Abstract: Disclosed is a system for fabricating a semiconductor device (100). An interconnect structure (110) is formed on the semiconductor device (100) and a cap (112) is deposited over the interconnect structure (110). The interconnect structure (110) is annealed with the overlying cap (112) in place. The cap (112) is then removed after the interconnect structure (110) is annealed.

Abstract: A method of manufacturing a semiconductor device includes the steps of providing a semiconductor substrate (202), forming a dielectric layer (204) over the semiconductor substrate (202), and etching a trench or a via (206) in the dielectric layer (204) to expose a portion of the surface of the semiconductor substrate (202). The method also includes the step of forming a conductive layer (212, 220) within in the trench or the via (206). The method further includes the steps of polishing a portion of the conductive layer (220) and annealing the conductive layer (212, 220) at a predetermined temperature. Moreover, the conductive layer (212, 220) also includes a dopant, and the dopant diffuses substantially to the surface of the top side of the conductive layer (212, 220) to form a dopant oxide layer (212a, 220a) when the conductive layer (212, 220) is annealed at the predetermined temperature and the dopant is exposed to oxygen.

Abstract: Disclosed is a system for fabricating a semiconductor device (100). An interconnect structure (110) is formed on the semiconductor device (100) and a cap (112) is deposited over the interconnect structure (110). The interconnect structure (110) is annealed with the overlying cap (112) in place. The cap (112) is then removed after the interconnect structure (110) is annealed.

Abstract: A method of manufacturing a semiconductor device includes the steps of providing a semiconductor substrate (202), forming a dielectric layer (204) over the semiconductor substrate (202), and etching a trench or a via (206) in the dielectric layer (204) to expose a portion of the surface of the semiconductor substrate (202). The method also includes the step of forming a conductive layer (212, 220) within in the trench or the via (206). The method further includes the steps of polishing a portion of the conductive layer (220) and annealing the conductive layer (212, 220) at a predetermined temperature. Moreover, the conductive layer (212, 220) also includes a dopant, and the dopant diffuses substantially to the surface of the top side of the conductive layer (212, 220) to form a dopant oxide layer (212a, 220a) when the conductive layer (212, 220) is annealed at the predetermined temperature and the dopant is exposed to oxygen.

Abstract: A method of forming an integrated circuit including an organosilicate low dielectric constant insulating layer (40) formed of a substitution group depleted silicon oxide, such as an organosilicate glass, is disclosed. Subsequent plasma processing has been observed to break bonds in such an insulating layer (40), resulting in molecules at the surface of the film with dangling bonds. Eventually, the damaged insulating layer (40) includes silanol molecules, which results in a degraded film. The disclosed method exposes the damaged insulating layer (40) to a thermally or plasma activated fluorine, hydrogen, or nitrogen, which reacts with the damaged molecules to form a passivated surface for the insulating layer (40).

Abstract: A surface treatment for porous silica to enhance adhesion of overlying layers. Treatments include surface group substitution, pore collapse, and gap filling layer (520) which invades open surface pores (514) of xerogel (510).

Abstract: A surface treatment for porous silica to enhance adhesion of overlying layers. Treatments include surface group substitution, pore collapse, and gap filling layer (520) which invades open surface pores (514) of xerogel (510).

Abstract: A xerogel aging system includes an aging chamber (190) with inlets and outlet and flows a gel catalyst in gas phase over a xerogel precursor film on a semiconductor wafer. Preferred embodiments use an ammonia and water vapor gas mixture catalyst.

Abstract: A method of forming an integrated circuit including an organosilicate low dielectric constant insulating layer (40) formed of a substitution group depleted silicon oxide, such as an organosilicate glass, is disclosed. Subsequent plasma processing has been observed to break bonds in such an insulating layer (40), resulting in molecules at the surface of the film with dangling bonds. Eventually, the damaged insulating layer (40) includes silanol molecules, which results in a degraded film. The disclosed method exposes the damaged insulating layer (40) to a thermally or plasma activated fluorine, hydrogen, or nitrogen, which reacts with the damaged molecules to form a passivated surface for the insulating layer (40).

Abstract: A method of forming an organosilicate low dielectric constant insulating layer (40) in an integrated circuit, and an integrated circuit structure having such a low-k insulating layer (40), are disclosed. In the case where the low-k dielectric material of the insulating layer (40) comprises an organosilicate glass, subsequent plasma processing has been observed to break bonds between silicon and organic moieties, either by replacing an organic group with a hydroxyl group or with hydrogen, or by leaving a dangling bond. Eventually, the damaged insulating layer (40) includes silanol molecules, which results in a degraded film. The disclosed method exposes the damaged insulating layer (40) to a silylation agent such as hexamethyldisilazane, which reacts with the damaged molecules, and forms molecules that restore the properties of the film.

Abstract: According to one embodiment of the invention, a method for forming multiple layers of a semiconductor device is provided. The method includes defining a via through a dielectric layer that overlies a first layer. The first layer comprises a conductive portion that at least partly underlies the via. The method also includes overfilling the via with a dielectric material to form a second layer that overlies the dielectric layer. The method also includes forming a trench that is connected to the via by etching through the second layer and the dielectric material in the via.

Abstract: A method of manufacturing a semiconductor device includes the steps of providing a semiconductor substrate (202), forming a dielectric layer (204) over the semiconductor substrate (202), and etching a trench or a via (206) in the dielectric layer (204) to expose a portion of the surface of the semiconductor substrate (202). The method also includes the step of forming a conductive layer (212, 220) within in the trench or the via (206). The method further includes the steps of polishing a portion of the conductive layer (220) and annealing the conductive layer (212, 220) at a predetermined temperature. Moreover, the conductive layer (212, 220) also includes a dopant, and the dopant diffuses substantially to the surface of the top side of the conductive layer (212, 220) to form a dopant oxide layer (212a, 220a) when the conductive layer (212, 220) is annealed at the predetermined temperature and the dopant is exposed to oxygen.

Abstract: Disclosed is a system for fabricating a semiconductor device (100). An interconnect structure (110) is formed on the semiconductor device (100) and a cap (112) is deposited over the interconnect structure (110). The interconnect structure (110) is annealed with the overlying cap (112) in place. The cap (112) is then removed after the interconnect structure (110) is annealed.

Abstract: A method of fabricating a copper interconnect using a sacrificial layer. A SiC layer (106) is formed over the dielectric layer (102). A sacrificial layer (108) is formed over the SiC layer (106). A trench (112) is etched in the sacrificial layer (108), the SiC layer (106) and the dielectric layer (102). A sputter etch of the sacrificial layer (108) is used to create a wider opening at a top of the sacrificial layer (108) than at a top of the dielectric layer (102). A barrier layer (114) and copper seed layer (116) are formed. The trench (112) is then filled with copper (124). CMP is used to remove the excess copper (124) and barrier layer (114) stopping on the SiC (106).

Abstract: A carbon hardmask (122) for etching hard-to-etch materials (110/112/114) such as Pt, Ir, Ru, IrO2, RuO2, BST, PZT, SBT, FeNi, and FeNiCo and other used in DRAMs, FeRAMs, and magnetic storage devices. Chemically assisted physical sputter etching using argon and limited or no oxygen may be used to etch the hard-to-etch materials (110/112/114) with high selectivity to the carbon hardmask (122).

Abstract: A method of fabricating a copper interconnect using a sacrificial layer. A SiC layer (106) is formed over the dielectric layer (102). A sacrificial layer (108) is formed over the SiC layer (106). A trench (112) is etched in the sacrificial layer (108), the SiC layer (106) and the dielectric layer (102). A sputter etch of the sacrificial layer (108) is used to create a wider opening at a top of the sacrificial layer (108) than at a top of the dielectric layer (102). A barrier layer (114) and copper seed layer (116) are formed. The trench (112) is then filled with copper (124). CMP is used to remove the excess copper (124) and barrier layer (114) stopping on the SiC (106).

Abstract: Deposition of titanium over fluoride-containing dielectrics requires the use of a method of passivation to prevent the formation of TiF4, which causes delamination of the metallization structure. Disclosed methods include the formation of layers of Al203, TiN, or Si3N4.

Abstract: An IC includes one or more gaps (18) substantially filled with silicon dioxide (30). The silicon dioxide (30) is deposited into the gaps (18) in response to the reaction of hexamethyldisiloxane (HMDSO) (26) with ozone (28) during a plasma-enhanced CVD (PECVD) process. The IC may be fabricated by inserting a substrate into a chamber. HMDSO (26) and ozone (28) are introduced into the chamber. The HMDSO (26) reacts with the ozone (28) to produce silicon dioxide (30), which is then deposited on the surface (10) of the substrate.

Abstract: A carbon hardmask (122) for etching hard-to-etch materials (110/112/114) such as Pt, Ir, Ru, IrO2, RuO2, BST, PZT, SBT, FeNi, and FeNiCo and other used in DRAMs, FeRAMs, and magnetic storage devices. Chemically assisted physical sputter etching using argon and limited or no oxygen may be used to etch the hard-to-etch materials (110/112/114) with high selectivity to the carbon hardmask (122).

Abstract: A surface treatment for porous silica to enhance adhesion of overlying layers. Treatments include surface group substitution, pore collapse, and gap filling layer (520) which invades open surface pores (514) of xerogel (510).