Abstract: A method and apparatus decrease the release of volatile radioactive iodine from a nuclear reactor pressure vessel containing a reactor core having fuel rods submerged in water. The method includes monitoring the pressure vessel to determine an accident condition and then injecting into the pressure vessel a stable iodide in liquid solution to mix with the reactor water for decreasing vaporization of volatile radioactive iodine discharged from the fuel rods. A reservoir initially stores the stable iodide in the liquid solution and is operatively joined to the pressure vessel through a supply conduit and a normally closed valve which is selectively opened following the accident condition to inject the stored iodide liquid solution into the pressure vessel to mix with the water therein.

Abstract: In a boiling water reactor nuclear plant, hydrogen is injected into the feed water to neutralize radiolysis which causes stress corrosion in stainless steel components. It has been discovered that by inhibiting volatile ammonia, and other gaseous nitrogen compounds from leaving the liquid phase portions of the plant to the steam phase portions of the plant, radiation is reduced to acceptable levels. Formation of ammonia is inhibited chemically, by altering the reaction paths for volatile nitrogen species with trace additives in the parts per billion range, suitable additives include nitrous oxide, copper, zinc, carbon dioxide, and other components. It has also been found that by manipulating the pH, the formation of the voltage nitrogen compounds, especially ammonia, is decreased. Similarly, by physically altering plant operating conditions to reduce sparging or scrubbing of the gases from areas of high radiation, confinement of the N-16 within the liquid phase of the plant within the reactor vessel occurs.