Abstract: A data storage system includes a plurality of data storage drives, and a system controller coupled to each data storage drive of the plurality of data storage drives. The system controller is configured to store internal drive management data for each data storage drive of the plurality of data storage drives.

Abstract: Disclosed herein is a process for achieving a palladium-catalyzed cyclative C(sp3)-H/C(sp2)-H coupling reaction using a native free carboxylic acid as a directing group, an amino acid ligand, and oxidant. The process is useful for synthesizing a range of biologically important scaffolds, including tetralins, chromanes, and indanes.

Abstract: Disclosed herein is a process for making a compound of formula (2) by (hetero)aromatic C—H hydroxylation of a compound of formula (1): catalyzed by palladium(II) and a bidentate ligand in the presence of O2. The process is useful for instance, in the late-stage modification of medicinally important heterocycles.

Abstract: Provided herein is a method of forming a beta-lactone from a carboxylic acid having a beta-carbon with a hydrogen atom disposed thereon. The method comprises contacting a carboxylic acid of formula (1) as described herein with an effective amount of a palladium(II) catalyst, an effective amount of an N-protected aminoacid ligand, and t-butylhydroperoxide in a solvent comprising hexafluoroisopropanol (HFIP), at about 60° C. to provide a beta-lactone of formula (2) as described herein.

Abstract: An alternate reality, such as virtual reality or augmented reality, environment can experience optimized performance with a data system arranged with an interaction device connected to a virtual reality assembly. Base content and user content can respectively be downloaded and stored to a local data storage of the virtual reality assembly. The content may be utilized to proactively generate comprehensive content that consists of merged aspects of the base content and the user content. The comprehensive content can then be executed to create an immersive digital reality conveyed to a user via the interaction device.

Abstract: A data storage system includes a plurality of data storage drives, and a system controller coupled to each data storage drive of the plurality of data storage drives. The system controller is configured to store internal drive management data for each data storage drive of the plurality of data storage drives.

Abstract: A device includes a servo controller that includes or that is coupled to memory. The memory stores multiple distinct disturbance control schemes. The servo controller is configured to select and implement one of the disturbance control schemes in response to receiving a command from a host. The servo controller can be implemented on a system on a chip.

Abstract: The technology disclosed herein pertains to a system and method for storing data on a storage media using both down-track super parity and cross-track super parity. Specifically, a method disclosed herein provides for generating down-track super parity values for data on the plurality of tracks and storing the down-track super parity values on a down-track super parity row of the storage block and generating cross-track super parity values for data on the plurality of rows and storing the cross-track super parity values on a cross-track upper parity track, wherein the cross-track super parity value for any given row is generated by inputting the data on the given row into an exclusive-OR (XOR) gate.

Abstract: A system and an apparatus for guiding an instrument may be provided, the apparatus comprising a main body; a holding member for holding an instrument, the holding member coupled to the main body; and one or more actuating members configured to effect movement of the holding member such that said movement of the holding member is capable of providing rotational movement of an instrument about a pivot point external the apparatus. The holding member may preferably be configured to co-operate with a compliance device, said compliance device capable of holding the instrument.

Abstract: Palladium-catalyzed C(sp3)—H arylation of aliphatic carboxylic acids, amides and ketones with BNA-encoded aryl iodides in water is disclosed, Furthermore, sequential C—H arylation chemistry enabled the on-DNA synthesis of structurally-diverse scaffolds containing enriched C(sp3) character, chiral centers, cyclopropane, cyclobutane, and heterocycles. That new chemistry permits preparation of a DNA—encoded library (BEL) technology that can dramatically expedite hit identification in drug discovery owing to its ability to perform protein affinity selection with millions or billions of molecules in a single experiment. The sequential functionalization of multiple C—H bonds provides an unique avenue for creating diversity and complexity from simple starting materials. The use of water as solvent, the presence of DMA, and the extremely low concentration of DMA-encoded coupling partners (0.

Abstract: Control systems and methods for operating a robot are disclosed. The control system includes a robot comprising a fixed end and a manipulator movable relative to the fixed end. The robot is configured to move an elongated tool attached to an end effector of the manipulator within a robot space for aligning the elongated tool with an occluded target, wherein the robot space comprises a 3-dimensional (3D) space with the fixed end as a center. The control system further includes a processor communicatively coupled with the robot and a 3D imaging device. The 3D imaging device is configured to capture 3D images within an imaging space, wherein the imaging space comprises a 3D space with a fixed reference point on the 3D imaging device as a center. The processor is configured to process a preliminary 3D image of the end effector captured by the 3D imaging device to calibrate the robot by integrating the robot space with the imaging space.

Abstract: Provided herein is a method of forming a beta-lactone from a carboxylic acid having a beta-carbon with a hydrogen atom disposed thereon. The method comprises contacting a carboxylic acid of formula (1) as described herein with an effective amount of a palladium(I) catalyst, an effective amount of an N-protected aminoacid ligand, and t-butylhydroperoxide in a solvent comprising hexafluoroisopropanol (HFIP), at about 60° C. to provide a beta-lactone of formula (2) as described herein.

Abstract: The technology disclosed herein pertains to a system and method for storing data on a storage media using both down-track super parity and cross-track super parity. Specifically, a method disclosed herein provides for generating down-track super parity values for data on the plurality of tracks and storing the down-track super parity values on a down-track super parity row of the storage block and generating cross-track super parity values for data on the plurality of rows and storing the cross-track super parity values on a cross-track upper parity track, wherein the cross-track super parity value for any given row is generated by inputting the data on the given row into an exclusive-OR (XOR) gate.

Abstract: A disk drive comprises non-volatile rotatable media and a controller operatively coupled to the non-volatile rotatable media. The controller is configured to receive a series of host commands to be executed by the controller and generate a command execution sequence comprising the series of host commands. A task manager, integral or coupled to the controller, is configured to receive a plurality of background tasks comprising a least two priority background tasks to be executed by the controller along with execution of the series of host commands, and insert one or more of the at least two priority background tasks into the command execution sequence while maintaining a specified ratio of priority background task execution and host command execution substantially constant. The controller is configured to execute the command execution sequence with the one or more inserted priority background tasks.

Abstract: Control systems and methods for operating a robot are disclosed. The control system includes a robot comprising a fixed end and a manipulator movable relative to the fixed end. The robot is configured to move an elongated tool attached to an end effector of the manipulator within a robot space for aligning the elongated tool with an occluded target, wherein the robot space comprises a 3-dimensional (3D) space with the fixed end as a center. The control system further includes a processor communicatively coupled with the robot and a 3D imaging device. The 3D imaging device is configured to capture 3D images within an imaging space, wherein the imaging space comprises a 3D space with a fixed reference point on the 3D imaging device as a center. The processor is configured to process a preliminary 3D image of the end effector captured by the 3D imaging device to calibrate the robot by integrating the robot space with the imaging space.

Abstract: A disk drive comprises non-volatile rotatable media and a controller operatively coupled to the non-volatile rotatable media. The controller is configured to receive a series of host commands to be executed by the controller and generate a command execution sequence comprising the series of host commands. A task manager, integral or coupled to the controller, is configured to receive a plurality of background tasks comprising a least two priority background tasks to be executed by the controller along with execution of the series of host commands, and insert one or more of the at least two priority background tasks into the command execution sequence while maintaining a specified ratio of priority background task execution and host command execution substantially constant. The controller is configured to execute the command execution sequence with the one or more inserted priority background tasks.

Abstract: A data storage system can connect a cache memory to a caching module, a host, and a data storage device. The caching module can employ one or more local controllers to generate a caching strategy in response to detected data storage operations and execute the caching strategy to divide the cache memory into a first pool having a first size and a second pool having a second size.

Abstract: Chiral acetyl-protected aminoethyl quinoline (APAQ), pyridine and imazoline ligands are disclosed that enable Pd (II)-catalyzed enantioselective arylation or heteroarylation of ubiquitous prochiral ?-methylene C—H bonds of aliphatic amides offers an alternative disconnection for constructing ?-chiral centers. Systematic tuning of the ligand structure reveals that a six-membered instead of a five-membered chelation of these types of ligands with the Pd(II) is important for accelerating the C(sp3)-H activation thereby achieving enantioselectivity for quinoline and pyridine ligands.

Abstract: A device includes a servo controller that includes or that is coupled to memory. The memory stores multiple distinct disturbance control schemes. The servo controller is configured to select and implement one of the disturbance control schemes in response to receiving a command from a host. The servo controller can be implemented on a system on a chip.

Abstract: A hard disk assembly (HDAs) that include a tuning data memory at least including tuning data regarding the HDA. The HDAs may lack an internal disk controller, but rather may communicate the tuning data and/or other HDA-specific data (e.g., firmware, certification data, etc.) to a reader device comprising a disk controller. In this regard, the reader device may coordinate with the HDA once the tuning data is received to operate the HDA to perform TO commands in response to commands received at the reader device from a host. In turn, upon failure of an HDA, a new HDA may be swapped into place to communicate with the reader device. Because the HDAs may lack onboard disk controllers, the cost and complexity of each HDA may be reduced.