Patents by Inventor Etsuo Nakagawa

Etsuo Nakagawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7081279
    Abstract: Liquid crystalline compounds having a large negative ?? low viscosity, a large K33/K11 value, a small ??/?? and mutually excellent solubility even at low temperature, compositions containing at least one of the compounds and liquid crystal display devices containing such a liquid crystal compositions are disclosed.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: July 25, 2006
    Assignee: Chisso Corporation
    Inventors: Takashi Kato, Tomoyuki Kondo, Henry Bernhardt, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6864397
    Abstract: The present invention provides a process for producing a difluoromethyl ether derivative simple and efficient process for producing the difluoromethyl ether derivative represented by Formula (1d?) or a difluoromethyl ether derivative represented by Formula (1c?): wherein all the variables are defined in the specification.
    Type: Grant
    Filed: June 18, 2003
    Date of Patent: March 8, 2005
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Tomoyuki Kondo, Kouki Sagou, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Etsuo Nakagawa
  • Patent number: 6827876
    Abstract: A liquid crystalline compound represented by Formula (1c′): wherein R1 and R2, rings A1, A2, A3, A4 and A5, Z1, Z2, Z3 and Z4, Y1, Y2, Y3 and Y4, and k, l, m and n are as defined in the specification. Also provided is a liquid crystal composition containing at least one of these liquid crystalline compounds.
    Type: Grant
    Filed: June 18, 2003
    Date of Patent: December 7, 2004
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Tomoyuki Kondo, Kouki Sagou, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Etsuo Nakagawa
  • Publication number: 20040065866
    Abstract: There are provided a liquid crystalline compound having a large negative &Dgr;&egr;, low viscosity, a large K33/K11 value, a small &Dgr;&egr;/&egr;L and mutually excellent solubility even at extremely low temperature; a liquid crystal composition prepared from a liquid crystalline compound; and a liquid crystal display device fabricated from such a liquid crystal composition.
    Type: Application
    Filed: August 29, 2003
    Publication date: April 8, 2004
    Applicant: CHISSO CORPORATION
    Inventors: Takashi Kato, Tomoyuki Kondo, Henry Bernhardt, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6692657
    Abstract: Liquid crystalline compounds having a large negative &Dgr;∈ low viscosity, a large K33/K11 value, a small &Dgr;∈/&Dgr;⊥ and mutually excellent solubility even at low temperature, compositions containing at least one of the compounds and liquid crystal display devices containing such a liquid crystal compositions are disclosed.
    Type: Grant
    Filed: June 2, 1999
    Date of Patent: February 17, 2004
    Assignee: Chisso Corporation
    Inventors: Takashi Kato, Tomoyuki Kondo, Henry Bernhardt, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6685995
    Abstract: Liquid crystalline compounds suitable for driving at a low voltage and at a wide temperature range, and suitable for high speed response, liquid crystal compositions comprising the compound, and liquid crystal display devices comprising the liquid crystal composition. The crystalline compounds are ester compounds expressed by the general formula (1) wherein R1 represents e.g. a hydrogen atom; A1 to A5 each independently represent e.g. 1,4-cyclohexylene, 1,4-phenylene, 1-cyclohexene-1,4-diyl, 3-cyclohexene-1,4-diyl, 1-sila-1,4-cyclohexylene, or 4-sila-1,4-cyclohexylene; bonding groups Za to Zd each independently represent e.g. a single bond, —CH2—, —O—, —C≡C—, or an alkylene group or alkenylene group having 2 to 4 carbon; bonding group Ze represents e.g.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: February 3, 2004
    Assignee: Chisso Corporation
    Inventors: Yasuhiro Haseba, Shuichi Matsui, Hiroyuki Takeuchi, Yoshitaka Yagi, Fusayuki Takeshita, Etsuo Nakagawa
  • Publication number: 20040016906
    Abstract: The present invention provides a difluoromethyl ether derivative which shows various suitable physical properties as a liquid crystal compound, a liquid crystal composition comprising the compound and a liquid crystal display element containing the composition, and also provides a simple and efficient process for producing the difluoromethyl ether derivative.
    Type: Application
    Filed: June 18, 2003
    Publication date: January 29, 2004
    Inventors: Tomoyuki Kondo, Kouki Sagou, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Etsuo Nakagawa
  • Publication number: 20040004207
    Abstract: The present invention provides a difluoromethyl ether derivative which shows various suitable physical properties as a liquid crystal compound, a liquid crystal composition comprising the compound and a liquid crystal display element containing the composition, and also provides a simple and efficient process for producing the difluoromethyl ether derivative.
    Type: Application
    Filed: June 18, 2003
    Publication date: January 8, 2004
    Inventors: Tomoyuki Kondo, Kouki Sagou, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Etsuo Nakagawa
  • Patent number: 6649227
    Abstract: Provided are liquid crystalline compounds having a wide liquid crystal phase temperature range, low viscosity, a large elastic constant ratio K33/K11 and excellent solubility at low temperature, a liquid crystal composition using the same and a liquid crystal display.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: November 18, 2003
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Takashi Kato, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Etsuo Nakagawa
  • Patent number: 6605747
    Abstract: The present invention provides a difluoromethyl ether derivative which shows various suitable physical properties as a liquid crystal compound, a liquid crystal composition comprising the compound and a liquid crystal display element containing the composition, and also provides a simple and efficient process for producing the difluoromethyl ether derivative. According to the present invention, a process for producing a difluoromethyl ether derivative represented by Formula (1d): wherein the variables are defined in the specification, is characterized by using an &agr;&agr;-difluorocyclohexylidene derivative represented by Formula (1a): wherein R1, rings A1 and A2, Z1, Z2, k and l have the same meanings as defined in the specification, as a starting material.
    Type: Grant
    Filed: August 10, 2001
    Date of Patent: August 12, 2003
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Tomoyuki Kondo, Kouki Sagou, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Etsuo Nakagawa
  • Patent number: 6599590
    Abstract: The invention relates to a fluoro-substituted alkenyl compound represented by formula (1) wherein Y1, Y2, Y3 and Y4 are each independently H or F, provided that at least one of Y1 and Y2 is F; Q1 is a single bond or an alkylene group of 1-20 carbon atoms, at least one —CH2— being optionally substituted by —O—, provided that two or more —O— are not adjacent to each other; Q2 is a single bond or —C≡C—; Rings A1, A2 and A3 are each independently a cyclohexane ring, a dioxane ring, a cyclohexene ring, a pyrimidine ring, a pyridine ring, or a benzene ring, or a benzene ring having at least one hydrogen atom substituted by F; Z1, Z2 and Z3 are each independently a single bond, —CH2CH2—, —CH2O—, —OCH2—, —COO—, —OCO—, —CH═CH—, —C≡C—, —CF2O—, or —OCF2; and m and n are each independently 0 or 1; provided that Y3 is F when Ring A3 is a cy
    Type: Grant
    Filed: May 22, 2001
    Date of Patent: July 29, 2003
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Yasuhiro Haseba, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Etsuo Nakagawa
  • Patent number: 6596349
    Abstract: The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties with temperature change, high &Dgr;n, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices made using these liquid crystal compositions.
    Type: Grant
    Filed: April 18, 2001
    Date of Patent: July 22, 2003
    Assignee: Chisso Corp.
    Inventors: Tomoyuki Kondou, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Yasuhiro Kubo, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6579577
    Abstract: There is provided a liquid crystalline compound having a high voltage holding ratio which has a very small degree of temperature dependence, a low threshold voltage which has a very small degree of temperature dependence, a high &Dgr;n, and excellent miscibility with other liquid crystal materials at low temperature; a liquid crystal composition; and a liquid crystal display element, and the liquid crystalline compound is a substituted benzene derivative represented by general formula (1), where, R represents a straight chain or branched alkyl group having 1 to 20 carbon atoms in which each of optional and nonadjacent methylene groups (—CH2—) may be substituted by an oxygen atom; X represents a halogen atom, —CF3, —CF2H, —CFH2, —OCF3 or —OCF2H; each of Z1 and Z2 independently represents —(CH2)2—, —(CH2)4—, —CH2O—, —OCH2— or a covalent bond, but Z1 and Z2 are not covalent bonds simultaneously; each of Y1
    Type: Grant
    Filed: July 30, 2001
    Date of Patent: June 17, 2003
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Yasuhiro Kubo, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6576303
    Abstract: Novel liquid crystal compound having a negative and absolutely large value of dielectric anisotropy, being excellent in compatibility with other liquid crystalline compounds at a low temperature and being stable chemically and physically, as well as a liquid crystal composition comprising this compound, and a liquid crystal display device comprising this liquid crystal composition are provided, said compound is expressed by the general formula (1): R1—A1—B1—A2—B2—A3—B3—Z—B4—A4—R2  (1) wherein A1, A2, A3 and A4 represent a single bond, 1,4-cyclohexylene, 1,4-phenylene which may be substituted with a fluorine atom(s) or the like; B1, B2, B3 and B4 represent a single bond, 1,2-ethylene, 1,2-ethenylene, 1,2-ethynylene, oxymethylene, methyleneoxy or the like; R1 and R2 represent an alkyl group having 1 to 10 carbon atoms or the like; and Z represents (I) to (VI): wherein X represents H or F, and Y represents difluoromethyl gr
    Type: Grant
    Filed: August 24, 2000
    Date of Patent: June 10, 2003
    Assignee: Chisso Corporation
    Inventors: Norio Tamura, Atsuko Fujita, Hiroyuki Tekeuchi, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6572938
    Abstract: The present invention is to provide a liquid crystal composition which has particularly a high upper limit temperature of a nematic phase, a low lower limit temperature of the nematic phase and a small birefringence while satisfying general characteristics required for the liquid crystal composition for an AM-LCD. Liquid crystal compositions are disclosed which comprise a component I comprising at least one compound selected from the group of compounds represented by Formula (I-1) or (I-2) as described in the specification, a component II comprising at least one compound selected from the group of compounds represented by Formulas (II-1) to (II-8) as described in the specification and a component III comprising at least one compound selected from the group of compounds represented by Formulas (III-1) to (III-5) as described in the specification.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: June 3, 2003
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Motoki Yanai, Yasuhiro Kubo, Etsuo Nakagawa
  • Patent number: 6558758
    Abstract: The present invention provides a liquid crystal composition with the characteristics satisfying various properties required for AM-LCD and having a suitable value of &agr;n in compliance with a cell thickness, particularly a negative and absolutely large value of dielectric anisotropy, comprising, as a first component, at least one compound selected from the compounds expressed by the general formula (I), and, as a second component, at least one compound selected from the compounds expressed by the general formulas (II-1) and (II-2): wherein R1 to R6 represent C1 to C10 alkyl; Z1 to Z5 represent a single bond or —CH2CH2—; rings A1 and A2 represent a 1,4-phenylene group or a trans-1,4-cyclohexylene group, and A liquid crystal display element comprising the composition.
    Type: Grant
    Filed: October 6, 2000
    Date of Patent: May 6, 2003
    Assignee: Chisso Corporation
    Inventors: Motoki Yanai, Yasuhiro Kubo, Etsuo Nakagawa
  • Patent number: 6555185
    Abstract: The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties with temperature change, high &Dgr;n, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices made using these liquid crystal compositions.
    Type: Grant
    Filed: April 18, 2001
    Date of Patent: April 29, 2003
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondou, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Yasuhiro Kubo, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6548126
    Abstract: The invention is to provide liquid crystalline compounds having a negative and extremely large dielectric anisotropy value and a small optical anisotropy value at the same time; liquid crystal compositions comprising the compound; and liquid crystal display devices fabricated by using the liquid crystal composition; the liquid crystalline compounds have 2,3-dihalogenophenylene moiety and are expressed by formula (1) wherein Ra and Rb each independently represents a linear or branched alkyl having 1 to 10 carbon, any methylene in the alkyl may be replaced by —O—, —S—, —CH═CH—, or —C≡C—, but —O— is not successive, and any hydrogen in the alkyl may be replaced by halogen; rings A1 to A4 each independently represents trans-1,4-cyclohexylene, cyclohexene-1,4-diyl, pyridine-1,4-diyl, pyrimidine-2,5-diyl, or 1,4-phenylene, wherein at least one hydrogen in these rings may be replaced by halogen, and any nonadjacent methylene in c
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: April 15, 2003
    Assignee: Chisso Corporation
    Inventors: Yasuyuki Sasada, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Etsuo Nakagawa
  • Patent number: 6544604
    Abstract: The present invention provides a liquid crystalline compound having a difluoropropyleneoxy group as a bonding group, which is represented by Formula (1): wherein R1 and R2 each independently represent hydrogen, halogen, a cyano group or an alkyl group having 1 to 20 carbon atoms; rings A1 to A5 each independently represent a 1,4-cyclohexylene group, a 1,4-cyclohexenylene group or a 1,4-phenylene group; Z1 to Z4 each independently represent a single bond, —CH2CH2—, —CH2O—, —OCH2—, —COO—, —OCO—, —CH═CH—, —C≡C—, —CF2O— or —OCF2—; Y1, Y2, Y3 and Y4 each independently represent hydrogen or fluorine; and k, l, m and n each independently represent 0 or 1. This liquid crystalline compound has a large absolute value (|&Dgr;&egr;|) of a dielectric anisotropy and shows a relatively small refractive anisotropy.
    Type: Grant
    Filed: August 10, 2001
    Date of Patent: April 8, 2003
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Shuichi Matsui, Yasuyuki Sasada, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Katsuyuki Kawano, Yasuhiro Kubo, Etsuo Nakagawa, Mayumi Furuya
  • Patent number: 6500503
    Abstract: Liquid crystalline compounds are disclosed which have large dielectric anisotropy and relatively low viscosity, and which are represented by formula (1) wherein R1 represents hydrogen or C1-C15 alkyl in which one or more non-adjacent methylene may be replaced by oxygen, sulfur or —CH═CH— and one or more hydrogen may be replaced by halogen; R2 represents hydrogen, cyano, halogen or C1-C15 alkyl in which one or more non-adjacent methylene may be replaced by oxygen, sulfur or —CH═CH— and one or more hydrogen may be replaced by halogen; L represents halogen or hydrogen; A1, A2, A4 and A5 each independently represent trans-1,4-cyclohexylene or 1,4-phenylene, one or more —CH2— in the trans-1,4-cyclohexylene may be replaced by oxygen or sulfur, one or more ═CH— in the 1,4-phenylene may be replaced by nitrogen, and one or more hydrogen in the 1,4-phenylene ring may be replaced by halogen; A3represents trans-1,4-cyclohexylene in which one or mo
    Type: Grant
    Filed: April 26, 2001
    Date of Patent: December 31, 2002
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Koichi Shibata, Shuichi Matsui, Hiroyuki Tekeuchi, Katsuyuki Kawano, Yasuhiro Kubo, Etsuo Nakagawa