Abstract: A method to increase the fracture resistance of titanium alloy matrix composites which comprises thermally treating a composite at a temperature about 5 to 10% above the beta-transus temperature of the alloy for about 4 to 60 minutes.
Type:
Grant
Filed:
March 23, 1992
Date of Patent:
August 3, 1993
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: This is an alloy comprising, by weight percent, 0.5-2.0 niobium, 0.7-1.5 tin, 0.07-0.14 iron, and 0.03-0.14 of at least one of nickel and chromium, and at least 0.12 total of iron, nickel and chromium, and up to 220 ppm C, and the balance essentially zirconium. Preferably, the alloy contains 0.03-0.08 chromium, and 0.03-0.08 nickel. The alloy is also preferably subjected intermediate recrystallization anneals at a temperature of about 1200.degree.-1300.degree. F., and to a beta quench two steps prior to final size.
Type:
Grant
Filed:
March 18, 1992
Date of Patent:
July 27, 1993
Assignee:
Westinghouse Electric Corp.
Inventors:
John P. Foster, Robert J. Comstock, Samuel A. Worcester, George P. Sabol
Abstract: This invention reveals steel alloys which are particularly suitable for use in manufacturing reinforcing wires for rubber products, such as tires. The steel filaments made by this process have an outstanding combination of strength and ductility. Additionally, the steel alloys of this invention can be patented in a low cost process due to their having a very fast rate of isothermal transformation. This allows the steel in the steel wire being patented to transform from a face centered cubic microstructure to an essentially body centered cubic microstructure within a very short period. This invention more specifically discloses a steel alloy composition which is particularly suitable for use in manufacturing reinforcing wire for rubber products which consists essentially of (a) about 92.8 to about 99.18 weight percent iron, (b) about 0.4 to about 1.5 weight percent carbon, (c) about 0.05 to about 1 weight percent silicon, (d) about 0.05 to about 1.2 weight percent manganese, (e) about 0.01 to about 1.
Abstract: A TiAl composition is prepared to have high strength, high oxidation resistance and to have acceptable ductility by altering the atomic ratio of the titanium and aluminum to have what has been found to be a highly desirable effective aluminum concentration and by addition of chromium, boron, and tantalum according to the approximate formulaTi-Al.sub.46-48 Cr.sub.1-3 Ta.sub.2-4 B.sub.0.1-0.3.The alloy is cast to form a body and the body is HIPped to impart a desirable combination of properties thereto.
Abstract: A first method for producing articles of gamma titanium alumide alloy having improved properties comprises the steps of: (a) shaping the article at a temperature between the titanium-aluminum eutectoid temperature of the alloy and the alpha-transus temperature of the alloy, and (b) aging the thus-shaped article at a temperature between about 750.degree. and 1050.degree. C. for about 4 to 150 hours. Shaping is preferably carried out at a temperature about 0.degree. to 50.degree. C. below the alpha-transus temperature.A second method for producing articles of gamma titanium aluminide alloy having improved properties comprises the steps of: (a) shaping the article at a temperature in the approximate range of about 130.degree. C. below the titanium-aluminum eutectoid temperature of the alloy to about 20.degree. C.
Type:
Grant
Filed:
January 22, 1992
Date of Patent:
July 13, 1993
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A method of manufacture of a net form product, including directing a stream of liquid from a nozzle onto a collector of the shape of the desired product, applying an amplitude and time dependent modulated disturbance to the stream to produce a droplet stream, and with the nozzle and collector in a chamber, controlling the chamber environment. An apparatus for manufacturing a net form product having a source of molten material under pressure, a support for positioning a product collector in a chamber with the collector defining a desired product, a droplet stream generator positioned within the chamber and including a nozzle, a conduit for conducting molten material from the material source to the generator nozzle, a mechanism, typically a modulator, for amplitude and time dependent modulation disturbance of the droplet stream, and a drive mechanism for relative movement of the nozzle and support.
Abstract: A method is provided for forming a thick and hard deposit having excellent thermal shock resistance on an engine valve made of a titanium material, particularly on its face and stem end, without allowing the formation of any brittle compound layer between the deposit and the valve material. An engine valve hardfaced on its face and stem end is also provided. A powder comprising a titanium material and 1 to 90% by weight of cobalt, or at least 25% by weight of a titanium material, 1 to 50% by weight of cobalt and 1 to 50% weight of a cobalt-based alloy is fused and deposited on an engine valve mad of a titanium material (e.g., on its face), and the deposited material is aged. The powder is prepared by mixing at least two powders, or from a molten alloy containing all of its constituents, to form a thick and hard deposit having excellent thermal shock and wear resistance on, e.g., the face of the engine valve and is, therefore, of high industrial utility.
Abstract: A method of manufacturing corrosion resistant tubing from seam welded stock of a titanium or titanium alloy metallic material having a hexagonal close-packed crystal structure. The method includes cold pilgering a seam welded tube hollow having a weld area along the seam in a single pass to a final sized tube. The cold pilgering effects a reduction in cross sectional area of the tube hollow of at least 50% and a reduction of wall thickness of at least 50% thereby orienting the crystals in a radial direction. The method also includes annealing the final sized tubing at a temperature and for a time sufficient to effect complete recrystallization and reform grains in the weld area into smaller, homogeneous radially oriented grains. After the recrystallization annealing step, the tubing exhibits enhanced corrosion resistance which is similar to seamless tubing.
Abstract: Leaders are attached to opposite ends of a titanium foil or thin strip element and are partially coiled on respective reels spaced at opposite sides of a cluster rolling mill to transfer the titanium element back and forth between the reels to move the element between pressure rolls of the mill a plurality of times and under forward and back tension in air at room temperature to initially reduce the element thickness enough to permit the element to be coiled on the reels and then to partially coil the element on the reels to further reduce element thickness. Iron aluminide material is interleaved with a loose coil of the element and the element is heated in a protective atmosphere to stress relieve and partially recrystallize the element material between the reductions in thickness.
Abstract: A method for producing hollow titanium alloy articles which comprises casting a plurality of segments which can be joined to provide a unitary, hollow article, treating the cast segments in such manner as to refine the microstructure of the segments and superplastic forming/diffusion bonding the segments into the desired hollow article.
Type:
Grant
Filed:
May 15, 1992
Date of Patent:
July 13, 1993
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: An amalgam and a method of preparing an amalgam for bonding two articles together, which includes mixing a composition of a liquid metal and a metal powder to thoroughly wet the metal powder with the liquid metal, and thereafter mixing a composition with a pestle element for mechanically amalgamating the composition. Other additives may be provided such as ductile metals, additives containing oxides, ceramics, or other non-metallic compounds, and volatile constituents. The amalgamated composition can then wet surfaces to be bonded and harden at or near room temperature.
Type:
Grant
Filed:
May 16, 1991
Date of Patent:
July 6, 1993
Assignee:
Microelectronics and Computer Technology Corporation
Abstract: A process for forming cast, magnesium based alloy articles having reduced microshrinkage comprising the steps of forming a molten alloy consisting essentially of magnesium together with 4 to 10% by weight aluminum, 0 to 1% by weight manganese, and either 0 to 3% by weight zinc or 0 to 1% by weight silicon, adding to the molten alloy 0.01 to 2% by weight strontium, and molding the molten alloy and solidifying to form a cast alloy article.
Type:
Grant
Filed:
September 16, 1991
Date of Patent:
June 29, 1993
Assignee:
Pechiney Electrometallurgie
Inventors:
Jean Charbonnier, Gilles Nussbaum, Gilles Regazzoni
Abstract: Hydrogen storage alloy includes porous base hydrogen storage alloy and Mg which is fused, conjugated with the base hydrogen storage alloy and diffused in the base hydrogen storage alloy.
Abstract: A method of making a strip of ZIRCALOY 2 or 4 is disclosed wherein an ingot is worked, roughly shaped into a billet then quenched from the beta range, hot rolled in alpha range, annealed and cold rolled to 0.3 to 0.9 mm. The O and C, in ppm, are selected to satisfy the formula: O.sub.2 <1200-0.75 x C (R) so that a T texture is obtained systematically for thicknesses of at least 0.8 mm. The disclosure also concerns the strips obtained. The method can be applied to obtaining strips of excellent formability for the production of components for nuclear water reactors.
Abstract: Disclosed are high strength magnesium-based alloys consisting essentially of a composition represented by the general formula (I) Mg.sub.a M.sub.b X.sub.d, (II) Mg.sub.a Ln.sub.c X.sub.d or (III) Mg.sub.a M.sub.b Ln.sub.c X.sub.d, wherein M is at least one element selected from the group consisting of Ni, Cu, Al, Zn and Ca; Ln is at least one element selected from the group consisting of Y, La, Ce, Sm and Nd or a misch metal (Mm) which is a combination of rare earth elements; X is at least one element selected from the group consisting of Sr, Ba and Ga; and a, b, c and d are, in atomic percent, 55.ltoreq.a.ltoreq.95, 3.ltoreq.b.ltoreq.25, 1.ltoreq.c.ltoreq.15 and 0.5.ltoreq.d.ltoreq.30, the alloy being at least 50 percent by volume composed of an amorphous phase.
Type:
Grant
Filed:
January 14, 1992
Date of Patent:
June 22, 1993
Assignees:
Tsuyoshi Masumoto, Japan Metals & Chemicals Co., Ltd., Yoshida Kogyo K.K.
Abstract: A process for generating in-situ low-cost atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals and ceramics, sealing glass to metals, and sintering metal and ceramic powders in a continuous furnace from non-cryogenically produced nitrogen containing up to 5% residual oxygen is presented. The disclosed process involves mixing nitrogen gas containing residual oxygen with a pre-determined amount of a reducing gas such as hydrogen, a hydrocarbon, or a mixture thereof, feeding the gaseous mixture through a non-conventional device into the hot zone of a continuous heat treating furnace, converting residual oxygen to an acceptable form such as moisture, a mixture of moisture and carbon dioxide, or a mixture of moisture, hydrogen, carbon monoxide and carbon dioxide, and using the resultant gaseous mixture for annealing and heat treating metals and alloys, brazing metals and ceramics, sintering metal and ceramic powders, and sealing glass to metals.
Type:
Grant
Filed:
July 8, 1991
Date of Patent:
June 22, 1993
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Donald J. Bowe, Brian B. Bonner, Diwakar Garg
Abstract: An alpha-beta titanium-base alloy having a good combination of strength and ductility with a relatively low cost composition. The composition, in percent by weight, is 5.5 to 6.5 aluminum, 1.5 to 2.2 iron, 0.07 to 0.13 silicon and balance titanium. The alloy may have oxygen restricted in an amount up to 0.25%. The alloy may be hot-worked solely at a temperature above the beta transus temperature of the alloy to result in low.TM.cost processing with improved product yields. The hot-working may include forging, which may be conducted at a temperature of 25.degree. to 450.degree. F. above the beta transus temperature of the alloy. The hot-working may also include hot-rolling, which also may be conducted at a temperature of 25.degree. to 450.degree. F. above the beta transus temperature of the alloy.
Type:
Grant
Filed:
July 29, 1991
Date of Patent:
June 15, 1993
Assignee:
Titanium Metals Corporation
Inventors:
Roy E. Adams, Warran M. Parris, Paul J. Bania
Abstract: A process for working .beta. titanium alloy comprises the steps of first elongating the alloy at a temperature not higher than a .beta. transus temperature and at a working ration of 30% or more. Next, conducting a subsequent aging treatment. Then, elongating the alloy at a temperature not higher than the aging treatment temperature and at a working ratio of 70% or more when combined with that in the first step for elongating. Then a recrystallization treatment is carried out at a treating temperature not higher than the .beta. transus temperature or isothermal working is carried out within a temperature range of the .beta. transus temperature minus 200.degree. C. to the .beta. transus.
Abstract: A sheet of Ti 6-2-2-2-2 alloy having a starting thickness of between approximately 0.040 inches and 0.187 inches is thermomechanically treated at a temperature of between approximately 1500 degrees F. and 1750 degrees F. at a mechanical strain rate in the range of between approximately 1.times.10.sup.-4 and 1.times.10.sup.-2 inch per inch per second to produce a formed part having a tensile strength which is approximately 33% greater than untreated rolled Ti 6-2-2-2-2 alloy sheet or plate.
Type:
Grant
Filed:
July 22, 1991
Date of Patent:
June 1, 1993
Assignee:
Rohr, Inc.
Inventors:
Mark S. Bertolini, Brian Norris, Michael J. Waring
Abstract: Intermetallic compounds or alloys comprising niobium with and from 10 to 28 atomic percent titanium and from 14 to 17.5 atomic percent aluminum characterized by very high temperature melting points, high compressive strength at room temperature, higher room temperature compressive strength after annealing, machineable with conventional tooling, a B2 crystal structure in the as-cast condition, a two-phase microstructure in the annealed condition consisting of a B2 matrix and a second phase with the A15 crystal structure, an expected low value for coefficient of thermal expansion and susceptible to fabrication into single crystals.
Type:
Grant
Filed:
July 23, 1991
Date of Patent:
June 1, 1993
Assignee:
The Ohio State University Research Foundation