Abstract: Disclosed is a catalyst suitable for the catalytic oxidative cracking of a H2S-containing gas stream. The catalyst comprises at least one or more active metals selected from the group consisting of iron, cobalt, and nickel, supported by a carrier comprising ceria and alumina. The active metal is preferably in the form of its sulphide. Also disclosed is a method for the production of hydrogen from a H2S-containing gas stream, comprising subjecting the gas stream to catalytic oxidative cracking so as to form H2 and S2, using a catalyst in accordance with any one of the composition claims.
Abstract: A dual pressure process for the synthesis of ammonia from a make-up gas, wherein the make-up gas is reacted in two steps in series, the second step operating at a greater pressure than the first step, and wherein a portion of the effluent of the first step is recycled back to the first step, said portion containing unreacted make-up gas.
Abstract: Methods for bi-reforming with a red mud catalyst support composition, one method including providing a methane feed in the presence of carbon dioxide and steam to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.
Type:
Grant
Filed:
January 28, 2020
Date of Patent:
February 15, 2022
Assignee:
SAUDI ARABIAN OIL COMPANY
Inventors:
Mohammed A. Albuali, Bandar H. Alsolami, Bandar A. Fadhel, Rami Bamagain
Abstract: Methods for steam reforming with a red mud catalyst support composition, one method including providing a methane feed and a steam feed to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.
Type:
Grant
Filed:
January 28, 2020
Date of Patent:
February 8, 2022
Assignee:
SAUDI ARABIAN OIL COMPANY
Inventors:
Bandar H. Alsolami, Bandar A. Fadhel, Rami Bamagain, Mohammed A. Albuali
Abstract: Disclosed is a method for producing a metal borohydride and/or H2, including: A. producing a metal borohydride in a synthesis process, in which H2 is a reactant and the reaction further takes metal hydroxide and boron oxide or further takes metal boron oxide; B. producing H2 in a chemical reaction process, in which metal borohydride produced in step A and H2O are reactants, the amount of H2 produced in step B being larger than the amount of H2 required as a reactant in step A for the same amounts of metal borohydride as a reactant and a reaction product in steps B and A, respectively; and C. providing H2 produced in step C to step A, and repeating steps A, B and C. Part of the metal borohydride and/or H2 is withdrawn while leaving an amount of metal borohydride and H2, respectively, so as to allow repeating steps A-C.
Abstract: Methods for autothermal reforming with a red mud catalyst support composition, one method including providing a methane feed with oxygen and carbon dioxide to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.
Type:
Grant
Filed:
January 28, 2020
Date of Patent:
February 8, 2022
Assignee:
SAUDI ARABIAN OIL COMPANY
Inventors:
Rami Bamagain, Bandar A. Fadhel, Bandar H. Alsolami, Mohammed A. Albuali
Abstract: Methods of selectively synthesizing n-tetrasilane are disclosed. N-tetrasilane is prepared by pyrolysis of silane (SiH4), disilane (Si2H6), trisilane (Si3H8), or mixtures thereof. More particularly, the disclosed synthesis methods tune and optimize the n-tetrasilane:i-tetrasilane isomer ratio. The isomer ratio may be optimized by selection of process parameters, such as temperature, residence time, and the relative amount of starting compounds. The disclosed synthesis methods allow facile preparation of n-tetrasilane.
Type:
Grant
Filed:
May 10, 2019
Date of Patent:
January 25, 2022
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Abstract: A method and system of using a type of wave rotor to reform a hydrocarbon fluid using pressure waves within the wave rotor to reformulate a hydrocarbon fluid, such as methane or the like, into a lighter hydrocarbon, hydrogen, or, in some instances, hydrogen, partially decomposed hydrocarbon fluid and carbon solids.
Abstract: A method of regenerating an activated carbon catalyst which is used in the production of polysulphide liquor. In the method, the catalyst is washed with a washing liquid in order to remove the sediment accumulated in the catalyst. According to the present invention, in this case, the activated carbon catalyst is regenerated most suitably by bringing it to a multi-stage washing which comprises at least one washing step in which the washing liquid used comprises sodium sulphide, and one washing step in which acidic washing liquid is used. The sulphur precipitate is peeled off using sodium sulphide, and the iron and other metals can be effectively removed by using an acidic washing, without damaging the catalyst.
Type:
Grant
Filed:
April 27, 2016
Date of Patent:
January 11, 2022
Assignee:
Andritz Oy
Inventors:
Sanna Hämäläinen, Pekka Kittilä, Outi Poukka
Abstract: A method for extending useful life of a sorbent for purifying a gas by sorption of an impurity is provided. The method generating a electrical discharge within the gas to obtain a spectral emission representative of a concentration of the impurity. The method also includes monitoring the concentration of the impurity according to the spectral emission. The method also includes lowering the concentration of the impurity by conversion of at least a portion of the impurity into a secondary impurity having a greater affinity to the sorbent than the impurity. The method also includes comparing the concentration of the impurity to a polluting concentration and managing the sorption of the gas onto the sorbent according to the comparison.
Abstract: A carbon material that is compact and exhibits an excellent hydrogen storage capacity. A carbon material has a specific surface area of 200 m2/g or less and exhibits a hydrogen storage capacity of 1.5×10?5 g/m2 or more at a hydrogen pressure of 10 MPa.
Type:
Grant
Filed:
November 30, 2015
Date of Patent:
January 4, 2022
Assignees:
NISSHINBO HOLDINGS INC., NATIONAL UNIVERSITY CORPORATION GUNMA UNIVERSITY
Abstract: Carbonaceous-containing material including biomass, municipal solid waste, and/or coal and/or contaminated soil, and/or other carbonaceous materials may be gasified at low temperatures utilizing a reactor designed to generate shockwaves in a supersonic gaseous vortex. Preprocessed waste may be introduced into the reactor. A gas stream may be introduced substantially tangentially to an inner surface of a chamber of the reactor to generate a gaseous vortex rotating about a longitudinal axis within the chamber. The gas stream may be introduced using a nozzle that accelerates the gas stream to a supersonic velocity, and may impinge on an impactor positioned within the reactor chamber. A frequency of shockwaves emitted from the nozzle into the gaseous vortex may be controlled. The processed waste discharged from the reactor, which may include a gas component and at least a solid component, can be subjected to separation, and at least some of the gas component and at least one solid component (i.e.
Abstract: The invention relates to a method and a device for producing diluted hydrofluoric acid using an electrode arrangement (1), which has an anode chamber (2) with an anode (4) and a cathode chamber (6) with a cathode (8), which are separated from one another by an anion exchange membrane (10), wherein in the method—pure water is guided through the anode chamber (2), —pure water, which includes at least one electrolyte which forms fluoride ions (F?), is guided through the cathode chamber (6), —and an electrical voltage is applied between the anode (4) and the cathode (8) such that the fluoride ions (F?) are moved through the anion exchange membrane (10) into the anode chamber (2), and an electrical current flows.
Abstract: To provide a metal-based structure or nanoparticles whose homogeneity is not deteriorated and whose sticking formation is easy, and a production method thereof with a high safety. A metal-based structure comprises a hydrogen compound, cluster, or an aggregate thereof, represented by the general formula: MmH. The M is a metal-based atom. The m is an integer of 3 or more and 300 or less. H is a hydrogen atom.
Abstract: A method for making a metal-hydride slurry includes adding metal to a liquid carrier to create a metal slurry and hydriding the metal in the metal slurry to create a metal-hydride slurry. In some embodiments, a metal hydride is added to the liquid carrier of the metal slurry prior to hydriding the metal. The metal can be magnesium and the metal hydride can be magnesium hydride.
Type:
Grant
Filed:
February 19, 2020
Date of Patent:
December 7, 2021
Assignee:
Safe Hydrogen, LLC
Inventors:
Kenneth S. Brown, Jr., David D. G. Bowen, Andrew W. McClaine
Abstract: A method and a system is provided for obtaining solid-state hydrogen storage and release in materials with at least theoretical loaded hydrogen densities of 11 wt % or greater that can deliver hydrogen and be recharged at moderate temperatures enabling incorporation into hydrogen storage systems suitable for transportation applications. These materials comprise ternary boride materials comprising certain light transition metals and alkaline or alkaline earth metals, and ideally have no or very little phase separation. A process of making these materials is also provided.
Type:
Grant
Filed:
November 14, 2017
Date of Patent:
December 7, 2021
Assignee:
National Technology & Engineering Solutions of Sandia, LLC
Abstract: Embodiments of the invention are directed to methods, processes, and systems for safely and reliably purifying hydrogen from a gas mixture containing hydrogen and oxygen.
Type:
Grant
Filed:
May 5, 2017
Date of Patent:
December 7, 2021
Assignee:
SABIC GLOBAL TECHNOLOGIES B.V.
Inventors:
Nasser Ali Aldalaan, Abdulaziz M. Al-Jodai, Mubarik Ali Bashir, Ashwin Ravi Sankar
Abstract: The present invention relates to a solid fuel, a system and a method for generating hydrogen. The solid fuel comprises sodium borohydride, catalyst loaded fibres and a binder, wherein the catalyst loaded fibres and the binder form a scaffold structure within which the sodium borohydride is positioned. The system comprises a fuel cartridge containing the solid fuel of the present invention for generating hydrogen gas, a reactor configured to house the fuel cartridge, a tank for storing water, a pump and a liquid conduit for conveying water from the tank to the fuel cartridge housed within the reactor to induce a hydrolysis reaction of the solid fuel contained in the fuel cartridge and a controller for regulating flow of the water.
Type:
Grant
Filed:
June 3, 2019
Date of Patent:
November 30, 2021
Assignee:
TEMASEK POLYTECHNIC
Inventors:
Lei Wang, Ming Han, Yunzhong Chen, Ee Ho Gareth Tang
Abstract: An object of the present invention is to provide a carrier for adsorbing organic matter, which achieves both of adsorption ability for organic matter and suppression of pressure increase. The present invention provides a carrier for adsorbing organic matter, comprising a sea-island type solid composite fiber, wherein the pore volume is 0.05 to 0.5 cm3/g and the fiber diameter is 25 to 60 ?m.
Abstract: A hollow fiber that generally extends in a longitudinal direction is provided. The hollow fiber comprises a hollow cavity that extends along at least a portion of the fiber in the longitudinal direction. The cavity is defined by an interior wall that is formed from a thermoplastic composition containing a continuous phase that includes a polyolefin matrix polymer and a nanoinclusion additive dispersed within the continuous phase in the form of discrete domains. A porous network is defined in the composition that includes a plurality of nanopores.
Type:
Grant
Filed:
December 11, 2014
Date of Patent:
November 30, 2021
Assignee:
Kimberly Clark Worldwide, Inc.
Inventors:
Vasily A. Topolkaraev, Mark M. Mleziva, Ryan J. McEneany, Neil T. Scholl, Antonio J. Carillo