Patents Examined by Thomas A. Waltz
  • Patent number: 4335247
    Abstract: The specification describes a nitrosourea derivative having the general formula: Cl--(CH.sub.2).sub.2 --N(NO)CO--NHR, wherein --NHR represents a 2-(1,3,4-thiadiazolyl)amino group, an amino residue of a neutral .alpha.-amino acid, or an amino residue of a neutral .alpha.-amino acid whose carboxyl group is amidated with 2-(1,3,4-thiadiazolyl)amine, or a pharmaceutically acceptable acid addition salt thereof. The above nitrosourea derivative and its salt are useful as antitumor drugs. The above nitrosourea derivative may be prepared either by nitrosating a urea derivative of the general formula: Cl--(CH.sub.2).sub.2 NHCONHR or by reacting N-(2-chloroethyl)-N-nitrosocarbamic acid or a reactive derivative thereof with an amino compound of the general formula: R--NH.sub.2.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: June 15, 1982
    Assignee: Kowa Co., Ltd.
    Inventors: Kichitaro Takatori, Takashi Yamaguchi, Masahiko Nagakura
  • Patent number: 4334118
    Abstract: Improved processes for polymerizing C.sub.3 -C.sub.12 olefins (e.g. propylene) comprising polymerizing olefins in the presence of a solid phosphoric acid catalyst and an alkanol. As well as catalyzing the polymerization, the catalyst also catalyzes the decomposition of the alkanol into water and olefin. The water in turn replaces water lost from the catalyst during the polymerization thus maintaining a more constant phosphoric acid strength catalyst without subjecting said catalyst to excess liquid water and substantially improving overall polymerization conversions and catalyst life.
    Type: Grant
    Filed: June 1, 1981
    Date of Patent: June 8, 1982
    Assignee: Chevron Research
    Inventor: John F. Manning
  • Patent number: 4334116
    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them at dehydrogenation conditions in the presence of a complex oxide catalyst comprising molybdenum, copper and tin and at least one element selected from the group consisting of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, La, Ce, Th and U. For example, an alkyl aromatic hydrocarbon, e.g. ethylbenzene, can be dehydrogenated to an alkenyl aromatic hydrocarbon, e.g. styrene, in the presence of an oxide complex catalyst comprising molybdenum, copper, tin and at least one element selected from the group consisting of K, Cs, Ba, Mg and Ca.
    Type: Grant
    Filed: April 27, 1981
    Date of Patent: June 8, 1982
    Assignee: Standard Oil Company
    Inventors: Louis J. Velenyi, Andrew S. Krupa
  • Patent number: 4334115
    Abstract: A process for obtaining at least one tert-butyltoluene comprising reacting isobutylene and isobutane in the presence of hydrogen fluoride and then separating said toluene from the hydrocarbon product.
    Type: Grant
    Filed: June 18, 1981
    Date of Patent: June 8, 1982
    Assignee: Phillips Petroleum Company
    Inventor: Raymond L. Cobb
  • Patent number: 4331826
    Abstract: A process and an apparatus therefor are described for separating p-xylene from a p-xylene containing hydrocarbon liquid feed material by crystallization, said process comprising (1) mixing a p-xylene containing hydrocarbon feed material with an inert liquid refrigerant, (2) feeding the mixed liquid into a lower part of a bubble tower type crystallization tower as an ascending current, (3) evaporating the refrigerant by the lowering of the liquid static pressure caused by ascent of the mixed liquid and by the transfer of heat into the refrigerant due to solidification of p-xylene and by the lowering of the temperature of the mixed liquid, cooling the ascending liquid to form a slurry of p-xylene crystals in the hydrocarbon liquid, (4) separating the inert refrigerant as a vapor from the liquid surface of the upper part of the crystallization zone, and (5) separating p-xylene crystals from the slurry discharged from the upper part of the crystallization zone.
    Type: Grant
    Filed: March 16, 1981
    Date of Patent: May 25, 1982
    Assignee: Kawasaki Jukogyo Kabushiki Kaisha
    Inventor: Saburo Kagawa
  • Patent number: 4330476
    Abstract: To synthesize triarylmethane dyestuffs of the general formula ##STR1## in which R.sup.1 and R.sup.2 represent optionally substituted alkyl, aryl or aralkyl orR.sup.1 and R.sup.2, together or with the ortho-position of the phenyl ring, form a heterocyclic ring and R.sup.1 can additionally represent hydrogen,R.sup.3 and R.sup.4 denote hydrogen or non-ionic substituents,n represents an integer from 1 to 4 andX.sup.- denotes an anion,by a one-pot process, an aldehyde of the general formula ##STR2## in which R.sup.4 and n have the abovementioned meaning,is subjected to a condensation reaction with an aromatic amine of the general formula ##STR3## in which R.sup.1, R.sup.2, R.sup.
    Type: Grant
    Filed: June 26, 1980
    Date of Patent: May 18, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventor: Karl H. Hermann
  • Patent number: 4330302
    Abstract: Liquid petroleum hydrocarbon blends having improved thermal stability at temperatures of 1000.degree. F. and higher are prepared by removing from the blends dissolved molecular oxygen and maintaining low levels of certain trace impurities in the blends. Trace impurity compounds that are maintained at low levels include: sulfur compounds classed as thiols, sulfides, disulfides and polysulfides; organic oxygen compounds classed as hydroperoxides, peroxides, paraffinic carboxylic acids, and phenols; nitrogen compounds classed as amides and alkyl-pyridines; and reactive olefins. Additional improvements in the blends can be obtained by providing them with a dibenzothiophene or a nitrogen compound classed as a paraffinic amine, carbazole or piperidine. The treated blends of this invention have substantially the same physical properties as similar blends that have not been so treated.
    Type: Grant
    Filed: August 28, 1975
    Date of Patent: May 18, 1982
    Assignee: Exxon Research & Engineering Co.
    Inventor: William F. Taylor
  • Patent number: 4329500
    Abstract: A process for hydrating a nitrile to the corresponding amide by contacting the nitrile in the presence of water with an essentially insoluble heterogeneous catalyst selected from the group consisting of unreduced and reduced cobalt oxide and unreduced and reduced cobalt-chromium oxide or mixture thereof.
    Type: Grant
    Filed: August 7, 1978
    Date of Patent: May 11, 1982
    Assignee: The Dow Chemical Company
    Inventor: Clarence E. Habermann
  • Patent number: 4328112
    Abstract: An improved process for preparing a sulfur-containing composition useful as a lubricant additive wherein an organic carboxylic acid is sulfurized in the form of the acid or an ester or amide derivative thereof is disclosed. The improvement comprises using as the acid or acid portion of an ester or amide derivative, a carboxylic acid or mixture thereof obtained by telomerizing an ethylenically unsaturated compound under inert conditions in a reaction medium containing from about 10.sup.-3 to about 10.sup.-10 moles per liter of an at least trivalent manganese compound and one or more carbonyl compounds having at least one hydrogen atom on an alpha-carbon atom wherein at least 60 percent by weight of the total carbonyl-containing compound content is present as carboxylic anhydride and the molar ratio of the reacted quantity of ethylenically unsaturated compounds to the at least trivalent manganese compound is at least 4.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: May 4, 1982
    Assignee: Akzona Incorporated
    Inventors: Jan Vis, Willem J. de Klein
  • Patent number: 4328248
    Abstract: Compounds of the formulae I and II ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, methoxy, halogen, trifluoromethyl or nitro, R.sub.4 is hydrogen or methyl, R.sub.5 is C.sub.1 -C.sub.3 -alkyl, R.sub.6 is C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.3 -C.sub.5 -alkynyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.4 -(alkoxyalkyl) or C.sub.2 -C.sub.4 -(alkylthioalkyl), and R.sub.7 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.5 -alkenyl or C.sub.3 -C.sub.8 -cycloalkyl, and the acid addition salts of compounds of the formula I, are novel. The compounds of the formula II can be used as starting materials for producing compounds of the formula I. The mentioned compounds of the formulae I and II have a pesticidal action, especially an acaricidal and insecticidal action, and are particularly effective against plant pests.
    Type: Grant
    Filed: April 7, 1981
    Date of Patent: May 4, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Manfred Boger, Jozef Drabek
  • Patent number: 4328113
    Abstract: Alkyl amines, alkyl diamines and borated adducts of alkyl amines and diamines are effective friction reducing additives when incorporated into lubricating oils.
    Type: Grant
    Filed: January 14, 1980
    Date of Patent: May 4, 1982
    Assignee: Mobil Oil Corporation
    Inventors: Andrew G. Horodysky, Joan M. Kaminski, Henry Ashjian, Henry A. Gawel
  • Patent number: 4327232
    Abstract: A stabilized methylchloroform solvent useful in degreasing operations in which the alkylene oxide stabilizer component normally employed is replaced by a tricyclic or quadricyclic compound containing a fused cyclopropane ring.
    Type: Grant
    Filed: February 19, 1981
    Date of Patent: April 27, 1982
    Assignee: The Dow Chemical Company
    Inventors: Alvetta Pryor, Nobuyuki Ishibe
  • Patent number: 4327233
    Abstract: A method is provided for producing a carbocyclic compound by contacting an rganic compound containing a 4-8 membered cyclic sulfide with ozone, in the vapor phase, and recovering a product containing a 3-7 membered carbocyclic ring.
    Type: Grant
    Filed: March 26, 1981
    Date of Patent: April 27, 1982
    Assignee: The United States of America as represented by the Secretary of Commerce
    Inventors: Richard I. Martinez, John T. Herron
  • Patent number: 4325939
    Abstract: A novel zinc compound, an alkali metal or ammonium zinc citrate, is prepared for use in dental compositions and especially in mouthwash compositions to provide mouthwashes with less astringency without loss of anti-odor properties, improved water solubility of the zinc compound and improved chemical compatibility when ionic fluoride salts are employed in compositions along with the zinc compound.
    Type: Grant
    Filed: September 22, 1980
    Date of Patent: April 20, 1982
    Assignee: Richardson-Vicks Inc.
    Inventor: Nutan B. Shah
  • Patent number: 4326077
    Abstract: Novel N-haloacetylphenylamino carbonyl oximes represented by the formula ##STR1## wherein Ar is phenyl or substituted phenyl; R.sup.1 is halomethyl; R.sup.2 and R.sup.3 are each independently hydrogen, alkyl, phenyl, benzyl, substituted phenyl or benzyl, haloalkyl, cyanoalkyl, alkoxyalkyl, alkylthioalkyl or thiocyanoalkyl; R.sup.4 is hydrogen or alkyl; n is 0 or 1; m is 0 or 1; R is hydrogen, alkyl, alkenyl, alkynyl, alkylthioalkyl, haloalkyl, alkoxyalkyl, cyanoalkyl, phenyl, benzyl, substituted phenyl or benzyl, or R is acyl of the formula ##STR2## wherein R.sup.5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl, alkoxy, alkylthio, acetonyl, or the group --NR'R" wherein R' and R" are independently hydrogen, alkyl or phenyl; with the proviso that R.sup.2 and R.sup.3 may be joined together to form a carbocyclic ring or a heterocyclic ring; or R and R.sup.2 may be joined together to form a heterocyclic ring; or R and R.sup.3 may be joined together to form a heterocyclic ring.
    Type: Grant
    Filed: September 22, 1980
    Date of Patent: April 20, 1982
    Assignee: Chevron Research Company
    Inventors: William L. Schinski, David C. K. Chan, Irene C. Huang
  • Patent number: 4324670
    Abstract: An improved process for making a mixed oxyaluminum acylate composition wherein the mole ratio of aromatic to aliphatic radicals ranges from about to 2:3 to 19:1 and improved aluminum complex greases made using a mixed oxyaluminum acylate wherein the mole ratio of aromatic to aliphatic radicals is from about 2:3 to 3:1.
    Type: Grant
    Filed: November 4, 1980
    Date of Patent: April 13, 1982
    Assignee: Chattem, Inc.
    Inventor: Charles E. Pratt
  • Patent number: 4324910
    Abstract: A substituted urea compound containing at least one 2,2,2-trichloro-1-hydroxyethyl group is provided which is useful as a flame retardant for polymers such as polyurethane.
    Type: Grant
    Filed: February 20, 1981
    Date of Patent: April 13, 1982
    Assignee: Pennwalt Corporation
    Inventors: Stanley R. Sandler, Mabel M. Chen
  • Patent number: 4324929
    Abstract: A process for producing mono, bis or tris(3,3,3-trifluoropropyl)benzene, which comprises bringing benzene into reaction with 3,3,3-trifluoropropylene in the presence of an acid catalyst selected from the group consisting of hydrogen fluoride, boron trifluoride and a mixture thereof, is disclosed.
    Type: Grant
    Filed: February 12, 1981
    Date of Patent: April 13, 1982
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yoshiro Kobayashi, Itsumaro Kumadaki, Masaaki Takahashi, Takashi Yamauchi
  • Patent number: 4322551
    Abstract: A process for the preparation of aromatic amide antioxidants from a simple aliphatic or aromatic ester and primary amine in the presence of a metal alkoxide and an alcohol. Unsaturated products produced using this process are sufficiently pure to use as comonomers in the preparation of elastomers.
    Type: Grant
    Filed: February 16, 1978
    Date of Patent: March 30, 1982
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Niranjan V. Shah
  • Patent number: 4322220
    Abstract: Substituted phenol/epichlorohydrin/amine adducts as multipurpose, low concentration additives for hydrocarbon fuels, lubricating oils and mixtures thereof.
    Type: Grant
    Filed: July 5, 1977
    Date of Patent: March 30, 1982
    Assignee: Rohm and Haas Company
    Inventors: Warren H. Machleder, Joseph M. Bollinger