Abstract: A polydentate organic ligand, a preparation method and an application method thereof, a metallo-supramolecular polymer and a preparation method thereof are provided. A structure of triphenylamine is combined with a structure of phenanthroline to serve as the polydentate organic ligand, which takes advantages of a large-volume distortion structure and excellent electroactivity of the triphenylamine. The polydentate organic ligands have good solubility, which provides lower-cost and diversified methods for preparing the metallo-supramolecular polymers. Meanwhile, the phenanthroline has a rigid structure and a conjugated large ? bond in its molecule, which facilitates chelating coordination with metal ions to form a stable compound. Therefore, the polydentate organic ligand enables the metallo-supramolecular polymer to have good transferability, stable electroactivity, and high conversion speed, i.e., fast response speed, excellent electrochromic cycling stability and long service lifetime.

Abstract: Catalysts and methods for use in conversion of glycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. Catalysts are capable of simultaneous esterification and transesterification under same process conditions. The described catalysts are thermostable, long lasting, and highly active.

Abstract: A zirconia-based porous body including an oxide of a rare earth element, in which when a pore volume in a pore distribution range of 30 nm or more and 200 nm or less after heating at 1150° C. for 12 hours under atmospheric pressure is defined as pore volume A and a pore volume in a pore distribution range of 30 nm or more and 200 nm or less before heating is defined as pore volume B, the pore volume A is 0.10 ml/g or more and 0.40 ml/g or less, and a pore volume retention ratio X in a pore distribution range of 30 nm or more and 200 nm or less represented by a formula [[(pore volume A)/(pore volume B)]×100] is 25% or more and 95% or less.

Abstract: To provide a disposable diaper enabling reduction in re-wet amount and having an excellent speed of incorporating liquid regardless of concentration and configuration of a water-absorbing agent in an absorbent material. A water-absorbing agent having excellent Gel Capillary Absorption (GCA) and Free Gel Bed Permeability (FGBP) is obtained by crushing a crosslinked hydrogel polymer obtained in a polymerization step to have a specific weight average particle diameter while fluid retention capacity and a surface tension of a water-absorbing agent are adjusted in a specific range, drying the crushed crosslinked hydrogel polymer, and then adding a liquid permeability enhancer thereto during surface crosslinking or after surface crosslinking.

Abstract: The present invention relates in part to a method of fabricating multimetallic nanoparticles, the method comprising the steps of providing a substrate; activating the substrate surface; adsorbing a cationic transition metal complex onto the substrate surface to form a substrate-supported cationic transition metal complex; adsorbing an anionic transition metal complex onto the substrate-supported cationic transition metal complex to form a substrate-supported multimetallic complex salt; and reducing the substrate-supported multimetallic complex salt to provide a plurality of multimetallic nanoparticles. The invention also relates in part to a composition of multimetallic nanoparticles comprising at least two metals Ma and Mb; wherein the ratio of Ma to Mb is between about 2:1 and about 1:2.

Abstract: The current invention relates to a method of separating polyunsaturated fatty acids containing lipids from a lipids containing biomass.

Abstract: An ammonia plant having a first and second reactor and a start-up oven having at least one first heat exchanger. The first reactor operates under a higher internal pressure than the second reactor. The start-up oven is connected via a piping system for at least one synthesis gas to the first and second reactor. Ammonia is produced by heating synthesis gas in the start-up oven and transferring the heated synthesis gas to the first reactor for initiating the chemical reaction. Synthesis gas is heated with the same start-up oven and is transferred to the second reactor for initiating the chemical reaction, wherein high-pressure synthesis of ammonia occurs in the first reactor and low-pressure synthesis of ammonia occurs in the second reactor at a lower process pressure than in the first reactor.

Abstract: The present invention provides a catalyst system for producing cyclic carbonates comprising: a pre-catalyst, which is BiCl3 having amounts in the range from 5 to 10% by weight of silica support; a compound having formula (I) wherein: Y is selected from bromide (Br?) or iodide (I?); R1, R2, and R3 are methyl group or R1, R2, and R3 are taken together to form a heteroaryl ring having formula (II) and a silica (SiO2) support.

Abstract: This invention discloses a method for extracting lithium from carbonate clay type lithium ore based on ion exchange, which belongs to the field of lithium extraction technologies. This method aims to, with iron salt as the extractant, extract lithium into the solution through exchange reaction with lithium ore, which mainly involves the following steps: have clay type lithium ores crushed and ground prior to high-temperature roasting activation, and then conduct iron exchange reaction by iron salt solution while heating, followed by solid-liquid separation by means of filtration. The filtrate obtained will be lithium-bearing solution, and the extraction rate of lithium can reach as high as over 90%.

Abstract: A method for manufacturing a lithium hydroxide powder includes a pulverizing step of pulverizing coarse particles of lithium hydroxide to obtain lithium hydroxide powder; and a carbonation-suppressing step of storing the lithium hydroxide powder in an airtight container in an atmosphere satisfying requirements (1) and (2). (1) A partial pressure of carbon dioxide gas is 100 Pa or less with respect to a total amount of gas present in the airtight container. (2) A relative humidity in the airtight container is 60% or less.

Abstract: A method of removing buffer gas from a mixture comprising the buffer gas and hyperpolarized noble gas is described. The method includes reacting the buffer gas to produce a reaction product different to the buffer gas. The buffer gas may be reactively removed by one or more of oxidation, reduction, polymerization and binding reactions with solid surfaces. The buffer gas may be molecular hydrogen and/or molecular nitrogen. Apparatus for carrying out the method are also disclosed.

Abstract: Compositions for regeneration of spent dialysis fluid are disclosed. The compositions include a sorbent comprising a titanium-glyoxal complex. Sorbent cartridges comprising the sorbents, and methods and systems for using the cartridges in dialysis also are disclosed.

Abstract: A procedure of minimum environmental impact and maximum lithium recovery for obtaining concentrated brines with minimal impurity content from brines that embed natural salt flats and salt marshes, the procedure wherein the following stages are comprised: a) building fractional crystallization ponds by solar evaporation; b) filling the ponds with natural brine; c) initially pre-concentrating natural brine to the maximum possible lithium concentration in the liquid phase without precipitating lithium-containing salts; d) cooling the pre-concentrated brine obtained in c) ensuring maximum precipitation of salts containing sulfate anion; e) chemically pre-treating the liquid phase of brine separated from precipitated salts by cooling to minimize sulfate anions in the liquid phase after cooling; f) finally pre-concentrating the pre-treated liquid phase to the maximum possible lithium concentration in it without precipitating lithium-containing salts; g) chemically treating the liquid phase of brine separated from p

Abstract: The present disclosure features a composition, including molecularly imprinted crosslinked polymers that have been imprinted with trimethylamine N-oxide. The molecularly imprinted crosslinked polymers have specific binding sites for trimethylamine N-oxide, and a trimethylamine N-oxide absorption capacity of at least 0.5 mg/g.

Abstract: Disclosed in the present disclosure are a lithium adsorbent and a preparation method therefor. The lithium adsorbent has a porous structure, and includes an aluminum-based lithium adsorbent active material and a hydrophilic binder; and the lithium adsorbent has an average pore diameter ranging from 1 nm to 10 nm, a pore volume ranging from 0.65 ml/g to 0.8 ml/g, and a specific surface area ranging from 400 m2/g to 600 m2/g. The lithium adsorbent of the present disclosure has a specific average pore size ranging from 1 nm to 10 nm, lithium ions have a diameter of 0.3 nm, and the pore size of the lithium adsorbent of the present disclosure is three times or more greater than the diameter of the ions so that the lithium ions can quickly enter and exit pores.

Abstract: An antimicrobial composition comprising 3-phenyl propanol or 2-methyl 3-phenylpropanol, or mixtures thereof, alone or in combination with an organic acid or salt thereof, or an alcohol, or mixtures thereof. Methods of preserving products and end-use applications for use of the inventive antimicrobial compositions are also provided.

Abstract: A dinuclear vanadyl-diisatin succinyldihydrazone complex (VO-diisatin succinyldihydrazone complex), a method of using the dinuclear vanadyl-diisatin succinyldihydrazone complex, and a method of making the dinuclear vanadyl-diisatin succinyldihydrazone complex are provided. The dinuclear vanadyl-diisatin succinyldihydrazone complex has improved catalytic effectiveness and increased efficiency by reducing catalytic reaction time and temperature.

Abstract: Sorbent materials that are treated with ions, salts, oxides, hydroxides, or carbonates of calcium, magnesium, strontium, or barium are useful in removing perfluoroalkyl and polyfluoroalkyl substances (PFAS), perfluorooctanoic acid (PFOA), perfluorooctanesulfonic acid (PFOS), 2,3,3,3,-tetrafluoro-2-(heptafluoropropoxy)propanoate and heptafluoropropyl 1,2,2,2-tetrafluoroethyl ether, and similar compounds from liquids and gases are disclosed. The sorbent materials with the disclosed treatments offer improved performance as measured against untreated sorbent materials.

Abstract: The present invention relates to a diatomaceous earth composition with a low endotoxin content, comprising an agglomerated mixture of calcined diatomaceous earth particles and water, wherein the mass ratio of calcined diatomaceous earth particles and water is in the range of 1:1.0 to 1:2.0, and wherein the endotoxin content of the diatomaceous earth composition is equal to or less than 0.5 EU/mL. In a further aspect, the present invention relates to a method for producing the diatomaceous earth composition with a low endotoxin content. In another aspect, the present invention relates to the use of the diatomaceous earth composition with a low endotoxin content as a precoat agent for the precoat filtration in biopharmaceutical applications.

Abstract: The disclosed subject matter relates to a microcapsule including a particle core selected from activated carbon (AC), super activated carbon (SAC), MOF composition, multifunctional material or a mixture thereof and a water-soluble polymer shell, including a membrane into which the microcapsule is incorporated, a membrane with exposed AC, SAC, MOF, or multifunctional materials or mixture thereof formed therefrom and methods used is the formation of all of the above.