Patents by Inventor Grazyna E. Kmiecik-Lawrynowicz

Grazyna E. Kmiecik-Lawrynowicz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20090263740
    Abstract: The present disclosure provides processes for reducing the particle size of latex resins and toners produced with such resins. In embodiments, a gel latex may be formed as a seed particle and then utilized to form latex resins and toner particles. In accordance with the present disclosure, one may be able to utilize materials for the production of latex resins and toners which may otherwise produce particles that are too large in the absence of the gel latex.
    Type: Application
    Filed: April 21, 2008
    Publication date: October 22, 2009
    Applicant: XEROX CORPORATION
    Inventors: Zhen Lai, Chieh-Min Cheng, Robert D. Bayley, Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Daniel G. Marsh, Emily L. Moore, Shigang Qiu, Tie Hwee Ng
  • Publication number: 20090136863
    Abstract: A toner for developing electrostatic images including emulsion aggregation toner particles with a styrene acrylate latex resin, at least one additive, at least one colorant, and a charge control agent comprising 3,5 di-tert-butylsalicyclic acid zinc salt.
    Type: Application
    Filed: November 16, 2007
    Publication date: May 28, 2009
    Applicant: XEROX CORPORATION
    Inventors: Daniel W. Asarese, Sarah Paulson, Maura A. Sweeney, Grazyna E. Kmiecik-Lawrynowicz
  • Publication number: 20090123865
    Abstract: A toner having a core with at least one resin and at least one colorant, and having physically attached on a surface thereof, an additive package including fluorinated polymer particles, and a method of forming toner particles having surface particles attached thereto, wherein the surface particles include fluorinated polymer particles, and the method includes aggregating a material with at least one resin and at least one colorant to produce toner particles, following aggregation, forming a mixture of the surface particles and the toner particles, and subjecting the mixture to a temperature above the glass transition temperature of the toner particles to coalesce the toner particles, whereby the surface particles become at least partially embedded within the surface of the toner particles.
    Type: Application
    Filed: January 8, 2009
    Publication date: May 14, 2009
    Applicant: XEROX CORPORATION
    Inventors: Maura A. Sweeney, Grazyna E. Kmiecik-Lawrynowicz, Robert D. Bayley
  • Publication number: 20090081575
    Abstract: A method for developing toner for use in a single component development system, wherein the process includes a) contacting a styrene acrylate polymer binder resin having a weight average molecular weight (Mw) of from about 50 to about 100 Kpse, and a number average molecular weight (Mn) of from about 10 to about 30 Kpse, a wax selected from the group consisting of polypropylene and polyethylene, and at least one colorant to produce a toner blend, b) aggregating the blend by heating at a temperature at or above the glass transition temperature of the styrene acrylate resin to form an aggregated toner core; c) adding a second binder resin to the aggregated toner core to form a shell over said toner core thereby forming a core-shell toner; d) growing said core-shell toner to a desired size; e) coalescing the core-shell toner by heating at a temperature above the glass transition temperature of the second latex; and f) recovering toner particles, wherein the toner particles have an onset glass transition temperat
    Type: Application
    Filed: September 26, 2007
    Publication date: March 26, 2009
    Applicant: XEROX CORPORATION
    Inventors: Grazyna E. Kmiecik-Lawrynowicz, Daniel W. Asarese, Maura A. Sweeney, Robert D. Bayley
  • Publication number: 20090081572
    Abstract: A toner for use in a single component development system, said toner including emulsion aggregation toner particles with a styrene acrylate polymer binder resin having a molecular weight Mw of from about 50 to about 100 Kpse and a number average molecular weight (Mn) of from about 10 to about 30 Kpse, a wax selected from the group consisting of polypropylene and polyethylene, and at least one colorant, wherein the toner particles have an onset glass transition temperature of from about 50° C. to about 60° C., and a circularity of from about 0.950 to about 0.990.
    Type: Application
    Filed: September 26, 2007
    Publication date: March 26, 2009
    Applicant: XEROX CORPORATION
    Inventors: Grazyna E. Kmiecik-Lawrynowicz, Daniel W. Asarese, Maura A. Sweeney, Robert D. Bayley
  • Publication number: 20090081576
    Abstract: The present disclosure provides processes for reducing the particle size of latex resins and toners produced with such resins. In embodiments, a carboxylic acid may be added to materials utilized to produce a latex in forming a seed resin or a master batch which, in turn, may be utilized to form latex resins and toner particles. In accordance with the present disclosure, one may be able to utilize materials for the production of latex resins and toners which may otherwise produce particles that are too large in the absence of the carboxylic acid.
    Type: Application
    Filed: September 25, 2007
    Publication date: March 26, 2009
    Inventors: Robert D. Bayley, Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Daniel W. Asarese
  • Patent number: 7479307
    Abstract: Disclosed are toner compositions comprised of a polymer, an optional colorant, and an UV light curable oligomer. Also disclosed are methods for producing a UV curable toner compositions, the toner compositions produced thereby, and methods of utilizing the UV curable toner compositions in various painting applications.
    Type: Grant
    Filed: November 16, 2006
    Date of Patent: January 20, 2009
    Assignee: Xerox Corporation
    Inventors: Mary C. Fromm, Michelle M. Bruzee, Grazyna E. Kmiecik-Lawrynowicz, Pinyen Lin, Chieh-Min Cheng
  • Publication number: 20080299478
    Abstract: The present disclosure provides processes for reducing the particle size of latex resins and toners produced with such resins. In embodiments, a carboxylic acid may be added to materials utilized to produce a latex and reduce the particle size of the resulting latex particles and toner particles. In accordance with the present disclosure, one may be able to utilize materials for the production of latex resins and toners which may otherwise produce particles that are too large in the absence of the carboxylic acid.
    Type: Application
    Filed: May 31, 2007
    Publication date: December 4, 2008
    Inventors: Robert D. Bayley, Timothy L. Lincoln, Kevin F. Marcell, Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Daniel W. Asarese, Chieh-Min Cheng, Zhen Lai
  • Patent number: 7452650
    Abstract: A carrier comprised of a core and a polymer generated from a mixture of two latexes, and wherein the first latex enables a polymer with a high molecular weight, and the second latex enables a polymer with a low molecular weight, and wherein high represents a weight average molecular weight of from about 1,000,000 to about 8,000,000, and said low represents a weight average molecular weight of from about 500,000 to about 750,000.
    Type: Grant
    Filed: January 26, 2005
    Date of Patent: November 18, 2008
    Assignee: Xerox Corporation
    Inventors: Robert D. Bayley, Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney
  • Publication number: 20080241723
    Abstract: Emulsion aggregation toner particles comprising at least one binder resin and a colorant, wherein the colorant comprises at least one ceramic pigment.
    Type: Application
    Filed: March 26, 2007
    Publication date: October 2, 2008
    Applicant: XEROX CORPORATION
    Inventors: Grazyna E. KMIECIK-LAWRYNOWICZ, Maura A. SWEENEY, Robert D. BAYLEY
  • Patent number: 7402370
    Abstract: A toner for developing electrostatic images in a single component development (SCD) system free of carrier and including emulsion aggregation toner particles of a styrene acrylate polymer binder, at least one release agent and at least one colorant, wherein the toner particles have a volume average particle size of from about 5 ?m to about 10 ?m, an average circularity of about 0.95 to about 0.99, a volume and number geometric standard deviation (GSDv and n) of from about 1.10 to about 1.30, and an onset glass transition temperature of from about 45° C. to about 65° C., is ideally suited for forming an image using a single component image forming device.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: July 22, 2008
    Assignee: Xerox Corporation
    Inventors: Grazyna E Kmiecik-Lawrynowicz, Maura A Sweeney, Daniel W Asarese, Eunhee Lee, Robert D Bayley
  • Publication number: 20080070141
    Abstract: A toner having a core with at least one resin and at least one colorant, and having on a surface thereof, an additive package including fluorinated polymer particles, and a method of forming toner particles having surface particles attached thereto, wherein the surface particles include fluorinated polymer particles, and the method includes aggregating a material with at least one resin and at least one colorant to produce toner particles, following aggregation, forming a mixture of the surface particles and the toner particles, and subjecting the mixture to a temperature above the glass transition temperature of the toner particles to coalesce the toner particles, whereby the surface particles become at least partially embedded within the surface of the toner particles.
    Type: Application
    Filed: September 19, 2006
    Publication date: March 20, 2008
    Inventors: Maura A. Sweeney, Grazyna E. Kmiecik-Lawrynowicz, Robert D. Bayley
  • Patent number: 7344813
    Abstract: A toner includes particles of a resin, an optional colorant, a first wax and a second wax, where the toner particles are prepared by an emulsion aggregation process. Additional waxes can also be added for different properties.
    Type: Grant
    Filed: May 5, 2005
    Date of Patent: March 18, 2008
    Assignee: Xerox Corporation
    Inventors: Maura A. Sweeney, Grazyna E. Kmiecik-Lawrynowicz, Matthew L. Fabrizio, Robert D. Bayley, Karen A. Moffat, David J. Sanders, Enno E. Agur, Daryl W. Vanbesien
  • Patent number: 7276320
    Abstract: A method of forming toner particles having surface particles attached thereto includes the steps of aggregating a material of at least one binder material and at least one colorant to produce toner particles, following aggregation, forming a mixture of the surface particles and the toner particles, and subjecting the mixture to a temperature above the glass transition temperature of the toner particles to coalesce the toner particles, whereby the surface particles become at least partially embedded within the surface of the toner particles. Toner particles prepared by such method include a core comprised of at least one binder and at least one colorant, and surface particles at an external surface of the toner particles, wherein at least about 50% of the surface particles are substantially completely covered by a portion of binder and a majority of the surface particles protrude from the toner particle surface a distance of at least 50% of the average particle size of the surface particles.
    Type: Grant
    Filed: January 19, 2005
    Date of Patent: October 2, 2007
    Assignee: Xerox Corporation
    Inventors: Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Robert D. Bayley, Ronald J. Koch, Mary L. McStravick, Daniel W. Asarese
  • Patent number: 7250238
    Abstract: Disclosed are toner compositions comprised of a polymer, an optional colorant, and an UV light curable oligomer. Also disclosed are methods for producing a UV curable toner compositions, the toner compositions produced thereby, and methods of utilizing the UV curable toner compositions in various painting applications.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: July 31, 2007
    Assignee: Xerox Corporation
    Inventors: Mary C. Fromm, Michelle M. Bruzee, Grazyna E. Kmiecik-Lawrynowicz, Pinyen Lin, Chieh-Min Cheng
  • Patent number: 7041420
    Abstract: A toner of the invention includes toner particles comprising a styrene acrylate binder and at least one colorant, and wherein the toner particles, in the absence of external additives, have a mean circularity of from about 0.94 to about 0.98 and a particle size distribution with a lower number ratio geometric standard deviation (GSD) of approximately 1.28 to approximately 1.31 and an upper volume GSD of approximately 1.24 to approximately 1.27. Also included is a set of toners for forming a color image, comprising a cyan toner, a magenta toner, a yellow toner and a black toner, wherein each of the cyan toner, the magenta toner, the yellow toner and the black toner, wherein each of about 70 to about 95% by weight, dry basis, of a styrene acrylate binder, about 5 to about 15% by weight, dry basis, of a wax dispersion, and at least one colorant.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: May 9, 2006
    Assignee: Xerox Corporation
    Inventors: Judith M. Vandewinckel, Vincenzo G. Marcello, Grazyna E. Kmiecik-Lawrynowicz, Tie Hwee Ng, Chieh-Min Cheng
  • Publication number: 20030017408
    Abstract: A process for the preparation of toner involving
    Type: Application
    Filed: September 11, 2002
    Publication date: January 23, 2003
    Applicant: Xerox Corporation
    Inventors: Chieh-Min Cheng, Grazyna E. Kmiecik-Lawrynowicz
  • Patent number: 6475691
    Abstract: A process for the preparation of toner involving (i) aggregating a colorant dispersion containing a suitable surfactant with a latex emulsion containing an anionic surfactant, a nonionic surfactant, and a water miscible chain transfer agent, or a nonionic surfactant with chain transfer characteristics to form toner sized aggregates; (ii) coalescing or fusing said aggregates; and optionally (iii) isolating, washing, and drying the resulting toner.
    Type: Grant
    Filed: October 29, 1997
    Date of Patent: November 5, 2002
    Assignee: Xerox Corporation
    Inventors: Chieh-Min Cheng, Grazyna E. Kmiecik-Lawrynowicz
  • Patent number: 6458501
    Abstract: The latex of an emulsion aggregation toner is prepared without the use of a surfactant. The process comprises preparing an emulsion of monomers in water without a surfactant; adding a free radical initiator to at least a portion of the emulsion to initiate seed polymerization to form seed polymer, wherein the free radical initiator attaches to the seed polymer to form ionic, hydrophilic end groups on the seed polymer; and adding additional monomer to the composition to complete polymerization to form a latex polymer.
    Type: Grant
    Filed: September 30, 1999
    Date of Patent: October 1, 2002
    Assignee: Xerox Corporation
    Inventors: Chieh-Min Cheng, Grazyna E. Kmiecik-Lawrynowicz, Allan K. Chen
  • Patent number: 6428941
    Abstract: A copolymer of styrene and an acrylic ester wherein the acrylic ester has an alkyl group with three or fewer carbons or is an aromatic acrylic ester and may be used to form toner particles having reduced vinyl offset.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: August 6, 2002
    Assignee: Xerox Corporation
    Inventors: Chieh-Min Cheng, Grazyna E. Kmiecik-Lawrynowicz, Karen LaMora