Patents by Inventor Etsuo Nakagawa

Etsuo Nakagawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6210761
    Abstract: The present invention is to provide liquid crystalline compounds which exhibit a negative dielectric anisotropy value, have an extremely high voltage holding ratio and a low threshold voltage, are remarkably small in their dependency on temperature, hardly exhibit smectic phase, and are excellent in miscibility with other liquid crystal materials; to provide liquid crystal compositions comprising the liquid crystalline compound; and to provide liquid crystal display devices fabricated by using the liquid crystal composition; the liquid crystalline compounds are expressed by the following general formula (1) wherein Ra, Rb, Y1 to Y6, Z1 and Z2 are herein defined.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: April 3, 2001
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6207076
    Abstract: There are herein disclosed a fluorovinyl derivative compound represented by the general formula (1) and having characteristics of a liquid crystal, a liquid crystal composition, and a liquid crystal display device formed by using this composition: wherein R1 is an alkyl group having 1 to 18 carbon atoms, and a methylene group in the alkyl group may be substituted by an oxygen atom, a sulfur atom, —CH═CH— or —C≡C— and a hydrogen atom in the alkyl group may be substituted a halogen atom or a cyano group; rings A, B and C are each 1,4-cyclohexylene, 1,4-phenylene or the like in which a hydrogen atom in the ring may be substituted by a halogen atom; Z1, Z2 and Z3 are each a single bond, —CH2CH2—, —CH═CH—, —C≡C—, —CH2O—, —OCH2—, —(CH2)4—, —(CH2)3—O—, —O—(CH2)3—, —(CH2)2—CH═CH—, —CH═CH—(CH2)2—, &mdash
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: March 27, 2001
    Assignee: Chisso Corporation
    Inventors: Kouji Koga, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Shuichi Matsui, Norihisa Hachiya, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6207075
    Abstract: A liquid crystal composition which has a superior voltage transmittance (sharpness) for good color and high-speed response characteristics. The composition contains at least one of the following first component (I-a, I-b), second component (II-a to II-d) and third component (III-a to III-c) respectively: wherein R1, R2, Z0, Z1, Q1, A1, A3, p, q, m and n are defined in the specification.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: March 27, 2001
    Assignee: Chisso Corporation
    Inventors: Toshihiko Muraoka, Katsuyuki Murashiro, Fusayuki Takeshita, Tetsuya Matsushita, Etsuo Nakagawa
  • Patent number: 6197217
    Abstract: Liquid crystalline compounds which exhibit a negative dielectric anisotropy value, have an extremely high voltage holding ratio and a low threshold voltage, are small in their dependency on temperature, hardly exhibit smectic phase, and are excellent in miscibility with other liquid crystal materials at the same time; liquid crystal compositions comprising the compound; and liquid crystal display devices fabricated by using the liquid crystal composition are provided; the liquid crystalline compounds being specific 3,3′-difluorobiphenyl derivatives expressed by the following general formula (1):
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: March 6, 2001
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6190576
    Abstract: The invention is to provide liquid crystalline compounds which have a low viscosity, high negative dielectric anisotropy, high resistivity, and high voltage holding ratio, and are stable against heat and ultraviolet light; to provide liquid crystal compositions comprising the liquid crystalline compound; and to provide liquid crystal display devices using the liquid crystal composition therein; the liquid crystalline compound is expressed by the general formula (1) wherein R1 and Y1 represent an alkyl group having 1 to 20 carbon atoms; X1, X2, and X3 independently represent single bond, 1,2-ethylene group, vinylene group, —COO—, —CF2O—, or —OCF2—; ring A1, ring A2, ring A3, and ring A4 independently represent trans-1,4-cyclohexylene, or 1,4-phenylene hydrogen atom on the ring may be replaced by fluorine atom or chlorine atom provided that at least one of ring A2, ring A3, and ring A4 represents 2,3-difluoro-1,4-phenylene; m and n are 0 or 1, and each elem
    Type: Grant
    Filed: September 30, 1998
    Date of Patent: February 20, 2001
    Assignee: Chisso Corporation
    Inventors: Tugumiti Andou, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Yasuyuki Koizumi, Yasuko Sekiguchi, Etsuo Nakagawa, Fusayuki Takeshita
  • Patent number: 6187223
    Abstract: A compound expressed by the general formula (1): wherein R1 denotes an alkyl group having from 1 to 20 carbon atoms in which one or more methylene groups in said group may be replaced by oxygen atoms or —CH═CH— and one or more hydrogen atoms in said group may be replaced by flourine or chlorine atoms, with the proviso that two or more methylene groups may not be continuously replaced by oxygen atoms, Y1 denotes an alkoxy group having 1 to 5 carbon atoms, in which at least one hydrogen atom is replaced by a fluorine atom and one or more hydrogen atoms may be further replaced by chlorine atoms, Z1, Z2 and Z3 each independently denote a covalent bond, —CH2CH2—, —CH═CH—, —COO— or —CF2)—, with the proviso that at least one of Z1, Z2 and Z3 is —COO— or —CF2O—, rings A1, A2, A3 and A4 each independently denote trans-1,4-cyclohexylene, 3-cyclohexen-1,4-ylene, 3-fluoro-3-cyclohexen-1,4-ylene, pyrimidine-2
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: February 13, 2001
    Assignee: Chisso Corporation
    Inventors: Tugumiti Andou, Koichi Shibata, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Yasusuke Hisatsune, Fusayuki Takeshita, Etsuo Nakagawa, Katsuhiko Kobayashi, Yoshitaka Tomi
  • Patent number: 6180027
    Abstract: Liquid crystalline compounds expressed by the following formula (1), liquid crystal compositions thereof obtained by combination with specified liquid crystal compounds, and liquid crystal display devices using them, wherein, A1, A2, A3 and A4 denote each independently trans-1,4-cyclohexylene group etc.; Z1, Z2 and Z3 denote each independently —(CH2)2— etc.; Q1 and Q2 denote each independently H, F, Cl or Br; Q3 and Q4 denote each independently F, Cl or Br; 1, m and n denote each independently an integer of from 0 to 5; and p and q denote each independently an integer of 0 or 1.
    Type: Grant
    Filed: July 22, 1998
    Date of Patent: January 30, 2001
    Assignee: Chisso Corporation
    Inventors: Takashi Kato, Shuichi Matsui, Kazutoshi Miyazawa, Yasuko Sekiguchi, Etsuo Nakagawa
  • Patent number: 6177154
    Abstract: Disclosed are (a) liquid crystalline compounds which are essential as component of the liquid crystal compositions, are excellent in miscibility with other liquid crystal compositions, particularly in the miscibility at low temperatures, and expressed by the general formula (1) wherein R0 and R1 independently represent an alkyl group having 1 to 10 carbon atoms; ring A0, ring A1, ring A2, and ring A3 represent 1,4-cyclohexylene group, 1,3-dioxane-2,5-diyl group, 1,4-phenylene group in which one or more hydrogen atoms on the ring may be represented by a halogen atom or R2O group, pyridine-2,5-diyl group, or pyrimidine-2,5-diyl group; Z0, Z1, Z2, and Z3 represent —CH2CH2—, —CH═CH—, —C≡C—, —CH2O—, —OCH2—, —CF2O—, —OCF2—, —COO—, —OCO—, —(CH2)4—, or single bond; Q1 and Q2 represent hydrogen atom or a halogen atom; Q3 represents hydrogen atom, a halogen atom, or R2O g
    Type: Grant
    Filed: March 16, 1999
    Date of Patent: January 23, 2001
    Assignee: Chisso Corporation
    Inventors: Shuichi Matsui, Tugumiti Andou, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Yasusuke Hisatsune, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6174459
    Abstract: A difluorophenyl derivative compound having characteristics of a liquid crystal represented by the following general formula (1), a liquid crystal composition and a liquid crystal display device in which the composition is used: wherein R0 is an alkyl group or an alkenyl group having 1 to 15 carbon atoms, and an optional methylene group in the alkyl group or the alkenyl group may be substituted by an oxygen atom; A1 and A2 are each a trans-1,4-cyclohexylene group, or one group selected from the group consisting of a 1,4-phenylene group, a pyrimidine-2,5-diyl group, a pyridine-2,5-diyl group, a 1,3-dioxane-2,5-diyl group, a tetrahydropyran-2,5-diyl group, a 1,3-dithian-2,5-diyl group and a tetrahydrothiopyran-2,5-diyl in which one or more hydrogen atoms on a six-membered ring may be substituted by halogen atoms; Z1 and Z2 are each —(CH2)4—, —(CH2)3O—, —O(CH2)3— or a single bond; and X1 and X2 are each H, F, Cl or Br.
    Type: Grant
    Filed: February 4, 1999
    Date of Patent: January 16, 2001
    Assignee: Chisso Corporation
    Inventors: Takashi Kato, Shuichi Matsui, Kazutoshi Miyazawa, Yasusuke Hisatsune, Etsuo Nakagawa
  • Patent number: 6174458
    Abstract: A tetracyclic compound expressed by the following general formula (1) wherein H1 to H12 represent hydrogen atom at least one of which is replaced by a halogen atom, when either H6 or H8 is replaced by a halogen atom, at least one of the remaining hydrogen atoms is replaced by a halogen atom; R1 and Y1 independently represent an alkyl group, alkoxy group, or alkoxyalkyl group having 1 to 20 carbon atoms, or an alkenyl group having 2 to 20 carbon atoms, one or more methylene group in R1 and Y1 may be replaced by oxygen atom, sulfur atom, dihydrosilylene group, dimethylsilylene group, —CH═CH—, or —C≡C—; and X1, X2, and X3 independently represent a covalent bond, 1,2-ethylene group, or 1,4-butylene group; and a novel liquid crystal composition comprising the tetracyclic compound and having, at the same time, a wide temperature range of a nematic phase, high optical anisotropy, and high chemical stability.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: January 16, 2001
    Assignee: Chisso Corporation
    Inventors: Koji Koga, Tsugumichi Ando, Hiroyuki Takeuchi, Shuichi Matsui, Kazutoshi Miyazawa, Norihisa Hachiya, Etsuo Nakagawa
  • Patent number: 6174456
    Abstract: The present invention provides liquid crystalline compounds having compatibility with the other liquid crystal materials and excellent stability, and having low viscosity and high transition temperature of the isotropic phase, liquid crystal compositions containing at least one kind of the liquid crystalline compounds, and liquid crystal display devices constituted by using the liquid crystal compositions. The liquid crystalline compounds are represented by the following formula: R—A1—Z1—A2—Z2—A3—Z3—A4—(CH2)m.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: January 16, 2001
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Kouichi Shibata, Shuichi Matsui, Kazutoshi Miyazawa, Norihisa Hachiya, Etsuo Nakagawa
  • Patent number: 6168839
    Abstract: Novel liquid crystalline compounds which have a wide temperature range of liquid crystal phase, are excellent in miscibility with other liquid crystalline compounds, have a low viscosity, are low in toxicity, and are safe; liquid crystal compositions comprising the liquid crystalline compound; and liquid crystal display devices fabricated by using the composition are provided; and the compounds are cyclohexane derivatives expressed by the general formula (1) wherein R represents an alkylene chain having 2 to 10 carbon atoms in which alkylene chain ethylene group (—CH2CH2—) may be replaced by ethenylene group (—CH═CH—) or methylenoxy group (—OCH2—); and M represents COOH or CN group.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: January 2, 2001
    Assignee: Chisso Corporation
    Inventors: Atsuko Fujita, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6168728
    Abstract: The present invention provides new liquid crystalline compounds having a high optical anisotropy value and excellent compatibility with the other liquid crystals, and liquid crystal composition comprising the compounds. The liquid crystalline compounds are represented by the general formula (1): wherein H1, H2, H3, H4, H5, H6, H7, H8, H9, H10, H11 and H12, each independently, represent H, F or Cl, at least one of H1, H2, H3, H4, H9, H10, H11 and H12 is F or Cl, R1 represents an alkyl group of C1-20, in which methylene groups may be replaced by —O—, —S—, —Si—, —CH═CH— or —C≡C—, any hydrogen atoms may be replaced by a halogen atom, and Y1 is replaced by R1, F, Cl, Br, I or a cyano group.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: January 2, 2001
    Assignee: Chisso Corporation
    Inventors: Kazutoshi Miyazawa, Kouji Koga, Shuichi Matsui, Norihisa Hachiya, Etsuo Nakagawa
  • Patent number: 6162372
    Abstract: A liquid crystal composition is disclosed which comprises three components. The first component comprises at least one of the compounds of the following formulas (1-1) and (1-2). The second component comprises at least one of the compounds of the following formula (2). The third component comprises at least one of the compounds of the following formulas (3-1) to (3-4). ##STR1## Each symbol in formulas (1-1) to (3-4) is defined in the specification. The liquid crystal composition has low threshold voltage and high stability to hear and ultraviolet rays while satisfying general characteristics required for the STN display mode.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: December 19, 2000
    Assignee: Chisso Corporation
    Inventors: Yoshitaka Tomi, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6149990
    Abstract: A compound represented by the following general formula (I), a liquid crystal composition comprising the same, and a liquid crystal element using this liquid crystal composition. ##STR1## (wherein B.sub.1 and B.sub.2 represent independently a trans-1,4-cyclohexylene group or a 1,4-phenylene group wherein at least one hydrogen atom on the six-membered ring is optionally substituted by a halogen atom, Y represents a halogen-substituted alkyl group having 1 to 3 carbon atoms, a halogen-substituted alkoxy group having 1 to 3 carbon atoms, a cyano group, a fluorine atom or a chlorine atom, X represents a fluorine atom, a chlorine atom or a hydrogen atom, R.sub.1 represents an alkyl group having 1 to 10 carbon atoms or an alkoxy group having 1 to 10 carbon atoms, n and m represent independently 1 or 2 and p represents 0 or 1.
    Type: Grant
    Filed: August 4, 1998
    Date of Patent: November 21, 2000
    Assignee: Chisso Corporation
    Inventors: Yoshiji Egami, Masatoshi Fukushima, Yasuko Sekiguchi, Makoto Tanimoto, Etsuo Nakagawa
  • Patent number: 6149838
    Abstract: Liquid crystalline compounds having a wide temperature range of liquid crystal phase, a high dielectric anisotropy, and a high optical anisotropy; and liquid crystal compositions and display devices containing the composition. The liquid crystalline compounds are conjugated nitrile derivatives expressed by the formula (1) ##STR1## wherein R represents an alkyl group or a fluoroalkyl group each having 1 to 10 carbon atoms, halogen atom, or cyano group provided that in the alkyl or fluoroalkyl group, one or not-adjacent two or more methylene or fluoromethylene groups may be replaced by oxygen atom or 1,2-ethenylene group; A.sub.1, A.sub.2, A.sub.3 and A.sub.4 represent 1,4-cyclohexylene group, 1,4-phenylene in which one or two hydrogen atoms on the ring may be replaced by fluorine atom, 1,3-dioxane-2,5-diyl, or pyrimidine-2,5-diyl; B.sub.1, B.sub.2, and B.sub.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: November 21, 2000
    Assignee: Chisso Corporation
    Inventors: Atsuko Fujita, Norio Tamura, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Yasuhiro Kubo, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6143198
    Abstract: A liquid crystalline compound represented by the general formula (1) ##STR1## wherein R.sub.1 represents an alkyl or alkoxy group having 1 to 10 carbon atoms, a cyano group, a halogen atom, or an alkyl or alkoxy halide group having 1 to 4 carbon atoms; R.sub.2 represents an alkyl group having 1 to 10 carbon atoms; rings A.sub.1, A.sub.2, A.sub.3, and A.sub.4 each independently represent a 1,4-phenylene or 1,4-cyclohexylene group; Z.sub.1, Z.sub.2, and Z.sub.3 each independently represent a covalint bond, --CH.sub.2 CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C-- or --COO--; 1 and m are 0 pr 1; and n is 0 to 10.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: November 7, 2000
    Assignee: Chisso Corporation
    Inventors: Kazutoshi Miyazawa, Shuichi Matsui, Yasuko Sekiguchi, Etsuo Nakagawa
  • Patent number: 6124005
    Abstract: Liquid crystalline compounds which have excellent compatibility with other liquid crystal materials, especially at low temperatures, high voltage holding ratio, low threshold voltage, their small temperature dependency, high .DELTA.n, and broad liquid phase temperature range, the compounds being represented by formula (1)Ra--A.sub.1 --Z.sub.1 --A.sub.2 --Z.sub.2 --(--A.sub.3 --Z.sub.3 --).sub.m --A.sub.0 --Rf (1)(wherein m is 0 or 1; A.sub.0, A.sub.1, A.sub.2 and A.sub.3 represent a six-membered ring, ring A.sub.0 is 1,4-phenylene which may be substituted with 1 to 3 of F and/or Cl, rings A.sub.1, A.sub.2 and A.sub.3, independently of one another, are selected from trans-1,4-cyclohexylene, 1,4-phenylene which may be substituted with one or more halogen atoms, cyclohexene-1,4-diyl or 1,3-dioxane-2,5-diyl; Z.sub.1, Z.sub.2 and Z.sub.3 represent a bridge between the rings and independently of one another, are selected from --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.4 --, --CH.sub.2 O--, --OCH.sub.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: September 26, 2000
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6117360
    Abstract: Liquid crystal compositions which have excellent miscibility at low temperatures, a properly large optical anisotropy, and a small threshold voltage while satisfying various characteristics required of liquid crystal compositions for active matrix mode liquid crystal display devices. The compositions contain, as a first component, at least one compound expressed by any one of formulas ##STR1## and as a second component, at least one compound expressed by any one of formulas ##STR2## wherein R represents a straight chain alkyl group having 1 to 10 carbon atoms, X represents CF.sub.3 or OCF.sub.3, X.sup.2 represents fluorine or OCF.sub.3, each Y represents, independently of each other, a hydrogen or fluorine atom, and m is 1 or 2.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: September 12, 2000
    Assignee: Chisso Corporation
    Inventors: Kazutoshi Miyazawa, Shuichi Matsui, Tomoyuki Kondo, Takashi Kato, Yasuko Sekiguchi, Etsuo Nakagawa
  • Patent number: 6117361
    Abstract: A compound represented by the following general formula (1) is provided. This has broader temperature range of nematic phase, lower viscosity and higher miscibility with other liquid crystal compounds at low temperature than those of conventional liquid crystal compounds, and the compounds have high chemical stability. ##STR1## wherein H.sub.1 to H.sub.8 represent independently a hydrogen atom or a halogen atom, provided that at least one of them is a halogen atom; R.sub.1 represents a moiety which is an alkyl group having 2 to 20 carbon atoms provided that one or more methylene groups (--CH.sub.2 --) which are not successive in the alkyl group are replaced with an oxygen atom (--O--) in the form of ether; Y.sub.1 represents an alkyl group having 1 to 20 carbon atoms, and one or more methylene groups in Y.sub.1 independently may be replaced with an oxygen atom, a sulfur atom, a dihydroxysilyl group, a dimethylsililene group, --CH.dbd.CH-- or --C.tbd.C--; X.sub.1 to X.sub.
    Type: Grant
    Filed: August 31, 1998
    Date of Patent: September 12, 2000
    Assignee: Chisso Corp.
    Inventors: Koichi Shibata, Tomoyuki Kondo, Shuichi Matsui, Kazutoshi Miyazawa, Norihisa Hachiya, Etsuo Nakagawa