Patents by Inventor Katsumi Nukada

Katsumi Nukada has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5731118
    Abstract: A charge transporting random copolyester resin comprising a repeating unit comprising at least one partial structural unit represented by formula (I-1) or (I-2), and at least one partial structural unit represented by formula (II) as a dicarboxylic acid component: ##STR1## where the symbols in the above formulae are defined in the specification. A process for producing the same and an organic electronic device comprising the charge transporting random copolyester resin are also disclosed.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: March 24, 1998
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Masahiro Iwasaki
  • Patent number: 5702856
    Abstract: In a method for making an image comprising the steps of forming an electrostatic image on a photosensitive body having a photosensitive layer and forming a visible image by means of a liquid development utilizing a developing liquid for electrostatic charge, the photosensitive layer comprises, as an electric charge transporting material, an electric charge transporting polymeric compound which contains as a partial moiety of repeating units the structures represented by the following general formulas 1-1 and/or 1-2, ##STR1## where R.sub.1 -R.sub.4 are each independently hydrogen, an alkyl radical that may have a substituent, or the like, X is a substituted or unsubstituted divalent aryl radical, k and l are each an integer of 0 or 1, and T is a divalent hydrocarbon radical of 1-10 carbon atoms that may be branched.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: December 30, 1997
    Assignee: Fuji Xerox Co, Ltd.
    Inventors: Kiyokazu Mashimo, Fumio Ojima, Toru Ishii, Katsumi Nukada
  • Patent number: 5677097
    Abstract: In an electrophotographic photoreceptor in which an undercoating layer and a photosensitive layer are provided on a conductive substrate, the undercoating layer preferably contains at least one electron transporting pigment and a reactive organometallic compound, the electron transporting pigment being selected from a group consisting of an electron transporting polycyclic quinone pigment such as brominated anthoanthrone, an electron transporting perylene pigment, an electron transporting phthalocyanine pigment, and an electron transporting azo pigment, and the surface of the electrophotographic photoreceptor contains at least one resin selected from electric charge transporting polycarbonate and electric charge transporting polyester.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: October 14, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hidemi Nukada, Katsumi Nukada
  • Patent number: 5654119
    Abstract: An organic electronic device comprises a layer containing a charge-transporting polyester comprising a repeating unit comprising at least one of partial structural units represented by the following formulae (I-a) and (I-b) as a partial structure of repeating unit: ##STR1## where the symbols in the above formulae are defined in the specification.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: August 5, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Toru Ishii, Fumio Ojima, Kiyokazu Mashimo, Tomozumi Uesaka, Tomoo Kobayashi, Katsumi Nukada, Akira Imai, Masahiro Iwasaki
  • Patent number: 5643703
    Abstract: A hydroxygallium phthalocyanine crystal, having distinct diffraction peaks at Bragg angles (20+/-0.2.degree.) of 7.0.degree., 13.4.degree., 16.6.degree., 26.0.degree. and 26.7.degree. to CuK.alpha. characteristic X-ray in X-ray diffraction spectrum; a process for preparing the hydroxygallium phthalocyanine crystal; and a electrophotographic photoreceptor comprising the hydroxygallium phthalocyanine crystal.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: July 1, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Daimon, Katsumi Nukada, Yasuo Sakaguchi, Ryosaku Igarashi
  • Patent number: 5639581
    Abstract: A charge transporting polymer represented by formula (I): ##STR1## wherein R represents a hydrogen atom, an alkyl group, an acyl group or --CONH--R' wherein R' represents an alkyl group or a substituted or unsubstituted aryl group; R.sub.1 and R.sub.2, which may be the same or different, each represent a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom, or a substituted or unsubstituted aryl group; X represents a substituted or unsubstituted divalent aromatic group; y represents 0 or 1; m represents 0 or 1; n represents an integer of 1 to 5; and p represents an integer of 5 to 5000,a process for producing the same, and an organic electron device containing the same, such as an electrophotographic photoreceptor are disclosed. The charge transporting polymer is excellent in solubility, film-forming properties, mechanical strength, positive hole mobility, and stability to repeated use.
    Type: Grant
    Filed: October 17, 1995
    Date of Patent: June 17, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Masahiro Iwasaki, Akira Imai, Katsumi Nukada, Katsuhiro Sato
  • Patent number: 5622801
    Abstract: An electrophotographic photoreceptor comprising a conductive substrate having thereon a photosensitive layer, the photosensitive layer containing a hydroxymetal or hydroxysilicon phthalocyanine pigment represented by formula (I) as a charge generating material, the phthalocyanine pigment having been treated with an organometallic compound having a hydrolyzable functional group or a hydrolysis product thereof: ##STR1## wherein Me represents Al, Ga, In, Si, Ge or Sn; X represents H, Cl, Br or I; m represents an integer of from 1 to 4; and n represents 1 where Me is Al, Ga or In, or 2 where Me is Si, Ge or Sn.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: April 22, 1997
    Assignee: Fuji Xerox Co., Ltd
    Inventors: Hidemi Nukada, Takahiro Suzuki, Katsumi Nukada, Katsumi Daimon, Yasuo Sakaguchi
  • Patent number: 5604064
    Abstract: A charge-transporting polymer which is excellent in solubility and film-forming property and usable in producing various organic electron devices and whose ionization potential is controllable, and an organic electronic device, in particular electrophotographic photoreceptor, containing the same are disclosed; the charge-transporting polymer being represented by formula (I-1) or (I-2) ##STR1## wherein Y represents a divalent hydrocarbon group; Z represents a divalent hydrocarbon group; A represents a group represented by formula (II) ##STR2## (wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, an alkoxy group, a substituted or unsubstituted aryl group, a substituted amino group, or a halogen atom, X represents a substituted or unsubstituted divalent aryl group, n represents an integer of 1 to 5, and k is 0 or 1); B represents a group represented by --O--(Y--O).sub.m --H or --O--(Y--O).sub.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: February 18, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Akira Imai, Masahiro Iwasaki, Ryosaku Igarashi
  • Patent number: 5587263
    Abstract: A triarylamine compound useful as a charge transport material of an electrophotographic photoreceptor, which represented by formula (I) ##STR1## wherein Ar.sub.1 and Ar.sub.2 each represents a phenyl group or a condensed ring group.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: December 24, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Akira Imai, Ryosaku Igarashi
  • Patent number: 5556967
    Abstract: Hydroxygallium phthalocyanine crystals are produced by reacting a gallium trihalide with phthalonitrile or diiminoisoindoline in a halogenated aromatic hydrocarbon solvent, treating the resulting halogenated gallium phthalocyanine with an amide solvent, and hydrolyzing the halogenated gallium phthalocyanine. The photoreceptor exhibits stabilized electrophotographic characteristics.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: September 17, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Katsumi Daimon, Yasuo Sakaguchi, Masakazu Iijima
  • Patent number: 5545733
    Abstract: A method for preparing hydroxygallium phthalocyanine crystals wherein hydroxygallium phthalocyanine crystals having distinct diffraction peaks at 7.0.degree., 13.4.degree., 16.6.degree., 26.0.degree. and 26.7.degree. of the Bragg angle (2.theta..+-.0.2.degree.) with respect to CuK.alpha. characteristics X-ray in the X-ray diffraction spectrum are crystal-transferred by solvent treatment. The crystals after crystal-transfer have distinct diffraction peaks at (i) 7.7.degree., 16.5.degree., 25.1.degree. and 26.6.degree., (ii) 7.9.degree., 16.5.degree., 24.4.degree. and 27.6.degree., (iii) 7.0.degree., 7.5.degree., 10.5.degree., 11.7.degree., 12.7.degree., 17.3.degree., 18.1.degree., 24.5.degree., 26.2.degree. and 27.1, (iv) 7.5.degree., 9.9.degree., 12.5.degree., 16.3.degree., 18.6.degree., 25.1.degree. and 28.8.degree. or (v) 6.8.degree., 12.8.degree., 15.8.degree. and 26.0.degree. of the Bragg angle (2.theta..+-.0.2.degree. C.) with respect to CuK.alpha. characteristics X-ray in the X-ray diffraction spectrum.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: August 13, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Daimon, Katsumi Nukada, Yasuo Sakaguchi, Ryosaku Igarashi
  • Patent number: 5512674
    Abstract: A process for preparing a titanyl phthalocyanine crystal showing at least one diffraction peak at a Bragg angle (2.theta..+-.0.2) of 27.3.degree. is disclosed, which comprises dissolving or suspending titanyl phthalocyanine in concentrated sulfuric acid to form a solution or a slurry and diluting the solution or slurry with an alcohol solvent, an aromatic solvent, a mixed solvent of an alcohol solvent and water, a mixed solvent of an aromatic solvent and water, or a mixed solvent of an alcohol solvent and an aromatic solvent with or without water thereby to precipitate a crystal, and, if desired, treating the precipitated crystal with an alcohol solvent, an aromatic solvent, a mixed solvent of an alcohol solvent and an aromatic solvent or a mixed solvent of an alcohol solvent and/or an aromatic solvent and water. The resulting titanyl phthalocyanine crystal exhibits high photosensitivity and excellent durability as a photoconductive material of an electrophotographic photoreceptor.
    Type: Grant
    Filed: December 6, 1993
    Date of Patent: April 30, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hidemi Nukada, Akihiko Tokida, Yasuo Sakaguchi, Katsumi Daimon, Katsumi Nukada
  • Patent number: 5510217
    Abstract: Gallium phthalocyanine halide crystals wherein a part of the crystals are changed into hydroxygallium phthalocyanine is disclosed. A method for preparing gallium phthalocyanine halide crystals wherein gallium phthalocyanine halide crystals are brought into contact with water and a part of the crystals are changed into hydroxygallium phthalocyanine is also disclosed. An electrophotographic photoreceptor formed by laminating at least a charge generating layer and a charge transporting layer successively on a conductive support wherein the charge generating layer contains gallium phthalocyanine halide crystals An which a part of the crystals are changed into hydroxygallium phthalocyanine is also disclosed.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: April 23, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Kazuya Hongo, Katsumi Nukada, Masakazu Iijima, Noriyoshi Takahashi, Masaaki Suwabe, Hitoshi Takimoto
  • Patent number: 5508395
    Abstract: A hydroxygallium phthalocyanine crystal, having distinct diffraction peaks at Bragg angles (2.theta.+/-0.2.degree.) of 7.0.degree., 13.4.degree., 16.6.degree., 26.0.degree. and 26.7.degree. to CuK.alpha. characteristic X-ray-in X-ray diffraction spectrum; a process for preparing the hydroxygallium phthalocyanine crystal; and a electrophotographic photoreceptor comprising the hydroxygallium phthalocyanine crystal.
    Type: Grant
    Filed: March 25, 1994
    Date of Patent: April 16, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Daimon, Katsumi Nukada, Yasuo Sakaguchi, Ryosaku Igarashi
  • Patent number: 5495049
    Abstract: A triarylamine compound useful as a charge transport material of an electrophotographic photoreceptor, which represented by formula (I) ##STR1## wherein Ar.sub.1 and Ar.sub.2 each represents a phenyl group or a condensed ring group.
    Type: Grant
    Filed: March 22, 1994
    Date of Patent: February 27, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Akira Imai, Ryosaku Igarashi
  • Patent number: 5495011
    Abstract: A process for preparing hydroxygallium phthalocyanine comprising reacting a gallium trialkoxide and phthalonitrile or diiminoisoindoline in an alcohol solvent, preferably an alcohol having a boiling point of not lower than 150.degree. C., such as ethylene glycol, and hydrolyzing the resulting gallium phthalocyanine, preferably in an aqueous solution of an acid, such as sulfuric acid. The resulting hydroxygallium phthalocyanine exhibits stable electrophotographic characteristics, particularly photosensitivity, charging properties, and a dark decay rate.
    Type: Grant
    Filed: August 19, 1993
    Date of Patent: February 27, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Katsumi Daimon, Masakazu Iijima, Yasuo Sakaguchi
  • Patent number: 5493016
    Abstract: A process for the preparation of alkoxy-bridged metallophthalocyanine dimers by the reaction of a trivalent metal compound with ortho-phthalodinitrile or 1,3-diiminoisoindoline in the presence of a diol.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: February 20, 1996
    Assignee: Xerox Corporation
    Inventors: Richard A. Burt, George Liebermann, Gordon K. Hamer, Sandra J. Gardner, Carol A. Jennings, Katsumi Daimon, Katsumi Nukada
  • Patent number: 5476968
    Abstract: A N,N'-bis(p-hydroxymethylphenyl)benzidine compound having the following formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom, a methyl group or a methoxy group; R.sub.2 represents an alkyl group having one to four carbon atoms, a methoxy group or an ethoxy group; and R.sub.3 represents a hydrogen atom or a methyl group, is intended to be used as a charge transporting material of an electrophotographic photoreceptor. A method for preparing the compound includes formylating a N,N'-diphenylbenzidine derivative having the following formula (II): ##STR2## by the conventional Viismeier reaction to obtain a N,N'-bis(p-formylphenyl) benzidine derivative of the following formula (III): ##STR3## and reducing the derivative with a boron hydride salt or an aluminum hydride salt.
    Type: Grant
    Filed: August 22, 1994
    Date of Patent: December 19, 1995
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Akira Imai, Katsumi Nukada
  • Patent number: 5472816
    Abstract: A halogen-containing hydroxygallium phthalocyanine crystal showing intense diffraction peaks at Bragg angles (2.theta..degree..+-.0.2.degree.) of (1) 7.7.degree., 16.5.degree., 25.1.degree. and 26.6.degree.; (2) 7.9.degree., 16.5.degree., 24.4.degree., and 27.6.degree.; (3) 7.0.degree., 7.5.degree., 10.5.degree., 11.7.degree., 12.7.degree., 17.3.degree., 18.1.degree., 24.5.degree., 26.2.degree., and 27.1.degree.; 4) 7.5.degree., 9.9.degree., 12.5.degree., 16.3.degree., 18.6.degree., 25.1.degree., and 28.3.degree.; or (5) 6.8.degree., 12.8.degree., 15.8.degree., and 26.0.degree. and an electrophotographic photoreceptor containing the halogen-containing hydroxygallium phthalocyanine crystal as a charge generating material are disclosed.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: December 5, 1995
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Katsumi Daimon
  • Patent number: 5466796
    Abstract: Alkoxy-bridged metallophthalocyanine dimers of the formula C.sub.32 H.sub.16 N.sub.8 MOROMN.sub.8 H.sub.16 C.sub.32, or of the formula ##STR1## wherein M is a metal, and R is an alkyl or an alkyl ether.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: November 14, 1995
    Assignee: Xerox Corporation
    Inventors: Richard A. Burt, George Liebermann, Gordon K. Hamer, Sandra J. Gardner, Carol A. Jennings, Katsumi Daimon, Katsumi Nukada