Patents by Inventor Jianhua Yao

Jianhua Yao has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20180022665
    Abstract: A process for post synthesis treatment of ZSM-5 catalyst for converting ethylene to liquid fuel products providing substantially improved catalyst life. The treatment comprises either a base treatment, an acid treatment or a two-step treatment where one is with an acid and the other is with a base. The base treatment is provided by a weak sodium hydroxide such as less than 1 Molar concentration. The acid treatment is stronger acid where, for example, a hydrogen chloride solution at greater than 2 Molar concentration is used.
    Type: Application
    Filed: July 21, 2016
    Publication date: January 25, 2018
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Jianhua Yao, Bruce B. Randolph
  • Publication number: 20180022664
    Abstract: A process for post synthesis treatment of ZSM-5 catalyst for converting ethylene to liquid fuel products providing substantially improved catalyst life. The treatment comprises either a base treatment, an acid treatment or a two-step treatment where one is with an acid and the other is with a base. The base treatment is provided by a weak sodium hydroxide such as less than 1 Molar concentration. The acid treatment is stronger acid where, for example, a hydrogen chloride solution at greater than 2 Molar concentration is used.
    Type: Application
    Filed: July 21, 2016
    Publication date: January 25, 2018
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Jianhua Yao, Bruce B. Randolph
  • Publication number: 20180022666
    Abstract: A process for post synthesis treatment of ZSM-5 catalyst for converting ethylene to liquid fuel products providing substantially improved catalyst life. The treatment comprises either a base treatment, an acid treatment or a two-step treatment where one is with an acid and the other is with a base. The base treatment is provided by a weak sodium hydroxide such as less than 1 Molar concentration. The acid treatment is stronger acid where, for example, a hydrogen chloride solution at greater than 2 Molar concentration is used.
    Type: Application
    Filed: July 21, 2016
    Publication date: January 25, 2018
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Jianhua Yao, Bruce B. Randolph
  • Patent number: 9862891
    Abstract: The present invention relates to processes for converting a feedstream comprising predominantly light alcohols into liquid transportation fuels in the gasoline boiling range. In certain embodiments, the feedstream is a bio-waste stream derived from the conversion of sorbitol or glycerol to propanediol.
    Type: Grant
    Filed: February 15, 2017
    Date of Patent: January 9, 2018
    Assignee: PHILLIPS 66 COMPANY
    Inventors: Uchenna P. Paul, Jianhua Yao
  • Patent number: 9758739
    Abstract: Cellulose and hemicellulose from biomass can be broken down to C6 and C5 sugars and further converted to corresponding sugar alcohols. It is now found that a new catalyst, MoS2, is active for the hydrogenation of sugar alcohols to hydrocarbons. Combining the technologies listed above allows us to convert the cellulose/hemicellulose to liquid hydrocarbons.
    Type: Grant
    Filed: January 30, 2014
    Date of Patent: September 12, 2017
    Assignee: PHILLIPS 66 COMPANY
    Inventors: Madhu Anand, Jianhua Yao, Edward L. Sughrue
  • Publication number: 20170240817
    Abstract: The present invention relates to processes for converting a feedstream comprising predominantly light alcohols into liquid transportation fuels in the gasoline boiling range. In certain embodiments, the feedstream is a bio-waste stream derived from the conversion of sorbitol or glycerol to propanediol.
    Type: Application
    Filed: February 15, 2017
    Publication date: August 24, 2017
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Uchenna P. PAUL, Jianhua YAO
  • Patent number: 9731270
    Abstract: Converting ethane may include directing a gaseous stream from a gas well into a fractionator for fractionating and producing a post-fractionator ethane stream, which is directed into a thermal activation unit for heating and raising the temperature of the post-fractionator ethane stream thereby creating an activated ethane stream, which is directed into a quench tower thereby creating a quenched stream, which may be converted in a catalytic conversion unit to a mixed product stream containing hydrogen and C1-C15 hydrocarbons; directing the mixed product stream into a first separation unit forming a stream of C4+ hydrocarbon product and a stream of C1-C3 hydrocarbons; directing the stream of C1-C3 hydrocarbons into a catalytic hydrogenation reactor thereby imparting hydrogen into a post-hydrogenation reactor stream, which is directed directly into a second separation unit thereby creating a light hydrocarbons recycle stream, which may be recycled into the thermal activation unit, and a hydrogen and methane str
    Type: Grant
    Filed: December 16, 2014
    Date of Patent: August 15, 2017
    Assignee: PHILLIPS 66 COMPANY
    Inventors: Jianhua Yao, Dhananjay Ghonasgi, Tushar Choudhary, Warren Ewert
  • Patent number: 9732283
    Abstract: System relating to the conversion of ethanol in a stripper unit of a fluidized catalytic cracking system. An ethanol stream comprising at least 4 volume percent water mixes with a catalyst in the stripper unit under conditions of temperature that favor conversion of the ethanol to hydrocarbons, thereby increasing incorporation of ethanol into liquid transportation fuels without exceeding regulatory limits on fuel vapor pressure. Certain embodiments additionally combine the ethanol stream with a hydrocarbon stream in the stripper and react in the presence of a catalyst to produce hydrocarbons that may have an increased boiling point, increased octane rating, decreased vapor pressure, decreased benzene content, or combinations of these properties.
    Type: Grant
    Filed: December 10, 2015
    Date of Patent: August 15, 2017
    Assignee: PHILLIPS 66 COMPANY
    Inventors: Jianhua Yao, William D. Henning, Walter E. Alvarez
  • Publication number: 20170145568
    Abstract: A metal-based/diamond laser composite coating preparation method includes: first selecting high-hardness metal powder and diamond powder of a proper grain size and shape; then uniformly mixing the high-hardness metal powder and diamond powder via a ball-milling method; and finally preparing a composite coating on a substrate by synchronously combining laser texturing technology, laser thermal treatment technology and cold spraying technology. The thickness of the composite coating is greater than 1 mm, and the volume content of diamond in the coating is greater than 45%. A metal-based/diamond laser composite coating is also provided.
    Type: Application
    Filed: July 1, 2014
    Publication date: May 25, 2017
    Applicants: ZHEJIANG UNIVERSITY OF TECHNOLOGY, HANGZHOU BOHUA LASER TECHNOLOGY CO., LTD
    Inventors: Jianhua YAO, Bo LI, Zhijun CHEN, Qunli ZHANG, Xiaodong HU, Gang DONG, Guolong WU, Liang WANG, Volodymyr KOVALENKO
  • Patent number: 9545613
    Abstract: Systems relating to thermal activation (or cracking) of ethane to an intermediate, low purity raw ethylene stream in a first stage. The system then mixes this stream with a stream of raw biomass-derived ethanol that may contain more than four volume percent of water. The resulting mixture is reacted over a suitable catalyst at temperatures and pressures suitable to produce gasoline-range and diesel-range blend stock.
    Type: Grant
    Filed: December 16, 2014
    Date of Patent: January 17, 2017
    Assignee: Phillips 66 Company
    Inventors: Jianhua Yao, Dhananjay Ghonasgi, Tushar Choudhary, Warren Ewert
  • Publication number: 20160340594
    Abstract: Systems relating to the conversion of ethanol in a stripper unit of a fluidized catalytic cracking system. An ethanol stream mixes with a catalyst in the stripper unit under conditions of temperature that favor conversion of the ethanol to hydrocarbons, thereby increasing incorporation of ethanol into liquid transportation fuels without exceeding regulatory limits on fuel vapor pressure. Certain embodiments combine the ethanol stream with a hydrocarbon stream and react in the presence of a catalyst in the stripper to produce hydrocarbons that may have an increased boiling point, increased octane rating, decreased vapor pressure, decreased benzene content, or combinations thereof.
    Type: Application
    Filed: December 1, 2015
    Publication date: November 24, 2016
    Applicant: PHILLIPS 66 COMPANY
    Inventors: William D. HENNING, Walter E. ALVAREZ, Jianhua YAO
  • Patent number: 9481836
    Abstract: Biomass derived gas oil is blended with petroleum derived gas oil and upgrading into more salable and more valuable products by co-processing the blended material in a gas oil hydrocracking system comprising two reactors where the blended material is first hydrotreated and then hydrocracked.
    Type: Grant
    Filed: June 25, 2015
    Date of Patent: November 1, 2016
    Assignee: Phillips 66 Company
    Inventors: Jianhua Yao, Sourabh S. Pansare
  • Publication number: 20160186077
    Abstract: Processes relating to the conversion of ethanol in a stripper unit of a fluidized catalytic cracking system. An ethanol stream comprising at least 4 volume percent water mixes with a catalyst in the stripper unit under conditions of temperature that favor conversion of the ethanol to hydrocarbons, thereby increasing incorporation of ethanol into liquid transportation fuels without exceeding regulatory limits on fuel vapor pressure. Certain embodiments additionally combine the ethanol stream with a hydrocarbon stream in the stripper and react in the presence of a catalyst to produce hydrocarbons that may have an increased boiling point, increased octane rating, decreased vapor pressure, decreased benzene content, or combinations of these properties.
    Type: Application
    Filed: December 10, 2015
    Publication date: June 30, 2016
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Jianhua YAO, William D. HENNING, Walter E. ALVAREZ
  • Publication number: 20160186074
    Abstract: System relating to the conversion of ethanol in a stripper unit of a fluidized catalytic cracking system. An ethanol stream comprising at least 4 volume percent water mixes with a catalyst in the stripper unit under conditions of temperature that favor conversion of the ethanol to hydrocarbons, thereby increasing incorporation of ethanol into liquid transportation fuels without exceeding regulatory limits on fuel vapor pressure. Certain embodiments additionally combine the ethanol stream with a hydrocarbon stream in the stripper and react in the presence of a catalyst to produce hydrocarbons that may have an increased boiling point, increased octane rating, decreased vapor pressure, decreased benzene content, or combinations of these properties.
    Type: Application
    Filed: December 10, 2015
    Publication date: June 30, 2016
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Jianhua YAO, William D. HENNING, Walter E. ALVAREZ
  • Publication number: 20160176777
    Abstract: A process for converting ethylene to liquid fuel products having substantially improved catalyst life. The catalyst has small zeolite crystallites and high pore volume to produce ethylene oligomerization and reduce coke production at productive temperature, pressure and flow rates.
    Type: Application
    Filed: December 11, 2015
    Publication date: June 23, 2016
    Applicant: Phillips 66 Company
    Inventors: Jianhua Yao, Bruce B. Randolph
  • Patent number: 9371256
    Abstract: A heated petroleum-derived hydrocarbon is contacted with a triglyceride feed in a thermal cracking zone to decompose and remove impurities prior to hydrotreating the mixture to fuel range hydrocarbon. This process allows the use of a variety of low cost triglyceride feeds while reducing fouling of process equipment and catalyst. The process also reduces the use of chemicals required for conventional degumming of triglyceride feeds.
    Type: Grant
    Filed: March 31, 2014
    Date of Patent: June 21, 2016
    Assignee: PHILLIPS 66 COMPANY
    Inventors: Jianhua Yao, Edward L. Sughrue, II, Dhananjay B. Ghonasgi, Xiaochun Xu
  • Publication number: 20160168491
    Abstract: A process for converting ethane to liquid fuels may involve directing an ethane stream into an ethane cracking unit to produce an intermediate hydrocarbon stream and a raw ethylene stream; fractionating the intermediate hydrocarbon stream into a gasoline fraction and a diesel fraction; introducing the raw ethylene stream into an oligomerization unit; contacting the raw ethylene stream with an oligomerization catalyst to produce a liquid hydrocarbon stream and an off-gas stream; recycling an off-gas recycle stream from an off-gas stream of the oligomerization unit separation unit to an inlet of the oligomerization reactor; introducing at least part of the off-gas stream into a hydrogenation reactor to remove unconverted olefins; separating a hydrogen component and a plurality of light paraffin components in a post hydrogenation reactor separation unit using a PSA technology or membrane technology; and recycling the light paraffins stream into the ethane cracking unit.
    Type: Application
    Filed: December 16, 2014
    Publication date: June 16, 2016
    Inventors: Jianhua Yao, Dhananjay Ghonasgi, Tushar Choudhary, Warren Ewert
  • Publication number: 20160168044
    Abstract: Processes relating to a one-step conversion to directly produce propylene from glycerol with a hydrotreating catalyst under a constrained hydrogen/glycerol feed ratio.
    Type: Application
    Filed: December 3, 2015
    Publication date: June 16, 2016
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Tie-Pan SHI, Jianhua YAO, Brian C. DUNN, Edward L. SUGHRUE
  • Publication number: 20160160133
    Abstract: Processes relating to the conversion of ethanol in a stripper unit of a fluidized catalytic cracking system. An ethanol stream mixes with a catalyst in the stripper unit under conditions of temperature that favor conversion of the ethanol to hydrocarbons, thereby increasing incorporation of ethanol into liquid transportation fuels without exceeding regulatory limits on fuel vapor pressure. Certain embodiments combine the ethanol stream with a hydrocarbon stream and react in the presence of a catalyst in a stripper to produce hydrocarbons that may have an increased boiling point, increased octane rating, decreased vapor pressure, decreased benzene content, or combinations thereof.
    Type: Application
    Filed: December 1, 2015
    Publication date: June 9, 2016
    Applicant: PHILLIPS 66 COMPANY
    Inventors: William D. HENNING, Walter E. ALVAREZ, Jianhua YAO
  • Patent number: 9358520
    Abstract: A method of hydrotreating liquefied biomass feedstock with diesel feedstock to produce alkanes is demonstrated that prevents damage to the reactor catalyst, reduces coke production, and converts nearly all of the polyols to alkanes. In order to mitigate the potential coking issue and to moderate the temperature of the catalyst bed while maintaining high conversion for sugar alcohol to hydrocarbon via a hydrotreating process, a diesel feedstock is fed over the reactor catalyst with multiple injections of polyol feedstock along the reactor.
    Type: Grant
    Filed: July 11, 2014
    Date of Patent: June 7, 2016
    Assignee: PHILLIPS 66 COMPANY
    Inventors: Jianhua Yao, Edward L. Sughrue, II, Ronald E. Brown