver halide emulsion layer coated thereon, and a dye donating substance capable of forming or releasing a mobile dye in response to, or in inverse response to, the reduction of silver halide in said emulsion to silver by heating, wherein the color of an image formed by the fixing of each of said mobile dyes released by exposure and heating to a dye fixing layer is within the range of a*=10 to -18 and b*=10 to -18 determined from tristimulus values in the 10 degree visual field XYZ system under standard light C.

Abstract: A cathode is provided for use in high energy primary lithium-thionyl chloe cell systems or calcium-thionyl chloride cell systems. The cathode comprises an expanded metallic current collector screen into which has been pasted a mixture of a low surface area conductive carbon black and a high surface area conductive carbon black previously mixed with a binder.

Abstract: Cadmium sulfide is formed successfully from the reactants hydrogen sulfide md the representative dialkylcadmium, dimethylcadmium, spontaneously when mixed in the gas phase. Reactions are monitored using fourier transform infrared spectroscopy which also permits the identification of gaseous products. The gaseous products of this reaction are identified as methane and ethene. The stoichiometry of the cadmium sulfide depends upon the reactant pressure ratios. The process procedure and sample handling is accomplished using standard vacuum line techniques. This particular process is extremely useful, as the stoichiometry of the product cadmium sulfide can be controlled by the purity of the starting materials and the ratios of reactant pressures. Typical reaction mixtures range from about 14 to 32 torr of dimethylcadmium and from about 30 to about 279 torr of hydrogen sulfide. The cadmium sulfide is formed as a reddish orange powder which is used as a precursor for a single crystal production for detector use.

Abstract: A decontamination system in combination with a work space maintained at subambient pressure. An inner vestibule is connected to the work space via a first portal, which can be selectively opened and closed by a first door. A middle vestibule, in which at least one shower bath is installed, is connected to the inner vestibule only via a second portal, which can be selectively closed by a second door or opened. An outer vestibule is connected to the middle vestibule only via a third portal, which can be selectively opened and closed by a third door, and to an ambient space only via a fourth portal, which can be selectively opened or closed by a fourth door. Each door is a rigid door. Except for the third door, which seals the third portal when the third portal is closed by the third door, each door has fixed louvers allowing small quantities of air to infiltrate.