Abstract: The present invention is directed to a process for the strengthening of geological formations in underground workings and mines by the introduction of reaction mixtures which react to form polyurethanes into the formations which are to be strengthened, the reaction mixtures being based on(a) a polyisocyanate component,(b) a polyol component and(c) an ester,the ester having a hydroxyl number of about 10 to 630 and an acid number of at most 10 and obtained from (i) an acid component having a carboxyl functionality of at least 1.5 and containing a polymerized fatty acid having at least 12 carbon atoms or mixtures thereof with unpolymerized saturated or unsaturated fatty acids having at least 12 carbon atoms and (ii) a polyol component containing at least one polyhydric alcohol, the ester being present in a positive amount of up to 5% by weight, based on the weight of component (b).

Abstract: The present invention is directed to a process for strengthening geological formations in underground mining or other operations introducing into the formation which is to be strengthened mixtures of a polyisocyanate component (a) and a polyol component (b) which react together to form polyurethanes, characterized in that the polyol component (b) is based on mixtures of (i) organic polyhydroxyl compounds having hydroxyl numbers of about 100 to 600 and (ii) dihydric alcohols having a molecular weight of 62 to about 150, component (ii) being present in an amount of about 0.01 to 20% by weight, based on the total quantity of component (b).

Abstract: The present invention is directed to a process for strengthening and sealing geological formations which are moist or contain water, in particular loose stone, by the injection of a mixture which reacts to form polyurethane, characterized in that a polyisocyanate component is injected before injection of the reaction mixture.

Abstract: An improved contamination control boom having walls defining an elongated hollow flotation chamber. Apertures may be provided in the walls of the flotation chamber to allow material from the body of liquid on which the boom is utilized, which may be the liquid, the contaminant, or a mixture thereof. Pump means may be incorporated to remove the material from the flotation chamber. A float means is positioned inside the flotation chamber to provide a desired freeboard for the condition of liquid in the flotation chamber. Special materials may be utilized to fabricate the boom for high temperature resistant applications where the contaminent is burning, but the boom must continue to operate as a boom during the burning.

Abstract: An apparatus for lashing goods, such as boards, bars, sheets, and the like. The apparatus includes portable supports for the goods which are to be lashed. The supports are provided with connections for lashing chains, ropes, or the like. The support has stops, counter-stops disposed at right angles to its longitudinal direction, and stacking surfaces. The supports can be stacked for transport in such a way that they cannot slip with respect to one another, and they can be placed reliably one on top of the other.

Abstract: Method for bonding of anchoring bolts in boreholes, in which an anchoring bolt is pushed with a rotary motion into a twin-chamber cartridge, one compartment of which is filled with a polyisocyanate component and the other one with a hydroxyl component, prepolymer from the conversion of polyisocyanates with one or several difunctional polyols of the molecular weight range 800-5000, preferably 1600-3000, being used as polyisocyanate component.

Abstract: A procedure of bonding roofbolt rods to boltholes whereby the roofbolt rod is pushed under rotating movements into a bolthole filled with an adhesive mass consisting of a mix by whose reaction is obtained polyurethane, characterized in that a mass consisting of polyisocyanate-prepolymerides is used which has been prepared from polyisocynates and one or more bifunctional polyols in a molecular weight range between 800 and 5,000, preferably between 1,200 and 3,000, and which reacts in the borehole with 1 to 25% by weight (related to the mass) of water and/or polyols serving as the hydroxyl component.

Abstract: For consolidation of geological formations and artificial beds of rock, earth, and coal by means of foaming and hardening polyisocyanate/polyol blends, diols with secondary hydroxyl functions of the OH number range 150-1000 are used as diol component. Preferably a crude polyisocyanate blend (MDI) obtained by phosgenation of aniline/formaldehyde condensates which at ambient temperature assumes a liquid state, and the liquid prepolymers of said crude MDI are used as isocyanate components.

Abstract: Processes for sealing and strengthening water-bearing geological formations by injection thereinto a polyurethane-resin-forming composition that is especially suitable for this purpose which comprises a conventional polyisocyanate, a conventional polyol, an accelerator for the reaction between the polyisocyanate and the polyol, and a foam stabilizer.

Abstract: A borehole closure, especially for injection of plastic material or cement into a borehole formed into rock for solidifying the latter and comprising a tube, a one-way valve connected to the leading end of said tube, a holding element including a spreading cone cooperating with a spreadable shell surrounding the tube in the region of its leading end, which in turn is followed by an axially compressible and radially expandable sealing element in form of a rubber sleeve surrounding the tube. In order to place the lost borehole closure at any desired distance from the outer end of the borehole, a plurality of tube sections and connecting bushings are provided for connecting the tube sections with different restraining forces to each other and to the trailing end of the tube, with one of the tube sections extending beyond the outer end of the borehole.

Abstract: A method of and an adhesive cartridge for securing an anchor or the like in a bore hole or the like. The cartridge comprises an outer tube and an inner tube within this outer tube. Between the inner and outer tube is a mass of synthetic-resin material and filler. The inner tube is filled with a hardener capable of reacting with the synthetic-resin to form a mass capable of holding the rock anchor or the like in the borehole. At least the outer tube is made of an elastomeric polymer with which is mixed a filler that renders the outer tube completely opaque. The inner tube may also be extruded simultaneously with the outer tube of the same synthetic-resin material. It is also possible otherwise to partition the interiors of the outer tube, or to provide the one component in the outer tube directly in contact with the other component but unmixed therewith.

Abstract: Waterglass solutions are mixed with polyisocyanates and these emulsions are then left to harden in the formations. Introduction of the mixture into the formations which are required to be consolidated, e.g. deposits of coal, is mainly carried out by forcing the mixture under pressure into bore-holes in the formations. According to one variation of the process, the components of the mixture are introduced into the multi-chamber cartridges which are introduced into the bore-holes and then destroyed as the components are mixed. Certain additives such as accelerators, blowing agents, polyols, stabilizers and/or thixotropic agents are advantageous for the quality of the composite masses formed by hardening of the mixture.

Abstract: An improved containment barrier or boom having a flotation means and a skirt section dependent therefrom. The boom may be wound around a reel for storage, and deployed from the reel as required. The flotation means comprises a flexible, longitudinally elongated tubular member, having a cavity extending throughout the elongated length thereof. A resilient, generally spring-like member having helical coil means is provided in the tubular member. The spring-like member extends substantially longitudinally throughout the length of the tubular member, and the helical coil means maintain the walls of the tubular member in a transversely expanded condition when the tubular member is deployed in the body of water. The spring-like member is resiliently deformable from the helical condition to a transversely flattened condition, when the tubular member is wound upon the reel for storage.

Abstract: A control system for actuators which can be separately energized. The controller of the system has a two-position control unit and a three-position control unit and is followed by constant current source circuits, a stepping switch unit with threshold switches having a stepped reference voltage, as well as a logic circuitry interconnecting the stepping switch unit and the two-position control output. Prevention of overshoot or undershoot is achieved by means of additional logic circuitry interconnecting the switches at the positive and negative output of said three-position control unit, said two-position control output, and said first mentioned logic circuitry between the stepping switch unit and two-position control output. In this manner overshoot can be prevented by quickly de-energizing the actuator, which was last energized, when the actual value in the controlled system closely approaches the set-point or reference value.

Abstract: The present invention relates to a two-compartment cartridge which is suitable for securing stay bars in bore holes by means of polyurethane resins and which is destructible by the stay bar, containing a polyisocyanate component on the one hand and a polyol component on the other hand, distinguished by the fact that the polyisocyanate component used is an aromatic polyisocyanate or a mixture of aromatic polyisocyanates, while the polyol component used is a polyol containing tertiary amine nitrogen and having a molecular weight of from about 119 to 3000 or a polyol mixture containing at least one such polyol.

Abstract: This invention concerns a method of consolidating geological formations, heaped rock and earth masses by applying a polyurethane reaction system to the material to be consolidated. The reaction system comprises a polyisocyanate component and a polyol component wherein the polyol component contains about 5 to 50 wt.% of a special polyether with an OH number under about 100. This polyether is produced by the reaction of a compound having more than one reactive hydrogen atom per molecule and a molecular excess of a 1,2-alkylene oxide. The reaction system can also contain conventional polyurethane additives such as foaming agents, fillers, foam stabilizers and catalysts. In a preferred embodiment, the special polyether is produced from ethylene diamine or triethanol amine.

Abstract: An improved containment barrier or boom section of the type having a flotation means for supporting the barrier or boom on the surface of a liquid body such as a lake, harbor, river, ocean, or the like, and also having a sinking means such as a flexible skirt section coupled to the bottom of the flotation means and extending below the surface, the skirt section containing ballast and, preferably, a tension member, to contain contamination or material floating on or near the surface, such as an oil spill, usually on one side thereof. End connectors are provided at each end of the barrier section for coupling to additional barrier or boom sections and/or to a towing means for deployment and/or recovery. The flotation means comprises an elongated tubular member having a cavity extending throughout the elongated length thereof and the tubular member is flexible.

Abstract: An arrangement for detecting the presence of contaminants, such as an oil spill, in a body of water. At a predetermined location in the body of water there is provided at least one detector station means having thereon at least one contaminant detector element. The contaminant detector element has a characteristic that changes for the condition of the presence of a contaminant impinging thereon. For example, the characteristic may be a dimension thereof. Sensing means are provided to detect changes in the characteristic and to generate an information signal responsive to such changes in the characteristic. A transmitter means is provided for transmitting a transmission signal responsive to the information signal when there has been a change in the characteristic. The transmission signal is transmitted to regions remote the detector station means.

Abstract: An object extends into a passage and defines a clearance space with the inner wall of the passage. A hardenable, foamable synthetic resin in flowable state is admitted into the clearance space. Upon hardening and foaming of the synthetic resin, the object is sealingly secured in the passage by the synthetic resin. In a preferred application, the passage is one provided in a coal mine and the object is a hose line for the purpose of suppressing dust. The synthetic resin is advantageously polyurethane including a polyhydroxyl component which contains a polyetherglycol having a hydroxyl number of 300 to 350 and a polyetherglycol having a hydroxyl number of 450 to 500. The polyetherglycol components respectively constitute 80 to 90 parts and 10 to 20 parts of the polyhydroxyl component. The polyhydroxyl component preferably includes a filler in an amount such that the weight of the latter at least equals that of the polyhydroxyl component.

Abstract: Waterglass solutions are mixed with polyisocyanates and these emulsions are then left to harden in the formations. Introduction of the mixture into the formations which are required to be consolidated, e.g. deposits of coal, is mainly carried out by forcing the mixture under pressure into bore-holes in the formations. According to one variation of the process, the components of the mixture are introduced into the multi-chamber cartridges which are introduced into the bore-holes and then destroyed as the components are mixed. Certain additives such as accelerators, blowing agents, polyols, stabilizers and/or thixotropic agents are advantageous for the quality of the composite masses formed by hardening of the mixture.