Abstract: A feed fluid mixture including at least one condensable component and at least one non-condensable component is separated into a gaseous permeate and an at least partially liquid retentate with a gas separation membrane through simultaneous condensation of at least one of said at least one condensable component on a retentate side of the membrane and permeation of at least one of said at least one non-condensable component through the membrane.
Type:
Grant
Filed:
August 28, 2018
Date of Patent:
May 18, 2021
Assignee:
Air Liquide Advanced Technologies U.S. LLC
Abstract: To provide a dehumidifying device and dehumidifying method each of which allows absorbed water to be efficiently extracted from a stimuli-responsive polymeric moisture absorbing material or a polymeric moisture absorbing material containing a stimuli-responsive polymeric moisture absorbing material, a dehumidifying device of an embodiment of the present invention includes (i) a stimulus providing section configured to provide an external stimulus to a stimuli-responsive polymeric moisture absorbing material or a polymeric moisture absorbing material containing a stimuli-responsive polymeric moisture absorbing material and (ii) a transfer section configured to transfer water released by the polymeric moisture absorbing material.
Type:
Grant
Filed:
February 16, 2016
Date of Patent:
May 18, 2021
Assignees:
SHARP KABUSHIKI KAISHA, THE SCHOOL CORPORATION KANSAI UNIVERSITY
Abstract: A modified UZM-14 zeolite is described. The modified UZM-14 zeolite has a Modification Factor of 6 or more. The modified UZM-14 zeolite may have one or more of: a Si/Al2 ratio of 14 to 30; a total pore volume in a range of 0.5 to 1.0 cc/g; at least 5% of a total pore volume being mesopores having a diameter of 10 nm of less; a cumulative pore volume of micropores and mesopores having a diameter of 100 ? or less of 0.25 cc/g or more; or a Collidine IR Bronsted acid site distribution greater than or equal to an area of 3/mg for a peak in a range of 1575 to 1700 cm?1 after desorption at 150° C. Processes of making the modified UZM-14 zeolite and transalkylation processes using the modified UZM-14 zeolite are also described.
Type:
Grant
Filed:
May 22, 2019
Date of Patent:
May 4, 2021
Assignee:
UOP LLC
Inventors:
Martha Leigh Abrams, Eseoghene Jeroro, Jaime G. Moscoso, Deng-Yang Jan, Pelin Cox
Abstract: The methods described herein provide an efficient way to remove and isolate short chain fatty acids from hydrocarbons that are produced upon the heating of a fatty acid resource. The short chain fatty acids can be continuously isolated and fed into the pyrolysis reactor, which in turn increases the overall efficiency of the production of the hydrocarbons. Alternatively, the short chain fatty acids can be isolated and used in other applications.
Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olens to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.
Type:
Grant
Filed:
October 16, 2019
Date of Patent:
May 4, 2021
Assignee:
SWIFT FUELS, LLC
Inventors:
Chris D'Acosta, Jeffery Miller, Kurtis Sluss, Benjamin Wegenhart
Abstract: It is an object of the present invention to provide a gasoline composition utilizing lignocellulosic biomass, which is a plant-derived resource that does not cause competition with food production, the gasoline composition satisfying properties required for use in gasoline engines, and a process for producing the gasoline composition. The gasoline composition contains 0.3 to 10.0 vol % of hemicellulose-derived pentene.
Abstract: An asphaltene dispersant composition is provided. The composition may contain an alkylphenol copolymer having the following repeating units (A) and (B): wherein, x is an integer from 1 to 200; y is an integer from 2 to 200; R1 is a straight or branched C1-C15 alkyl; and R2 is a straight or branched C2-C40 alkyl, wherein R2 is different than R1.
Type:
Grant
Filed:
March 6, 2019
Date of Patent:
March 30, 2021
Assignee:
SI Group, Inc.
Inventors:
Joseph T. Doane, Kelly S. Chichak, Brian Christofel, Elliott W. Shanklin
Abstract: A paraffin inhibitor composition that exhibits stable properties at low temperature is provided. The composition may contain, for instance, an alkylphenol copolymer having the following repeating units (A) and (B): wherein, x is an integer from 1 to 200; y is an integer from 2 to 200; R1 is a straight or branched C1-C15 alkyl; and R2 is a straight or branched C16-C40 alkyl.
Type:
Grant
Filed:
March 6, 2019
Date of Patent:
March 30, 2021
Assignee:
SI Group, Inc.
Inventors:
Kelly S. Chichak, Joseph T. Doane, Brian Christofel, Elliott W. Shanklin
Abstract: An alkylphenol copolymer, such as for use in a petroleum composition, is provided. The alkylphenol copolymer has the following repeating units (A) and (B): wherein, x is an integer from 1 to 200; y is an integer from 2 to 200; R1 is a straight or branched C1-C15 alkyl; and R2 is a straight or branched C2-C40 alkyl, wherein R2 is different than R1.
Type:
Grant
Filed:
March 6, 2019
Date of Patent:
March 30, 2021
Assignee:
SI Group, Inc.
Inventors:
Kelly S. Chichak, Joseph T. Doane, Brian Christofel, Elliott W. Shanklin
Abstract: A method and system for increasing olefin production and quality from a hydrocarbon feed comprising a fully integrated multi-stage catalyst regeneration zones with multi-stage reaction zones in series and/or parallel. The multi-stage regeneration with at least one partial and one full burn zone provides an independent control to achieve the lowest possible regenerated catalyst temperature, resulting in highest possible catalyst to oil ratio required to maximize olefins yields through increased catalytic cracking in a multi stage FCC riser/risers.
Abstract: The present invention relates to a method for production of a fuel composition, more specifically a middle distillate fuel composition, and a composition—in particular a co feed composition comprising a furanyl containing oligomerisation composition admixed with one or more material component comprising fatty acids or fatty acid derivatives and the use of such composition.
Abstract: Disclosed is a process for converting C2-5 alkanes to higher-value C5-24+ hydrocarbon fuels and fuel blendstocks including reacting the C2-5 alkanes in a thermal olefination reactor operating at a temperature, pressure and space velocity to convent the alkanes to olefins and in the absence of both a dehydrogenation catalyst and steam. At least a portion of the product olefin stream is oligomerized using a zeolite catalyst to crack, oligomerize and cyclize the product olefins to form the fuel products, which are then recovered. The process is useful in removing sulfur and nitrogen-based compounds in a single step process, while reducing total costs of processing and eliminating the need for additives used in the field.
Type:
Grant
Filed:
April 16, 2019
Date of Patent:
March 9, 2021
Assignee:
SWIFT FUELS, LLC
Inventors:
Chris D'Acosta, Jeffery Miller, Kurtis Sluss, Benjamin Wegenhart
Abstract: Polymer membranes include a polymer material that is selectively permeable to acidic gases over methane in a gas stream, such as natural gas. The polymer material may be a polymer membrane comprising a fluorinated polytriazole polymer. The fluorinated polytriazole polymer may further comprise a substituted phenyl or a substituted benzenaminyl. The substituted phenyl or substituted benzenaminyl may be substituted with hydrogen, bromo, fluoro, chloro, iodo, hydroxy, methyl, trifluoromethyl, dimethylamino, tert-butyl, or difluoromethoxy groups. The polymer material may have a degree of polymerization of from 100 to 175. The polymer membranes may be incorporated into systems or methods for removing separable gases, such as acidic gases, from gas streams, such as natural gas.
Abstract: Methods for making higher-octane fuel components from a feed stream of C8+ paraffins, including catalytically cracking the C8+ paraffins using a Zeolite catalyst to produce a reaction product of mid-chain paraffins and olefins and short-chain paraffins and olefins. The reaction product comprises liquid phase paraffins having an increased Octane Value over the feed stream paraffins. The reaction product further comprises a gas phase of short-chain paraffins which are separated from the liquid phase. In embodiments, the short chain olefins are hydrogenated to form mid-chain paraffins and a gas phase containing short-chain paraffins.
Type:
Grant
Filed:
January 8, 2019
Date of Patent:
January 26, 2021
Assignee:
SWIFT FUELS, LLC
Inventors:
Chris D'Acosta, Jeffery Miller, Robert Hoch
Abstract: A method for recovering hydrocarbons with two multistage columns includes receiving a carbon dioxide recycle stream. The carbon dioxide recycle stream is separated in a first multistage column to produce a purified carbon dioxide recycle stream and a light hydrocarbon stream. The light hydrocarbon stream is separated in a second multistage column to produce a liquefied petroleum stream and a natural gas liquids stream. The first multistage column and the second multistage column are the only two multistage columns used in the method.
Abstract: The invention relates to the compression of a pyrolysis product to facilitate light olefin separation. The pyrolysis product is produced in a pyrolysis reaction. A power generator produces a first shaft power and a second shaft power. The pyrolysis product is compressed using at least part of the first shaft power and at least part of the second shaft power.
Type:
Grant
Filed:
August 15, 2017
Date of Patent:
January 26, 2021
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Thomas W. Pavia, Federico Barrai, Frank Hershkowitz, Gregory E. Yeo
Abstract: Methods and systems for operating and NGL recovery process are provided. In an exemplary method, an absorber column upstream of a fractionator column is operated at a higher pressure than a pressure in the fractionator column. An NGL (C3 plus) stream is taken from the bottom of a fractionator column and then ethylene/ethane stream is taken from the top of the fractionator column. A differential pressure between the absorber column and the fraction are column is controlled based, at least in part, on a flow rate of the fractionator feed stream from the absorber column to the fractionator column.
Type:
Grant
Filed:
October 2, 2019
Date of Patent:
January 19, 2021
Assignee:
Saudi Arabian Oil Company
Inventors:
Ayman M. Mohammad, Diki Andrian, Yaqoub Y. Al-Kalaf
Abstract: Disclosed are compositions for catalysts comprising a zeolite promoted by metal and or metal oxide. In some aspects, the metal and/or metal oxide comprise a mixture of two or more metal or metal oxides. In various aspects, the zeolite is a pentasil zeolite and/or a ZSM-5 type zeolite. Also disclosed are processes for making the disclosed heterogeneous catalysts comprising preparing a mixture of a zeolite and one or more metal salts, which can include use of incipient wetness impregnation methods. In various aspects, also disclosed are methods for direct, non-oxidative preparation of higher hydrocarbons from natural gas, including selective for high yield production of C6 and higher hydrocarbons. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.
Abstract: A method for simultaneously extracting Lycopene and Citrulline from a watermelon includes: separating the rind and the pulp of the watermelon, preprocessing the rind, and using the preprocessed rind to extract the Citrulline; subjecting the pulp to biological enzymolysis and filtering, centrifuging a filtrate, using a precipitate and a filter residue obtained after the centrifuging to extract the Lycopene, and using a supernatant obtained after the centrifuging to extract the Citrulline. By using the method for synchronously extracting Lycopene and Citrulline from the watermelon of the present invention, about 0.5 kg of Lycopene (6% content) and more than 1.2 kg of Citrulline which are worthy of nearly ten thousand yuan can be extracted from each ton of imperfect watermelons, the economic benefit of each ton of watermelons can be increased by more than 5000 yuan after extraction costs are deducted, and the method is high in economic benefits.
Type:
Grant
Filed:
May 31, 2020
Date of Patent:
December 22, 2020
Assignee:
ZHENGZHOU FRUIT RESEARCH INSTITUTE CHINESE ACADEMY OF AGRICULTURAL SCIENCES