Abstract: A catalyst for methanation reaction and a method for preparing methane are provided. The catalyst for methanation reaction includes a core, a shell encapsulating the core, and an active metal. The core includes cerium dioxide (CeO2), the shell includes zirconium dioxide (ZrO2), and the active metal is in particle form and is disposed on an outer surface of the shell layer.

Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of forming a supported chromium catalyst comprising chromium in a hexavalent oxidation state, irradiating the hydrocarbon reactant and the supported chromium catalyst with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. The supported chromium catalyst can be formed by heat treating a supported chromium precursor, contacting a chromium precursor with a solid support while heat treating, or heat treating a solid support and then contacting a chromium precursor with the solid support.

Abstract: A method of immobilizing a metal catalyst in a porous support includes additively forming a precursor structure on a substrate from a metal catalyst and at least one of a metal oxide or a metal cluster compound; exposing the precursor structure to a vapor of an organic linker; and reacting the at least one of the metal oxide or the metal cluster compound in the precursor structure with the organic linker to form a porous support that immobilizes the metal catalyst.

Abstract: Provided are a bifunctional catalyst for deep desulfurization and gasoline quality improvement and a preparation method therefore and a use thereof. The bifunctional catalyst includes a modified catalyst and a loaded active metal, where the modified catalyst carrier is a ?-Al2O3 modified with a rare earth element, or the modified catalyst carrier is a composite carrier prepared by mixing and calcinating ?-Al2O3 and an acid molecular sieve through a binder, and then modifying with the rare earth element. The bifunctional catalyst for deep desulfurization and gasoline quality improvement can achieve deep desulfurization of high-sulfur fluid catalytic cracking gasoline, and ensure no significant loss of octane number under relatively mild conditions.

Abstract: The present invention relates to a phosphine precursor for the preparation of a quantum dot, and a quantum dot prepared therefrom. Using the phosphine precursor for the preparation of a quantum dot of the present invention, a quantum dot with improved luminous efficiency and higher luminous color purity can be provided.

Abstract: The present disclosure provides msect-4 molecular sieves with OFF and ERI topologies, a preparation method therefor, and applications thereof. An eight-membered ring small pore molecular sieve used as a raw material is dispersed in an aqueous phase. Following that, caustic potash, an aluminum source, and an organic structure-directing agent (OSDA) are added. The pH value is then adjusted to be greater than 10, and a silicon source is introduced to attain the desired silicon-aluminum ratio, followed by stirring reaction, aging, crystallization, filtration, washing, ammonia exchange reaction, drying, and calcination. The msect-4 molecular sieves with OFF and ERI topologies, the preparation method therefor, and applications exhibit excellent hydrothermal stability, a plurality of adsorption sites exposed by a regular bone-like structure, and a large specific surface area.

Abstract: Methods of solid catalyst manufacture using a peptization agent, and formed solid catalyst materials having improved structural properties are provided. The peptization agent includes one or more oxidized disulfide oil (“ODSO”) compounds. These ODSO compounds peptization agents serve to improve the adhesion characteristics of the binder material, and as a result increase the particle strength of the final catalyst particles.

Abstract: A sulfuric acid generating system can include: a primary burn chamber; an exhaust pipe extending from the burn chamber at a first end to an opposite second end; a secondary burn chamber located between the first end and second end; and a primary venturi pump having a gas inlet coupled to an outlet at the second end of the exhaust pipe and having an aqueous media inlet and having a fluid outlet. A method of producing sulfurous acid can include: providing sulfur to the primary burn chamber; burning a first portion of the sulfur in the primary burn chamber to form a first portion of sulfur dioxide; burning a second portion of the sulfur in the secondary burn chamber to form a second portion of sulfur dioxide; and mixing the first portion and second portion of sulfur dioxide with an aqueous composition so as to produce aqueous sulfurous acid.

Abstract: A nanocomposite photocatalyst CuNPs@PVDF including polyvinylidene fluoride (PVDF) nanoparticles loaded with copper nanoparticles (CuNps). In an embodiment, the nanocomposite photocatalyst can be effectively used to degrade industrial contaminants and dye compounds typically found in wastewater environments. The nanocomposite photocatalyst can be contacted with a solution including an organic dye under sun irradiation to achieve photochemical degradation of the organic dye.

Abstract: A solid-supported Pd catalyst is suitable for C—C bond formation, e.g., via Suzuki-Miyaura and Mizoroki-Heck cross-coupling reactions, with a support that is reusable, cost-efficient, regioselective, and naturally available. Such catalysts may contain Pd nanoparticles on jute plant sticks (GS), i.e., Pd@GS, and may be formed by reducing, e.g., K2PdCl4 with NaBH4 in water, and then used this as a “dip catalyst.” The dip catalyst can catalyze Suzuki-Miyaura and Mizoroki-Heck cross coupling-reactions in water. The catalysts may have a homogeneous distribution of Pd nanoparticles with average dimensions, e.g., within a range of 7 to 10 nm on the solid support. Suzuki-Miyaura cross-coupling reactions may achieve conversions of, e.g., 97% with TOFs around 4692 h?1, Mizoroki-Heck reactions with conversions of, e.g., a 98% and TOFs of 237 h?1, while the same catalyst sample may be used for 7 consecutive cycles, i.e., without addition of any fresh catalyst.

Abstract: A water absorption treatment material includes a first grain and a second grain that absorb a liquid. The first grain includes a first core portion and a first coating portion. The first core portion has a grain-like shape. The first coating portion contains an adhesive material, and entirely covers the first core portion. The second grain includes a second core portion and a second coating portion. The second core portion has a grain-like shape. The second coating portion contains an adhesive material, and partially covers the second core portion.

Abstract: Modified chemical structures of cardanol extracted from cashew nut shell oil, and the use of the same to prepare imidazolium ionic liquids (IILs). The IILs can be used to prepare different types of silica, magnetite and calcium carbonate nanoparticles (NPs) as multifunctional oilfield chemicals for use in various oil spill collection, de-emulsification, viscosity improvement, asphaltene dispersant, and enhanced oil recovery applications.

Abstract: A polydentate organic ligand, a preparation method and an application method thereof, a metallo-supramolecular polymer and a preparation method thereof are provided. A structure of triphenylamine is combined with a structure of phenanthroline to serve as the polydentate organic ligand, which takes advantages of a large-volume distortion structure and excellent electroactivity of the triphenylamine. The polydentate organic ligands have good solubility, which provides lower-cost and diversified methods for preparing the metallo-supramolecular polymers. Meanwhile, the phenanthroline has a rigid structure and a conjugated large ? bond in its molecule, which facilitates chelating coordination with metal ions to form a stable compound. Therefore, the polydentate organic ligand enables the metallo-supramolecular polymer to have good transferability, stable electroactivity, and high conversion speed, i.e., fast response speed, excellent electrochromic cycling stability and long service lifetime.

Abstract: Catalysts and methods for use in conversion of glycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. Catalysts are capable of simultaneous esterification and transesterification under same process conditions. The described catalysts are thermostable, long lasting, and highly active.

Abstract: To provide a disposable diaper enabling reduction in re-wet amount and having an excellent speed of incorporating liquid regardless of concentration and configuration of a water-absorbing agent in an absorbent material. A water-absorbing agent having excellent Gel Capillary Absorption (GCA) and Free Gel Bed Permeability (FGBP) is obtained by crushing a crosslinked hydrogel polymer obtained in a polymerization step to have a specific weight average particle diameter while fluid retention capacity and a surface tension of a water-absorbing agent are adjusted in a specific range, drying the crushed crosslinked hydrogel polymer, and then adding a liquid permeability enhancer thereto during surface crosslinking or after surface crosslinking.

Abstract: A zirconia-based porous body including an oxide of a rare earth element, in which when a pore volume in a pore distribution range of 30 nm or more and 200 nm or less after heating at 1150° C. for 12 hours under atmospheric pressure is defined as pore volume A and a pore volume in a pore distribution range of 30 nm or more and 200 nm or less before heating is defined as pore volume B, the pore volume A is 0.10 ml/g or more and 0.40 ml/g or less, and a pore volume retention ratio X in a pore distribution range of 30 nm or more and 200 nm or less represented by a formula [[(pore volume A)/(pore volume B)]×100] is 25% or more and 95% or less.

Abstract: The present invention relates in part to a method of fabricating multimetallic nanoparticles, the method comprising the steps of providing a substrate; activating the substrate surface; adsorbing a cationic transition metal complex onto the substrate surface to form a substrate-supported cationic transition metal complex; adsorbing an anionic transition metal complex onto the substrate-supported cationic transition metal complex to form a substrate-supported multimetallic complex salt; and reducing the substrate-supported multimetallic complex salt to provide a plurality of multimetallic nanoparticles. The invention also relates in part to a composition of multimetallic nanoparticles comprising at least two metals Ma and Mb; wherein the ratio of Ma to Mb is between about 2:1 and about 1:2.

Abstract: The current invention relates to a method of separating polyunsaturated fatty acids containing lipids from a lipids containing biomass.

Abstract: The present invention provides a catalyst system for producing cyclic carbonates comprising: a pre-catalyst, which is BiCl3 having amounts in the range from 5 to 10% by weight of silica support; a compound having formula (I) wherein: Y is selected from bromide (Br?) or iodide (I?); R1, R2, and R3 are methyl group or R1, R2, and R3 are taken together to form a heteroaryl ring having formula (II) and a silica (SiO2) support.

Abstract: This invention discloses a method for extracting lithium from carbonate clay type lithium ore based on ion exchange, which belongs to the field of lithium extraction technologies. This method aims to, with iron salt as the extractant, extract lithium into the solution through exchange reaction with lithium ore, which mainly involves the following steps: have clay type lithium ores crushed and ground prior to high-temperature roasting activation, and then conduct iron exchange reaction by iron salt solution while heating, followed by solid-liquid separation by means of filtration. The filtrate obtained will be lithium-bearing solution, and the extraction rate of lithium can reach as high as over 90%.