Abstract: A hydrochloric acid acidizing composition for treating a subterranean formation penetrated by a well bore to increase the production of desired materials (e.g., hydrocarbons) therefrom that includes a corrosion inhibitor for protecting both ferrous based alloy surfaces (e.g., low alloy steel surfaces) and titanium based alloy surfaces associated with the treatment from corrosion by the acid. The corrosion inhibitor includes an effective amount of a first inhibitor component for inhibiting corrosion of ferrous based alloys, the first inhibitor component including at least one chemical reducing compound, and an effective amount of a second inhibitor component for inhibiting corrosion of titanium based alloys, the second inhibitor component including at least one source of molybdate ions such as sodium molybdate. A method of treating a subterranean formation penetrated by a well bore to increase the production of desired materials therefrom is also provided.
Abstract: A method of extracting corrosion inhibiting constituents from tobacco comprises the steps of soaking tobacco in an aqueous solution under certain extraction conditions, followed by filtration to remove tobacco residue from the resultant aqueous tobacco solution. This tobacco solution is used as a corrosion inhibitor to minimize the amount of corrosion occurring at galvanic corrosion cells that are established at areas of union of metals having different electrochemical potentials.
Abstract: An aqueous polymer preservative and protectant composition containing a silicone emulsion, an aminofunctional silicone emulsion, a film forming thickening agent and a polyol.
Type:
Grant
Filed:
July 19, 1994
Date of Patent:
July 18, 1995
Assignee:
First Brands Corporation
Inventors:
Kenneth L. Meyer, Edward T. Turner, Richard L. Wolstoncroft
Abstract: The invention provides a cleaning agent and method for removing stains from fabrics comprising a combination of dense gas, a source of hydrogen peroxide and an organic bleach activator therefor.
Type:
Grant
Filed:
September 4, 1991
Date of Patent:
July 11, 1995
Assignee:
The Clorox Company
Inventors:
James D. Mitchell, Vincent E. Alvarez, Daniel T. Carty, James R. Latham
Abstract: The present invention provides low viscosity acid-in-oil emulsions, surfactant systems and methods of using the emulsions and surfactants for stimulating the production of hydrocarbons from subterranean producing formations. The low viscosity acid-in-oil emulsions are basically comprised of a hydrocarbon oil forming the external phase of the emulsion, an emulsifying agent of a type which forms and stabilizes an acid-in-oil emulsion, an emulsion viscosity reducing agent comprising a fatty ammonium salt of a fatty acid and an aqueous acid solution forming the internal phase of the emulsion.
Type:
Grant
Filed:
May 12, 1994
Date of Patent:
June 27, 1995
Assignee:
Halliburton Company
Inventors:
Richard W. Pauls, William G. F. Ford, Keith H. Hollenbeak
Abstract: Amines which are compounds of the formula I: ##STR1## where R is a C.sub.6-20 hydrocarbon;X is --NR.sub.1 -- or --O--;each R.sub.1 is independently H or --[(CH.sub.2).sub.1-4 ]COOH or a C.sub.6-20 hydrocarbon;n is 1, 2 or 3;and which contains at least one (CH.sub.2).sub.1-4 COOH group; or salt thereof are useful in inhibiting corrosion of metals in a marine or freshwater environment e.g. in oil- and gas-field applications since they show relatively low toxicity to marine organisms.
Type:
Grant
Filed:
May 14, 1992
Date of Patent:
June 27, 1995
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Paul J. Clewlow, John A. Haslegrave, Niall Carruthers, Daniel S. Sullivan, III, Brent Bourland
Abstract: Compounds of the formula ##STR1## wherein X is an anion selected from the group consisting of phosphate, borate and molybdate groups, and a method for making these compounds. The compounds are useful in the control of microorganisms in aqueous systems and in the inhibition of corrosion of metal surfaces in contact with aqueous systems.
Type:
Grant
Filed:
September 20, 1994
Date of Patent:
June 13, 1995
Assignee:
Buckman Laboratories International, Inc.
Abstract: A method for producing a relatively low viscosity tannin extract from bark and/or wood and suitable for use in formaldehyde-condensation adhesives comprises providing tannin extract obtained from bark and/or wood, separating from the tannin extract the high molecular weight material, subjecting the high molecular weight material to treatment with one or more sulphite compounds to reduce the molecular weight and recombining the sulphited material with the tannin extract. The tannin extract may be recovered by subjecting bark and/or wood to a first stage hot aqueous tannin extraction process, thereby obtaining a first stage tannin extract, subjecting the extracted bark and/or wood to a second stage hot aqueous extraction process at a higher pH than the first stage, thereby obtaining a second stage tannin extract, and optionally recombining the first and second stage tannin extracts.
Type:
Grant
Filed:
January 24, 1994
Date of Patent:
May 23, 1995
Assignee:
Commonwealth Scientific and Industrial Research
Abstract: A method for determining the concentration of dissolved oxygen in a water sample comprising the steps:(a) providing a water sample of predetermined volume, the oxygen content of which is to be determined;(b) mixing additives with the water sample to form a mixture, the additives comprising an oxidizable metal salt comprising a transition metal cation selected from the group consisting of scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel and copper, and an anion selected from the group consisting of an inorganic anion and an organic anion which, with the cation, results in a water soluble oxidizable metal salt, at least one water soluble alkali metal compound selected from the group consisting of an alkali metal oxide and an alkali metal hydroxide and at least one oxidation-reduction indicator capable of a color change upon oxidation of the metal salt;(c) preventing any substantial contact of the mixture with atmospheric oxygen; and(d) comparing the color of the mixture to a predetermined
Abstract: A mixture containing phenothiazines which is obtainable by reacting a mixture of diphenylamines comprising______________________________________ 1 to 5% by weight of a) diphenylamine 8 to 18% by weight of b) 4-tert-butyldiphenylamine 21 to 31% by weight of c) one or more compounds selected from i) 4-tert-octyldiphenylamine ii) 4,4'-di-tert-butyldiphenylamine iii) 2,4,4'-tris-tert-butyldiphenylamine 20 to 31% by weight of d) one or more compounds selected from i) 4-tert-butyl-4'-tert-octyldiphenylamine ii) 2,2'- or 2,4'-di-tert- octyldiphenylamine iii) 2,4-di-tert-butyl-4'-tert- octyldiphenylamine, and 15 to 29% by weight of e) the compound i) 4,4'-di-tert-octyldiphenylamine, or the compounds i) 4,4'-di-tert-octyldiphenylamine and ii) 2,4-di-tert-octyl-4'-tert- butyldiphenylamine, ______________________________________with 1 to 200 mol % of elemental sulfur, in the presence of 0.
Abstract: C.sub.1 -C.sub.6 -Alkyl nitrites can be prepared by reacting nitrogen dioxide with C.sub.1 -C.sub.6 -alcohols, by, in a counterflow-operated column, feeding the alcohol or an alcohol/water mixture into the upper part of the column and the nitrogen dioxide or a nitrogen dioxide/inert gas mixture into the lower part of the column. The resulting alkyl nitrite is removed from the column as the top product and the co-formed nitric acid is removed from the column as the bottom product.
Type:
Grant
Filed:
November 24, 1993
Date of Patent:
May 2, 1995
Assignee:
Bayer Aktiengesellschaft
Inventors:
Heinz Landscheidt, Paul Wagner, Alexander Klausener
Abstract: A corrosion inhibitor composition and a method for employing the same to prevent corrosion of copper and copper containing metals in contact are disclosed. Protection is afforded thereto by contacting the metal surface with the medium containing sufficient amount of benzotriazole/its derivatives and halogen, preferentially iodide or bromide ions. The inhibitor has particular utility in protecting metal surfaces which are subject to corrosion in aggressive aqueous systems.
Abstract: A white rust inhibiting composition and method of inhibiting white rust for evaporative water coolers are disclosed. The composition includes in combination a blend of one or more organophosphorus compounds, one or more carbamate compounds, and one or more water soluble metal compounds.
Abstract: This invention relates to a composition and method of inhibiting catalyzed oxidation of carbon-carbon composites. The invention includes compositions, capable of impregnating carbon-carbon composites, comprising an aqueous mixture of (a) phosphoric acid, (b) a metal phosphate, and (c) a penetration and retention improving amount of a compatible wetting agent selected from the group consisting of polyols, alkoxylated monohydric alcohols, and mixtures thereof. The invention also includes a method of inhibiting catalyzed oxidation of carbon-carbon composites comprising the steps of treating a carbon-carbon composite with the catalyzed oxidation inhibiting aqueous mixture, and heating the treated carbon-carbon composite to a temperature sufficient to remove water. Articles, including friction brakes, made by this method are also part of this invention. Treated brake lugs, and other exposed areas of aircraft braking systems have improved resistance to catalyzed oxidation.
Abstract: A fire extinguishing material that comprises a particulate material to be projected onto a fire having a particle size of no more that 212 microns, a moisture content of no more than 0.50 parts by weight, a hygroscopicity of no more than 3.00 parts by weight, and a bulk density of about 125 milliliters per 100 grams. The particulate material consists essentially of from about 40 to about 80 parts by weight monoammonium phosphate, from about 32 to 0 parts by weight ammonium sulfate, from about 10 to about 18 parts by weight of one or more carbonates selected from the group consisting essentially of magnesium carbonate, potassium carbonate and calcium carbonate, from about 0 to 15 parts by weight of barium sulfate, about 2.0 parts by weight hydrated aluminum-magnesium silicate, about 0.04 parts by weight of diarylide yellow, and about 0.8 parts by weight of methylhydrogen siloxane.
Abstract: A chromium and ferricyanide free aqueous deoxidizer/desmutter for aluminum and magnesium alloys contains nitric acid, ferric ions, persulfate, and molybdate and preferably also sulfate, fluoride, and ethoxylated acetylenic diol surfactant.
Abstract: A vapor phase corrosion inhibitor-desiccant composite comprising silica gel granules coated with a vapor phase corrosion inhibitor component. The corrosion inhibitor component is selected from a formulation comprising anhydrous molybdates such as ammonium dimolybdate, sodium molybdate and amine molybdates mixed with benzotriazole and sodium nitrate, or from a formulation comprising amine benzoates, amine nitrates and benzotriazole. The composites can be impregnated into foam, extruded with polyolefin films which can additionally be laminated with metallized second film, or encapsulated in an air-permeable container. The corrosion inhibitor formulations have vapor pressures which provide ongoing corrosion protection for susceptible articles situated favorably with respect to the composite.
Type:
Grant
Filed:
October 14, 1993
Date of Patent:
February 28, 1995
Inventors:
Boris A. Miksic, Tsi-Zong Tzou, Joseph M. Foley
Abstract: A method for inhibiting corrosion in an aqueous medium is disclosed. The method comprises incorporating into the medium an amount of a water-soluble corrosion inhibitor sufficient to inhibit corrosion. The corrosion inhibitor comprises an N-ethoxy,2-substituted imidazoline, the N-ethoxy substituent having from one to about thirty ethoxy units and the 2-substituent being an unsaturated or polyunsaturated fatty chain of from about six to about thirty carbons. If the medium is sweet, the inhibitor further comprises a phosphate ester derived from a water-soluble oxyethylated, straight chain alcohol of from about two to about thirty carbons. Corrosion inhibitor compositions useful in such method are also disclosed.
Type:
Grant
Filed:
November 2, 1993
Date of Patent:
February 28, 1995
Inventors:
Richard L. Martin, Jo Ann McMahon, Bernardus A. Oude Alink
Abstract: A composition for inhibiting corrosion. The composition contains a mixture of a dessicant and a vapor-corrosion inhibitor. The mixture of dessicant and inhibitor is synergistic: the service life of the corrosion inhibitor is significantly longer when so used than when used alone or in in the presence of but not physically mixed with the dessicant.
Abstract: The present invention relates to an agent or concentrate for protecting sawn timber against wood-discolouring fungi, containing a fungicide on phenol basis and a fungicide on organo-iodine basis, optionally fungicides and insecticides, dissolved in an organochemical solvent or solvent mixture or in a mixture of water and organochemical solvent or solvent mixture and at least one emulsifier.
Type:
Grant
Filed:
May 19, 1993
Date of Patent:
February 14, 1995
Assignee:
Bayer Aktiengesellschaft
Inventors:
Hans-Georg Schmitt, Otto Exner, Hans-Ulrich Buschhaus