Patents by Inventor Graylon K. Williams
Graylon K. Williams has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9162933Abstract: An auto ignition composition is provided that contains a sugar and/or carboxylic acid such as DL-tartaric acid as a first fuel; a binder; and an alkali or alkaline earth metal chlorate such as potassium chlorate as a first oxidizer. Alkali metal perchlorates such as potassium perchlorate may also be included as a second oxidizer. The composition(s) is typically contained within a gas generating system such as an airbag inflator or seat belt assembly, or more broadly within a vehicle occupant protection system. The compositions may also be applied to the insides of military armament.Type: GrantFiled: February 5, 2010Date of Patent: October 20, 2015Assignee: TK Holding Inc.Inventors: Deborah L. Hordos, Sean P. Burns, Graylon K. Williams, Larry A. Moquin, Paresh S. Khandhadia
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Patent number: 9045380Abstract: A novel composition containing a bi-tetrazole having a primary tetrazole ring substituted or connected to a second tetrazole ring by an aliphatic bridge such as an ethyl or ethylene bridge. The composition may be contained within a gas generator as a gas generating composition when combined with an oxidizer such as phase stabilized ammonium nitrate. The gas generator may be contained within a gas generating system such as an airbag inflator or seat belt assembly, or more broadly within a vehicle occupant protection system.Type: GrantFiled: October 31, 2008Date of Patent: June 2, 2015Assignee: TK Holdings Inc.Inventors: Sudhakar R. Ganta, Graylon K. Williams
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Patent number: 8657974Abstract: A gas generator 10 includes an auto-ignition/booster composition 212 that contains a metal chlorate such as potassium chlorate as an oxidizer, a carboxylic acid such as DL-tartaric acid as a primary fuel, a secondary oxidizer such as strontium nitrate, and if desired, a secondary fuel such as 5-aminotetrazole. The auto-ignition/booster composition 212 and a separate provision of ammonium nitrate or phase stabilized ammonium nitrate 228 are provided within a single combustion/decomposition chamber 222 for the production of gas, upon actuation of the gas generator 10. Vehicle occupant protection systems 180, containing the gas generator 10, are also provided.Type: GrantFiled: August 31, 2010Date of Patent: February 25, 2014Assignee: TK Holdings, Inc.Inventors: Brian A. Mayville, Deborah L. Hordos, Graylon K. Williams
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Publication number: 20130153098Abstract: A fuel component for an airbag inflator, dinitrosalyicylic acid and derivatives thereof, is used as a primary fuel in a gas generating composition 12. A novel gas generating composition 12, containing the primary fuel, and phase stabilized ammonium nitrate is also provided. The fuel component may be contained within a gas generant composition 12, within a gas generator 10. The gas generator 10 may be contained within a gas generating system 200 such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.Type: ApplicationFiled: March 28, 2011Publication date: June 20, 2013Inventors: Sudhakar R. Ganta, Graylon K. Williams
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Publication number: 20130068354Abstract: A method of forming a gas generating composition containing a salt of dinitrosalicylic acid and ammonium nitrate or phase stabilized ammonium nitrate. The method involves the co-precipitation of a salt of 3,5-dinitrosalicylic acid with phase stabilized ammonium nitrate. A gas generating composition 12 is also presented along with a gas generator 10 containing the gas generating composition 12. The gas generator 10 may be contained within a gas generating system 200 such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.Type: ApplicationFiled: March 28, 2011Publication date: March 21, 2013Inventors: Slaven Domazet, Deborah L. Hordos, Sudhakar R. Ganta, Graylon K. Williams
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Patent number: 8273199Abstract: The present invention generally relates to auto-ignition/booster compositions for inflators of occupant restraint systems, for example. An auto-ignition/booster and/or gas generant composition in accordance with the present invention includes an aromatic acid selected from tetrazoles, carboxylic acid/benzene-based fuels, nitrotriazoles, aminonitrotriazoles, aminotriazoles, bistetrazolylamines, bitetrazoles, and mixtures thereof; an alkali metal nitrate selected from potassium nitrate and sodium nitrate, and mixtures thereof; a basic constituent; and a catalytic non-oxidizing molybdenum-containing additive. A gas generator and a gas generating system including compositions of the present invention are also contemplated.Type: GrantFiled: April 7, 2009Date of Patent: September 25, 2012Assignee: TK Holdings, Inc.Inventors: Deborah L. Hordos, Sudhakar R. Ganta, Graylon K. Williams, Sean P. Burns
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Patent number: 8088235Abstract: A novel compound, used for example, as a gas generating fuel, is defined as a compound having the structural formula of R3—R1—R2, wherein R1 is a benzene ring with nitro substitution, R2 is a tetrazolyl group with a C—C bond to the benzene ring, and R3 is a tetrazolyl group with a C—C bond to the benzene ring. Other fuels used in the gas generant compositions of the present invention include methylene bi(tetrazole); and 2,3-bis(tetrazolo) pyrazine. A method of making the compound is also provided. Gas generant compositions 12 containing these fuels are provided within a gas generator 10. The gas generator 10 may be contained within a gas generating system 200 such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.Type: GrantFiled: May 7, 2007Date of Patent: January 3, 2012Assignee: TK Holdings, Inc.Inventors: Sudhakar R. Ganta, Graylon K. Williams, Cory G. Miller
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Patent number: 8084619Abstract: A novel compound, used for example, as a gas generating fuel, is defined as a compound having the structural formula of R3—R1—R2, wherein R1 is a urea group, R2 is a tetrazolyl group with a C—N bond to the urea group, and R3 may be defined as a non-tetrazolyl, triazolyl, heterocyclic, heterocyclic amine, aliphatic, aliphatic amine, aryl, alkyl, hydrogen, or nitrogen group linked to the free nitrogen on the urea group. A method of making the compound is also provided. A gas generating composition 12 containing the novel compound as a fuel, and an oxidizer is also provided. The novel compound may be contained within a gas generant composition 12, within a gas generator 10. The gas generator 10 may be contained within a gas generating system such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.Type: GrantFiled: November 1, 2010Date of Patent: December 27, 2011Assignee: TK Holdings, Inc.Inventors: Sudhakar R. Ganta, Graylon K. Williams, Cory G. Miller
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Patent number: 8017770Abstract: A novel compound, tris (5-amino tetrazolo) triazine is used for example, as a gas generating fuel. A method of making the compound is also provided. A gas generating composition, containing the novel compound as a fuel, and an oxidizer is also provided. The novel compound may be contained within a gas generant composition 12, within a gas generator 10. The gas generator 10 may be contained within a gas generating system 200 such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.Type: GrantFiled: May 7, 2007Date of Patent: September 13, 2011Assignee: TK Holdings, Inc.Inventors: Sudhakar R. Ganta, Graylon K. Williams, Cory G. Miller
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Patent number: 8002915Abstract: A novel compound, used for example, as a gas generating fuel, is defined as a compound having the structural formula of wherein: R4 is a triazine ring; R1 is selected from the group consisting of a tetrazolyl group, CH3, OCH3, —CN, —C2H, NCO, —NHNH2, NO, NO2, OH, Cl, —NHCONH2, —OCOR, NHNO2, substituted tetrazoles, and substituted triazoles; R2 is selected from the group consisting of a tetrazolyl group, CH3, OCH3, —CN, —C2H, NCO, —NHNH2, NO, NO2, OH, Cl, —NHCONH2, —OCOR, NHNO2, substituted tetrazoles, and substituted triazoles; R3 is selected from the group consisting of a tetrazolyl group, CH3, OCH3, —CN, —C2H, NCO, —NHNH2, NO, NO2, OH, Cl, —NHCONH2, —OCOR, NHNO2, substituted tetrazoles, and substituted triazoles.Type: GrantFiled: October 1, 2007Date of Patent: August 23, 2011Assignee: TK Holdings, Inc.Inventors: Sudhakar R. Ganta, Cory G. Miller, Graylon K. Williams
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Patent number: 7914632Abstract: A novel compound, used for example, as a gas generating fuel, is methoxy carbonyl-5 amino tetrazole. A method of making the compound is also provided. A gas generating composition, containing the novel compound as a fuel, and an oxidizer is also provided. The novel compound may be contained within a gas generant composition 12, within a gas generator 10. The gas generator 10 may be contained within a gas generating system 200 such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.Type: GrantFiled: May 7, 2007Date of Patent: March 29, 2011Assignee: TK Holdings, Inc.Inventors: Sudhakar R. Ganta, Graylon K. Williams, Cory G. Miller
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Publication number: 20110046390Abstract: A novel compound, used for example, as a gas generating fuel, is defined as a compound having the structural formula of R3—R1—R2, wherein R1 is a urea group, R2 is a tetrazolyl group with a C—N bond to the urea group, and R3 may be defined as a non-tetrazolyl, triazolyl, heterocyclic, heterocyclic amine, aliphatic, aliphatic amine, aryl, alkyl, hydrogen, or nitrogen group linked to the free nitrogen on the urea group. A method of making the compound is also provided. A gas generating composition 12 containing the novel compound as a fuel, and an oxidizer is also provided. The novel compound may be contained within a gas generant composition 12, within a gas generator 10. The gas generator 10 may be contained within a gas generating system such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.Type: ApplicationFiled: November 1, 2010Publication date: February 24, 2011Inventors: Sudhakar R. Ganta, Graylon K. Williams, Cory G. Miller
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Patent number: 7879167Abstract: A gas generating composition containing a tetrazole amide as a fuel, 5-formamido-1H-tetrazole for example, and an oxidizer is provided. The gas generant is contained within a gas generator. The gas generator may be contained within a gas generating system such as an airbag inflator or seat belt assembly, or more broadly within a vehicle occupant protection system.Type: GrantFiled: February 25, 2008Date of Patent: February 1, 2011Assignee: TK Holdings, Inc.Inventors: Sudhakar R. Ganta, Graylon K. Williams
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Patent number: 7847102Abstract: A novel compound, used for example, as a gas generating fuel, is defined as a compound having the structural formula of R3—R1—R2, wherein R1 is a urea group, R2 is a tetrazolyl group with a C—N bond to the urea group, and R3 may be defined as a non-tetrazolyl, triazolyl, heterocyclic, heterocyclic amine, aliphatic, aliphatic amine, aryl, alkyl, hydrogen, or nitrogen group linked to the free nitrogen on the urea group. A method of making the compound is also provided. A gas generating composition 12 containing the novel compound as a fuel, and an oxidizer is also provided. The novel compound may be contained within a gas generant composition 12, within a gas generator 10. The gas generator 10 may be contained within a gas generating system such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.Type: GrantFiled: May 7, 2007Date of Patent: December 7, 2010Assignee: TK Holdings, Inc.Inventors: Sudhakar R. Ganta, Graylon K. Williams, Cory G. Miller
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Publication number: 20100269965Abstract: The present invention generally relates to gas generant compositions for inflators of occupant restraint systems, for example. An extrudable pyrotechnic composition includes polyvinylazoles for use within an airbag gas generator. The fuel may be selected from exemplary polyvinylazoles including 5-amino-1-vinyltetrazole, poly(5-vinyltetrazole), poly(2-methyl-5-vinyl) tetrazole, poly(1-vinyl) tetrazole, poly(3-vinyl) 1,2,5 oxadiazole, and poly(3-vinyl) 1,2,4-triazole. An oxidizer is combined with the fuel and preferably contains phase stabilized ammonium nitrate. A novel method of forming the compositions is also presented wherein the various constituents are wetted and/or dissolved, and then cured within the polyvinylazole matrix thereby forming a more intimate combination within the gas generant composition. A vehicle occupant protection system 180, and other gas generating systems, incorporate the compositions of the present invention.Type: ApplicationFiled: June 22, 2010Publication date: October 28, 2010Inventors: Graylon K. Williams, Robert J. Matlock
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Publication number: 20100258221Abstract: A novel compound, used for example, as a gas generating fuel, is defined as a compound having the structural formula of R3—R1—R2, wherein R1 is a benzene ring with nitro substitution, R2 is a tetrazolyl group with a C—C bond to the benzene ring, and R3 is a tetrazolyl group with a C—C bond to the benzene ring. Other fuels used in the gas generant compositions of the present invention include methylene bi(tetrazole); and 2,3-bis(tetrazolo) pyrazine. A method of making the compound is also provided. Gas generant compositions 12 containing these fuels are provided within a gas generator 10. The gas generator 10 may be contained within a gas generating system 200 such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.Type: ApplicationFiled: May 7, 2007Publication date: October 14, 2010Inventors: Sudhakar R. Ganta, Graylon K. Williams, Cory G. Miller
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Patent number: 7776169Abstract: A polyvinyl(tetrazole) is formed by a water-based method. A gas generating composition 12 containing the polyvinyl(tetrazole) is contained within an exemplary gas generator 10. An article or gas generating system 200 incorporates the polyvinyl(tetrazole) therein. A vehicle occupant protection system 180 incorporates the gas generating system 200. An article or substrate 300 containing a coating 302 formed from the product of the water-based method is also described.Type: GrantFiled: July 31, 2006Date of Patent: August 17, 2010Assignee: Automotive Systems Laboratory, Inc.Inventors: Cory G. Miller, Graylon K. Williams
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Patent number: 7692024Abstract: A novel compound, used for example, as a gas generating fuel, is defined as a compound having the structural formula of R3—R1—R2, wherein R1 is a benzene ring with nitro substitution, R2 is a tetrazolyl group with a C—C bond to the benzene ring, and R3 is a tetrazolyl group with a C—C bond to the benzene ring. A method of making the compound is also provided. A gas generating composition containing the novel compound as a fuel, and an oxidizer is also provided. The novel compound is contained within a gas generant composition, within a gas generator. The gas generator may be contained within a gas generating system such as an airbag inflator or seat belt assembly, or more broadly within a vehicle occupant protection system.Type: GrantFiled: May 4, 2007Date of Patent: April 6, 2010Assignee: TK Holdings, Inc.Inventors: Sudhakar R. Ganta, Graylon K. Williams, Cory G. Miller
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Patent number: 7686901Abstract: A gas generating composition 12 containing a polyvinylazole is contained within an exemplary gas generator 10. A gas generating system 200 incorporates the polyvinylazole therein. A vehicle occupant protection system 180 incorporates the gas generating system 200.Type: GrantFiled: November 1, 2005Date of Patent: March 30, 2010Assignee: Automotive Systems Laboratory, Inc.Inventors: Cory G. Miller, Graylon K. Williams
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Patent number: 7667045Abstract: A vinylated tetrazole substituted at the 5-position of the tetrazole ring is formed by a water-based method. A gas generating composition 12 containing the vinylated tetrazole is contained within an exemplary gas generator 10. A gas generating system 200 incorporates the vinylated tetrazole therein. A vehicle occupant protection system 180 incorporates the gas generating system 200.Type: GrantFiled: June 1, 2005Date of Patent: February 23, 2010Assignee: Automotive Systems Laboratory, Inc.Inventors: Cory G. Miller, Graylon K. Williams