Patents Examined by T. Pertilla
-
Patent number: 4026862Abstract: A resinous composition, suitable for insulating electrical members, is made from a mixture containing about 100 parts of an epoxy resin, about 55 to 165 parts of an acid anhydride, an effective amount of a latent catalyst and about 1 to 20 parts of a carboxylic acid stabilizer selected from the group of acetic, propionic, butyric, isobutyric, valeric, caproic, heptanoic and hexanoic acids.Type: GrantFiled: February 11, 1974Date of Patent: May 31, 1977Assignee: Westinghouse Electric CorporationInventors: James D. B. Smith, Robert N. Kauffman
-
Patent number: 4014854Abstract: Linear copolymers of glycidol, glycidyl esters of unsaturated fatty acids and, optionally, alkylene oxides, are made by the reaction of an unsaturated fatty acid with a polymer or copolymer of tert.-butyl glycidyl ether in the presence of an acid catalyst. The products are polymerizable and copolymerizable with vinyl monomers and are useful as curable resins.Type: GrantFiled: February 20, 1974Date of Patent: March 29, 1977Assignee: The Dow Chemical CompanyInventors: Violete L. Stevens, Arthur R. Sexton, Frederick P. Corson
-
Patent number: 4014955Abstract: The cross-linked macromolecular polyethers containing ionic bonds are obtained by reacting polyhydric phenols which contain amino groups (Mannich bases) on the one hand with compounds which contain on average more than one epoxide group per molecule, and on the other hand with organic compounds which contain at least 2 halogen atoms. The reaction is on the one hand a polyaddition, and on the other a polyquaternization. The adducts manufactured in this way have a reduced tendency to take on a static charge and can be used with advantage in the textile and paper sectors.Type: GrantFiled: February 7, 1974Date of Patent: March 29, 1977Assignee: Ciba-Geigy AGInventor: Alfred Renner
-
Patent number: 4001156Abstract: Resins containing epoxy groups and quaternary ammonium groups can be prepared by reacting an epoxy group-containing material and an amine acid salt. Boron is added to the composition either by adding a member selected from the group consisting of aqueous boric acid solution, boric acid, and compounds hydrolyzable to form boric acid in aqueous medium to the reaction product or by utilizing a material selected from the group consisting of amine salts of boric acid and amino-containing esters of boric acid as the amine salt constituent. It has now been found that when the reaction between the amine acid salt and the epoxy is conducted in the presence of a controlled amount of water, more uniform and desirable products can be obtained.Type: GrantFiled: March 28, 1974Date of Patent: January 4, 1977Assignee: PPG Industries, Inc.Inventors: Joseph F. Bosso, Marco Wismer
-
Patent number: 4001155Abstract: Paint binders substantially free from epoxide groups and manufactured by reactingA. Mannich bases ofA.sub.1. condensed phenols,A.sub.2. a secondary amine bearing at least 1 hydroxyalkyl group andA.sub.3. formaldehyde withB. at least one epoxy resin.These binders are suitable, in the acid-protonized form, for use in cathodic immersion electrocoating of electrically conductive surfaces.Type: GrantFiled: November 11, 1974Date of Patent: January 4, 1977Assignee: BASF AktiengesellschaftInventors: Firtz Erdmann Kempter, Guenther Sabelus, Herbert Spoor
-
Patent number: 4000116Abstract: The cross-linked macromolecular polyethers containing ionic bonds are obtained by reacting polyhydric phenols which contain amino groups (Mannich bases) with compounds which contain simultaneously epoxide groups and halogen atoms. An addition and a quaternization reaction occur. Optionally, it is possible to add simple organic halides to the reaction mixture. The adducts manufactured in this way have a reduced tendency to acquire a static charge and can be used with advantage in the textile and paper sectors.Type: GrantFiled: February 7, 1974Date of Patent: December 28, 1976Assignee: Ciba-Geigy CorporationInventor: Alfred Renner
-
Patent number: 3985825Abstract: Adducts containing epoxide groups, which have been (so-called) "advanced" with polyesters containing rings are obtained by reacting adducts containing epoxide groups, which have been obtained by reaction of certain long-chain aliphatic polyesters with diepoxide compounds in excess, with polyesterdicarboxylic acids, containing carbocyclic or heterocyclic rings, while heating, 0.3 - 0.5 carboxyl group equivalent of the polyester-dicarboxylic acid containing rings being employed per 1 epoxide equivalent of the adduct containing epoxide groups. Curing of the (so-called) "advanced" adducts containing epoxide groups gives flexible moulded materials which are distinguished, in particular, by high tear propagation resistance.Type: GrantFiled: December 6, 1974Date of Patent: October 12, 1976Assignee: Ciba-Geigy CorporationInventors: Rolf Schmid, Friedrich Lohse, Willy Fatzer, Hans Batzer
-
Patent number: 3985695Abstract: A water reducible epoxy ester is prepared by reacting an epoxy resin, preferably a diglycidyl ether of bisphenol A, and a monofunctional epoxy, such as phenyl glycidyl ether, with a dibasic acid (e.g., azelaic acid) followed by reaction with trimellitic anhydride and neutralization of free carboxyl groups. This material is dispersed in an aqueous vehicle, applied to a metal substrate and baked.Type: GrantFiled: November 25, 1974Date of Patent: October 12, 1976Assignee: Mobil Oil CorporationInventors: Michael A. Tobias, Richard A. Lamanna
-
Patent number: 3984373Abstract: An epoxy resin composition containing an N,N'-unsaturated amic acid compound represented by the general formula, HOCO--R.sub.2 --CONH--R.sub.1 --Y, wherein R.sub.1 is a divalent group having 2 or more carbon atoms, R.sub.2 is a divalent group having a carbon-to-carbon double bond, and Y is ##EQU1## or --NHCO--R.sub.2 --COOH. The composition is characterized, by being favorable in curing characteristics, heat resistance, and flame retardance.Type: GrantFiled: March 27, 1974Date of Patent: October 5, 1976Assignee: Hitachi, Ltd.Inventors: Akio Takahashi, Motoyo Wajima, Ritsuro Tada
-
Patent number: 3981832Abstract: Glass fiber-reinforced epoxy resins are rendered fire-protecting by incorporating in their moulding compositions a combination of three materials: a source of carbon, such as e.g. pentaerythritol, a source of phosphoric acid, such as e.g. a water-insoluble nitrogen-containing polymer phosphate, and a source of non-inflammable gases such as e.g. melamine.Type: GrantFiled: July 12, 1974Date of Patent: September 21, 1976Assignee: Fokker-V.F.W. B.V.Inventor: Leo M. Godfried
-
Patent number: 3979354Abstract: Objects which are designed to be submersed or submerged are rendered antiling by using an organotin polymer wherein the tin is chemically combined in or bonded to the polymer. The polymer inhibits fouling of the exposed surface of the object while minimizing the effect on the surrounding environment due to reduced leaching of the organometallic compound from the polymer.Type: GrantFiled: January 31, 1974Date of Patent: September 7, 1976Assignee: The United States of America as represented by the Secretary of the NavyInventors: Edward J. Dyckman, Jean A. Montemarano, Eugene C. Fischer, Robert R. Ressler
-
Patent number: 3979355Abstract: A resinous composition, suitable for insulating electrical members, is made from a mixture containing about 100 parts of an epoxy resin, about 55 to 165 parts of an acid anhydride and about 0.04 to 0.5 parts of a quaternary organic arsonium compound acting as a latent catalyst.Type: GrantFiled: February 13, 1974Date of Patent: September 7, 1976Assignee: Westinghouse Electric CorporationInventor: James D. B. Smith
-
Patent number: 3977980Abstract: A solid fabric conditioner composition comprising a mixture of a conditioning agent and diatomaceous earth in compressed form is employed to condition fabrics in an automatic clothes dryer. Methods for utilizing such products wherein the rate of release of conditioner to fabrics being treated is predetermined and controlled are also provided.Type: GrantFiled: January 4, 1974Date of Patent: August 31, 1976Assignee: American Can CompanyInventors: Franklin Hornor Fry, Orville Reinke, Wayne A. Marthaler, Richard K. Wylie, Frederick C. Boye
-
Patent number: 3978152Abstract: Polymers possessing imide groups are disclosed. These polymers display good impact strength and are obtained by reacting:A. a bis-imide of the formula ##EQU1## in which Y represents a divalent hydrocarbon radical with 2 to 20 carbon atoms which is free from unsaturated bonds other than aromatic bonds, a divalent mono- or bis-heterocyclic radical with 2 to 10 carbon atoms, or a divalent organic radical with 4 to 20 carbon atoms consisting of several of the hydrocarbon radicals defined above connected to one another by --O--, --S--, --CO-- or --SO.sub.2 --, andB. either an adduct (A) obtained by reacting an epoxy resin and a polyamine of the general formula:Z(-- NH.sub.2 ).sub.v (II)in which Z represents an organic radical of valency v and v represents an integer at least equal to 2, or a mixture comprising the adduct (A) and an amine of the formula:X NH.sub.2 ).sub.Type: GrantFiled: January 31, 1975Date of Patent: August 31, 1976Assignee: Rhone-Poulenc IndustriesInventors: Max Gruffaz, Gerard Lefebvre
-
Patent number: 3978027Abstract: A process for reacting a phenol with an epoxy-containing compound is disclosed. This process comprises reacting a polyepoxide having more than one vic-epoxy group with a phenol in the presence of a potassium iodide catalyst. The products resulting from this process are also disclosed.Type: GrantFiled: May 7, 1975Date of Patent: August 31, 1976Assignee: Shell Oil CompanyInventor: Clifford D. Marshall
-
Patent number: 3975346Abstract: Synthetic resins which are water-dispersible resins, containing boron and chemically-bound quaternary ammonium base salts, can be dissolved or dispersed in water to provide aqueous coating compositions. The resins are derived from epoxy group containing organic materials and are essentially epoxy group free. When dispersed or dissolved in water, the boron-containing, quaternary ammonium salt-containing resins can be applied to a wide variety of different substrates by electrodeposition, and will deposit on the cathode to provide coatings of unique properties.Type: GrantFiled: April 25, 1974Date of Patent: August 17, 1976Assignee: PPG Industries, Inc.Inventors: Joseph F. Bosso, Marco Wismer
-
Patent number: 3975325Abstract: Disclosed is an antistatic agent composition for incorporation in synthetic resins comprised of a blend ofA. a zinc salt of a C.sub.8-22 fatty acid or a mixture of a zinc salt of a C.sub.8-22 fatty acid and a calcium salt of a C.sub.8-22 fatty acid, andB. a tertiary amine component selected from the group consisting of those represented by the formulas ##EQU1## or 3. A MIXTURE OF TERTIARY AMINES (1) OR (2) WITH A HIGHER ALIPHATIC ALCOHOL REPRESENTED BY THE GENERAL FORMULAR.sub.3 OHwhere each R.sub.1, R.sub.2, and R.sub.3 is independently selected from the group consisting of alkyl and alkenyl radicals containing from about 8 to 22 carbon atoms and n is a number of from 1 to 5.Type: GrantFiled: August 27, 1973Date of Patent: August 17, 1976Assignee: ICI United States Inc.Inventor: William Penuel Long, Jr.
-
Patent number: 3971750Abstract: We have developed new and useful epoxy resins which have excellent fire resistance. We prepare these resins by using phosphorus trihalides or phosphorus oxyhalides to cure conventional epoxy resins.Type: GrantFiled: April 21, 1975Date of Patent: July 27, 1976Assignee: Owens-Corning Fiberglas CorporationInventors: Kevin M. Foley, Reuben H. Bell, Frank P. McCombs
-
Patent number: 3968181Abstract: A modified photocurable acrylate resin with improved adhesion to metals is prepared by reacting a liquid polyepoxide, an ethylenically unsaturated conjugated organic carboxylic acid, and the half ester of an aliphatic monohydric alcohol and a polycarboxylic acid anhydride.Type: GrantFiled: March 17, 1975Date of Patent: July 6, 1976Assignee: Shell Oil CompanyInventors: Christopher W. Uzelmeier, Paul D. Jones
-
Patent number: 3968084Abstract: A curable epoxy resin composition containing an epoxy resin and, as a curing agent, 3,9-bis(2-hydrazidoethyl)-2,4,8,10-tetraoxaspiro-[5,5]-undecane, as well as the cured resins produced from such composition, the curable resin being useful for paints, adhesives, and molded articles.Type: GrantFiled: November 25, 1974Date of Patent: July 6, 1976Assignee: Bridgestone Tire Company LimitedInventors: Toshio Yukuta, Takashi Ohashi